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11. 发明公开

EP1776396A1 POLYMERISATION AND OLIGOMERISATION CATALYSTS 有权
标题翻译：聚合和低聚
公开(公告)号：EP1776396A1
公开(公告)日：2007-04-25
申请号：EP05762803.4
申请日：2005-07-25
申请人： INEOS EUROPE LIMITED
发明人： GIBSON, Vernon Charles , TOMOV, Atanas Kostadinov , JACOBSEN, Grant, Berent
IPC分类号： C08F10/00
CPC分类号： C08F10/02 , C08F10/00 , C08F110/02 , C08F4/022 , C08F4/69224 , C08F2500/01 , C08F4/64099 , C08F4/64089 , C08F4/68224 , C08F4/6825 , C08F4/68215 , C08F4/69275 , C08F4/6925 , C08F4/69215 , C08F4/69034 , C08F4/69146
摘要： A polymerisation catalyst composition comprising (1) a transition metal compound of Formula (A), Z being 5-membered heterocyclic containing at least one carbon, at least one nitrogen and at least one of nitrogen, sulphur and oxygen, the others being nitrogen or carbon; M is a Group 3 to 11 metal or a lanthanide metal; E1 and E2 are divalent groups of aliphatic, alicyclic, aromatic or alkyl substituted aromatic hydrocarbon, or heterocyclic; D1 and D2 are donor atoms or groups; X is an anionic group, L is a neutral donor group; n = m = zero or 1; y and z are zero or integer such that X and L satisfy valency/oxidation state of M, (2) a catalyst-activating support which is a solid particulate substance, insoluble in hydrocarbons, comprising at least magnesium and aluminium atoms and hydrocarbyloxy groups containing 1 to 20 carbons atoms, the molar ratio of Mg/Al being in the range 1.0 to 300 and the molar ratio of hydrocarbyloxy groups to aluminium atoms being in the range 0.05 to 2.0, and optionally, (3) an additional activator selected from aluminium alkyl and boron compounds.

12. 发明公开

EP1741486A1 Catalyst systems based on macrocyclic ligands 审中-公开
标题翻译： Katalysatorsysteme auf Basis von macrocyclischen Liganden
公开(公告)号：EP1741486A1
公开(公告)日：2007-01-10
申请号：EP05106167.9
申请日：2005-07-07
申请人： TOTAL PETROCHEMICALS RESEARCH FELUY
发明人： Hillairet, Caroline , Michaud, Guillaume , Sirol, Sabine
IPC分类号： B01J31/18
CPC分类号： B01J31/1815 , B01J2231/122 , B01J2231/20 , B01J2531/842 , C07D273/00 , C08F10/00 , C08F110/02 , C08F2500/02 , C08F4/64089 , C08F4/68224 , C08F4/69224 , C08F4/7042
摘要： The present invention discloses the use of rotoxane ligands to prepare catalyst systems suitable for the oligomerisation or polymerisation of ethylene and alpha-olefins.
摘要翻译：本发明公开了使用环丁烷配体来制备适用于乙烯和α-烯烃低聚或聚合的催化剂体系。

