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    • 3. 发明公开
    • Thermosetting resin composition
    • WärmehärtbareHarzzusammensetzung
    • EP2743313A1
    • 2014-06-18
    • EP12197528.8
    • 2012-12-17
    • DSM IP Assets B.V.
    • Haveman, DanielBaarzel van, Jacobus HermanusBouwman, René StéphanJansen, Johan Franz Gradus Antonius
    • C08L67/00C09D167/00C08L75/06C08L67/07
    • C08F283/01C08F290/061C08L67/07C08L75/14C08L75/16
    • This invention relates to a radically curable, thermosetting resin composition comprising:
      (a) at least one telechelic urethane methacrylate functional polyester resin,
      (b) at least one unsaturated polyester resin, and
      (c) at least one methacrylate containing compound, wherein
      the telechelic urethane methacrylate functional polyester resins (a) have a weight per unsaturation WPU (a) from 460 up to and including 1000 Dalton, the unsaturated polyester resins (b) have a weight per fumarate unsaturation WPU fumarate(b) from 200 up to and including 1000 Dalton, and
      the resin composition is further characterized in that the molar ratio between the methacrylates present in the resin composition and the fumarates present in the resin composition is is from 1 up to and including 25, and in that the amount of styrene in the resin composition is lower than 2 wt.% (relative to the total resin composition).
    • 本发明涉及可自由基固化的热固性树脂组合物,其包含:(a)至少一种遥爪氨基甲酸酯甲基丙烯酸酯官能聚酯树脂,(b)至少一种不饱和聚酯树脂,和(c)至少一种含甲基丙烯酸酯的化合物,其中所述遥爪 氨基甲酸酯甲基丙烯酸酯官能聚酯树脂(a)具有从460直至并包括1000道尔顿的每不饱和度WPU(a)的重量,不饱和聚酯树脂(b)具有每200重量至200包括富马酸盐不饱和度WPU富马酸盐(b)的重量 1000道尔顿,树脂组合物的特征还在于,存在于树脂组合物中的甲基丙烯酸酯和树脂组合物中存在的富马酸酯的摩尔比为1以上且25以下,苯乙烯的量 树脂组合物低于2重量%(相对于总树脂组合物)。