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1. 发明公开

EP1899060A2 CATALYST SYSTEMS BASED ON MACROCYCLIC LIGANDS 有权
标题翻译：基于大环配体催化剂体系
公开(公告)号：EP1899060A2
公开(公告)日：2008-03-19
申请号：EP06777539.5
申请日：2006-07-03
申请人： TOTAL PETROCHEMICALS RESEARCH FELUY
发明人： HILLAIRET, Caroline , MICHAUD, Guillaume , SIROL, Sabine
IPC分类号： B01J31/18
CPC分类号： B01J31/1815 , B01J2231/122 , B01J2231/20 , B01J2531/842 , C07D273/00 , C08F10/00 , C08F110/02 , C08F2500/02 , C08F4/64089 , C08F4/68224 , C08F4/69224 , C08F4/7042
摘要： The present invention discloses the use of rotoxane ligands to prepare catalyst systems suitable for the oligomerisation or polymerisation of ethylene and alpha-olefins.

2. 发明授权

EP1776396B1 POLYMERISATION AND OLIGOMERISATION CATALYSTS 有权
标题翻译：聚合和低聚
公开(公告)号：EP1776396B1
公开(公告)日：2008-11-05
申请号：EP05762803.4
申请日：2005-07-25
申请人： INEOS EUROPE LIMITED
发明人： GIBSON, Vernon Charles , TOMOV, Atanas Kostadinov , JACOBSEN, Grant, Berent
IPC分类号： C08F10/00
CPC分类号： C08F10/02 , C08F10/00 , C08F110/02 , C08F4/022 , C08F4/69224 , C08F2500/01 , C08F4/64099 , C08F4/64089 , C08F4/68224 , C08F4/6825 , C08F4/68215 , C08F4/69275 , C08F4/6925 , C08F4/69215 , C08F4/69034 , C08F4/69146
摘要： A polymerisation catalyst composition comprising (1) a transition metal compound of Formula (A), Z being 5-membered heterocyclic containing at least one carbon, at least one nitrogen and at least one of nitrogen, sulphur and oxygen, the others being nitrogen or carbon; M is a Group 3 to 11 metal or a lanthanide metal; E1 and E2 are divalent groups of aliphatic, alicyclic, aromatic or alkyl substituted aromatic hydrocarbon, or heterocyclic; D1 and D2 are donor atoms or groups; X is an anionic group, L is a neutral donor group; n = m = zero or 1; y and z are zero or integer such that X and L satisfy valency/oxidation state of M, (2) a catalyst-activating support which is a solid particulate substance, insoluble in hydrocarbons, comprising at least magnesium and aluminium atoms and hydrocarbyloxy groups containing 1 to 20 carbons atoms, the molar ratio of Mg/Al being in the range 1.0 to 300 and the molar ratio of hydrocarbyloxy groups to aluminium atoms being in the range 0.05 to 2.0, and optionally, (3) an additional activator selected from aluminium alkyl and boron compounds.

