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61. 发明授权

EP1087916B1 SUBSTRAT A REVETEMENT PHOTOCATALYTIQUE 有权
标题翻译：光催化层衬底
公开(公告)号：EP1087916B1
公开(公告)日：2006-04-12
申请号：EP99937921.7
申请日：1999-03-05
申请人： SAINT-GOBAIN GLASS FRANCE , RHODIA CHIMIE
发明人： TALPAERT, Xavier , SIMONET, Michel , LEHAUT, Corinne , CHOPIN, Thierry , MAGNIN-FEYSOT, Frédéric
IPC分类号： C03C17/25 , C03C17/00 , B01J35/00
CPC分类号： C04B41/5041 , B01J35/002 , B01J35/004 , C03C17/007 , C03C17/256 , C03C2217/212 , C03C2217/45 , C03C2217/475 , C03C2217/477 , C03C2217/71 , C03C2218/113 , C09D1/00 , C23C30/00 , H01J29/88 , Y10T428/1266 , Y10T428/12667 , Y10T428/249953 , Y10T428/249956 , Y10T428/249967 , Y10T428/24997 , Y10T428/249987 , Y10T428/249988 , Y10T428/24999 , Y10T428/256 , Y10T428/259 , C04B20/008 , C04B41/4554 , C04B41/4582 , C04B41/463
摘要： The invention concerns a method for obtaining a substrate (1) provided with a coating (3) with photocatalytic properties, crystallised particles of an oxide of metal A with photocatalytic properties being incorporated in said coating by means of a mineral binder (5) comprising at least an oxide of metal B also having photocatalytic properties in crystallised form and optionally at least an oxide of metal M devoid of photocatalytic properties and/or at least a silicon compound such as silicon oxide SiO2. It consists in depositing the coating (3) from liquid phase dispersions containing: said crystallised particles of metal A oxide; at least a precursor compound of the binder (5) of metal B oxide and optionally a precursor compound of metal M oxide and of the Si compound, in a relative proportion A(B + M + Si) by weight ranging between 60/40 and 40/60. The invention also concerns the resulting coated substrate and its various applications.

62. 发明公开

EP1641871A1 COMPOSITIONS POLYORGANOSILOXANES (POS) MONOCOMPOSANTES RETICULANT PAR DES REACTIONS DE POLYCONDENSATION EN ELASTOMERES A TEMPERATURE AMBIANTE ET EN PRESENCE D'EAU, ET ELASTOMERES AINSI OBTENUS 有权转让
标题翻译：单组分聚有机硅氧烷（POS组合物）通过在环境温度和水以弹性体NETWORKING存在下获得的弹性体的缩聚反应，AND
公开(公告)号：EP1641871A1
公开(公告)日：2006-04-05
申请号：EP04767291.0
申请日：2004-06-09
申请人： RHODIA CHIMIE
发明人： GUENNOUNI, Nathalie , CHAUSSADE, Marc
IPC分类号： C08K5/00 , C08L83/04 , C08L83/14
CPC分类号： C08K5/5419 , C08G77/14 , C08G77/18 , C08K5/0025 , C08K5/057 , C08K5/098 , C08K5/56 , C08L83/04 , C08L83/14 , C08L83/00
摘要： The invention relates to single-component silicon compositions which are storage stable in the absence of humidity and which, by means of polycondensation reactions that are catalysed by a mixed titanium/metal catalyst, crosslink to form non-yellowing elastomers that adhere to different supports, said reactions taking place at ambient temperature and in the presence of water. Each single-component POS composition comprises: 100 parts by weight linear diorganopolysiloxane(s) A which are functionalised at the chain ends by alkoxy-, acyloxy-, iminoxy-, enoxy-type functions Rfo; between 0 and 30 parts by weight polysiloxane resin(s) B; between 0 and 15 parts by weight crosslinking agent(s) C; between 0 and 2 parts by weight aliphatic alcohol(s) E; between 0 and 30 parts by weight unfunctionalised, unreactive linear diorganopolysiloxane(s) F; between 2 and 40 parts by weight mineral filler G; between 0 and 20 parts by weight auxiliary agent(s) H; and between 1 and 150 µat.g (microgram atom) metals M1 + M2 per 1g of single-component POS composition, wherein M1 is selected from among titanium, zirconium and mixtures of same, and M2 is selected from among zinc, aluminium, borium, bismuth and mixtures of same.

