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1. 发明授权

EP0736509B1 Processes for preparing optically active alcohols and optically active amines 失效
标题翻译：一种制备光学活性醇与光学活性胺的方法
公开(公告)号：EP0736509B1
公开(公告)日：2001-11-14
申请号：EP96105569.6
申请日：1996-04-09
申请人： Sumitomo Chemical Company, Limited
发明人： Yoneyoshi, Yukio , Konya, Naoto , Suzukamo, Gohfu , Kamitamari, Masashi , Miyawaki, Takashi
IPC分类号： C07C29/143 , C07C33/20 , C07C33/22 , C07C33/46 , C07C209/40 , C07C211/27 , C07C211/29 , C07C217/58
CPC分类号： C07B53/00 , C07B57/00 , C07B2200/07 , C07C29/143 , C07C209/40 , C07C213/02 , C07C33/20 , C07C33/46

2. 发明授权

EP0713848B1 Process for producing optically active carbinols 失效转让
标题翻译：一种制备光学活性的原醇处理
公开(公告)号：EP0713848B1
公开(公告)日：1999-09-08
申请号：EP95116951.5
申请日：1995-10-27
申请人： SUMIKA FINE CHEMICALS Company, Limited , SUMITOMO CHEMICAL COMPANY LIMITED
发明人： Saito, Kenji , Kometani, Norio , Fujiwara, Azusa , Yoneyoshi, Yukio , Suzukamo, Gohfu
IPC分类号： C07C29/143 , C07C33/46 , C07C33/24 , C07C33/22 , C07D317/54
CPC分类号： C07D317/54 , C07B2200/07 , C07C29/143 , C07C33/46 , C07C33/20

3. 发明授权

EP0121284B1 (+)-Triazolylpentenol derivative, its production and use as herbicide and/or plant growth regulant 有权转让
标题翻译：（+） - 三唑并噻吩衍生物，其生产和用作除草剂和/或植物生长调节剂
公开(公告)号：EP0121284B1
公开(公告)日：1992-03-11
申请号：EP84200456.6
申请日：1981-12-14
申请人： SUMITOMO CHEMICAL COMPANY, LIMITED
发明人： Funaki, Yuji , Yoneyoshi, Yukio , Ishiguri, Yukio , Izumi, Kazuo
IPC分类号： C07D249/08 , A01N43/64
CPC分类号： C07D231/12 , A01N43/653 , C07D249/08

4. 发明公开

EP0091753A1 Method for racemization of optically active 2,2-dimethylcyclopropane-1-carboxylic acid halide 有权
标题翻译：方法外消旋化的光学活性2,2-二甲基环-1-羰基卤化物。
公开(公告)号：EP0091753A1
公开(公告)日：1983-10-19
申请号：EP83301732.0
申请日：1983-03-28
申请人： SUMITOMO CHEMICAL COMPANY, LIMITED
发明人： Suzukamo, Gohfu , Fukao, Masami , Yoneyoshi, Yukio
IPC分类号： C07C61/04 , C07C61/15 , C07C51/487 , C07C51/64
CPC分类号： C07C61/15 , C07C51/487 , C07C61/04
摘要： A method for racemization of optically active 2,2-dimethylcyclopropane-1-carboxylic acid by converting said acid to the corresponding halide thereof represented by the general formula;
wherein X is a halogen atom, which is heated to a temperature of about 80°C to about 300°C, preferably about 100°C to about 200°C, and then, if desired, producing 2,2-dimethylcyclopropane-1-carboxylic acid by hydrolysis of the resultant acid halide.

5. 发明授权

EP0641786B1 Process for producing optically active alcohol 失效
标题翻译：一种用于生产光学活性醇的方法
公开(公告)号：EP0641786B1
公开(公告)日：1997-08-20
申请号：EP94117505.1
申请日：1990-01-30
申请人： SUMITOMO CHEMICAL COMPANY, LIMITED
发明人： Yoneyoshi, Yukio , Suzukamo, Gohfu , Konya, Naoto , Ikeda, Takaharu, Sumitomokagaku Higashicho Ap. 213
IPC分类号： C07D249/08
CPC分类号： C07D231/12 , C07B2200/07 , C07C29/143 , C07D233/56 , C07D249/08 , C07C31/125 , C07C33/02 , C07C31/12

