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    • 49. 发明公开
    • CABLE DOWNHOLE GAS CHROMATOGRAPH AND A DOWNHOLE GAS CHROMATOGRAPHY METHOD
    • BABRLOCH-GASCHROMATOGRAPHIEVERFAHREN的KABELBOHRLOCH-GASCHROMATOGRAPH
    • EP1988254A2
    • 2008-11-05
    • EP06847423.8
    • 2006-12-27
    • Services Pétroliers SchlumbergerSchlumberger Holdings LimitedSchlumberger Technology B.V.PRAD Research and Development N.V.
    • IAKIMOV, Mikhail Nikolaevich
    • E21B49/08G01N30/02
    • E21B49/10E21B47/10G01N30/20G01N30/88G01N33/2823G01N2030/8854G01N2030/8886
    • This invention relates to the devices used in the oil and gas industry. Disclosed herein is the use of a high resolution gas chromatograph in the borehole for borehole fluid type determination in real time mode. The Wireline Downhole Gas Chromatograph comprises a sample chamber with a piston position sensor, the chamber being connected through the sampling valve to the pipeline and through oil pump to hydraulic oil pressure compensation tank; an electric thermostat with a temperature sensor and a chromatograph tube installed inside the thermostat, one side of tube is connected in series through a rotating sample injector, a zeolite filter, a first check valve and a chromatograph isolating valve with a line connecting said sampling valve and said sample chamber, and the other side of tube is connected in series to a second check valve, a fraction detector, a sample portion cylinder and a second pressure gage, wherein said rotating sample injector is connected in series to a pressure reducer, a transporting medium valve, a compressed nitrogen cylinder and a first pressure gage; a bypass line with a bypass valve is connected in parallel to said rotating sample injector, said chromatograph tube and said fraction detector, and the electronic telemetry loop is connected to the output of said fraction detector.
      Also disclosed herein is a Downhole gas chromatography method according to which the Downhole gas chromatograph device is lowered into the well to the required depth, and a hydraulic contact with the formation fluids is made; the formation fluids are injected by the pump; the pumping cycle is completed; the sampling valve is opened, and fluid from pipeline is taken into the sample chamber; the sampling valve is closed, and the chromatograph isolating valve is opened to supply the sample for analysis; at the same time the bypass valve is opened in order to wash the contents from previous samples or other unwanted fluids; the transporting medium valve is opened; the rotating sample injector is opened for introducing the fluid sample for analysis; the chromatograph valve is closed, and the sampling valve is opened for fluid supply from the sample fluid chamber into the pipeline; piston is moved by oil pump, the oil pump is stopped, and the sampling valve is closed upon the receipt of a piston position sensor signal; the sample separated in the chromatographic tube is analyzed with the detector; the transporting medium residuals and samples are supplied to the washing section; upon the completion of the analysis, the transporting medium valve is closed. In some embodiments of this invention, said Wireline Downhole Gas Chromatograph is installed in the vicinity of the Modular Dynamic Tester (MDT) bar in a way so that the formation fluid sampling point and the LFA module are at one side, and the pump module (MRPO) or other sampling equipment at the other; during formation fluid injection by the pump, the MDT device performs resistivity, temperature and pressure measurements, and the LFA readings are taken, and the injection cycle is stopped once the required purity is achieved.