3. 发明公开

EP1765881A1 POLYMERISATION CATALYST 审中-公开
标题翻译：聚合催化剂
公开(公告)号：EP1765881A1
公开(公告)日：2007-03-28
申请号：EP05755161.6
申请日：2005-06-23
申请人： INEOS EUROPE LIMITED
发明人： GIBSON, Vernon Charles , TOMOV, Atanas Kostadinov , JACOBSEN, Grant Berent
IPC分类号： C08F10/00 , C08F4/70
CPC分类号： C08F10/00 , C08F4/68224
摘要： A polymerisation catalyst comprising (1) a transition metal compound of Formula (A), and optionally (2) an activator, wherein Z is 5-membered heterocyclic containing carbon, nitrogen and at least one other selected from nitrogen, sulphur and oxygen, the remaining atoms in the ring being nitrogen and carbon; M is a metal from Group 3 to 11 or a lanthanide metal; E1 and E2 are divalent hydrocarbon, heterocyclic or heterosubstituted derivatives of these; D1 and D2 are donor atoms or groups; X is an anionic group, L is a neutral donor group; n = m = zero or 1; y and z are zero or integers so that X and L satisfy the valency/oxidation state of M, characterised in that the complex contains at least one polymerisable olefinic double bond which is present in, or substituent to, at least one of the atoms, groups or ligands represented by Z, E, D and L. the catalyst binds to the forming polymer providing product with good particle morphology.
摘要翻译：一种聚合催化剂，其包含（1）式（A）的过渡金属化合物和任选的（2）活化剂，其中Z是含有碳，氮和至少一个选自氮，硫和氧的其它的5元杂环，环中剩余的原子是氮和碳; M是第3-11族的金属或镧系金属; E1和E2是这些的二价烃基，杂环或杂取代衍生物; D1和D2是供体原子或基团; X是阴离子基团，L是中性供体基团; n = m = 0或1; y和z是零或整数，使得X和L满足M的化合价/氧化态，其特征在于配合物含有至少一个可聚合的烯属双键，其存在于或取代至少一个原子，由Z，E，D和L表示的基团或配体。催化剂结合形成聚合物，提供具有良好颗粒形态的产物。

4. 发明公开

EP1238989A2 Olefin polymerization catalyst and process for producing olefin polymer with the catalyst 有权
标题翻译： Olefinpolymerisationskatalysator和Verfahren zur Herstellung von Olefinpolymeren damit
公开(公告)号：EP1238989A2
公开(公告)日：2002-09-11
申请号：EP02003261.1
申请日：2002-02-21
申请人： MITSUI CHEMICALS, INC.
发明人： Nakayama, Yasushi , Kaneko, Hideyuki , Bandoh, Hideki , Sonobe, Yoshiho , Saito, Junji , Kojoh, Shinichi , Mitani, Makoto , Suzuki, Yasuhiko , Matsui, Shigekazu , Kashiwa, Norio , Fujita, Terunori
IPC分类号： C08F4/626 , C08F4/16 , C08F4/68 , C08F10/02
CPC分类号： C08F10/00 , C08F10/02 , C08F110/02 , C08F210/16 , C08F4/68 , C08F4/62 , C08F4/626 , C08F4/025 , C08F4/16 , C08F2500/17 , C08F2500/03 , C08F210/06 , C08F4/68112 , C08F4/6812 , C08F4/68181 , C08F4/68224 , C08F4/68293 , C08F4/6831 , C08F4/68413 , C08F4/68396 , C08F4/64044 , C08F4/64048 , C08F4/64072 , C08F4/64079 , C08F4/7042 , C08F4/7006
摘要： A novel olefin polymerization catalyst is provided which comprises (A) a transition metal compound or lanthanoid compound containing two or more atoms selected from the group consisting of boron, nitrogen, oxygen, phosphorus, sulfur, and selenium; and (B) a Lewis acid. A process for producing an olefin polymer is alsoprovided. The catalyst has a high olefin polymerization activity without a combined use of an expensive organoaluminum oxy-compound or organoboron compound, and can maintain the high activity for a long polymerization time.
摘要翻译：提供一种新型的烯烃聚合催化剂，其包含（A）含有选自硼，氮，氧，磷，硫和硒中的两个或多个原子的过渡金属化合物或镧系元素化合物; 和（B）路易斯酸。还提供了制备烯烃聚合物的方法。催化剂具有高的烯烃聚合活性，而不需要昂贵的有机铝氧化合物或有机硼化合物的组合使用，并且可以在长时间聚合时保持高活性。

