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21. 发明公开

EP0508307A3 Optically active secondary amine compound; process for producing optically active secondary amine compound and process for producing optically active carboxylic acid by using said compound 有权转让
标题翻译：光活性二级胺化合物; 用于生产光活性二级胺化合物的方法和使用化合物生产光学活性羧酸的方法
公开(公告)号：EP0508307A3
公开(公告)日：1993-02-03
申请号：EP92105682.6
申请日：1992-04-02
申请人： SUMITOMO CHEMICAL COMPANY, LIMITED
发明人： Yoneyoshi, Yukio , Kudo, Junko , Nishioka, Toshio
IPC分类号： C07C217/58 , C07C215/20 , C07C251/24 , C07C251/20 , C07C51/487 , C07C61/37 , C07C61/40 , C07C53/128 , C07C59/84 , C07C59/50
CPC分类号： C07C217/58 , C07B57/00 , C07C215/50 , C07C251/24 , C07C2601/14
摘要： Disclosed are optically active secondary amine compounds and salts thereof having the general formula (I):

a process for the preparation of the optically active secondary amine compounds and salts thereof, and the use of such compounds. Such compounds exhibit a high resolution power and hence are useful agents for optical resolution.
摘要翻译：公开了具有通式（I）的光学活性仲胺化合物及其盐：＆lt; CHEM＆gt;用于制备光学活性仲胺化合物及其盐的方法，以及这些化合物的用途。这样的化合物表现出高分辨率的功率，因此是有用的光学拆分剂。

22. 发明公开

EP0508307A2 Optically active secondary amine compound; process for producing optically active secondary amine compound and process for producing optically active carboxylic acid by using said compound 有权转让
标题翻译：制备用于通过使用该化合物的制备光学活性羧酸的光学活性仲胺化合物和方法的光学活性仲胺化合物的方法。
公开(公告)号：EP0508307A2
公开(公告)日：1992-10-14
申请号：EP92105682.6
申请日：1992-04-02
申请人： SUMITOMO CHEMICAL COMPANY, LIMITED
发明人： Yoneyoshi, Yukio , Kudo, Junko , Nishioka, Toshio
IPC分类号： C07C217/58 , C07C215/20 , C07C251/24 , C07C251/20 , C07C51/487 , C07C61/37 , C07C61/40 , C07C53/128 , C07C59/84 , C07C59/50
CPC分类号： C07C217/58 , C07B57/00 , C07C215/50 , C07C251/24 , C07C2601/14
摘要： Disclosed are optically active secondary amine compounds and salts thereof having the general formula (I):

a process for the preparation of the optically active secondary amine compounds and salts thereof, and the use of such compounds. Such compounds exhibit a high resolution power and hence are useful agents for optical resolution.
摘要翻译：本发明公开了光学其具有通式（I）活性仲胺化合物及其盐：为光学活性仲胺化合物及其盐的制备方法，以及使用测试化合物。搜索化合物表现出高的分辨率的功率和因此可用于光学拆分的试剂。

23. 发明公开

EP0381434A1 Process for producing optically active alcohol 有权转让
标题翻译： Verfahren zur Herstellung optisch aktiver Alkohole。
公开(公告)号：EP0381434A1
公开(公告)日：1990-08-08
申请号：EP90300938.9
申请日：1990-01-30
申请人： SUMITOMO CHEMICAL COMPANY, LIMITED
发明人： Yoneyoshi, Yukio , Suzukamo, Gohfu , Konya, Naoto , Ikeda, Takaharu
IPC分类号： C07D249/08 , C07F5/02 , C07C29/143
CPC分类号： C07D231/12 , C07B2200/07 , C07C29/143 , C07D233/56 , C07D249/08 , C07C31/125 , C07C33/02 , C07C31/12
摘要： A process for producing an optically active alcohol of the formula
[R⁴ and R⁵ are different and each is a lower alkyl group, an aryl group, and aralkyl group or a 2-substituted-1-triazoleethylene group represented by the general formula (III)
(R⁶ is a halogen- or haloalkyl-substituted or unsubstituted phenyl group or a cycloalkyl group)] comprises allowing

(A) an optically active amino alcohol represented by the general formula (I)
(R¹ is an aryl group, R² is a lower alkyl group, R³ is a hydrogen atom or a lower alkyl group, and the carbon atoms having a mark * are each an asymmetric carbon atom) and an acid, or a salt of the optically active amino alcohol (I) and an acid,
(B) a metal borohydride, and
(C) at least one of water, sulfides, cyclic ethers and ethers of mono alcohols
to react with
a prochiral ketone represented by the general formula (II)
[R⁴ and R⁵ are as defined above].
摘要翻译：制备式CHEM的光学活性醇的方法[R 4和R 5不同，各自为低级烷基，芳基和芳烷基或2-取代-1-三唑基由通式（III）表示的基团（R 6是卤素或卤代烷基取代或未取代的苯基或环烷基）]包括使（A）由通式（III）表示的光学活性氨基醇（I）（R 1是芳基，R 2是低级烷基，R 3是氢原子或低级烷基，并且具有标记*的碳原子各自不对称碳原子）和酸，或光学活性氨基醇（I）和酸的盐，（B）金属硼氢化物，和（C）至少一种水，硫醚，环醚和单醚与通式（II）表示的前手性酮反应的醇 [R 4和R 5如上所定义]。

