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51. 发明公开

EP0211342A3 Composition of matter and method for conversion of C3 and C4 hydrocarbons 失效
标题翻译： C3和C4烃转化的物质组成和方法
公开(公告)号：EP0211342A3
公开(公告)日：1987-12-09
申请号：EP86110206
申请日：1986-07-24
申请人： PHILLIPS PETROLEUM COMPANY
发明人： Delzer, Gary Albert , Kolts, John Henry
IPC分类号： C07C11/04 , C07C05/333 , C07C04/06 , B01J21/14 , B01J21/06 , B01J23/34 , B01J23/78 , B01J23/84
CPC分类号： C07C5/322 , C07C4/06 , C07C4/10 , C07C2521/04 , C07C2521/06 , C07C2521/08 , C07C2521/10 , C07C2523/02 , C07C2523/14 , C07C2523/18 , C07C2523/34 , Y02P20/52 , C07C11/04
摘要： Compositions of matter comprise oxides of silicon, aluminum and/or titanium mixed with combinations of manganese oxide and magnesium oxide; iron oxide and magnesium oxide; calcium, strontium, barium, tin and/or antimony oxides, manganese oxide and magnesium oxide; and iron oxide, manganese oxide and magnesium oxide. These compositions are particulary useful as catalysts for selectively converting propane and butanes to ethylene and ethane and particularly to ethlyene. A method for converting propane and butanes to less saturated hydrocarbons is also disclosed in which the catalyst life is extended and the selectivity to ethylene and ethane, particularly ethylene, is improved by carrying out the contacting with the catalyst in the presence of steam, when the catalyst contains an oxide of iron and, optionally, when the catalyst does not contain an oxide of iron.

52. 发明公开

EP0211341A3 Composition of matter and method for conversion C3 and C4 hydrocarbons 失效
标题翻译：用于转化C3和C4烃的物质和方法的组合物
公开(公告)号：EP0211341A3
公开(公告)日：1987-12-09
申请号：EP86110205
申请日：1986-07-24
申请人： PHILLIPS PETROLEUM COMPANY
发明人： Kolts, John Henry , Delzer, Gary Albert
IPC分类号： C07C11/06 , C07C11/04 , C07C05/333 , C07C04/06 , B01J23/26 , B01J23/34 , B01J23/86
CPC分类号： C07C5/322 , C07C4/06 , C07C4/10 , C07C2521/10 , C07C2523/02 , C07C2523/10 , C07C2523/14 , C07C2523/18 , C07C2523/20 , C07C2523/26 , C07C2523/34 , Y02P20/52 , C07C11/04
摘要： Novel compositions of matter include: mixed oxides of (a) at least one oxide of chromium, at least one oxide of manganese and at least one oxide of magnesium, Lanthanum Series metals, preferably lanthanum and cerium, and/or niobium; (b) at least one oxide of chromium, at least one oxide of calcium, strontium, tin and/or antimony, at least one oxide of manganese and at least one oxide of magnesium, Lanthanum Series metals and/or niobium; - (c) at least one oxide of chromium, at least one oxide of iron and at least one oxide of magnesium, , Lanthanum Series metals and/or niobium; and (d) at least one oxide of chromium, at least one oxide of liron, at least one oxide of manganese and at least one oxide of magnesium, Lanthanum Series metals and/or niobium. These compositions are particularly effective as catalyst compositions for the conversion of C, and C, hydrocarbons to less saturated hydrocarbons, with high selectivities to ethylene and ethane and particularly ethylene, and the addition of the chromium significantly extends the activity of the catalyst for such selective conversion before regeneration is necessary. A method of converting C, and C, hydrocarbons to less saturated hydrocarbons, and selectively to ethylene and ethane and particularly ethylene, is also disclosed. Carrying out the process in the presence of steam is essential to the process when the catalyst contains iron and is optional when the catalyst does not contain iron. Limiting the amount of bound or fixed sulfur in the catalyst also improves the catalyst.

