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    • 13. 发明公开
    • PHOTOELECTRIC CONVERSION ELEMENT AND METHOD FOR MANUFACTURING THE SAME
    • 光电转换元件及其制造方法
    • EP2169759A1
    • 2010-03-31
    • EP08791075.8
    • 2008-07-11
    • Hitachi Zosen Corporation
    • INOUE, TetsuyaSUGIYO, Takeshi
    • H01M14/00H01L31/04
    • H01M14/005H01G9/2022H01G9/2031H01G9/2059H01L51/444Y02E10/542Y02P70/521
    • The present invention provides a photoelectric conversion element having a high power generation efficiency, raising no problem of corrosion, and being applicable to a substrate having a low heat resistance, as well as a method of producing the same. It is a photoelectric conversion element formed in such a manner that a reference electrode serving as a negative electrode and a counter electrode serving as a positive electrode are arranged to oppose each other. The reference electrode is constructed by forming a photocatalyst film (8) dyed with a photosensitizing dye via a transparent conductive film (2) on one surface of a transparent substrate (1). The counter electrode is constructed by disposing, on one surface of a substrate (4) for the counter electrode, a brush-shaped carbon nanotube film (5) oriented substantially perpendicularly to the substrate surface via a conductive adhesive agent layer (7) that covers the surface.
    • 本发明提供具有高发电效率,不会产生腐蚀问题,并且可应用于具有低耐热性的基板的光电转换元件及其制造方法。 它是以这样的方式形成的光电转换元件,即用作负电极的参考电极和用作正电极的相对电极被布置为彼此相对。 参比电极通过在透明基板(1)的一个表面上经透明导电膜(2)形成用光敏染料染色的光催化剂膜(8)而构成。 对电极通过在用于反电极的基板(4)的一个表面上布置经由导电粘合剂层(7)基本上垂直于基板表面取向的刷状碳纳米管膜(5)来制造,所述导电粘合剂层(7)覆盖 表面。
    • 16. 发明公开
    • CONTINUOUS PRODUCTION METHOD FOR HYDROGEN
    • KONTINUIERLICHES HERSTELLUNGSVERFAHRENFÜRWASSERSTOFF
    • EP2832685A1
    • 2015-02-04
    • EP13769247.1
    • 2013-01-11
    • Hitachi Zosen CorporationKyoto University
    • HIKAZUDANI, SusumuWAKUI, AtsushiFURUTERA, MasaharuOSHIRO, HitoshiINOUE, TetsuyaHIRAO, Kazuyuki
    • C01B3/00C01F7/00
    • C01B3/063C01B3/06C01F7/164Y02E60/324Y02E60/36
    • The present invention provides a continuous production method of hydrogen which is able to produce hydrogen, which is clean energy, simply and continuously without using ammonia as stated in BACKGROUND ART and which has a very high level of safety. The invention of the continuous production method of hydrogen includes a hydrogen production step comprising introducing mayenite (Ca 12 Al 14 O 33 ) and calcium hydroxide [Ca(OH) 2 ] into water and allowing them to react with water, thereby generating hydrogen and also forming katoite [Ca 3 Al 2 (OH) 12 ]; a regeneration step comprising baking the formed katoite to regenerate mayenite and calcium hydroxide; and a circulation step comprising returning the regenerated mayenite and calcium hydroxide into the hydrogen production step. It is preferable that a temperature of water in the hydrogen production step is from 50 to 100°C, and a molar ratio of mayenite to calcium hydroxide is 1/9. In addition, it is preferable that a baking temperature of katoite in the regeneration step is from 300 to 500°C.
    • 本发明提供一种氢气的连续制造方法,其能够如背景技术所述那样简单且连续地产生清洁能量,而不使用氨,并且其具有非常高的安全性。 氢的连续生产方法的发明包括氢生产步骤,包括将钙铝石(Ca 12 Al 14 O 33)和氢氧化钙[Ca(OH)2]引入水中并使其与水反应,从而产生氢气 形成katoite [Ca 3 Al 2(OH)12]; 一种再生步骤,包括烘焙所形成的高铁矿以再生钙铝石和氢氧化钙; 以及循环步骤,包括将再生的钙铝石和氢氧化钙返回到氢生产步骤中。 氢制造工序中的水的温度优选为50〜100℃,钙铝石与氢氧化钙的摩尔比为1/9。 此外,再生步骤中的高铁氧体的烧成温度优选为300〜500℃。
    • 17. 发明公开
    • METHOD FOR MANUFACTURING DYE-SENSITIZED SOLAR CELL
    • VERFAHREN ZUR HERSTELLUNG EINER FARBSTOFFSENSIBILISIERTEN SOLARZELLE
    • EP2523250A1
    • 2012-11-14
    • EP10842201.5
    • 2010-12-22
    • Hitachi Zosen Corporation
    • SUGIYO, TakeshiINOUE, Tetsuya
    • H01M14/00H01L31/04
    • H01G9/2031H01G9/2059H01L51/0027Y02E10/542Y02P70/521
    • Disclosed is a method for manufacturing a dye-sensitized solar cell including a transparent electrode (1), a counter electrode (2), an electrolyte layer (3) disposed between the electrodes (1) and (2), and a photocatalyst film (4) disposed between the electrodes (1) and (2) and near the transparent electrode (1), the method including: forming the photocatalyst film (4) by applying a mixed solution to a surface of the transparent electrode (1) and sintering the mixed solution by laser beam irradiation, the mixed solution containing fine particles of titanium oxide serving as photocatalyst fine particles and a solution of titanium isopropoxide serving as a photocatalyst precursor.
    • 公开了一种染料敏化太阳能电池的制造方法,其包括透明电极(1),对电极(2),设置在电极(1)和(2)之间的电解质层(3)和光催化膜 4)设置在电极(1)和(2)之间并且在透明电极(1)附近,所述方法包括:通过将混合溶液施加到透明电极(1)的表面上并烧结来形成光催化膜(4) 通过激光束照射的混合溶液,含有作为光催化剂微粒的氧化钛的微粒的混合溶液和作为光催化剂前体的异丙醇钛的溶液。