24. 发明授权

EP0170350B1 An asymmetrically modified boron hydride type compound, a production method thereof, and a method for producing an optically active alcohol derivative by the use thereof 有权转让
标题翻译：非对称改性的硼氢化物型化合物及其制备方法，以及通过其使用生产光学活性醇衍生物的方法
公开(公告)号：EP0170350B1
公开(公告)日：1989-07-19
申请号：EP85303017.9
申请日：1985-04-29
申请人： SUMITOMO CHEMICAL COMPANY, LIMITED
发明人： Yoneyoshi, Yukio , Suzukamo, Gohfu , Hamada, Kazuhiko , Nishioka, Toshio
IPC分类号： C07F5/02 , C07D249/08
CPC分类号： C07D231/12 , C07D233/56 , C07D249/08 , C07F5/022

25. 发明公开

EP0121284A3 Optical isomer of triazolylpentenols, and their production and use as fungicide, herbicide and/or plant growth regulant 有权转让
标题翻译：三唑并苯的光学异构体及其生产和使用作为杀真菌剂，除草剂和/或植物生长调节剂
公开(公告)号：EP0121284A3
公开(公告)日：1985-09-25
申请号：EP84200456
申请日：1981-12-14
申请人： SUMITOMO CHEMICAL COMPANY, LIMITED
发明人： Funaki, Yuji , Yoneyoshi, Yukio , Ishiguri, Yukio , Izumi, Kazuo
IPC分类号： C07D249/08 , A01N43/64
CPC分类号： C07D231/12 , A01N43/653 , C07D249/08
摘要： Triazolyl alcohol derivative having an optical activity of (-) or (+) and represented by the general formula (I),
wherein X represents a hydrogen atom or a chlorine atom and the asterisk indicates an asymmetric carbon atom, are prepared by stereospecific reduction of the corresponding ketone or by resolution of the racemate. The (-)-isomer is useful as a fungicide while the (+)-isomer is useful as a plant growth regulant or herbicide.

26. 发明公开

EP0736509A3 Processes for preparing optically active alcohols and optically active amines 失效
标题翻译：一种制备光学活性醇与光学活性胺的方法
公开(公告)号：EP0736509A3
公开(公告)日：1997-03-19
申请号：EP96105569.6
申请日：1996-04-09
申请人： SUMITOMO CHEMICAL COMPANY, LIMITED
发明人： Yoneyoshi, Yukio , Konya, Naoto , Suzukamo, Gohfu , Kamitamari , Miyawaki, Takashi
IPC分类号： C07C29/143 , C07C33/20 , C07C33/22 , C07C33/46 , C07C209/40 , C07C211/27 , C07C211/29 , C07C217/58
CPC分类号： C07B53/00 , C07B57/00 , C07B2200/07 , C07C29/143 , C07C209/40 , C07C213/02 , C07C33/20 , C07C33/46
摘要： A process for preparing an optically active alcohol by reacting a prochiral ketone corresponding to the optically active alcohol and an acid with a mixture of (1) a boron-containing compound selected from the group consisting of i) a borane compound which is obtained from an optically active β-aminoalcohol and a boron hydride; or obtained from the optically active β-aminoalcohol, a metal borohydride and an acid and ii) an optically active oxazaborolidine and (2) a metal borohydride; and a process for preparing an optically active amine by reacting an oxime derivative and an acid with a mixture of (1) a boron-containing compound selected from the group consisting of i) a borane compound which is obtained from an optically active β-aminoalcohol and a boron hydride, or obtained from said optically active β-aminoalcohol, a metal borohydride and an acid and ii) an optically active oxazaborolidine, and (2) a metal borohydride.