6. 发明公开

EP0641786A1 Process for producing optically active alcohol 失效
标题翻译： Verfahren zur Herstellung von optisch aktivem Alkohol。
公开(公告)号：EP0641786A1
公开(公告)日：1995-03-08
申请号：EP94117505.1
申请日：1990-01-30
申请人： SUMITOMO CHEMICAL COMPANY, LIMITED
发明人： Yoneyoshi, Yukio , Suzukamo, Gohfu , Konya, Naoto , Ikeda, Takaharu, Sumitomokagaku Higashicho Ap. 213
IPC分类号： C07D249/08
CPC分类号： C07D231/12 , C07B2200/07 , C07C29/143 , C07D233/56 , C07D249/08 , C07C31/125 , C07C33/02 , C07C31/12
摘要： A process for producing an optically active alcohol of the formula

wherein R⁴ and R⁵ are different from one another and each is a C₁₋₆ alkyl group, a C₆₋₁₇ aryl group, a C₇₋₁₁ aralkyl group or a 2-substituted-1-triazoleethylene group represented by the general formula (III)

(R⁶ is a halogen- or halomethyl-substituted or unsubstituted phenyl group or a cycloalkyl group) comprises bringing each of

(A) an optically active amino alcohol represented by the general formula (I)
wherein R¹ is an aryl group selected from a phenyl group optionally substituted with halogen, C₁₋₅ alkyl, C₁₋₅ alkoxy, cyano, C₇₋₁₀ aralkoxy, C₆₋₁₀ aryloxy or C₁₋₆ alkoxycarbonyl and a naphthyl group optionally substituted with halogen, C₁₋₅ alkyl, cyano, C₁₋₅ alkoxy or C₁₋₅ alkoxycarbonyl, R² is a C₁₋₄ alkyl group, R³ is a hydrogen atom or a C₁₋₄ alkyl group, and the carbon atoms having a mark * are each an asymmetric carbon atom and an acid, or a salt of the optically active amino alcohol (I) and an acid;
(B) a metal borohydride; and
(C) water;
into contact with
a prochiral ketone represented by the general formula (II)

wherein R⁴ and R⁵ are as defined above.
摘要翻译：制备式的光学活性醇的方法，其中R 4和R 5彼此不同，并且各自为C 1-6烷基，C 6-17芳基，C 7-11 芳烷基或由通式（III）表示的2-取代-1-三唑乙基（CH 3）（R 6是卤素或卤代甲基取代或未取代的苯基或环烷基）包括使（ A）由通式（I）表示的光学活性氨基醇其中R 1是选自任选被卤素取代的苯基的芳基，C 1-5烷基，C 1-5烷氧基，氰基，C 7 -10芳烷氧基，C6-10芳氧基或C1-6烷氧基羰基和任选被卤素取代的萘基，C 1-5烷基，氰基，C 1-5烷氧基或C 1-5烷氧基羰基，R 2是C 1-4烷基 R 3为氢原子或C 1-4烷基，具有标记*的碳原子分别为不对称碳原子，酸或光学活性氨基酸的盐（I）和酸; （B）金属硼氢化物; 和（C）水; 与由通式（II）表示的前手性酮接触其中R 4和R 5如上所定义。

7. 发明授权

EP0485069B1 Process for producing optically active amines 有权转让
标题翻译：一种制备光学活性胺的方法。
公开(公告)号：EP0485069B1
公开(公告)日：1995-02-15
申请号：EP91309150.0
申请日：1991-10-07
申请人： SUMITOMO CHEMICAL COMPANY LIMITED
发明人： Konya, Naoto , Yoneyoshi, Yukio , Sakito, Yoji , Nishii, Shinji , Suzukamo, Gohfu , Sakane, Hiroko
IPC分类号： C07C209/40
CPC分类号： C07C209/40

8. 发明授权

EP0171175B1 An optically active borane complex and a method for producing an optically active alcohol derivative by the use thereof 有权转让
标题翻译：一种光学活性硼烷复合物及其用途生产光学活性醇衍生物的方法
公开(公告)号：EP0171175B1
公开(公告)日：1989-05-24
申请号：EP85304755.3
申请日：1985-07-03
申请人： SUMITOMO CHEMICAL COMPANY, LIMITED
发明人： Yoneyoshi, Yukio , Suzukamo, Gohfu , Hamada, Kazuhiko , Nishioka, Toshio
IPC分类号： C07F5/02 , C07D233/60 , C07D249/08
CPC分类号： C07D231/12 , C07D233/56 , C07D249/08 , C07F5/022

