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1. 发明公开

EP3135681A4 RUTHENIUM COMPLEX, METHOD FOR PRODUCING SAME, AND USE OF SAME 有权
标题翻译： RUTHENIUMKOMPLEX，VERFAHREN ZUR HERSTELLUNG DAVON UND VERWENDUNG DAVON
公开(公告)号：EP3135681A4
公开(公告)日：2017-09-20
申请号：EP15783902
申请日：2015-04-24
申请人： TAKASAGO PERFUMERY CO LTD
发明人： OGATA OSAMU , NARA HIDEKI , NAKAYAMA YUJI
IPC分类号： C07F19/00 , B01J31/22 , B01J31/24 , C07B61/00 , C07C29/132 , C07C29/141 , C07C29/145 , C07C29/149 , C07C31/20 , C07C33/22 , C07C45/29 , C07C49/78 , C07C209/18 , C07C211/48 , C07D213/30 , C07F9/50 , C07F15/00
CPC分类号： C07F15/0046 , B01J31/22 , B01J31/24 , B01J31/2409 , B01J2231/643 , B01J2231/70 , B01J2531/0216 , B01J2531/821 , C07B61/00 , C07C29/132 , C07C29/141 , C07C29/145 , C07C29/149 , C07C31/20 , C07C33/22 , C07C45/29 , C07C49/78 , C07C209/18 , C07C211/48 , C07D213/30 , C07F9/50 , C07F15/00 , C07F15/0053 , C07F19/00
摘要： The present invention provides a novel ruthenium complex that is easy to produce and handle and that can be supplied relatively inexpensively, a method for producing this ruthenium complex, a method for producing alcohols and the like using this ruthenium complex as a catalyst, a method for producing carbonyl compounds using this ruthenium complex as a catalyst, and a method for producing N-alkylamine compounds using this ruthenium complex as a catalyst. The present invention pertains to a ruthenium complex represented by general formula (1) RuX 1 X 2 (PNP)(NHC) m (Solv) n (1) (in general formula (1), X 1 and X 2 each independently represent a monovalent anionic monodentate ligand; PNP represents a tridentate aminodiphosphine ligand, NHC represents an N-heterocyclic carbene derived from a nitrogen-containing heterocyclic ring, and Solv represents a coordinating solvent; and m represents an integer from 1 to 3, n represents an integer from 0 to 2, and 1 ‰¤ m + n ‰¤ 3.), a method for producing the same, a catalyst including the same, and methods for producing various organic compounds using this catalyst.
摘要翻译：本发明提供一种易于生产和操作并且可以相对廉价地供应的新型钌配合物，该钌配合物的生产方法，使用该钌配合物作为催化剂的生产醇等的方法，用于使用该钌络合物作为催化剂来制造羰基化合物的方法以及使用该钌络合物作为催化剂来制造N-烷基胺化合物的方法。（1）所示的钌络合物，通式（1）中，X 1和X 2分别独立地表示由通式（1）表示的钌络合物，Ru 1 X 2（PNP）（NHC）m（Solv）n 单价阴离子单齿配体; PNP表示三齿氨基二膦配体，NHC表示衍生自含氮杂环的N-杂环卡宾，并且Solv表示配位溶剂; m表示1至3的整数，n表示与 0至2，和1‰m + n‰3），其制备方法，包含其的催化剂，以及使用该催化剂生产各种有机化合物的方法。

