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11. 发明公开

EP3197890A1 DISUBSTITUTED DIARYLOXYBENZOHETERODIAZOLE COMPOUNDS 有权
标题翻译：分散的二芳氧基苯并二碲化合物
公开(公告)号：EP3197890A1
公开(公告)日：2017-08-02
申请号：EP15767176.9
申请日：2015-09-24
申请人： ENI S.p.A.
发明人： ABBONDANZA, Luigi , ALESSI, Andrea , PROTO, Antonio Alfonso , SCHIMPERNA, Giuliana , GILA, Liliana
IPC分类号： C07D417/14 , C09K11/06 , H01L31/055
CPC分类号： H01L51/0071 , C07D417/14 , C09K11/02 , C09K11/06 , C09K2211/1007 , C09K2211/1011 , C09K2211/1051 , C09K2211/1092 , H01L27/301 , H01L51/004 , H01L51/0058 , H01L51/0068 , H01L51/4206 , H01L51/447 , H02S40/22 , Y02E10/52
摘要： Disubstituted diaryloxybenzoheterodiazole compound of general formula (1): in which: ∙ - Z represents a sulfur atom, an oxygen atom, a selenium atom; or an NR 5group in which R5 is selected from linear or branched C1-C20, preferably C1-C8, alkyl groups, or from optionally substituted aryl groups; ∙ - R1, R2 and R3 are as defined in the claims. The said disubstituted diaryloxybenzoheterodiazole compound of general formula (I) can advantageously be used as a spectrum converter in luminescent solar concentrators (LSCs) which are in turn capable of improving the performance of photovoltaic devices (or solar devices) selected, for example, from photovoltaic cells (or solar cells), photovoltaic modules (or solar modules) on either a rigid substrate or a flexible substrate.
摘要翻译：通式（1）的二取代的二芳基氧基苯并杂二唑化合物：其中：-Z代表硫原子，氧原子，硒原子; 或NR 5基团，其中R 5选自直链或支链C 1 -C 20，优选C 1 -C 8烷基或选自任选取代的芳基; R 1，R 2和R 3如权利要求中所定义。所述通式（I）的二取代的二芳基氧基苯并杂二唑化合物可以有利地用作发光太阳能聚光器（LSC）中的光谱转换器，其又能够改进选自例如光伏电池（或太阳能电池），在刚性基板或柔性基板上的光伏模块（或太阳能模块）。

12. 发明公开

EP3027596A1 COMPOUNDS CONTAINING A PENTALENE UNIT AND PROCESS FOR THEIR PREPARATION 有权转让
标题翻译： VERBINDUNGEN MIT EINER PENTALENEINHEIT UND VERFAHREN ZU DEREN HERSTELLUNG
公开(公告)号：EP3027596A1
公开(公告)日：2016-06-08
申请号：EP14759320.6
申请日：2014-07-22
申请人： ENI S.p.A.
发明人： BIANCHI, Gabriele , SCHIMPERNA, Giuliana
IPC分类号： C07D333/18 , C09K11/00 , H01L51/00
CPC分类号： C07D333/16 , C07D333/18 , C09K11/06 , C09K2211/1011 , C09K2211/1092 , H01L51/0036 , H01L51/0054 , H01L51/0068 , Y02E10/549
摘要： Compound containing a pentalene unit having general formula (I) wherein R1 and R2, equal to or different from each other, are selected from: linear or branched C1-C20, preferably C2-C12, alkyl groups, saturated or unsaturated, optionally containing heteroatoms, cycloalkyl groups optionally substituted, linear or branched C1-C20, preferably C2-C12, alkoxyl groups, saturated or unsaturated, optionally substituted; or the groups R1 and R2 can be optionally bound to each other so as to form, together with the carbon atoms to which they are bound, a cycle or a polycyclic system containing from 3 to 14 carbon atoms, preferably from 4 to 6 carbon atoms, saturated, unsaturated, or aromatic, optionally containing one or more heteroatoms such as, for example, oxygen, sulfur, nitrogen, silicon, phosphorous, selenium; R3 is selected from aryl groups optionally substituted, heteroaryl groups optionally substituted; n is 0 or 1; with the proviso that: when n is 0, X represents a covalent bond and Y represents a sulfur atom (S); when n is 1, X is equal to Y, and represents a CH group, or a nitrogen atom (N). Said compound containing a pentalene unit, as such or after suit able functionalization and polymerization, can be advantageously used in the construction of photovoltaic devices (or solar devices) such as, for example, photovoltaic cells (or solar cells), photovoltaic modules (or solar modules), on both rigid and flexible supports. Said compound containing a pentalene unit can also be advantageously used as a constitutive unit of luminescent solar concentrators (LSCs). Furthermore, said compound containing a pentalene unit can be advantageously used as precursor of monomeric units in the preparation of semiconductor polymers.
摘要翻译：含有具有通式（I）的柔性烯单元的化合物，其中R1和R2彼此相同或不同，选自：直链或支链C 1 -C 20，优选C 2 -C 12烷基，饱和或不饱和，任选地含有杂原子，任选取代的环烷基，直链或支链C 1 -C 20，优选C 2 -C 12烷氧基，饱和或不饱和的，任选取代的; 或者R1和R2基团可以任选地彼此结合，以便与它们所结合的碳原子一起形成含有3至14个碳原子，优选4至6个碳原子的环状或多环体系饱和的，不饱和的或芳族的，任选地含有一个或多个杂原子，例如氧，硫，氮，硅，磷，硒; R 3选自任选取代的芳基，任选取代的杂芳基; n为0或1; 条件是：当n为0时，X表示共价键，Y表示硫原子（S）; 当n为1时，X等于Y，代表CH基团或氮原子（N）。包含柔性单元的所述化合物本身或经过适当的官能化和聚合反应可以有利地用于太阳能电池（或太阳能电池），光伏模块（或太阳能模块），刚性和柔性支撑。所述含有柔丝单元的化合物也可有利地用作发光太阳能集中器（LSC）的组成单元。此外，含有柔丝单元的所述化合物可有利地用作制备半导体聚合物中单体单元的前体。