9. 发明公开

EP0237305A2 A method for producing optically active amines 有权转让
标题翻译：阿尔卑斯。
公开(公告)号：EP0237305A2
公开(公告)日：1987-09-16
申请号：EP87301992.1
申请日：1987-03-09
申请人： SUMITOMO CHEMICAL COMPANY, LIMITED
发明人： Sakito, Yoji , Suzukamo, Gohfu , Yoneyoshi, Yukio
IPC分类号： C07C209/30 , C07C211/26 , C07B53/00
CPC分类号： C07B53/00
摘要： An optically active amine, which is an important compound as a resolving agent for medicines, agricultural chemicals, intermediates thereof, etc. and has the general formula (III),
wherein R₆ and R₇, which are different from each other, represent an aryl group which may be substituted with an alkyl group, an aralkyl group which may be substituted with an alkyl group, or an alkyl group, and * represents an asymmetric carbon atom, is prepared by (a) forming an asymmetric reducing agent by reacting an optically active aminoalcohol represented by the general formula (I),
wherein R₁ and R₂ represent a hydrogen atom or an alkyl or alkoxyl group, R₃ represents a hydrogen atom or an alkyl group, R₄ represents an alkyl group, and * is as defined above, with a boron hydride compound and (b) reacting the asymmetric reducing agent thus formed with the anti-form or syn-form isomer of an oxime derivative represented by the general formula (II),
wherein R₅ represents an alkyl, aralkyl or alkyl-substituted silyl group, and R₆ and R₇ are as defined above, or a mixture of the isomers which is rich in either one of them, said optically active amine represented by the general formula (III) having an absolute steric configuration which is the same as that of the amino group-substituted carbon atom in the general formula (I) when the oxime derivative of the general formula (II) is of the anti-form structure or rich in the same and opposite to that of the amino group-substituted carbon atom in the general formula (I) when the oxime derivative of the general formula (II) is of the syn-form structure or rich in the same.
摘要翻译：作为药物的分解剂，农药，其中间体等的重要化合物，具有通式（III），的光学活性胺，其中R6和R7彼此不同，表示可以被烷基取代的芳基，可被烷基取代的芳烷基或烷基，和*表示不对称碳原子，是通过（a）通过使（a）形成不对称还原剂，通过使由通式（I）表示的光学活性氨基醇，其中R1和R2表示氢原子或烷基或烷氧基，R3表示氢原子或烷基，R4表示烷基，*表示如上定义，与硼化氢化合物反应，和（b）使由此形成的不对称还原剂与由通式（II）表示的肟衍生物的抗形式或顺式异构体反应，其中R 5表示烷基，芳基烷基或烷基取代的甲硅烷基，R 6和R 7如上所定义，或富含其中任何一个的异构体的混合物，所述通式（III）所示的光学活性胺具有绝对立体构型，与通式（I）中的氨基取代的碳原子相同时，通式（II）的肟衍生物为抗结构或与氨基相同或相反的氨基当通式（II）的肟衍生物是同形式结构或富集时，通式（I）中的取代的碳原子。

10. 发明公开

EP0175278A2 Optical isomer of triazolylpentenols, and their production and use as fungicide herbicide and/or plant growth regulant 失效
标题翻译： Triazolylpentenolen的光学异构体及其制备方法和用作杀真菌剂，除草剂和/或植物生长调节剂。
公开(公告)号：EP0175278A2
公开(公告)日：1986-03-26
申请号：EP85111505.5
申请日：1981-12-14
申请人： SUMITOMO CHEMICAL COMPANY, LIMITED
发明人： Funaki, Yuji , Yoneyoshi, Yukio , Ishiguri, Yukio , Izumi, Kazuo
IPC分类号： C07D249/08 , A01N43/64
CPC分类号： C07D231/12 , A01N43/653 , C07D249/08
摘要： Triazolyl alcohol derivative having an optical activity of (-) or (+) and represented by the general formula (I),
wherein X represents a hydrogen atom or a chlorine atom and the asterisk indicates an asymmetric carbon atom, are prepared by stereospecific reduction of the corresponding ketone or by resolution of the racemate. The (-)-isomer is useful as a fungicide while the (+)-isomer is useful as a plant growth regulant or herbicide.
摘要翻译：三唑基醇衍生物具有上的光学活性（ - ）或（+）和由通式（I）代表worin X darstellt一个氢原子或一个氯原子和星号表示不对称碳原子，由制备立体特异性酮还原相应的或通过拆分外消旋体的。异构体是作为一种植物生长调节或除草剂有用 - 的（ - ） - ，而（+）异构体作为杀菌剂是有用的。

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