2. 发明公开

EP3089802A1 IMPROVEMENTS RELATING TO ALKYLENE OXIDE PRODUCTION 有权转让
标题翻译：与氧化烯生产相关的改进
公开(公告)号：EP3089802A1
公开(公告)日：2016-11-09
申请号：EP14828172.8
申请日：2014-12-30
申请人： Shell Internationale Research Maatschappij B.V.
发明人： VAN MOURIK, Arian , PLOEMEN, Ingmar, Hubertus, Josephina
IPC分类号： B01D17/04 , C07C407/00 , C07C7/11
CPC分类号： C07D301/04 , B01D17/045 , C07C7/11 , C07C29/132 , C07C45/53 , C07C407/00 , C07D301/19 , C07C409/08 , C07C15/073 , C07C33/22 , C07C49/78
摘要： A process for preparing an alkylene oxide comprising contacting an alkyl phenyl hydroperoxide with an alkene in an epoxidation reaction to obtain an alkylene oxide and an alkyl phenyl alcohol, wherein the alkyl phenyl hydroperoxide is prepared by a process comprising reacting an alkyl aryl compound and oxygen to produce a reaction mixture comprising alkyl phenyl hydroperoxide, alkyl aryl compound and oxygen; separating at least a part of the reaction mixture into a product stream comprising alkyl phenyl hydroperoxide and an alkyl aryl compound stream; mixing at least a part of the alkyl aryl compound stream with a basic aqueous solution; separating at least a part of the mixture of alkyl aryl compound and basic aqueous solution with the help of a coalescer to obtain an organic phase containing alkyl aryl compound, and an aqueous phase; and recycling at least a part of the organic phase to the reacting step.
摘要翻译：一种制备烯化氧的方法，该方法包括制备烷基苯基氢过氧化物，并使该烷基苯基氢过氧化物与烯烃在环氧化反应中接触以获得烯化氧和烷基苯基醇，其中烷基苯基氢过氧化物通过包括 a）使烷基芳基化合物和氧气反应以制备包含烷基苯基氢过氧化物，烷基芳基化合物和氧气的反应混合物; （b）将至少一部分反应混合物分离成包含烷基苯基氢过氧化物和包含烷基芳基化合物的物流的产物物流; （c）将至少一部分分离的烷基芳基化合物流与碱性水溶液混合; （d）借助聚结器分离至少一部分步骤（c）的混合物以获得含有烷基芳基化合物的分离的有机相和分离的水相; 和（e）将至少一部分含有烷基芳基化合物的分离的有机相再循环至步骤（a）。

3. 发明公开

EP2966081A4 LIGAND, METAL COMPLEX CONTAINING LIGAND, AND REACTION USING METAL COMPLEX CONTAINING LIGAND 审中-公开
标题翻译： LIGAND，METALLKOMPLEX MIT DEM LIGANDEN UND REAKING UNTER VERWENDUNG DES METALLKOMPLEXES MIT DEM LIGANDEN
公开(公告)号：EP2966081A4
公开(公告)日：2016-08-24
申请号：EP14760209
申请日：2014-03-04
申请人： UNIV NAGOYA NAT UNIV CORP
发明人： SAITO SUSUMU , NOYORI RYOJI , MIURA TAKASHI , NARUTO MASAYUKI , IIDA KAZUKI , TAKADA YUKI , TODA KATSUAKI , NIMURA SOTA , AGRAWAL SANTOSH , LEE SUNKOOK
IPC分类号： C07F9/58 , B01J31/24 , C07B61/00 , C07C29/145 , C07C29/149 , C07C31/04 , C07C31/20 , C07C33/20 , C07C33/22 , C07C33/24 , C07C209/50 , C07C211/27 , C07C213/02 , C07C215/08 , C07F9/6561 , C07F15/00 , C07F15/02 , C07F15/04
CPC分类号： B01J31/2414 , B01J31/24 , B01J2231/641 , B01J2231/76 , B01J2531/821 , B01J2531/822 , B01J2531/827 , B01J2531/828 , B01J2531/842 , B01J2531/845 , B01J2531/847 , C07C29/132 , C07C29/145 , C07C29/149 , C07C67/28 , C07C209/50 , C07C213/00 , C07C213/02 , C07D207/33 , C07F9/582 , C07F9/6561 , C07F15/004 , C07F15/0053 , C07F15/0066 , C07F15/008 , C07F15/0093 , C07F15/025 , C07F15/045 , C07F15/065 , Y02P20/52 , C07C33/24 , C07C31/207 , C07C31/04 , C07C33/22 , C07C33/20 , C07C211/27 , C07C215/28
摘要： A hydrogen transfer reaction may be more efficiently promoted by using a metal complex represented by Formula (2): (wherein, R 1 to R 8 are the same or different, and each represents a hydrogen atom, a substituted or unsubstituted alkyl group or the like; or wherein; R 1 and R 2 , R 2 and R 3 , R 3 and R 4 , R 4 and R 5 , and R 5 and R 6 are respectively bonded to each other to form a bivalent hydrocarbon group; R 9 are the same or different, and each represents an alkyl group or cycloalkyl group; M is ruthenium (Ru) or the like; X is a ligand; and n is 0, 1 or 2). More specifically, the metal complex enables a hydrogenation reaction of various substrates having a stable carbonyl group or the like to be advanced with a high yield under mild conditions.
摘要翻译：通过使用由式（2）表示的金属络合物可以更有效地促进氢转移反应：（其中，R 1〜R 8相同或不同，各自表示氢原子，取代或未取代的烷基或或其中R 1和R 2，R 2和R 3，R 3和R 4，R 4和R 5以及R 5和R 6分别相互键合形成二价烃基; R 9 各自表示烷基或环烷基; M为钌（Ru）等; X为配体，n为0,1或2）。更具体地说，金属络合物能够在温和条件下使具有稳定羰基等的各种基材的氢化反应以高产率前进。