5. 发明授权

EP1603957B1 POLYMERISATION AND OLIGOMERISATION CATALYSTS 有权转让
标题翻译：聚合和低聚
公开(公告)号：EP1603957B1
公开(公告)日：2015-10-28
申请号：EP04721578.5
申请日：2004-03-18
申请人： Ineos Sales (UK) Limited
发明人： GIBSON, Vernon Charles , TOMOV, Atanas
IPC分类号： C08F10/02 , C08F4/639
CPC分类号： C08F136/06 , C08F4/63912 , C08F4/7006 , C08F10/00 , C08F110/02 , C08F210/02 , C08F210/16 , C08F4/639 , C08F4/69224 , C08F4/70 , C08F2500/04 , C08F2500/03 , C08F212/08 , C08F232/00 , C08F2500/25 , C08F220/00 , C08F210/14 , C08F4/69284 , C08F4/6925 , C08F4/69215 , C08F4/69146 , C08F4/68224 , C08F4/6825 , C08F4/68215 , C08F4/68043 , C08F4/64089 , C08F4/64099 , C08F4/64093

6. 发明公开

EP2526129A1 ETHYLENE POLYMERISATION 失效
标题翻译： VERFAHREN ZUR POLYMERISIERUNG VON ETHYLEN
公开(公告)号：EP2526129A1
公开(公告)日：2012-11-28
申请号：EP11700894.6
申请日：2011-01-19
申请人： SAUDI BASIC INDUSTRIES CORPORATION (SABIC)
发明人： ALT, Helmut , ELAGAB, Hamdi Ali , AL-HUMYDI, Abdulaziz Hamad
IPC分类号： C08F10/00 , C08F4/64 , C08F4/649 , C08F10/02
CPC分类号： C08F10/00 , B01J2231/12 , B01J2531/46 , B01J2531/48 , B01J2531/49 , B01J2531/56 , C08F110/02 , C08F4/64013 , C08F4/68034 , C08F4/68224 , C08F2500/04
摘要： The invention is directed to a process for the polymerization of ethylene in the presence of a catalyst comprising a Ti, Zr, Hf or V metal centre; and a ligand according to Formula (I), in which B = -CH
2 -, -CH
2 CH
2 -, -CH=CH-, 1,2-phenylene or 2,6-pyridyl, R
1, R
2 , R
3 ,R
4 may be independently of one other the same or different H, C
1 -C
4 alkyl radical, Br or Cl and X =NH, O or S; or a ligand containing a pyridine moiety or a N-allyl-2-benzimidazolyl ligand.
摘要翻译：本发明涉及在含Ti，Zr，Hf或V金属中心的催化剂存在下聚合乙烯的方法; 和式（I）的配体，其中B = -CH 2 - ， - CH 2 CH 2 - ， - CH = CH-，1,2-亚苯基或2,6-吡啶基，R 1，R 2，R 3，R 4可以独立地另一个相同或不同的H，C 1 -C 4烷基，Br或Cl和X = NH，O或S; 或含有吡啶部分或N-烯丙基-2-苯并咪唑基配体的配体。

7. 发明公开

EP1918311A1 Diene polymerisation 审中-公开
标题翻译：二烯聚合
公开(公告)号：EP1918311A1
公开(公告)日：2008-05-07
申请号：EP06255605.5
申请日：2006-10-31
申请人： INEOS EUROPE LIMITED
发明人： The designation of the inventor has not yet been filed
IPC分类号： C08F36/04 , C08F4/69 , C08F4/70
CPC分类号： C08F36/04 , C08F10/00 , C08F2410/04 , C08F4/69224 , C08F4/7042 , C08F4/6925 , C08F4/68224 , C08F4/6825 , C08F4/69034 , C08F4/69146 , C08F4/69215 , C08F4/68215 , C08F4/64089
摘要： A process for producing homopolymers or copolymers of conjugated dienes comprising polymerising the diene monomer with a catalyst system comprising (A) two or more different transition metal compounds (B) a catalyst modifier (eg triphenyl phosphine) and optionally (C) one or more catalyst activators (eg MAO). The cis, trans and 1,2-vinyl microstructure of the produced diene polymer can be controlled.
摘要翻译：一种生产共轭二烯均聚物或共聚物的方法，包括使二烯单体与催化剂体系聚合，所述催化剂体系包含（A）两种或更多种不同的过渡金属化合物（B）催化剂改性剂（例如三苯膦）和任选的（C）一种或多种催化剂活化剂（如MAO）。生产的二烯聚合物的顺式，反式和1,2-乙烯基微结构可以被控制。

