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    • 102. 发明公开
    • Electric storage device and its production method
    • Elektrische Speichervorrichtung und Herstellungsverfahrendafür
    • EP2234194A1
    • 2010-09-29
    • EP10157829.2
    • 2010-03-25
    • Fuji Jukogyo Kabushiki Kaisha
    • Fujii, TsutomuHatozaki, Osamu
    • H01M10/0525H01M4/133H01M12/00H01M4/02H01M4/74
    • When an electrode material having a weight-average mesopore/macropore specific surface area within a specific range is used in a negative electrode mixture member (31), there arises an expansion of a cell caused by the generation of decomposed gas from a component of electrolyte solution during the pre-doping process of lithium ions. A potential drop upon the pre-doping process is adjusted so as to reduce or suppress the expansion of the cell. Specifically, since the pre-doping speed is increased, the negative electrode (30) can speedily reach the potential by which an SEI component made of lithium alkyl carbonate can be produced on the surface of the negative electrode (30). Consequently, the absolute amount of the gas produced by the decomposition of the electrolyte solution can be reduced, whereby the expansion of electric storage devices (A) and (B) can be reduced.
    • 当在负极混合构件(31)中使用具有特定范围内的重均中孔/大孔比表面积的电极材料时,由电解质成分产生分解气体而引起的电池膨胀 在锂离子的预掺杂过程中的溶液。 调整预掺杂工艺的电位降低,以便减小或抑制电池的膨胀。 具体地说,由于预掺杂速度增加,所以负极(30)可以迅速达到在负极(30)的表面上可以制造由碳酸烷基酯制成的SEI成分的电位。 因此,可以减少由电解液分解产生的气体的绝对量,从而可以减少蓄电装置(A)和(B)的膨胀。