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1. 发明公开

EP3898889A1 LUMINESCENT SOLAR CONCENTRATOR COMPRISING DITHIENYLPYRIDINETHIADIAZOLE COMPOUNDS 有权
公开(公告)号：EP3898889A1
公开(公告)日：2021-10-27
申请号：EP19836589.2
申请日：2019-12-20
申请人： ENI S.p.A.
发明人： ABBONDANZA, Luigi , PROTO, Antonio Alfonso , SCHIMPERNA, Giuliana
IPC分类号： C09K11/06

2. 发明授权

EP3027596B1 COMPOUNDS CONTAINING A PENTALENE UNIT AND PROCESS FOR THEIR PREPARATION 有权转让
公开(公告)号：EP3027596B1
公开(公告)日：2018-11-21
申请号：EP14759320.6
申请日：2014-07-22
申请人： ENI S.p.A.
发明人： BIANCHI, Gabriele , SCHIMPERNA, Giuliana
IPC分类号： C07D333/18 , C09K11/00 , H01L51/00
CPC分类号： C07D333/16 , C07D333/18 , C09K11/06 , C09K2211/1011 , C09K2211/1092 , H01L51/0036 , H01L51/0054 , H01L51/0068 , Y02E10/549
摘要： Compound containing a pentalene unit having general formula (I) wherein R1 and R2, equal to or different from each other, are selected from: linear or branched C1-C20, preferably C2-C12, alkyl groups, saturated or unsaturated, optionally containing heteroatoms, cycloalkyl groups optionally substituted, linear or branched C1-C20, preferably C2-C12, alkoxyl groups, saturated or unsaturated, optionally substituted; or the groups R1 and R2 can be optionally bound to each other so as to form, together with the carbon atoms to which they are bound, a cycle or a polycyclic system containing from 3 to 14 carbon atoms, preferably from 4 to 6 carbon atoms, saturated, unsaturated, or aromatic, optionally containing one or more heteroatoms such as, for example, oxygen, sulfur, nitrogen, silicon, phosphorous, selenium; R3 is selected from aryl groups optionally substituted, heteroaryl groups optionally substituted; n is 0 or 1; with the proviso that: when n is 0, X represents a covalent bond and Y represents a sulfur atom (S); when n is 1, X is equal to Y, and represents a CH group, or a nitrogen atom (N). Said compound containing a pentalene unit, as such or after suit able functionalization and polymerization, can be advantageously used in the construction of photovoltaic devices (or solar devices) such as, for example, photovoltaic cells (or solar cells), photovoltaic modules (or solar modules), on both rigid and flexible supports. Said compound containing a pentalene unit can also be advantageously used as a constitutive unit of luminescent solar concentrators (LSCs). Furthermore, said compound containing a pentalene unit can be advantageously used as precursor of monomeric units in the preparation of semiconductor polymers.

3. 发明公开

EP2828260A1 PROCESS FOR THE PREPARATION OF TETRACARBOXYNAPHTHALENEDIIMIDE COMPOUNDS DISUBSTITUTED WITH HETEROARYL GROUPS 有权
标题翻译：制备杂芳基基团取代四氮杂苯并卟啉化合物的方法
公开(公告)号：EP2828260A1
公开(公告)日：2015-01-28
申请号：EP13721079.5
申请日：2013-03-18
申请人： ENI S.p.A.
发明人： SCHIMPERNA, Giuliana , PELLEGRINO, Andrea , CHIABERGE, Stefano , BIANCHI, Gabriele
IPC分类号： C07D471/06
CPC分类号： C07D471/06 , C09B57/08
摘要： A process for the preparation of a tetracarboxynaphthalenediimide compound disubstituted with heteroaryl groups having general formula (I), comprising the reaction of at least one disubstituted N,N
I- dialkyl-1,4,5,8-tetracarboxynaphthalenediimide with at least one heteroaryl compound. Said tetracarboxynaphthalenediimide compound disubstituted with heteroaryl groups can be advantageously used as monomer in the synthesis of semiconductor polymers which can be advantageously used in the construction of organic field effect transistors (OFET) or of organic thin film transistors (OTFT).
摘要翻译：一种制备用通式（I）的杂芳基二取代的四羧基萘二酰亚胺化合物的方法，该方法包括使至少一种二取代的N，N'-二烷基-1,4,5,8-四羧基萘二酰亚胺与至少一种杂芳基化合物。所述用杂芳基二取代的四羧基萘二酰亚胺化合物可以有利地用作半导体聚合物合成中的单体，其可以有利地用于构建有机场效应晶体管（OFET）或有机薄膜晶体管（OTFT）。