4. 发明公开

EP2734299A4 CATALYSTS AND PROCESSES FOR THE HYDROGENATION OF AMIDES 审中-公开
标题翻译：催化剂和氢化方法来说酰胺类
公开(公告)号：EP2734299A4
公开(公告)日：2016-05-11
申请号：EP12815389
申请日：2012-07-18
申请人： UNIV ALBERTA
发明人： BERGENS STEVEN , JOHN JEREMY M
IPC分类号： B01J31/18 , B01J31/24 , C07B31/00
CPC分类号： C07F15/0053 , B01J31/1805 , B01J31/189 , B01J31/2409 , B01J31/2452 , B01J2231/643 , B01J2531/0244 , B01J2531/0255 , B01J2531/0266 , B01J2531/821 , C07B31/00 , C07B2200/07 , C07C29/149 , C07C41/26 , C07C209/50 , C07C213/00 , C07C231/08 , C07C303/40 , C07D201/02 , C07D295/023 , C07D295/027 , C07F15/0046 , C07C233/18 , C07C311/04 , C07C215/16 , C07C215/08 , C07C211/55 , C07C211/48 , C07C211/04 , C07C33/22 , C07C43/23 , C07C31/08

5. 发明公开

EP3012260A1 METAL COMPLEX INCLUDING TRIDENTATE AMINODICARBENE LIGAND AND HYDROGENATION REDUCTION METHOD USING SAME 有权转让
标题翻译：金属络合物，包括三元的氨基配体和氢化还原方法
公开(公告)号：EP3012260A1
公开(公告)日：2016-04-27
申请号：EP14813824.1
申请日：2014-06-19
申请人： Kuraray Co., Ltd.
发明人： MURATA, Yusuke , TORIHARA, Masahiro
IPC分类号： C07F15/00 , B01J31/24 , C07C29/145 , C07C29/149 , C07C31/125 , C07C31/20 , C07C33/22 , C07B61/00
CPC分类号： C07F15/0046 , B01J31/1805 , B01J31/2295 , B01J31/24 , B01J31/2404 , B01J2231/643 , B01J2531/0238 , B01J2531/17 , B01J2531/821 , C07B31/00 , C07C29/145 , C07C29/149 , C07C31/125 , C07C31/20 , C07C33/22 , C07F1/10
摘要： The use of a metal complex containing a ruthenium ion or an osmium ion, and a tridentate aminodicarbene ligand, the tridentate aminodicarbene ligand having one secondary amino group and two specific heterocyclic carbene groups sandwiching the amino group, enables hydrogenation reduction of carbonyl compounds, such as ketones, carboxylic acid esters, lactones, carboxylic acid amides, and lactams, and imine compounds under relatively mild conditions to produce corresponding alcohols, amines, and the like in a high yield with high catalytic efficiency. The metal complex is obtained by a method comprising steps of reacting a specific metal compound with a specific aminodicarbene precursor and subsequently reacting a specific compound. Reduction of a carbonyl compound or an imine compound in the presence of this metal complex using a hydrogen donor makes it possible to reduce the carbonyl compound or imine compound by hydrogenation.
摘要翻译：使用含有钌离子或锇离子的金属络合物和三齿氨基二碳烯配体（具有一个仲氨基的三齿氨基二卡宾配体和两个将氨基夹在中间的特定杂环卡宾基团）能够使羰基化合物例如酮，羧酸酯，内酯，羧酸酰胺和内酰胺以及亚胺化合物在相对温和的条件下以高收率以高催化效率生产相应的醇，胺等。该金属络合物通过包括以下步骤的方法获得：使特定金属化合物与特定氨基二碳烯前体反应并随后使特定化合物反应。使用供氢体在该金属配合物存在下还原羰基化合物或亚胺化合物使得可以通过氢化还原羰基化合物或亚胺化合物。

