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91. 发明公开

EP0918840A1 METAL LIGAND CONTAINING BLEACHING COMPOSITIONS 失效
标题翻译：含金属配合物的漂白组合物
公开(公告)号：EP0918840A1
公开(公告)日：1999-06-02
申请号：EP97933485.0
申请日：1997-07-21
申请人： CARNEGIE MELLON UNIVERSITY
发明人： COLLINS, Terrence, J. , HORWITZ, Colin, P.
IPC分类号： C07D257 , C11D3 , D06L3 , D21C9
CPC分类号： D21C9/1036 , B01J31/006 , B01J31/184 , B01J2231/70 , B01J2531/72 , B01J2531/842 , C07D257/10 , C11D3/3932
摘要： The invention provides a novel bleaching composition comprising: an oxidatively stable bleach activator having structure 1 wherein Y1, Y3 and Y4 each represent a bridging group having zero, one, two or three carbon containing nodes for substitution, and Y2 is a bridging group having at least one carbon containing node for substitution, each said node containing a C(R), C(R1)(R2), or a C(R)2 unit and each R substituent is the same or different from the remaining R substituents and is selected from the group consisting of alkyl, cycloalkyl, cycloalkenyl, alkenyl, aryl, alkynyl, alkylaryl, halogen, alkoxy or phenoxy, CH2CF3, CF3 and combinations thereof, or form a substituted or unsubstituted benzene ring of which two carbon atoms in the ring form nodes in the Y unit, or together with a paired R substituent bound to the same carbon atom form a cycloalkyl or cycloalkenyl ring, which may include an atom other than carbon, e.g., cyclopentyl or cyclohexyl; M is a transition metal with oxidation states of I, II, III, IV, V or VI, or selected from Groups 6, 7, 8, 9, 10 and 11 of the Periodic Table of the Elements; Q is any counterion which would balance the charge of the compound on a stoichiometric basis; L is any labile ligand; and an effective amount of a source of an oxidizing compound.
摘要翻译：本发明提供了一种新型漂白组合物，其包含：具有结构1的氧化稳定的漂白活化剂，其中Y 1，Y 3和Y 4各自代表具有0,1,2或3个用于取代的含碳节点的桥连基团，并且Y 2是桥连基团，每个所述节点含有C（R），C（R1）（R2）或C（R）2单元，并且每个R取代基与剩余的R取代基相同或不同，并且是选自烷基，环烷基，环烯基，烯基，芳基，炔基，烷基芳基，卤素，烷氧基或苯氧基，CH 2 CF 3，CF 3及其组合，或者形成取代或未取代的苯环， Y单元中的节点，或与连接至相同碳原子的成对R取代基一起形成环烷基或环烯基环，其可以包括除碳以外的原子，例如环戊基或环己基; M是氧化态为I，II，III，IV，V或VI或选自元素周期表第6,7,8,9,10和11族的过渡金属; Q是在化学计量基础上平衡化合物电荷的任何抗衡离子; L是任何不稳定的配体; 和有效量的氧化化合物来源。

92. 发明公开

EP0914206A1 LONG-LIVED HOMOGENOUS OXIDATION CATALYSTS 失效
标题翻译：长效均相氧化催化剂
公开(公告)号：EP0914206A1
公开(公告)日：1999-05-12
申请号：EP97938014.0
申请日：1997-07-21
申请人： CARNEGIE MELLON UNIVERSITY
发明人： COLLINS, Terrence, J. , GORDON-WYLIE, Scott, W.
IPC分类号： B01J31 , C07D257 , C07F15
CPC分类号： C07F15/0026 , B01J31/182 , B01J31/4023 , B01J2231/70 , B01J2531/16 , B01J2531/17 , B01J2531/18 , B01J2531/62 , B01J2531/64 , B01J2531/66 , B01J2531/70 , B01J2531/72 , B01J2531/74 , B01J2531/821 , B01J2531/822 , B01J2531/824 , B01J2531/825 , B01J2531/827 , B01J2531/828 , B01J2531/842 , B01J2531/845 , B01J2531/847 , C07D257/02 , C07D257/10 , Y02P20/582 , Y02P20/584
摘要： A robust chelate complex is provided having formula (I) wherein M is a metal, preferably a transition metal; Z is an anionic donor atom, at least three of which are nitrogen, and the other is preferably nitrogen or oxygen; L1 is a labile ligand; Ch1, Ch2 and Ch3 are oxidation resistant chelate groups which are the same or different and which form 5- or 6-membered rings with the metal, and Ch4 is a chelate group having structure (a) wherein R1 and R2 are the same or different and are preferably selected from the group consisting of hydrogen, halogen, methyl, and CF3 or when linked, a 5- or 6-membered ring cyclo substituent. The complex provides a stable, long-lived oxidation catalyst or catalyst activator.
摘要翻译：提供具有式（I）的稳定的螯合络合物，其中M是金属，优选过渡金属; Z是阴离子供体原子，其中至少三个是氮，另一个优选是氮或氧; L1是不稳定的配体; Ch1，Ch2和Ch3是抗氧化的螯合基团，它们相同或不同并且与金属形成5或6元环，并且Ch4是具有结构（a）的螯合基团，其中R1和R2相同或不同并且优选选自氢，卤素，甲基和CF 3或当连接时为5或6元环的环取代基。该络合物提供稳定的，长寿命的氧化催化剂或催化剂活化剂。