13. 发明授权

EP2566857B1 AROMATIC MONOMERS DERIVING FROM GLYCEROL UNITS, PROCESS FOR THEIR PREPARATION AND USE THEREOF FOR THE PREPARATION OF WATER-SOLUBLE CONJUGATED POLYMERS 有权
标题翻译：甘油衍生物单元的芳族单体，工艺及其使用体和水溶性共轭聚合物生产
公开(公告)号：EP2566857B1
公开(公告)日：2014-12-10
申请号：EP11727758.2
申请日：2011-04-29
申请人： ENI S.p.A.
发明人： SCHIMPERNA, Giuliana , PO', Riccardo , PELLEGRINO, Andrea , CALDARARO, Maria
IPC分类号： C07D317/22 , C07D405/12 , C07D409/12 , C08G61/12 , H01L51/00
CPC分类号： C07D405/12 , C07D317/22 , C07D409/12 , C08G61/123 , C08G61/124 , C08G61/126 , C08G75/06 , C08G2261/124 , C08G2261/1422 , C08G2261/1424 , C08G2261/3142 , C08G2261/3223 , C08G2261/3241 , C08G2261/3246 , C08G2261/411 , C08G2261/91 , H01L51/0036 , H01L51/0039 , H01L51/0043 , H01L51/0068 , H01L51/0072 , H01L51/42

14. 发明公开

EP2491092A1 PHOTOLUMINESCENT COMPOSITIONS FOR SPECTRUM CONVERTERS WITH ENHANCED EFFICIENCY 有权
标题翻译：频谱转换器夜光组合物以更高的效率
公开(公告)号：EP2491092A1
公开(公告)日：2012-08-29
申请号：EP10785185.9
申请日：2010-10-14
申请人： ENI S.p.A.
发明人： ALESSI, Andrea , FUSCO, Roberto , PROTO, Antonio, Alfonso , SCHIMPERNA, Giuliana , SCUDO, Petra
IPC分类号： C09K11/06 , H01L31/00
CPC分类号： H01L31/0256 , C09K11/06 , C09K2211/1011 , C09K2211/1051 , H01L31/055 , Y02E10/52
摘要： The present invention relates to a photoluminescent composition comprising an acene compound having general formula (I) or (Ia) and a benzothiadiazole compound having general formula (II), and the relative use as photoluminescent composition in a spectrum converter. A spectrum converter comprising the photoluminescent composition defined above, comprising the above compounds having general formula (I) or (Ia) and (II) and a solar device comprising said spectrum converter, are also described.

15. 发明公开

EP3898889A1 LUMINESCENT SOLAR CONCENTRATOR COMPRISING DITHIENYLPYRIDINETHIADIAZOLE COMPOUNDS 有权
公开(公告)号：EP3898889A1
公开(公告)日：2021-10-27
申请号：EP19836589.2
申请日：2019-12-20
申请人： ENI S.p.A.
发明人： ABBONDANZA, Luigi , PROTO, Antonio Alfonso , SCHIMPERNA, Giuliana
IPC分类号： C09K11/06