63. 发明公开

EP1637536A1 Procédé d'obtention de monoorganoxysilanes halogénés utilisables notamment en tant qu'intermédiaires de synthèse 审中-公开
标题翻译： Herstellung von haloierten Monoorganoxysilanen，Verwendung als Zwischenverbindungen
公开(公告)号：EP1637536A1
公开(公告)日：2006-03-22
申请号：EP05026551.1
申请日：2002-09-10
申请人： RHODIA CHIMIE
发明人： Guennouni, Nathalie , Mignani, Gérald , Pevere, Virginie
IPC分类号： C07F7/18
CPC分类号： C07F7/1892 , C07F7/188
摘要： La présente invention concerne l'utilisation de monoorganoxysilanes halogénés ayant la formule donnée ci-après :

comme intermédiaire de synthèse en chimie organique que l'on fait réagir avec au moins un agent nucléophile approprié, pour former un monoorganoxysilane fonctionnalisé de formule :

avec, par exemple, R 1 = alkyle C 1 -C 4 ; R 2 , R 3 = alkyle C 1 -C 6 ; B = alkylène C 1 -C 10 ; m = 1 ou 2 ; Hal = halogène ; W = radical amino, mercapto, (organoxysilyl)-organopolythio.
摘要翻译：从卤代烷基硅烷合成卤代单有机氧基硅烷，作为生产由卤素以外的基团官能化的单官能团硅烷的中间体。卤代单有机氧硅烷符合式（R 1> O）-Si（R 2）（R 3） - B-（Hal）m（I）; R 1 H，1-4C烷基或2-8 C烷氧基烷基; R 2，R 31〜6C烷基，6〜18 C芳基，芳烷基或烷基芳基（6〜18 C芳基; 1〜8烷基）; m：1或2; B：1〜10的亚烷基，当m = 1时，B为式-B 1> -CR 4> H-CR 5> R 6→ - 的二价残基：-CR 1> -CR 4> -CR 5> R 6>或 - （B 2）a-CR 7> R 8> -CR 9> R 10> -CR 11> R 12>; 条件是基团R 7> -R 13>之一是价键; B 1>和B 2> 1-10C亚烷基或二价芳族残基形成亚苯基（o，m或p）-2-8亚烷基，2-8亚烷基 - 亚苯基（o，m或p）或2-8亚烷基 - 亚苯基（o，拖把）-2- a：0或1; R 4> -R 13> H或C 1-3烷基; 当m = 2时：B是式-B 1> -CR 4> -CR 5> R 6> - 的三价残基。该制备包括以下步骤：（a）Hal-Si（R 2> R 3） - Hal（A）+ R 0 -M-Hal - > Hal-Si（R 2> R 3） - R 0 >（C）+ Hal-M-Ha; （b）当R 0> = R 01>时，：（C）+ H-Hal→Hal-Si（R 2> R 3）-B 1> -CR 4> H-CR 5> R 6 -Hal和/或Hal-Si（R 2> R 3）-B 1> -CR 4> Hal-CR 5> R 6> H; 或（C）+ Hal-Hal - > Hal-SI（R 2> R 3） - B 1> -CR 4> Hal-CR 5> R 6> Hal; 当R 0> = R 02>： - （C）+ Hal-Hal或SO 2（Hal）2→Hal-Si（R 2> R 3） - （B 2）a-CR 7> R （R 2> R 3） - （B 2）a-CR 7> R 8> -CR 9> Hal -CR 11> R 12> R 13>和/或Hal-Si（R 2> R 3） - （B 2）a-CR 7> Hal-CR 9> R 10> -CR 11> R 12> R 13>（R 13>和/或R 10>和/或R 8> = H的情况）; 所得混合产物可用于（c）阶段; （c）作为混合物或单独分离; R 0> R 01>，对应于CR 5> R 6> = CR 4> -B 1> - 或R 02>，对应于CR 11> R 12> R 13> -CR 9> R 10 - （R 2> R 1> 3中的至少一个为H）;（B 2）和M：碱金属或碱土金属; （R 2> R 3）-B（Hal）M + R 1> OH - >（R 1> O）-Si（R 2> R 3） -Hal; 符号Hal最好是Cl。更优选R 0> = R 0> 1，阶段（b）为：（C）+ H-Hal→Hal-Si（R 2> R 3）-B 1> -CR 4> H- CR 5> R 6> - （Hal）和/或Hal-Si（R 2> R 3）-B 1> -CR 4> Hal-CR 5> R 6> H。或者，在m = 1的阶段（a），（b）和（c），（a）和（b）中，可以用“或a”代替：-a'）Hal-Si（Hal） 2-B-Hal + 2R，M-Hal - > Hal-Si（R 3）2-B-Hal + 2Hal-M-Hal; 或Hal-Si（Hal）（R 3） - B-Hal + R 2> -M-Hal→Hal-Si（R 2> R 3） - B-Hal + Hal-M -Hal（R 03>对应于R 2>和/或R 3>） - 或（a），（b）和（c）可以被a1，b1和c1（m = 1）代替：a1） Si（R 2> R 3） - Hal（A）+ 2R 1> OH - > R 1> O-Si（R 2> R 3）-OR 1（F）+ 2H-Hal b1）R （R 2> R 3）-R 0>（G）+ R 1> OM-Hal c1）式（G）的基团R 0>（R 0> 1或R 0> 2）的氢卤化得到基团B-Hal，由反应物Hal-Hal和/或SO 2 （Hal）2.优选用途：所获得的硅烷（I）可与亲核剂反应生成通式为R 1> O）-Si（R 2> R 3） - - （W）m的官能化有机硅烷（II）; W：烷氧基，酰基，氨基（任选取代的），巯基，氰基，氰硫基，氰基氰化物或（有机甲硅烷基）有机多硫基或混合物的单价官能团。烷氧基可以通过以下反应获得： - （I）+ R 20> -O-M' - （I）-OR 20 + + M'-Hal-; M'：碱金属和R 20>相当于R 1>; 类似地，通过（I）与M'OCOR 21>的反应获得酰基衍生物; R 21> R 1>，以及2〜10个烯基; 更优选-OCOR 21>符合（甲基）丙烯酸酯; 同样地，通过（I）与HR 22> R 23> N，S =（NH 2）2，M'CN，M'R 24的反应可以获得取代的氨基，巯基，氰基，氰硫基，氰基和硫化物 > -CN（R 24> = O或S）和M'2S。要求保护含有有效量的烷氧基硅烷（I）或（II）的组合物。