4. 发明公开

EP4444723A1 DIARYLOXYBENZOHETERODIAZOLE COMPOUNDS DISUBSTITUTED WITH THIENOTHIOPHENE GROUPS 审中-实审
公开(公告)号：EP4444723A1
公开(公告)日：2024-10-16
申请号：EP22822684.1
申请日：2022-12-09
申请人： ENI S.p.A.
发明人： ABBONDANZA, Luigi , SCHIMPERNA, Giuliana , TACCA, Alessandra , MARRAZZO, Rosamaria
IPC分类号： C07D495/04 , H10K30/80
CPC分类号： C07D495/04 , H10K85/6565 , H10K85/6576 , Y02E10/549 , H10K10/484 , H10K30/40

5. 发明公开

EP3941995A1 DISUBSTITUTED FLUOROARYLOXYBENZOHETERODIAZOLE COMPOUNDS 有权
公开(公告)号：EP3941995A1
公开(公告)日：2022-01-26
申请号：EP20714700.0
申请日：2020-03-19
申请人： ENI S.p.A.
发明人： ABBONDANZA, Luigi , PROTO, Antonio Alfonso , SCHIMPERNA, Giuliana
IPC分类号： C09K11/06 , H01L31/055 , C07D417/14

6. 发明授权

EP2491092B1 PHOTOLUMINESCENT COMPOSITIONS FOR SPECTRUM CONVERTERS WITH ENHANCED EFFICIENCY 有权
标题翻译：频谱转换器夜光组合物以更高的效率
公开(公告)号：EP2491092B1
公开(公告)日：2016-09-14
申请号：EP10785185.9
申请日：2010-10-14
申请人： ENI S.p.A.
发明人： ALESSI, Andrea , FUSCO, Roberto , PROTO, Antonio, Alfonso , SCHIMPERNA, Giuliana , SCUDO, Petra
IPC分类号： C09K11/06 , H01L31/00
CPC分类号： H01L31/0256 , C09K11/06 , C09K2211/1011 , C09K2211/1051 , H01L31/055 , Y02E10/52

7. 发明授权

EP2841507B1 ORGANIC DYE FOR A DYE-SENSITIZED SOLAR CELL 有权
标题翻译：有机染料用于染料敏化太阳能电池
公开(公告)号：EP2841507B1
公开(公告)日：2016-05-18
申请号：EP13717505.5
申请日：2013-04-19
申请人： ENI S.p.A. , Centre National de la Recherche Scientifique (CNRS)
发明人： BIAGINI, Paolo , DEMETER, Dora , LERICHE, Philippe , PELLEGRINO, Andrea , RONCALI, Jean , SCHIMPERNA, Giuliana
IPC分类号： C09B57/00 , H01G9/20 , H01L31/042
CPC分类号： H01G9/2059 , C07D333/08 , C09B57/00 , H01G9/2031 , H01L51/0067 , H01L51/0068 , Y02E10/542 , Y02E10/549