53. 发明公开

EP0179856A4 METHANE CONVERSION PROCESS. 失效
标题翻译：转化法甲烷。
公开(公告)号：EP0179856A4
公开(公告)日：1986-09-15
申请号：EP85902265
申请日：1985-04-11
申请人： ATLANTIC RICHFIELD CO
发明人： JONES C ANDREW , LEONARD JOHN J , SOFRANKO JOHN A , WITHERS HOWARD P
IPC分类号： C07C2/84 , B01J23/08 , B01J23/10 , B01J23/14 , B01J23/18 , B01J23/34 , B01J27/18 , C07C1/00 , C07C2/86 , C07C9/00 , C07C67/00 , C07C2/00
CPC分类号： C07C2/84 , C07C2523/02 , C07C2523/04 , C07C2523/08 , C07C2523/10 , C07C2523/14 , C07C2523/18 , C07C2523/34 , C07C2527/18 , Y10S585/943
摘要： A method for converting methane to higher hydrocarbon products by contacting a hydrocarbon gas comprising methane, an oxygen-containing gas and a reducible metal oxide under synthesis conditions, the improvement which comprises contacting methane and oxygen with a contact solid which also contains a promoting amount of alkali metal, alkaline earth metal, and/or compounds thereof. Sodium is a particularly effective promotor. Stability of the promoted contact agent is enhanced by the presence of minor amounts of phosphorus.

54. 发明公开

EP0179856A1 METHANE CONVERSION PROCESS 失效
标题翻译：转化法甲烷。
公开(公告)号：EP0179856A1
公开(公告)日：1986-05-07
申请号：EP85902265.0
申请日：1985-04-11
申请人： ATLANTIC RICHFIELD COMPANY
发明人： JONES, C., Andrew , LEONARD, John, J. , SOFRANKO, John, A. , WITHERS, Howard, P.
IPC分类号： C07C2 , B01J23 , B01J27 , C07C1 , C07C9 , C07C67
CPC分类号： C07C2/84 , C07C2523/02 , C07C2523/04 , C07C2523/08 , C07C2523/10 , C07C2523/14 , C07C2523/18 , C07C2523/34 , C07C2527/18 , Y10S585/943
摘要： Procédé de conversion du méthane en produits d'hydrocarbures supérieurs par mise en contact d'un gaz d'hydrocarbure comportant du méthane, d'un gaz contenant de l'oxygène et d'un oxyde métallique réductible sous des conditions de synthèse, l'amélioration comportant la mise en contact du méthane et de l'oxygène avec un solide de contact contenant également une quantité promotrice de métal alcalin, de métal alcalino-terreux et/ou de composés de ceux-ci. Le sodium est un promoteur particulièrement efficace. La stabilité de l'agent de contact de promotion est accrue par la présence de faibles quantités de phosphore.

55. 发明公开

EP0152470A4 METHANE CONVERSION. 失效
公开(公告)号：EP0152470A4
公开(公告)日：1985-12-12
申请号：EP84903233
申请日：1984-08-10
申请人： ATLANTIC RICHFIELD CO
发明人： JONES C ANDREW , SOFRANKO JOHN A
IPC分类号： B01J23/08 , B01J23/14 , B01J23/18 , B01J23/34 , B01J27/18 , C07C2/84 , C07C2/00 , C07C2/76 , C07C15/02
CPC分类号： C07C2/84 , B01J23/08 , B01J23/14 , B01J23/18 , B01J23/34 , B01J27/18 , C07C2521/10 , C07C2523/02 , C07C2523/08 , C07C2523/14 , C07C2523/18 , C07C2523/34 , Y10S585/943

57. 发明授权

EP0031654B1 Dehydrocoupling of toluene 失效
标题翻译：。。。。。
公开(公告)号：EP0031654B1
公开(公告)日：1983-02-16
申请号：EP80304414.8
申请日：1980-12-08
申请人： MONSANTO COMPANY
发明人： Williamson, Alex Nathan , Tremont, Samuel Joseph , Solodar, Arthur John
IPC分类号： C07C2/84 , C07C15/52
CPC分类号： C07C2/84 , C07C2523/14 , C07C2523/18 , C07C15/52