16. 发明授权

EP3027596B1 COMPOUNDS CONTAINING A PENTALENE UNIT AND PROCESS FOR THEIR PREPARATION 有权转让
公开(公告)号：EP3027596B1
公开(公告)日：2018-11-21
申请号：EP14759320.6
申请日：2014-07-22
申请人： ENI S.p.A.
发明人： BIANCHI, Gabriele , SCHIMPERNA, Giuliana
IPC分类号： C07D333/18 , C09K11/00 , H01L51/00
CPC分类号： C07D333/16 , C07D333/18 , C09K11/06 , C09K2211/1011 , C09K2211/1092 , H01L51/0036 , H01L51/0054 , H01L51/0068 , Y02E10/549
摘要： Compound containing a pentalene unit having general formula (I) wherein R1 and R2, equal to or different from each other, are selected from: linear or branched C1-C20, preferably C2-C12, alkyl groups, saturated or unsaturated, optionally containing heteroatoms, cycloalkyl groups optionally substituted, linear or branched C1-C20, preferably C2-C12, alkoxyl groups, saturated or unsaturated, optionally substituted; or the groups R1 and R2 can be optionally bound to each other so as to form, together with the carbon atoms to which they are bound, a cycle or a polycyclic system containing from 3 to 14 carbon atoms, preferably from 4 to 6 carbon atoms, saturated, unsaturated, or aromatic, optionally containing one or more heteroatoms such as, for example, oxygen, sulfur, nitrogen, silicon, phosphorous, selenium; R3 is selected from aryl groups optionally substituted, heteroaryl groups optionally substituted; n is 0 or 1; with the proviso that: when n is 0, X represents a covalent bond and Y represents a sulfur atom (S); when n is 1, X is equal to Y, and represents a CH group, or a nitrogen atom (N). Said compound containing a pentalene unit, as such or after suit able functionalization and polymerization, can be advantageously used in the construction of photovoltaic devices (or solar devices) such as, for example, photovoltaic cells (or solar cells), photovoltaic modules (or solar modules), on both rigid and flexible supports. Said compound containing a pentalene unit can also be advantageously used as a constitutive unit of luminescent solar concentrators (LSCs). Furthermore, said compound containing a pentalene unit can be advantageously used as precursor of monomeric units in the preparation of semiconductor polymers.

17. 发明公开

EP2828260A1 PROCESS FOR THE PREPARATION OF TETRACARBOXYNAPHTHALENEDIIMIDE COMPOUNDS DISUBSTITUTED WITH HETEROARYL GROUPS 有权
标题翻译：制备杂芳基基团取代四氮杂苯并卟啉化合物的方法
公开(公告)号：EP2828260A1
公开(公告)日：2015-01-28
申请号：EP13721079.5
申请日：2013-03-18
申请人： ENI S.p.A.
发明人： SCHIMPERNA, Giuliana , PELLEGRINO, Andrea , CHIABERGE, Stefano , BIANCHI, Gabriele
IPC分类号： C07D471/06
CPC分类号： C07D471/06 , C09B57/08
摘要： A process for the preparation of a tetracarboxynaphthalenediimide compound disubstituted with heteroaryl groups having general formula (I), comprising the reaction of at least one disubstituted N,N
I- dialkyl-1,4,5,8-tetracarboxynaphthalenediimide with at least one heteroaryl compound. Said tetracarboxynaphthalenediimide compound disubstituted with heteroaryl groups can be advantageously used as monomer in the synthesis of semiconductor polymers which can be advantageously used in the construction of organic field effect transistors (OFET) or of organic thin film transistors (OTFT).
摘要翻译：一种制备用通式（I）的杂芳基二取代的四羧基萘二酰亚胺化合物的方法，该方法包括使至少一种二取代的N，N'-二烷基-1,4,5,8-四羧基萘二酰亚胺与至少一种杂芳基化合物。所述用杂芳基二取代的四羧基萘二酰亚胺化合物可以有利地用作半导体聚合物合成中的单体，其可以有利地用于构建有机场效应晶体管（OFET）或有机薄膜晶体管（OTFT）。

18. 发明公开

EP3737678A1 PROCESS FOR THE PREPARATION OF DISUBSTITUTED DIARYLOXYBENZOHETERODIAZOLE COMPOUNDS 有权
公开(公告)号：EP3737678A1
公开(公告)日：2020-11-18
申请号：EP19700626.5
申请日：2019-01-09
申请人： ENI S.p.A.
发明人： SCHIMPERNA, Giuliana , BEVERINA, Luca , SASSI, Mauro
IPC分类号： C07D407/14

19. 发明授权

EP3516704B1 LUMINESCENT SOLAR CONCENTRATOR 有权
公开(公告)号：EP3516704B1
公开(公告)日：2020-08-05
申请号：EP17772390.5
申请日：2017-09-22
申请人： Eni S.p.A.
发明人： SCHIMPERNA, Giuliana , GILA, Liliana
IPC分类号： H01L31/054

20. 发明公开

EP3516704A1 LUMINESCENT SOLAR CONCENTRATOR 有权
公开(公告)号：EP3516704A1
公开(公告)日：2019-07-31
申请号：EP17772390.5
申请日：2017-09-22
申请人： Eni S.p.A.
发明人： SCHIMPERNA, Giuliana , GILA, Liliana
IPC分类号： H01L31/054
摘要： Luminescent solar concentrator (LSC) comprising at least one solution including at least one photoluminescent compound and at least one polyether polyol. Said luminescent solar concentrator (LSC) can be advantageously used in photovoltaic devices (or solar devices) such as, for example, photovoltaic cells (or solar cells), photoelectrolytic cells. In addition, said luminescent solar concentrator (LSC) can be advantageously used in photovoltaic windows.

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