93. 发明授权

EP0564406B1 Ferrocenyldiphosphine als Liganden für homogene Katalysatoren 失效
标题翻译： Ferrocenyldiphosphines作为配体的均相催化剂
公开(公告)号：EP0564406B1
公开(公告)日：1999-05-06
申请号：EP93810212.6
申请日：1993-03-24
申请人： Novartis AG
发明人： Togni, Antonio, Dr. , Spindler, Felix, Dr. , Zanetti, Nadia , Tijani, Amina, Dr.
IPC分类号： C07F17/02 , B01J31/28 , C07B31/00 , C07B53/00
CPC分类号： C07F17/02 , B01J31/2291 , B01J31/2295 , B01J31/2409 , B01J31/2471 , B01J2231/643 , B01J2231/645 , B01J2531/0205 , B01J2531/0286 , B01J2531/822 , B01J2531/827 , B01J2531/842 , C07C67/303 , C07C67/31 , C07C209/52 , C07C231/18 , Y10S526/943 , C07C69/34 , C07C69/732

94. 发明公开

EP0798296A3 Verfahren zur Herstellung von Arylamiden Heteroaromatischer Carbonsäuren 失效
标题翻译：维尔法赫恩·祖尔·赫斯特伦
公开(公告)号：EP0798296A3
公开(公告)日：1999-01-13
申请号：EP97103981.3
申请日：1997-03-10
申请人： LONZA AG
发明人： Roduit, Jean-Paul, Dr. , Kalbermatten, Georges
IPC分类号： C07D213/81 , C07D239/42 , C07D241/24 , C07D253/06 , B01J31/24
CPC分类号： C07D241/24 , B01J31/2295 , B01J31/2409 , B01J2231/4205 , B01J2531/824 , B01J2531/842 , C07D213/81
摘要： Beschrieben wird ein Verfahren zur Herstellung von Arylamiden heteroaromatischer Carbonsäuren der Formel
worin jedes A n Stickstoff oder CR n ( n = 1-5) ist, mit der Massgabe dass wenigstens eines der Ringglieder Stickstoff ist und nicht zwei Stickstoffatome unmittelbar miteinander verbunden sind; R 1 bis R 5 , soweit vorhanden, unabhängig voneinander Wasserstoff, C 1-4 -Alkyl oder Aryl, wobei einer der Substituenten R 1 bis R 5 auch eine Gruppe der Formel ―OR sein kann, in welcher R ein gegebenenfalls substituierter aromatischer oder heteroaromatischer Rest ist; R 6 Wasserstoff oder C 1-4 -Alkyl und R 7 einen gegebenenfalls substituierten aromatischen oder heteroaromatischen Rest bedeutet. Die Amide werden aus den entsprechenden heteroaromatischen Halogenverbindungen, den entsprechenden aromatischen Aminen und Kohlenmonoxid in Gegenwart eines Palladium-Diphosphin-Komplexes erhalten.
Verbindungen dieser Klasse, insbesondere solche, bei denen einer der Substituenten R 1 bis R 5 eine Aryloxygruppe ist, sind wichtige Herbizide.
摘要翻译：制备式ArCONR 6 R 7（I）的杂环羧酰胺化合物包括使式ArX（II）的卤素化合物与一氧化碳和式R 6 -NH-R 7的胺（ III），在钯的存在下，式（IV）的二膦和碱。 Ar =式（a）的6-元杂环基; A 1 = N或CR 1; A 2 = N或CR 2; A 3 = N或CR 3; A 4 = N或CR 4; A 5 = N或CR 5; 条件是A 1 -A 5中的至少一个为N，并且该环不含有两个相邻的N原子; R 1 -R 5 = H，1-4C烷基或芳基; 并且R 1 -R 5之一也可以是OR; R 6，R 8 = H或1-4C烷基; R 7，R 7 =任选取代的芳族或杂芳基; R 9 -R 12 = sec。或叔。 3-6C烷基，5-7C环烷基或任选取代的苯基; Y = CH，NH，CHCH或O; n = 0或1; Q完成任选取代的5或6元饱和或芳族碳 - 或杂环（如果芳香族，任选与过渡金属络合）。还要求保护的是一种制备（Ⅰa）（作为（Ⅰ），其中Ar被OR取代）的方法，包括（1）形成（Ⅱa）（作为（Ⅱ）），其中Ar被OR取代）由与Cl，Br或I相应的化合物代替OR，与ROH反应; 和（2）如上所述使（IIa）反应。在两步法中要求作为中间体使用3-氯-2-（3-（三氟甲基）苯氧基）吡啶（IIb）。