6. 发明授权

EP2619162B1 METHOD FOR PRODUCING ALCOHOL AND/OR AMINE FROM AMIDE COMPOUND 有权
标题翻译： METHOD FOR醇和/或胺从酰胺生产
公开(公告)号：EP2619162B1
公开(公告)日：2016-04-06
申请号：EP11760580.8
申请日：2011-09-01
申请人： Takasago International Corporation
发明人： OGATA, Osamu , KURIYAMA, Wataru , MATSUMOTO, Takaji
IPC分类号： C07C29/149 , C07C209/50
CPC分类号： C07C209/50 , B01J31/1805 , B01J31/189 , B01J31/20 , B01J31/24 , B01J2231/643 , B01J2531/821 , C07B41/02 , C07B43/04 , C07C29/149 , C07C29/36 , C07C209/62 , C07D295/02 , C07D295/18 , C07C211/04 , C07C211/46 , C07C211/48 , C07C211/55 , C07C31/125 , C07C33/22

7. 发明公开

EP2805765A1 Process for hydrogenating ketones in the presence of RU (II) catalysts 有权
标题翻译：格尔瓦特·冯茹（II）Katalysatoren的Verfahren zur Hydrierung von Ketonen
公开(公告)号：EP2805765A1
公开(公告)日：2014-11-26
申请号：EP14171583.9
申请日：2010-03-17
申请人： Johnson Matthey Public Limited Company
发明人： Dyke, Alan, Malcolm , Grainger, Damian, Mark , Medlock, Jonathan, Alan , Nedden, Hans, Guenter , Le Paih, Jacques Jean-Marie , Roseblade, Stephen James , Seger, Andreas , Sivakumar, Vilvanathan , Zanotti-Gerosa Antonio
IPC分类号： B01J23/46 , C07C29/145 , C07C311/05 , C07C311/18 , C07C33/20
CPC分类号： B01J31/1805 , B01J31/2295 , B01J2231/643 , B01J2531/0238 , B01J2531/821 , C07C29/145 , C07C311/05 , C07C311/07 , C07C311/18 , C07C311/20 , C07C2523/70 , C07C2531/18 , C07C2601/14 , C07C2601/16 , C07F15/0046 , C07F15/0053 , C07C33/22
摘要： The present invention relates to a process for hydrogenating a substrate comprising a carbon-heteroatom double bond, the process comprising the step of reacting the substrate with hydrogen gas in the presence of a hydrogenation catalyst, wherein the hydrogenation catalyst is a complex of formula (I):