27. 发明公开

EP0736509A2 Processes for preparing optically active alcohols and optically active amines 失效
标题翻译：一种制备光学活性醇与光学活性胺的方法
公开(公告)号：EP0736509A2
公开(公告)日：1996-10-09
申请号：EP96105569.6
申请日：1996-04-09
申请人： SUMITOMO CHEMICAL COMPANY, LIMITED
发明人： Yoneyoshi, Yukio , Konya, Naoto , Suzukamo, Gohfu , Kamitamari , Miyawaki, Takashi
IPC分类号： C07C29/143 , C07C33/20 , C07C33/22 , C07C33/46 , C07C209/40 , C07C211/27 , C07C211/29 , C07C217/58
CPC分类号： C07B53/00 , C07B57/00 , C07B2200/07 , C07C29/143 , C07C209/40 , C07C213/02 , C07C33/20 , C07C33/46
摘要： A process for preparing an optically active alcohol by reacting a prochiral ketone corresponding to the optically active alcohol and an acid with a mixture of (1) a boron-containing compound selected from the group consisting of i) a borane compound which is obtained from an optically active β-aminoalcohol and a boron hydride; or obtained from the optically active β-aminoalcohol, a metal borohydride and an acid and ii) an optically active oxazaborolidine and (2) a metal borohydride; and a process for preparing an optically active amine by reacting an oxime derivative and an acid with a mixture of (1) a boron-containing compound selected from the group consisting of i) a borane compound which is obtained from an optically active β-aminoalcohol and a boron hydride, or obtained from said optically active β-aminoalcohol, a metal borohydride and an acid and ii) an optically active oxazaborolidine, and (2) a metal borohydride.
摘要翻译：一种用于通过使前手性酮对应于光学活性醇以及酸与（1）的含硼化合物的选自硼烷化合物的i）由所有这是从到获得选择的混合物的光学活性醇的制备方法光学活性的β-氨基醇与硼氢化物; 获得或从光学活性的β氨基醇，金属硼氢化物和酸和ii）光学活性的恶唑硼烷，（2）金属硼氢化物; 和用于通过反应到肟衍生物和酸与（1）的含硼化合物的选自硼烷化合物的i）由所有其从光学活性的β-氨基醇的获得选择的混合物制备上的光学活性胺的方法和硼氢化物，或得自所述光学活性的β-氨基醇，金属硼氢化物和酸和ii）光学活性的恶唑硼烷，和（2）的金属硼氢化物。

28. 发明公开

EP0713848A1 Process for producing optically active carbinols 失效转让
标题翻译：维尔法赫恩·赫斯特伦
公开(公告)号：EP0713848A1
公开(公告)日：1996-05-29
申请号：EP95116951.5
申请日：1995-10-27
申请人： SUMIKA FINE CHEMICALS Company, Limited , SUMITOMO CHEMICAL COMPANY LIMITED
发明人： Saito, Kenji , Kometani, Norio , Fujiwara, Azusa , Yoneyoshi, Yukio , Suzukamo, Gohfu
IPC分类号： C07C29/143 , C07C33/46 , C07C33/24 , C07C33/22 , C07D317/54
CPC分类号： C07D317/54 , C07B2200/07 , C07C29/143 , C07C33/46 , C07C33/20
摘要： The present invention relates to a process for producing optically active halomethyl phenyl carbinols of the formula (1), comprising reducing halomethyl phenyl ketones of the formula (2) using an asymmetric reducing agent obtained from boranes and optically active α-phenyl-substituted-β-amino alcohols of the formula (3) or optically active α-non-substituted-β-amino alcohols of the formula (4).
The present invention further relates to a process for producing optically active carbinols, comprising reacting with an unsymmetric ketone, an asymmetric reducing agent obtained from optically active β-amino alcohols of the formula (5), a metal boron hydride and Lewis acid or lower dialkyl sulfuric acid.
摘要翻译：本发明涉及一种制备式（1）的光学活性卤代甲基苯基甲醇的方法，包括使用由硼烷和光学活性的α-苯基取代的β取代的β取代的不对称还原剂还原式（2）的卤代甲基苯基酮（3）的氨基醇或式（4）的光学活性α-壬基取代的β-氨基醇。本发明还涉及一种光学活性甲醇的制备方法，其包括与不对称酮反应，由式（5）的光学活性β-氨基醇获得的不对称还原剂，金属硼氢化物和路易斯酸或低级二烷基硫酸。

29. 发明授权

EP0311385B1 Optically active hydroxybenzylamine derivative, optically active amine-boron compound containing said derivative, and process for producing optically active compound by using said compound 有权转让
标题翻译：光活性羟基苯甲酰衍生物，含有衍生物的光学活性的胺 - 硼烷化合物，以及使用化合物生产光学活性化合物的方法
公开(公告)号：EP0311385B1
公开(公告)日：1993-02-03
申请号：EP88309295.9
申请日：1988-10-06
申请人： SUMITOMO CHEMICAL COMPANY, LIMITED
发明人： Yoneyoshi, Yukio , Suzukamo, Gohfu , Sakito, Yoji
IPC分类号： C07C215/50 , C07C217/58 , C07C209/40 , C07D249/08 , C07C29/136
CPC分类号： C07D249/08 , C07B2200/07 , C07C29/143 , C07D231/12 , C07D233/56 , C07C31/125 , C07C33/20 , C07C33/22

30. 发明授权

EP0237305B1 A method for producing optically active amines 有权转让
标题翻译：一种生产光活性胺的方法
公开(公告)号：EP0237305B1
公开(公告)日：1992-06-03
申请号：EP87301992.1
申请日：1987-03-09
申请人： SUMITOMO CHEMICAL COMPANY, LIMITED
发明人： Sakito, Yoji , Suzukamo, Gohfu , Yoneyoshi, Yukio
IPC分类号： C07C209/30 , C07C211/26 , C07B53/00
CPC分类号： C07B53/00

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