95. 发明授权

EP0763069B1 PREPARATION OF COPOLYMERS OF CARBON MONOXIDE AND AN ALIPHATIC ALPHA-OLEFIN 失效
标题翻译：由一氧化碳共聚物和α-烯烃
公开(公告)号：EP0763069B1
公开(公告)日：1998-11-18
申请号：EP95923218.2
申请日：1995-05-30
申请人： SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V.
发明人： BRONCO, Simona , CONSIGLIO, Giambattista , DI BENEDETTO, Silvia , DRENT, Eit , HEERES, Hero, Jan , VAN BROEKHOVEN, Johannes, Adrianus, Maria , REYNHOUT, Marinus, Johannes
IPC分类号： C08G67/02
CPC分类号： B01J31/2295 , B01J31/24 , B01J31/2409 , B01J2231/10 , B01J2531/0205 , B01J2531/824 , B01J2531/842 , C08G67/02
摘要： A catalyst composition suitable for the copolymerisation of carbon monoxide with an aliphatic alpha -olefin, which catalyst composition comprises: a) a palladium compound, and b) an asymmetric phosphorus bidentate ligand of the general formula R R P-Q-CHR -PR R , wherein Q is a 1,2-ferrocenyl bridging group, R , R , R and R are identical or different optionally polar substituted hydrocarbyl groups and R is hydrogen or an optionally polar substituted hydrocarbyl group; a process for the preparation of linear alternating copolymers of carbon monoxide with an aliphatic alpha -olefin having at least 3 carbon atoms, which process comprises contacting a mixture of the monomers with said catalyst composition; isotactic linear alternating copolymers of carbon monoxide with an aliphatic alpha -olefin having at least 3 carbon atoms.

96. 发明公开

EP0861688A1 Process for the hydroxylation of aromatic hydrocarbons 失效
标题翻译： Verfahren zur Hydroxylierung von aromatischen Kohlenwasserstoffen
公开(公告)号：EP0861688A1
公开(公告)日：1998-09-02
申请号：EP98102068.8
申请日：1998-02-06
申请人： ENICHEM S.p.A.
发明人： Vignola, Rodolfo , Battistel, Ezio , Bianchi, Daniele , Bortolo, Rossella , Tassinari, Roberto
IPC分类号： B01J31/28 , C07C37/60
CPC分类号： B01J31/403 , B01J23/745 , B01J31/04 , B01J31/181 , B01J31/2208 , B01J2531/842 , C07B41/02 , C07C37/60 , Y02P20/52 , Y02P20/584 , C07C39/04 , C07C39/07
摘要： The invention relates to a process for the hydroxylation of aromatic hydrocarbons by direct oxidation with hydrogen peroxide.
The process is carried out in the presence of a catalyst comprising:

iron, administered as inorganic salt;
iron ligand, consisting of carboxylic acids of ether-aromatic compounds containing nitrogen, in particular pyrazin-2-carboxylic acid and derivatives;
acidifying agent, especially trifluoracetic acid, and a solvent system comprising an organic phase consisting of a substrate and acetonitrile and an aqueous phase containing the catalyst and hydrogen peroxide.
摘要翻译：本发明涉及通过用过氧化氢直接氧化来芳族烃羟基化的方法。该方法在催化剂存在下进行，所述催化剂包括：作为无机盐施用的铁; 铁配体，由含氮的醚 - 芳族化合物的羧酸组成，特别是吡嗪-2-羧酸及其衍生物; 酸性剂，特别是三氟乙酸，以及包含由底物和乙腈组成的有机相和含有催化剂和过氧化氢的水相的溶剂体系。