8. 发明公开

EP1238989A3 Olefin polymerization catalyst and process for producing olefin polymer with the catalyst 有权
标题翻译：用于产生与其烯烃聚合物的烯烃聚合催化剂和方法
公开(公告)号：EP1238989A3
公开(公告)日：2004-01-02
申请号：EP02003261.1
申请日：2002-02-21
申请人： MITSUI CHEMICALS, INC.
发明人： Nakayama, Yasushi , Kaneko, Hideyuki , Bandoh, Hideki , Sonobe, Yoshiho , Saito, Junji , Kojoh, Shinichi , Mitani, Makoto , Suzuki, Yasuhiko , Matsui, Shigekazu , Kashiwa, Norio , Fujita, Terunori
IPC分类号： C08F4/626 , C08F4/16 , C08F4/68 , C08F10/02
CPC分类号： C08F10/00 , C08F10/02 , C08F110/02 , C08F210/16 , C08F4/68 , C08F4/62 , C08F4/626 , C08F4/025 , C08F4/16 , C08F2500/17 , C08F2500/03 , C08F210/06 , C08F4/68112 , C08F4/6812 , C08F4/68181 , C08F4/68224 , C08F4/68293 , C08F4/6831 , C08F4/68413 , C08F4/68396 , C08F4/64044 , C08F4/64048 , C08F4/64072 , C08F4/64079 , C08F4/7042 , C08F4/7006
摘要： A novel olefin polymerization catalyst is provided which comprises (A) a transition metal compound or lanthanoid compound containing two or more atoms selected from the group consisting of boron, nitrogen, oxygen, phosphorus, sulfur, and selenium; and (B) a Lewis acid. A process for producing an olefin polymer is alsoprovided. The catalyst has a high olefin polymerization activity without a combined use of an expensive organoaluminum oxy-compound or organoboron compound, and can maintain the high activity for a long polymerization time.

9. 发明授权

EP1789459B1 POLYOLEFINS 有权转让
标题翻译：聚烯烃
公开(公告)号：EP1789459B1
公开(公告)日：2014-04-30
申请号：EP05782880.8
申请日：2005-09-13
申请人： Ineos Sales (UK) Limited
发明人： GIBSON, Vernon, Charles , JACOBSEN, Grant, Berent , TOMOV, Atanas Kostadinov
IPC分类号： C08F210/18 , C08F4/68
CPC分类号： C08F210/18 , C08F10/00 , C08F4/69224 , C08F4/68224 , C08F210/06 , C08F232/00 , C08F2500/25 , C08F4/6925 , C08F4/69275 , C08F4/6825 , C08F4/68215 , C08F4/69215 , C08F4/69146 , C08F4/69034 , C08F4/64013

10. 发明授权

EP1899060B1 CATALYST SYSTEMS BASED ON MACROCYCLIC LIGANDS 有权
标题翻译：基于大环配体催化剂体系
公开(公告)号：EP1899060B1
公开(公告)日：2012-10-10
申请号：EP06777539.5
申请日：2006-07-03
申请人： TOTAL RESEARCH & TECHNOLOGY FELUY
发明人： HILLAIRET, Caroline , MICHAUD, Guillaume , SIROL, Sabine
IPC分类号： B01J31/18
CPC分类号： B01J31/1815 , B01J2231/122 , B01J2231/20 , B01J2531/842 , C07D273/00 , C08F10/00 , C08F110/02 , C08F2500/02 , C08F4/64089 , C08F4/68224 , C08F4/69224 , C08F4/7042

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