13. 发明公开

EP1367069A1 Process for homo-or copolymerization of conjugated diens 审中-公开
标题翻译： Verfahren zur Homo oder Copolymerization von konjugierten Dienen
公开(公告)号：EP1367069A1
公开(公告)日：2003-12-03
申请号：EP03012330.1
申请日：2003-05-28
申请人： DOW GLOBAL TECHNOLOGIES INC.
发明人： Thiele, Sven , Wilson, David R. , Boone, Harold W. , Feng, Shaoguang , Mullins, Michael J. , Monroy, Victor M.
IPC分类号： C08F36/04 , C08F4/68 , C08F4/54 , C08F4/70
CPC分类号： C08F36/04 , C08F10/00 , C08F4/545 , C08F4/68224 , C08F4/7042
摘要： According to this invention, pyridine or phosphabenzene ligand-containing Group 5, 8, 9, lanthanide and actinide metal complexes corresponding to the formula:
are disclosed as useful for polymerization of conjugated ethylenically unsaturated addition polymerizable monomers or copolymerization of one type of conjugated ethylenically unsaturated addition polymerizable monomer with at least one different type of conjugated ethylenically unsaturated addition polymerizable monomer or copolymerization of at least one type of conjugated ethylenically unsaturated addition polymerizable monomers with ethylenically monounsaturated addition polymerizable monomers. M is a metal from one of Groups 5, 8 or 9 of the Periodic Table of the Elements, the lanthanides or actinides; T is nitrogen or phosphorus; R A , R B and R C are independently each occurrence hydrogen or a group having from 1 to 80 atoms not counting hydrogen further defined herein, the R B and R A groups are optionally bonded to the same T=C grouping may be joined together to form a divalent ligand group and two R C groups are optionally joined together forming a divalent ligand group; X is an anionic ligand group having up to 60 atoms not counting hydrogen, provided however that in no occurrence is X a cyclic, delocalized, aromatic group that is π-bonded to M, and optionally two X groups together form a divalent ligand group; X' independently each occurrence is a neutral Lewis base ligand having up to 30 nonhydrogen atoms; x is an integer number from 0 to 5; and x' is a number from 0 to 3. Novel homo- and copolymers are obtained which have advantageous properties for the production of a wide range of products and for the modification of plastics, such as high impact polystyrene or impact-modified polypropylene
摘要翻译：根据本发明，公开了对应于下式的的含有5,8,9族镧系元素和锕系金属络合物的吡啶或膦酰基配位体可用于共轭烯属不饱和可加成单体的聚合或一种共轭烯键式不饱和可加成聚合单体与至少一种不同类型的共轭烯键式不饱和加成聚合单体或至少一种类型的共轭烯属不饱和加成聚合单体与烯属单不饱和可加成聚合单体的共聚合。 M是元素周期表第5,8或9族之一的金属，镧系元素或锕系元素; T是氮或磷; R A，R B和R C独立地各自出现氢或具有1至80个原子的基团，不计算本文进一步定义的氢，R B和R A A基团任选地键合至相同的T = C基团可以连接在一起以形成二价配体基团，并且两个R C基团任选地连接在一起形成二价配体基团; X是具有至多60个不计氢的原子的阴离子配体基团，条件是，X不是π的π-环状，离域的芳基，并且任选地两个X基团一起形成二价配体基团。独立地，X'是具有至多30个非氢原子的中性路易斯碱配体; x是从0到5的整数; 并且x'是0至3的数字。获得了新颖的均聚物和共聚物，其具有用于生产各种产品和改性塑料的有利性质，例如高抗冲聚苯乙烯或抗冲改性聚丙烯

14. 发明授权

EP1187856B1 TRANSITION METAL COMPLEXES AND OLEFIN POLYMERIZATION PROCESS 有权
标题翻译：过渡金属络合物和烯烃聚合
公开(公告)号：EP1187856B1
公开(公告)日：2003-09-10
申请号：EP00919456.4
申请日：2000-03-17
申请人： Dow Global Technologies Inc.
发明人： DEVORE, David, D. , FENG, Shaoguang, S. , FRAZIER, Kevin, A. , PATTON, Jasson, T.
IPC分类号： C08F10/00 , C08F4/60 , C07F5/00 , C07F7/00 , C07F9/00 , C07F11/00 , C07F13/00 , C07F15/00
CPC分类号： C08F10/06 , C07F5/003 , C07F7/006 , C07F9/005 , C07F11/005 , C07F13/005 , C07F15/025 , C08F10/00 , C08F110/06 , C08F4/619 , C08F4/52 , C08F4/64089 , C08F4/69224 , C08F4/68224 , C08F4/60089 , C08F2500/03 , C08F2500/15 , C08F4/7042
摘要： Metal complexes comprising a polydentate chelating group, catalysts and polymerization processes using the same for the polymerization of olefins, especially propylene, are disclosed.