97. 发明公开

EP0854858A1 PROCEDE D'HYDROCYANATION DE COMPOSES ORGANIQUES A INSATURATION ETHYLENIQUE 失效
标题翻译：用于有机氢氰化方法烯属不饱和化合物的
公开(公告)号：EP0854858A1
公开(公告)日：1998-07-29
申请号：EP96932661.0
申请日：1996-09-27
申请人： RHODIA FIBER & RESIN INTERMEDIATES
发明人： HUSER, Marc , PERRON, Robert
IPC分类号： B01J27 , B01J31 , C07B61 , C07C253 , C07C255 , C07F9
CPC分类号： B01J31/2404 , B01J31/2409 , B01J31/2414 , B01J31/26 , B01J2231/32 , B01J2231/52 , B01J2531/824 , B01J2531/842 , B01J2531/847 , B01J2531/96 , C07C253/10 , C07C253/30 , C07C255/04 , C07C255/07
摘要： A method for the hydrocyanation of ethylenically nitrile-unsaturated organic compounds, and particularly diolefins or substituted olefins such as alkene nitriles. Specifically, the method is for hydrocyanating organic compounds comprising at least one double ethylene bond by reacting them with hydrogen cyanide in the presence of an aqueous solution of a catalyst that includes at least one transition metal compound and at least one water-soluble phosphine, wherein said water-soluble phosphine is a monodentate or bidentate phosphine.

98. 发明授权

EP0484754B1 Geformte polymere Übergangsmetall-Komplexkatalysatoren mit Organosiloxan-Diphenylphosphinliganden 失效
标题翻译：形，聚合，过渡金属配合物催化剂具有有机硅氧烷Diphenylphosphinliganden
公开(公告)号：EP0484754B1
公开(公告)日：1998-05-13
申请号：EP91118159.2
申请日：1991-10-24
申请人： Degussa Aktiengesellschaft
发明人： Panster, Peter, Dr. , Gradl, Robert , Kleinschmit, Peter, Dr.
IPC分类号： C08G77/58 , C08G77/54 , B01J31/28
CPC分类号： C08G77/58 , B01J31/1608 , B01J31/1675 , B01J31/18 , B01J31/1805 , B01J31/2404 , B01J2231/20 , B01J2231/321 , B01J2231/323 , B01J2231/52 , B01J2231/645 , B01J2531/821 , B01J2531/822 , B01J2531/824 , B01J2531/825 , B01J2531/827 , B01J2531/828 , B01J2531/842 , B01J2531/845 , B01J2531/847 , C07C45/50 , C08G77/22 , C08G77/54 , C07C47/02