    • 本发明涉及石油和天然气工业中使用的装置。 本文公开了在实时模式中在钻孔中使用高分辨率气相色谱仪进行井眼流体类型测定。 电缆井下气相色谱仪包括具有活塞位置传感器的样品室,该室通过采样阀连接到管道,并通过油泵连接到液压油压力补偿罐; 具有温度传感器的电子恒温器和安装在恒温器内的色谱管,管的一侧通过旋转的样品注射器,沸石过滤器,第一止回阀和色谱隔离阀串联连接,其中连接所述取样阀 和所述样品室,并且所述管的另一侧与第二止回阀,分数检测器,样品部分气缸和第二压力表串联连接,其中所述旋转样品注射器与减压器串联连接, 输送介质阀,压缩氮气瓶和第一压力表; 具有旁通阀的旁路管与所述旋转样品注射器,所述色谱管和所述分数检测器并联连接,并且所述电子遥测回路连接到所述分数检测器的输出。 本文还公开了一种井下气相色谱法,其中将井下气相色谱装置下降到井中至所需深度,并与地层流体进行液压接触; 地层流体由泵注入; 泵送周期完成; 打开采样阀,将流体从管道中取入样品室; 取样阀关闭,打开色谱隔离阀,供样品进行分析; 同时打开旁通阀以便从先前的样品或其它不需要的流体中洗涤内容物; 输送介质阀打开; 打开旋转样品注射器以引入流体样品进行分析; 色谱阀关闭,取样阀打开,用于从样品流体室流入管道中进行流体供应; 活塞由油泵移动,油泵停止,并且在接收到活塞位置传感器信号时取样阀关闭; 用检测器分析色谱管中分离的样品; 输送介质残留物和样品供应到洗涤部分; 在完成分析之后,输送介质阀关闭。 在本发明的一些实施方案中,所述电缆井下气相色谱仪以一种方式安装在模块化动态测试仪(MDT)棒附近,使得地层流体取样点和LFA模块位于一侧,并且泵模块 MRPO)或其他采样设备; 在通过泵的地层流体注入期间,MDT装置执行电阻率,温度和压力测量,并且获取LFA读数,并且一旦达到所需的纯度,则停止注射循环。
    • 50. 发明公开
    • PROBENGEBER, INSBESONDERE FÜR DIE HOCHLEISTUNGS-FLÜSSIGKEITSCHROMATOGRAPHIE
    • 样品传感器,尤其是高高效液相
    • EP1955059A1
    • 2008-08-13
    • EP06828595.6
    • 2006-12-01
    • Dionex Softron GmbH
    • TREMINTIN, GuillaumeSWART, Remco
    • G01N30/20G01N30/24G01N30/82G01N30/88G01N30/44G01N30/02G01N30/46G01N30/08G01N35/10
    • G01N30/20G01N30/24G01N30/44G01N30/463G01N30/465G01N30/80G01N30/82G01N30/88G01N2030/027G01N2030/085G01N2030/201G01N2030/202G01N2030/8804
    • The invention relates to an apparatus for supplying samples to a separating device and for collecting sample fractions which have been produced using the separating device, in particular for high-power liquid chromatography, said apparatus having a first relay valve unit (201) which has at least eight ports (port numbers 1 to 8) and two switching positions, wherein, in a first switching position (1-2), exactly two adjacent ports are respectively connected to one another and, in a second switching position (8-1), precisely those adjacent ports which are not connected to one another in the first switching position are respectively connected to one another. The apparatus has a metering device (4) for supplying a sample to the relay valve unit (201), said metering device being connected to an intake port (port number 1) of the first relay valve unit (201) and interacting with a removal and discharge device (6) for removing a sample from at least one sample vessel (7) and for discharging a respective fraction into one of several fraction vessels (12), said removal and discharge device being connected to an intake and discharge port (port number 6) of the first relay valve unit (201). The ports of the first relay valve unit (201) are assigned in such a manner that, in the first switching position (1-2), the intake port (port number 1) and the first sample reservoir port (port number 2), the solvent supply port (port number 3) and the separating device transfer port (port number 4), the second sample reservoir port (port number 5) and the intake and discharge port (port number 6) as well as the separating device acceptance port (port number 7) and the waste port (port number 8) are connected to one another and, in the second switching position (8-1), the first sample reservoir port (port number 2) and the solvent supply port (port number 3), the separating device transfer port (port number 4) and the second sample reservoir port (port number 5), the intake and discharge port (port number 6) and the separating device acceptance port (port number 7) as well as the waste port (port number 8) and the intake port (port number 1) are connected to one another.