15. 发明公开

EP1165568A4 METAL COMPOUNDS CONTAINING NEUTRAL, MULTIDENTATE AZACYCLIC LIGANDS, CATALYSTS USING THEM, OLEFIN POLYMERIZATION METHODS USING THEM 审中-公开
标题翻译：金属化合物通过该使用以及使用该烯烃聚合方法含中性的，多齿配体的氮杂环，CATALYST
公开(公告)号：EP1165568A4
公开(公告)日：2002-10-16
申请号：EP00911957
申请日：2000-02-25
申请人： EQUISTAR CHEM LP
发明人： HLATKY GREGORY G
IPC分类号： C07F7/10 , B01J31/14 , B01J31/16 , B01J31/18 , C07F7/08 , C08F4/02 , C08F4/44 , C08F4/60 , C08F4/645 , C08F10/00 , C08F110/02 , C07F5/00 , B01J31/00 , B01J37/00 , C07D231/00 , C07D293/00
CPC分类号： C08F10/00 , B01J31/14 , B01J31/1608 , B01J31/1815 , B01J2531/46 , B01J2531/56 , B01J2531/62 , B01J2531/845 , B01J2531/847 , C07F7/0814 , C08F110/02 , C08F4/64089 , C08F4/69224 , C08F4/68224 , C08F4/7006
摘要： Neutral, multidentate azacyclic ligands and their complexes with group 3-10 and lanthanide metals are disclosed. The ligands are of the general formula Ra-A-(L)b where R is hydrogen or hydrocarbyl, A is silicon, germanium, tin or lead, each L is pyrazolyl, triazolyl or tetraazolyl, a = 0-2, b = 2-4, a + b = 4. When activated with common activators, the metal complexes polymerize olefins.
摘要翻译：中性，多齿氮杂环配体和3-10族过渡金属配合物确实含有他们是游离缺失盘。所述配体具有以下通式：镭-A-（L）b其中R是氢或烃基，A是硅，锡，锗，铅或，每个L是吡唑基，三唑基，四唑基或烷基，= 0至2 ，b = 2至4，并且a + b =第四当与活化剂共同使用时，过渡金属配合物，提供用于烯烃聚合的优良的单中心催化剂。

16. 发明授权

EP2526129B1 ETHYLENE POLYMERISATION PROCESS 失效
标题翻译：乙烯聚合工艺
公开(公告)号：EP2526129B1
公开(公告)日：2017-09-27
申请号：EP11700894.6
申请日：2011-01-19
申请人： SAUDI BASIC INDUSTRIES CORPORATION (SABIC)
发明人： ALT, Helmut , ELAGAB, Hamdi Ali , AL-HUMYDI, Abdulaziz Hamad
IPC分类号： C08F110/02 , C08F10/00
CPC分类号： C08F10/00 , B01J2231/12 , B01J2531/46 , B01J2531/48 , B01J2531/49 , B01J2531/56 , C08F110/02 , C08F4/64013 , C08F4/68034 , C08F4/68224 , C08F2500/04

18. 发明公开

EP1789459A1 POLYOLEFINS 有权转让
标题翻译：聚烯烃
公开(公告)号：EP1789459A1
公开(公告)日：2007-05-30
申请号：EP05782880.8
申请日：2005-09-13
申请人： INEOS EUROPE LIMITED
发明人： GIBSON, Vernon, Charles , JACOBSEN, Grant, Berent , TOMOV, Atanas Kostadinov
IPC分类号： C08F210/18 , C08F4/622
CPC分类号： C08F210/18 , C08F10/00 , C08F4/69224 , C08F4/68224 , C08F210/06 , C08F232/00 , C08F2500/25 , C08F4/6925 , C08F4/69275 , C08F4/6825 , C08F4/68215 , C08F4/69215 , C08F4/69146 , C08F4/69034 , C08F4/64013
摘要： Process for making copolymer (eg elastomeric copolymer) by copolymerising (1) ethylene with (2) at least one comonomer aliphatic C3-C20 alpha-olefins and (3) at least one C4 to C30 conjugated or non-conjugated dienes. The monomers are contacted with (a) a transition metal catalyst of Formula A, and (b) an activating quantity of a suitable activator, Z is five-membered heterocyclic group having at least one carbon atom, at least one nitrogen atom and at least one other hetero atom selected from nitrogen, sulphur and oxygen, the remaining atoms being nitrogen or carbon; M is a metal from Group 3 to 11 or lanthanide; E1 and E2 are divalent (i) aliphatic hydrocarbon, (ii) alicyclic hydrocarbon, (iii) aromatic hydrocarbon, (iv) alkyl substituted aromatic hydrocarbon (v) heterocyclic groups and (vi) heterosubstituted derivatives of said groups (i) to (v); D1 and D2 are donor atoms or groups; X is an anionic group, L is a neutral donor group; n = m = zero or 1; y and z are independently zero or integers such that the number of X and L groups satisfy the valency and oxidation state of the metal M.