99. 发明公开

EP0820460A1 DIHALOGENATED FERROCENES AND PROCESSES FOR THE PREPARATION THEREOF 失效
标题翻译：二卤代二茂铁和方法及其
公开(公告)号：EP0820460A1
公开(公告)日：1998-01-28
申请号：EP96911992.0
申请日：1996-04-02
申请人： Novartis AG
发明人： PUGIN, Benoît
IPC分类号： B01J31 , C07B31 , C07B35 , C07B53 , C07F17
CPC分类号： C07F17/02 , B01J31/1625 , B01J31/1658 , B01J31/189 , B01J31/2295 , B01J31/2409 , B01J2231/643 , B01J2231/645 , B01J2531/822 , B01J2531/827 , B01J2531/842 , C07B31/00 , C07B35/02 , C07B53/00 , Y02P20/588
摘要： The invention relates to a compound of formula (I), wherein R1 is C1-C8alkyl, phenyl or phenyl substituted by from 1 to 3 C1-C4alkyl or C1-C4alkoxy substituents; R2 and R3 are each independently of the other hydrogen or C1-C12alkyl; and Hal is F, Cl, Br or I. Compounds of formula (I) are valuable intermediates for compounds of formula (III) which are also a subject of this invention, wherein R1, R2, R3 and Hal are as defined above; R10 and R11 are identical or different and are C1-C12alkyl, C5-C12cycloalkyl, phenyl, C5-C12cycloalkyl substituted by C1-C4alkyl or by C1-C4alkoxy, or phenyl substituted by from one to three C1-C4alkyl, C1-C4alkoxy, -SiR4R5R6, halogen, -SO3M, -CO2M, -PO3M, -NR7R8, -[+NR7R8R9]X- or C1-C5fluoroalkyl substituents; or the group -PR10R11 is a radical of formula (IV, IVa, IVb or IVc); R4, R5 and R6 are each independently of the others C1-C12alkyl or phenyl; R7 and R8 are H, C1-C12alkyl or phenyl or R7 and R8 together are tetramethylene, pentamethylene or 3-oxa-1,5-pentylene; R9 is H or C1-C4alkyl; M is H or an alkali metal; X- is the anion of a monobasic acid. The compounds of formula (III) are themselves important intermediates for silylated ferrocenyldiphosphines and their metal complexes. Ferrocenyldiphosphines that contain an organic radical bonded via a silylene group to a cyclopentadienyl ring can be immobilised in a simple manner both on inorganic and on polymeric organic carriers or, after the introduction of a polymerisable group, can be immobilised also by copolymerisation. With rhodium and iridium the immobilised ferrocenyldiphosphine ligands form complexes that can be used as highly active catalysts in the enantioselective hydrogenation of carbon-carbon, carbon-nitrogen or carbon-oxygen double bonds.

100. 发明公开

EP0798296A2 Verfahren zur Herstellung von Arylamiden Heteroaromatischer Carbonsäuren 失效
标题翻译：一种用于杂芳族羧酸芳基酰胺的制备方法
公开(公告)号：EP0798296A2
公开(公告)日：1997-10-01
申请号：EP97103981.3
申请日：1997-03-10
申请人： LONZA AG
发明人： Roduit, Jean-Paul, Dr. , Kalbermatten, Georges
IPC分类号： C07D213/81 , C07D239/42 , C07D241/24 , C07D253/06 , B01J31/24
CPC分类号： C07D241/24 , B01J31/2295 , B01J31/2409 , B01J2231/4205 , B01J2531/824 , B01J2531/842 , C07D213/81
摘要： Beschrieben wird ein Verfahren zur Herstellung von Arylamiden heteroaromatischer Carbonsäuren der Formel
worin jedes A n Stickstoff oder CR n ( n = 1-5) ist, mit der Massgabe dass wenigstens eines der Ringglieder Stickstoff ist und nicht zwei Stickstoffatome unmittelbar miteinander verbunden sind; R 1 bis R 5 , soweit vorhanden, unabhängig voneinander Wasserstoff, C 1-4 -Alkyl oder Aryl, wobei einer der Substituenten R 1 bis R 5 auch eine Gruppe der Formel ―OR sein kann, in welcher R ein gegebenenfalls substituierter aromatischer oder heteroaromatischer Rest ist; R 6 Wasserstoff oder C 1-4 -Alkyl und R 7 einen gegebenenfalls substituierten aromatischen oder heteroaromatischen Rest bedeutet. Die Amide werden aus den entsprechenden heteroaromatischen Halogenverbindungen, den entsprechenden aromatischen Aminen und Kohlenmonoxid in Gegenwart eines Palladium-Diphosphin-Komplexes erhalten.
Verbindungen dieser Klasse, insbesondere solche, bei denen einer der Substituenten R 1 bis R 5 eine Aryloxygruppe ist, sind wichtige Herbizide.
摘要翻译：公开了一种用于下式的杂芳族羧酸芳基酰胺的制备方法，其中每个A 是氮或CR （N = 1-5），条件氮的环成员，至少，不是两个氮原子中的一个被直接连接到彼此; [R <1>至R <5>，当存在时，独立地是氢，C 1-4烷基或芳基，其中取代基的一个R <1>也可以是下式基团OR至R <5>，其中R 是任选取代的芳族或杂芳族基团; [R <6>是氢或C 1-4烷基且R <7>表示任选取代的芳族或杂芳族基团。酰胺由相应的杂芳族卤素化合物，相应的芳族胺和一氧化碳在钯二膦络合物的存在下获得的。这个类的化合物，特别是那些其中取代基R <1>到R的一<5>是芳氧基，是重要的除草剂。

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