64. 发明公开

EP1637534A1 Synthèse d'organodialkylalkoxysilanes 有权
标题翻译： Verfahren zur Herstellung von有机二烷基烷氧基硅烷
公开(公告)号：EP1637534A1
公开(公告)日：2006-03-22
申请号：EP05026550.3
申请日：2003-06-23
申请人： RHODIA CHIMIE
发明人： Ramdani, Kamel , Guennouni, Nathalie , Vogin, Bernard
IPC分类号： C07F7/14 , C07F7/18
CPC分类号： C07F7/14 , C07F7/1892
摘要： La présente invention concerne un procédé de préparation de composés organosiliciques contenant du soufre de formule générale :

par réaction de sulfuration, à l'aide d'un polysulfure de métal alcalin, d'un oméga-halogénoalkyl dialkylalcoxysilane, lui-même obtenu par réaction d'alcoolyse consistant à mettre en contact dans un réacteur à contre-courant, tel que notamment dans une colonne à plateaux ou à garnissage, un alcanol sur un oméga-halogénoalkyl dialkylhalogénosilane.
摘要翻译：在不存在碱的情况下通过与ω-卤代烷基二烷基烷氧基硅烷与链烷醇逆流的连续反应获得有机二烷基烷氧基硅烷的方法。获得式（IX）有机二烷基烷氧基硅烷的方法; R 1> O-（R 2> R 3）Si-（CH 2）3-A; - 包括与醇（VIII）R 1> OH与式（VII）的硅烷：Hal-（R 2> R 3））Si-（CH 2）3-A反应，以实现通过反应进行醇解： - Hal-（R 2> R 3）Si-（CH 2）3 -A + R 1> OH --------------- R 1> O- （R 2> R 3））Si-（CH 2）3-A + H-Hal - 在产物H-Hal的汽提下操作，并在反应器中回收有机二烷基烷氧基 - 硅烷，其中Hal：Cl ，Br或I（优选Cl）; R 1> 1〜15 C烷基或2〜8烷氧基烷基; R 2>，R 3> 1〜6C烷基或苯基; A：Hal的可分离基团，基团对R 0> -C 6 H 4 -SO 2 -O-或R 0 -SO 2 -O-（优选甲苯磺酸酯或甲磺酸酯）或R 0> -CO-O- （R 0 = C 1-4烷基）。 A优选为Cl。还包括制备硅烷（VII）和衍生自二烷基烷氧基硅烷的多硫化物的独立权利要求。