19. 发明公开

EP1625168A1 TRANSITION-METAL COMPLEXES WITH TRIDENTATE, NITROGEN-CONTAINING LIGANDS 审中-公开
标题翻译： ÜBERGANGSMETALLKOMLEX含有三齿配体包含氮原子
公开(公告)号：EP1625168A1
公开(公告)日：2006-02-15
申请号：EP04733787.8
申请日：2004-05-19
申请人： Basell Polyolefine GmbH
发明人： MIHAN, Shahram , ENDERS, Markus , FRITZ, Olaf
IPC分类号： C08F4/68 , C08F4/69 , C08F4/642 , C08F10/00 , C07F7/28 , C07F11/00
CPC分类号： C08F10/00 , B01J31/1815 , B01J2531/0247 , B01J2531/46 , B01J2531/56 , B01J2531/62 , C07F7/006 , C07F9/005 , C07F9/65066 , C07F11/005 , C08F110/02 , C08F2500/04 , C08F2500/17 , C08F2500/10 , C08F2500/07 , C08F4/64089 , C08F4/69224 , C08F4/68224 , C08F4/64179 , C08F4/68448 , C08F4/69448
摘要： Transition metal complexes with tridentate, nitrogen-containing, uncharged ligand systems, a catalyst system comprising at least one of the transition metal complexes, the use of the catalyst system for the polymerization or copolymerization of olefins and a process for preparing polyolefins by polymerization or copolymerization of olefins in the presence of the catalyst system.

20. 发明公开

EP1603957A1 POLYMERISATION AND OLIGOMERISATION CATALYSTS 有权转让
标题翻译：聚合和低聚
公开(公告)号：EP1603957A1
公开(公告)日：2005-12-14
申请号：EP04721578.5
申请日：2004-03-18
申请人： Innovene Europe Limited
发明人： GIBSON, Vernon Charles , TOMOV, Atanas
IPC分类号： C08F10/02
CPC分类号： C08F136/06 , C08F4/63912 , C08F4/7006 , C08F10/00 , C08F110/02 , C08F210/02 , C08F210/16 , C08F4/639 , C08F4/69224 , C08F4/70 , C08F2500/04 , C08F2500/03 , C08F212/08 , C08F232/00 , C08F2500/25 , C08F220/00 , C08F210/14 , C08F4/69284 , C08F4/6925 , C08F4/69215 , C08F4/69146 , C08F4/68224 , C08F4/6825 , C08F4/68215 , C08F4/68043 , C08F4/64089 , C08F4/64099 , C08F4/64093
摘要： A polymerisation catalyst comprising (1) a transition metal compound of Formula A, and optionally (2) an activating quantity of a Lewis acid activator, Formula (A), wherein Z is a five-membered heterocyclic group containing at least one carbon atom, at least one nitrogen atom and at least one other hetero atom selected from nitrogen, sulphur and oxygen, the remaining atoms in the ring being nitrogen or carbon; M is a metal from Group 3 to 11 of the Periodic Table or a lanthanide metal; E1 and E2 are divalent groups from (i) aliphatic hydrocarbon, (ii) alicyclic hydrocarbon, (iii) aromatic hydrocarbon, (iv) alkyl substituted aromatic hydrocarbon (v) heterocyclic groups and (vi) heterosubstituted derivatives of groups (i) to (v); D' and D2 are donor groups; X is an anionic group, L is a neutral donor group; n = m = zero or 1; y and z are zero or integers. The catalysts are useful for polymerising or oligomerising 1-olefins.

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