R 1-10 , A and Hal are as defined in the specification. The present invention also provides processes for the preparation of the complex of formula (I) and intermediates thereof.
摘要翻译：本发明涉及一种用于氢化包含碳 - 杂原子双键的底物的方法，该方法包括在氢化催化剂存在下使底物与氢气反应的步骤，其中氢化催化剂是式（I ）：R 1-10，A和Hal如说明书中所定义。本发明还提供制备式（I）的络合物及其中间体的方法。

8. 发明授权

EP2095875B1 Homogeneous asymmetric hydrogenation catalyst 有权
标题翻译： Homogenkatalysatorfürdie不对称性Hydrierung
公开(公告)号：EP2095875B1
公开(公告)日：2014-10-01
申请号：EP09162782.8
申请日：2006-07-06
申请人： Takasago International Corporation
发明人： Shimizu, Hideo , Igarashi, Daisuke , Kuriyama, Wataru , Yusa, Yukinori
IPC分类号： B01J31/24 , C07B35/02 , C07B53/00 , C07C29/145 , C07C29/17 , C07C67/303 , C07F9/50 , C07C41/26 , C07F9/655 , C07C45/62 , C07C231/12 , C07D209/08 , C07D307/46
CPC分类号： C07C29/145 , B01J31/2409 , B01J31/2452 , B01J31/2457 , B01J2231/643 , B01J2531/0266 , B01J2531/16 , C07B35/02 , C07B53/00 , C07B2200/07 , C07C29/175 , C07C41/26 , C07C45/62 , C07C67/303 , C07C231/12 , C07C2601/14 , C07C2601/16 , C07D209/08 , C07D307/46 , C07F9/5045 , C07F9/65517 , C07C49/403 , C07C69/612 , C07C69/24 , C07C233/47 , C07C43/196 , C07C31/125 , C07C33/18 , C07C33/22 , C07C35/08 , C07C35/18

9. 发明公开

EP2463262A4 METHOD FOR PRODUCING ALCOHOL COMPOUND 审中-公开
标题翻译：方法用于生产酒精相关
公开(公告)号：EP2463262A4
公开(公告)日：2014-07-09
申请号：EP10806408
申请日：2010-08-02
申请人： UNIV YAMAGUCHI , UBE INDUSTRIES
发明人： KAMIMURA AKIO , KAISO KOUJI , SUGIMOTO TSUNEMI
IPC分类号： C07C29/128 , C07C31/125 , C07C33/22
CPC分类号： C07C29/128 , Y02P20/544 , C07C31/125 , C07C33/22 , C07C31/20

10. 发明公开

EP2619162A1 METHOD FOR PRODUCING ALCOHOL AND/OR AMINE FROM AMIDE COMPOUND 有权
标题翻译： METHOD FOR醇和/或胺从酰胺生产
公开(公告)号：EP2619162A1
公开(公告)日：2013-07-31
申请号：EP11760580.8
申请日：2011-09-01
申请人： Takasago International Corporation
发明人： OGATA, Osamu , KURIYAMA, Wataru , MATSUMOTO, Takaji
IPC分类号： C07C29/149 , C07C209/50
CPC分类号： C07C209/50 , B01J31/1805 , B01J31/189 , B01J31/20 , B01J31/24 , B01J2231/643 , B01J2531/821 , C07B41/02 , C07B43/04 , C07C29/149 , C07C29/36 , C07C209/62 , C07D295/02 , C07D295/18 , C07C211/04 , C07C211/46 , C07C211/48 , C07C211/55 , C07C31/125 , C07C33/22
摘要： Disclosed herein is a method for producing an alcohol and an amine from an amide under an atmosphere of hydrogen with the use of, as a catalyst, a ruthenium complex that is easily prepared, easy to handle, and relatively cheaply obtained. Specifically, the method is a method for producing an alcohol and/or an amine from an amide compound under an atmosphere of hydrogen with the use of, as a catalyst, a ruthenium carbonyl complex represented by the following general formula (1): RuXY(CO)(L) (1) wherein X and Y may be the same or different from each other and each represents an anionic ligand and L represents a tridentate aminodiphosphine ligand containing two phosphino groups and a - NH - group.

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