65. 发明授权

EP1399451B1 COMPOSES ORGANOSILICIQUES UTILISABLES COMME AGENT DE COUPLAGE 有权
标题翻译：有机硅化合物用作粘结
公开(公告)号：EP1399451B1
公开(公告)日：2006-03-15
申请号：EP02748970.7
申请日：2002-06-27
申请人： RHODIA CHIMIE
发明人： BARRUEL, Pierre , GUENNOUNI, Nathalie , KIRSCH, Gilbert , MIGNANI, Gérard
IPC分类号： C07F7/18 , C08K5/54 , C08C19/26 , C08C19/42
CPC分类号： C07F7/1836
摘要： The invention relates to organosilicon compounds selected from, inter alia , functional polysi lylated organosilicon compounds bearing polythiosulphenamide function groups having formula (I): R1-Sx-NR2-R3, wherein R1, x, R2 and R3 are as defined in claim 1. Said compounds can be used as white filler/elastomer coupling agents in diene rubber compositions comprising, by way of reinforcing filler, a white filler such as a siliceous material.

66. 发明授权

EP1319027B1 PROCEDE DE SYNTHESE DE POLYMERES A BLOCS PAR POLYMERISATION RADICALAIRE CONTROLEE EN PRESENCE D'UN COMPOSE DISULFURE 有权
标题翻译：用于生产嵌段共聚物由可控自由基在二硫化碳的存在
公开(公告)号：EP1319027B1
公开(公告)日：2006-03-15
申请号：EP01969876.0
申请日：2001-09-11
申请人： RHODIA CHIMIE
发明人： DESTARAC, Mathias
IPC分类号： C08F2/38 , C08F293/00 , C08F8/34
CPC分类号： C08F293/005 , C08F2/38 , C08L53/00
摘要： The invention concerns a method for preparing a first generation polymer comprising a step which consists in radical polymerisation of a composition containing: at least an ethylenically unsaturated monomer, a free radical source, at least a compound (I) of general formula (IA) or (IB), a compound of formula (II).

67. 发明公开

EP1628983A1 PROCEDE D AGGLOMERATION DE LA MASSE USEE OU DES FINES ISSUES DE LA PRODUCTION D' ORGANOHALOSILANES 有权
标题翻译：方法二手材料或结块生产有机卤代的精细股份
公开(公告)号：EP1628983A1
公开(公告)日：2006-03-01
申请号：EP04742614.3
申请日：2004-04-30
申请人： RHODIA CHIMIE
发明人： SIMON, Gérard
IPC分类号： C07F7/16
CPC分类号： C22B1/24 , C22B1/244 , C22B15/0058 , Y02P10/22
摘要： A method for the agglomeration of a used powdery material and/or powdery fines from the production of organohalosilanes, comprising a mixture of said used material and/or fines with a binder selected from polyholosides, i.e. starches and dextrines, the addition of an amount of water to said mixture, the amount of water added ranging from 3 to 10 %, preferably 4 to 8 % by weight in relation to the total amount of used material and binder, agitation of the solid mixture obtained in the previous stage in order to obtain a homogeneous mixture; and the production of a solid agglomerated product by compression in a press. Agglomerated product thus obtained.