8. 发明公开

EP2742080A1 PROCESS FOR THE PREPARATION OF POLYMERS CONTAINING BENZOHETERO [1, 3]DIAZOLE UNITS 有权
标题翻译：用于生产聚合物，BENZOHETERO [1，3]二唑UNITS
公开(公告)号：EP2742080A1
公开(公告)日：2014-06-18
申请号：EP12759260.8
申请日：2012-08-01
申请人： ENI S.p.A.
发明人： SCHIMPERNA, Giuliana , BIANCHI, Gabriele
IPC分类号： C08G61/12 , C08G73/00 , H01B1/00 , H01L51/00
CPC分类号： C08G75/32 , C08G61/123 , C08G61/126 , C08G73/0611 , C08G2261/1412 , C08G2261/3223 , C08G2261/3241 , C08G2261/3246 , C08G2261/92 , H01B1/00 , H01L51/00 , H01L51/0036 , Y02E10/549
摘要： Process for the preparation of a polymer containing benzohetero [1, 3 ] diazole. units which comprises reacting at least one disubstituted benzohetero [1, 3 ] diazole compound with at least one heteroaryl compound. Said polymer can be advantageously used in the construction of photovoltaic devices such as, for example, photovoltaic cells, photovoltaic modules, solar cells, solar modules, on both a rigid and flexible support. Furthermore, said polymer can be advantageously used in the construction of Organic Thin Film Transistors (OTFTs), or of Organic Field Effect Transistors (OFETs).

9. 发明公开

EP2566857A1 AROMATIC MONOMERS DERIVING FROM GLYCEROL UNITS, PROCESS FOR THEIR PREPARATION AND USE THEREOF FOR THE PREPARATION OF WATER-SOLUBLE CONJUGATED POLYMERS 有权
标题翻译：甘油衍生物单元的芳族单体，工艺及其使用体和水溶性共轭聚合物生产
公开(公告)号：EP2566857A1
公开(公告)日：2013-03-13
申请号：EP11727758.2
申请日：2011-04-29
申请人： ENI S.p.A.
发明人： SCHIMPERNA, Giuliana , PO', Riccardo , PELLEGRINO, Andrea , CALDARARO, Maria
IPC分类号： C07D317/22 , C07D405/12 , C07D409/12 , C08G61/12 , H01L51/00
CPC分类号： C07D405/12 , C07D317/22 , C07D409/12 , C08G61/123 , C08G61/124 , C08G61/126 , C08G75/06 , C08G2261/124 , C08G2261/1422 , C08G2261/1424 , C08G2261/3142 , C08G2261/3223 , C08G2261/3241 , C08G2261/3246 , C08G2261/411 , C08G2261/91 , H01L51/0036 , H01L51/0039 , H01L51/0043 , H01L51/0068 , H01L51/0072 , H01L51/42
摘要： Monomers having formula (I) and process for their synthesis which comprises the etherification reaction of a halogen-derivative (Z = C1, Br, I) having formula (III) with the hydroxyl group of the glycerol derivative (IV), according to the following scheme:(Formula III, IV & I) (III) (IV) (I)

10. 发明公开

EP2382259A2 PHI-CONJUGATED LOW-BAND-GAP COPOLYMERS CONTAINING BENZOTRIAZOLE UNITS 审中-公开
标题翻译：苯并三唑单位含P共轭共聚物具有小的带隙
公开(公告)号：EP2382259A2
公开(公告)日：2011-11-02
申请号：EP09751785.8
申请日：2009-10-16
申请人： ENI S.p.A.
发明人： PO', Riccardo , PELLEGRINO, Andrea , SCHIMPERNA, Giuliana , CALDARARO, Maria
IPC分类号： C08G73/08 , C08G61/00 , H01B1/12 , H01L51/00
CPC分类号： C08G73/08 , C08G61/123 , C08G61/126 , C08G73/0672 , C08G2261/3142 , C08G2261/3223 , C08G2261/3241 , H01L51/0035 , H01L51/0036 , H01L51/0043 , H01L51/42 , Y02E10/549
摘要： The present invention relates to an alternating or statistical conjugated copolymer comprising: at least one benzotriazole unit B having general formula (Ia) or (Ib) : wherein the group R is selected from alkyl, aryl, acyl or thioacyl groups, possibly substituted; at least one conjugated structural unit A, wherein each unit B is connected with at least one unit A in any of the positions 4, 5, 6 or 7, preferably in positions 4 or 7.

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