58. 发明公开

EP0064821A2 Promoted bismuth cerium molybdate catalysts and use thereof in oxidation-type reactions 失效
标题翻译： Aktivierte Wismut-Cer-Molybdat-Katalysatoren und deren Verwendung in Oxidationsreaktionen。
公开(公告)号：EP0064821A2
公开(公告)日：1982-11-17
申请号：EP82301991.4
申请日：1982-04-19
申请人： THE STANDARD OIL COMPANY
发明人： Brazdil, James Frank , Suresh, Dev Dhanaraj , Grasselli, Robert Karl
IPC分类号： B01J23/31 , C07C120/14 , C07C121/32
CPC分类号： C07C253/26 , B01J23/31 , B01J23/686 , B01J23/885 , B01J2523/00 , C07C5/48 , C07C45/34 , C07C45/35 , C07C45/37 , C07C45/38 , C07C2521/06 , C07C2523/04 , C07C2523/08 , C07C2523/10 , C07C2523/12 , C07C2523/18 , C07C2523/26 , C07C2523/28 , C07C2523/31 , C07C2523/50 , C07C2523/72 , C07C2527/057 , Y02P20/52 , C07C47/22 , B01J2523/13 , B01J2523/3712 , B01J2523/54 , B01J2523/68 , B01J2523/15 , B01J2523/34 , B01J2523/69 , B01J2523/41 , B01J2523/53 , B01J2523/67 , B01J2523/64 , B01J2523/3706 , B01J2523/36 , B01J2523/3718 , B01J2523/3725 , B01J2523/47 , C07C255/08
摘要： A bismuth cerium molybdate catalysts oxide complex catalyst contains a promoting amount of an alkali metal TI, Sm, Ag, Cu, Cr, Sb, rare earth metal other than Ce and Sm, Te, Ti, Zr, Th or mixture thereof.
Such catalyst provides high yields of acrylonitrile in the ammoxidation of propylene and give improved results in other oxidation-type reactions.
摘要翻译：钼酸铋催化剂氧化物络合物催化剂含有除Ce和Sm，Te，Ti，Zr，Th或其混合物之外的碱金属Ti，Sm，Ag，Cu，Cr，Sb，稀土金属的促进量。这种催化剂在丙烯的氨氧化中提供高产率的丙烯腈，并在其它氧化型反应中得到改善的结果。

59. 发明公开

EP0030837A1 Dehydrocoupling of toluene 失效
标题翻译：甲苯脱氢偶联
公开(公告)号：EP0030837A1
公开(公告)日：1981-06-24
申请号：EP80304415.5
申请日：1980-12-08
申请人： MONSANTO COMPANY
发明人： Williamson, Alex Nathan , Tremont, Samuel Joseph
IPC分类号： C07C2/84 , C07C15/52 , C07C15/18 , B01J23/16 , B01J23/66
CPC分类号： C07C2/84 , C07C2523/02 , C07C2523/08 , C07C2523/18 , C07C2523/50 , Y02P20/52
摘要： Toluene dehydrocoupled products are produced by heating toluene in the vapor phase with an inorganic metal/oxygen composition which functions as an oxygen carrier and has the empirical formula:
where M is bismuth and M 2 is at least one element selected from indium, silver, Group 2a of the Periodic Table of the Elements, and mixtures thereof, and wherein a is 1, b is 0.01 to 100, and x is a number taken to satisfy the average valences of M 1 and M 2 in the oxidation states in which they exist in the composition. Alternatively, the same inorganic metal/oxygen composition can be employed as a catalyst or as a combination catalyst/oxygen carrier for the dehydrocoupling reaction when oxygen or an oxygen-containing gas is heated with the toluene.
摘要翻译：甲苯脱氢偶联产物是通过将气相中的甲苯与用作氧载体的无机金属/氧组合物加热来制备的，其具有以下经验式：其中M是铋，M2是选自铟，银，2a族中的至少一种元素元素周期表及其混合物，并且其中a为1，b为0.01至100，并且x为满足其存在于组合物中的氧化态中M1和M2的平均化合价的数字。或者，当氧气或含氧气体与甲苯一起加热时，可以使用相同的无机金属/氧气组合物作为催化剂或用作脱氢偶联反应的组合催化剂/氧气载体。

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