68. 发明公开

EP1611204A2 AGGLOMERE DE PARTICULES COMPRENANT UN LIANT SILICONE VULCANISE POUR LA FABRICATION DE BOUCHON 审中-公开
标题翻译：有机硅树脂联颗粒FOR PRODUCING插头
公开(公告)号：EP1611204A2
公开(公告)日：2006-01-04
申请号：EP04742391.8
申请日：2004-03-30
申请人： RHODIA CHIMIE
发明人： BREUNIG, Stephan , DELCHET, Luc
IPC分类号： C08L83/07 , C08L97/00
CPC分类号： C08L83/04 , C08G77/12 , C08G77/14 , C08G77/16 , C08G77/18 , C08G77/20 , C08G77/26 , C08G77/70 , C08L2666/26 , C08L83/00
摘要： The invention relates to the production of particle board comprising a vulcanized silicon composition. The aim of the invention is to provide a new raw material consisting of a particle board whose cohesiveness is provided by a cross-linked silicon binder and which can be used as raw material for the production of corks for wine bottles enabling good bottling and good winemaking. The binder comprises: (1) at least one vinyl polyorganosiloxane (POS), (2) at least one hydrogenated POS, (3) one platinum catalyst, (4) at least one POS resin (4.1) which is hydrogenated, which is optionally alcenated and/or associated with at least one other POS resin (4.2) which is alcenylated, (5) and optionally at least one cross-linking inhibitor/ retarder. The particles are made of cork. However, the board can also comprise expandable plastic particles. The invention also relates to methods for the production of said particle board and corks.

69. 发明公开

EP1601628A2 UN PROCEDE POUR AUGMENTER L'HYDROFUGATION DE COMPOSITIONS DE LIANTS MINERAUX AINSI QUE LES COMPOSITIONS SUSCEPTIBLES D'ETRE OBTENUES PAR CE PROCEDE ET LEURS UTILISATIONS 审中-公开
标题翻译：用于增加粘合剂组合这样制作的组合物的防水性能和方法及其用途
公开(公告)号：EP1601628A2
公开(公告)日：2005-12-07
申请号：EP04717663.1
申请日：2004-03-05
申请人： RHODIA CHIMIE
发明人： DERUELLE, Martial , JOUBERT, Daniel , CASTAING, Jean-Christophe
IPC分类号： C04B24/42
CPC分类号： C08G77/04 , C04B24/42 , C04B40/0039 , C04B2103/0057 , C04B2103/65 , C04B2111/00663 , C09K8/467 , Y10T428/2995 , C04B24/26 , C04B24/2641 , C04B24/2635 , C04B24/2676
摘要： The invention relates to a method for increasing the waterproofing of a mineral binder compound consisting in adding the sufficient quantity of at least one type of polyalkylalkylsiloxane containing at least one hydrocarbon graft which has 6-18 carbon atoms to said compound. Compounds which can be produced with the inventive method and the use thereof for construction are also disclosed.

70. 发明公开

EP1595022A1 UTILISATION D'UNE FORMULATION SILICONE LIQUIDE RETICULABLE COMME BASE D'ENDUCTION TEXTILE 有权
标题翻译：使用液体交联硅组合纺织品涂层剂
公开(公告)号：EP1595022A1
公开(公告)日：2005-11-16
申请号：EP04710899.8
申请日：2004-02-13
申请人： RHODIA CHIMIE
发明人： DERUELLE, Martial , GIRAUD, Yves
IPC分类号： D06M15/643 , D06N3/12 , C08K5/57 , C09D183/04
CPC分类号： D06N3/128 , C08G77/045 , C08G77/16 , C08G77/18 , C08G77/46 , C08G77/80 , C08K5/057 , C08L83/04 , C09D183/04 , D06M15/643 , C08L83/00
摘要： The invention relates to the use of a silicon formulation as a textile coating base comprising a silicon resin, a metal alkoxide and a functional additive which can react with at least one of the preceding components. One of the essential objectives of the invention is to supply a treatment which can be used to provide a large number of textile materials with long-lasting characteristics. Another essential objective is to supply a treatment for fixing a functional siloxane network to the surface of the textile material. In order to achieve the aforementioned objectives, the invention relates to the use of at least one cross-linkable liquid silicon formulation as a base for coating textile material. In this way, by cross-linking around the constituent threads, fibres and/or filaments of the textile material, the material is provided with a large protective covering which is little dependent on the nature of said material given that it requires no or few anchoring points. In addition, by producing a chemically-cross-linking silicon sheath, the textile material is provided with excellent resistance against stresses which occur during usage and, thus, long-lasting protection. Moreover, by providing additional specific use characteristics, it is possible to form coatings having use properties such as softness, water repellency, oil repellency, water absorbency and an anti-static effect. Finally, owing to the special nature of the components of the formulation, the operations consisting in depositing the liquid formulation and cross-linking same can be performed at any point in the processes involving the creation and/or alteration and/or maintenance of the textile material which is made from natural and/or synthetic materials.

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