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1. 发明授权

US06632568B1 NON-SINTERED NICKEL ELECTRODE WITH EXCELLENT OVER-DISCHARGE CHARACTERISTICS, AN ALKALINE STORAGE CELL HAVING THE NON-SINTERED NICKEL ELECTRODE, AND A MANUFACTURING METHOD OF THE NON-SINTERED NICKEL ELECTRODE 失效
标题翻译：具有优异的超放电特性的非烧结镍电极，具有非烧结镍电极的碱性存储单元以及非烧结镍电极的制造方法
公开(公告)号：US06632568B1
公开(公告)日：2003-10-14
申请号：US08929253
申请日：1997-09-15
申请人： Akifumi Yamawaki , Shinsuke Nakahori , Takeo Hamamatsu , Yoshitaka Baba
发明人： Akifumi Yamawaki , Shinsuke Nakahori , Takeo Hamamatsu , Yoshitaka Baba
IPC分类号： H01M452
CPC分类号： H01M4/52 , C01G53/006 , C01G53/42 , C01P2002/54 , C01P2002/72 , C01P2004/84 , C01P2006/40 , H01M4/32 , H01M10/30 , H01M10/345 , Y10T29/49108
摘要： A alkali storage cell includes a non-sintered type nickel electrode which includes a highly efficient nickel hydroxide active material and which causes no capacity decrease during an over-discharge operation. The nickel electrode contains an active material composed of nickel hydroxide, a solid solution of at least one of zinc, cadmium, magnesium, and calcium which are added to the nickel hydroxide, and cobalt compound layers which are formed over the surfaces of particles of the nickel hydroxide. The cobalt compound layers have an oxidation number of larger than 2 and a disordered crystal structure. Such an active material can be manufactured by mixing nickel hydroxide powder containing a solid solution of at least one of zinc, cadmium, magnesium, and calcium with either metallic cobalt or a cobalt compound, and subjecting the mixture to heat treatment in the presence of oxygen and alkali. Another production method is to precipitate a cobalt compound over the surfaces of the nickel hydroxide powder containing a solid solution of at least one of zinc, cadmium, magnesium, and calcium so as to form cobalt compound layers, before subjecting it to the heat treatment in the same conditions.
摘要翻译：碱性蓄电池包括非烧结型镍电极，其包括高效氢氧化镍活性材料，并且在过放电操作期间不引起容量减小。镍电极含有由氢氧化镍组成的活性物质，添加到氢氧化镍中的锌，镉，镁和钙中的至少一种的固溶体，以及形成在氧化镍颗粒表面上的钴化合物层氢氧化镍。钴化合物层具有大于2的氧化数和无序的晶体结构。可以通过将含有锌，镉，镁和钙中的至少一种的固溶体的氢氧化镍粉末与金属钴或钴化合物混合并在氧气存在下进行热处理来制造这种活性物质和碱。另一种制造方法是在含有锌，镉，镁和钙中的至少一种的固溶体的氢氧化镍粉末的表面上析出钴化合物，以形成钴化合物层，然后在其中进行热处理相同的条件。

2. 发明授权

US06416902B1 Non-aqueous lithium ion secondary battery 失效
标题翻译：非水锂离子二次电池
公开(公告)号：US06416902B1
公开(公告)日：2002-07-09
申请号：US09065614
申请日：1998-04-24
申请人： Tsutomu Miyasaka
发明人： Tsutomu Miyasaka
IPC分类号： H01M452
CPC分类号： H01M4/525 , H01M4/131 , H01M4/1315 , H01M4/485 , H01M4/505 , H01M4/523 , H01M4/58 , H01M4/621 , H01M4/622 , H01M4/623 , H01M6/164 , H01M10/0525 , H01M10/0569 , H01M2300/0034
摘要： A non-aqueous lithium ion secondary battery is composed of a positive electrode layer, a negative electrode layer, and a non-aqueous electrolyte. The positive electrode layer contains positive electrode active material of the following formula: LixNi1−yCoy−zMzO2−aXb wherein M is Mg, Ca, Ba, Ti, V, Cr, Mn, Fe, Co, Cu, Zn, Nb, Mo, Ag, Ta, W, B, Al, Ga, In, C, Si, Ge, Sn, or Pb; X is a halogen atom; 0.2
摘要翻译：非水性锂离子二次电池由正极层，负极层和非水电解质构成。正极层含有正极活性物质，其中M为Mg，Ca，Ba，Ti，V，Cr，Mn，Fe，Co，Cu，Zn，Nb，Mo，Ag，Ta，W，B ，Al，Ga，In，C，Si，Ge，Sn或Pb; X是卤原子; 0.2

3. 发明授权

US06368748B1 Nickel-metal hydride storage cell having a high capacity and an excellent cycle characteristic and manufacturing 有权
标题翻译：具有高容量和优异的循环特性和制造的镍氢蓄电池
公开(公告)号：US06368748B1
公开(公告)日：2002-04-09
申请号：US09531600
申请日：2000-03-20
申请人： Masao Takee , Motoo Tadokoro , Tadashi Ise , Akifumi Yamawaki
发明人： Masao Takee , Motoo Tadokoro , Tadashi Ise , Akifumi Yamawaki
IPC分类号： H01M452
CPC分类号： H01M10/345 , H01M4/32 , H01M4/52 , H01M10/30
摘要： A nickel-metal hydride storage cell is composed of a non-sintered positive electrode which is filled with a nickel active material whose particles are coated with cobalt compound layers of divalent or greater and a metal hydride electrode which is filled with a surface-treated hydrogen-absorbing alloy. In the cell, the positive electrode non-reactive capacity rate (represented by the Equation 1) and the negative electrode charge depth (represented by the Equation 2) after the initial charge/discharge are 16% or lower, and 80% or lower, respectively. This construction makes it possible to take larger actual cell capacity by setting the value of the negative electrode charge depth to the degree which causes no rise in the cell internal pressure, thereby expanding the capacity of the cell. positive electrode non-reactive capacity rate %=(positive electrode theoretical capacity−actual cell capacity)/positive electrode theoretical capacity×100 Eq. 1; negative electrode charge depth %=(negative electrode remaining capacity+actual cell capacity)/negative electrode whole capacity×100 Eq. 2.
摘要翻译：镍氢蓄电池由非烧结正电极组成，其中填充有用二价以上的钴化合物层涂覆其颗粒的镍活性材料和填充有表面处理氢的金属氢化物电极吸收合金。在电池中，初始充放电后的正极非反应容量率（由式1表示）和负极电荷深度（以式2表示）为16％以下，80％以下，分别。这种结构使得可以通过将负极电荷深度的值设定为不使电池内部压力升高的程度来获得更大的实际电池容量，从而扩大电池的容量。

4. 发明授权

US06207325B1 Lithium-containing complex metal oxide, preparation methods thereof, and cathode electroactive material using the same and lithium secondary cells 失效
标题翻译：含锂复合金属氧化物及其制备方法以及使用其的阴极电活性材料和锂二次电池
公开(公告)号：US06207325B1
公开(公告)日：2001-03-27
申请号：US09080346
申请日：1998-05-18
申请人： Yasushi Matsui , Masatoshi Shirao
发明人： Yasushi Matsui , Masatoshi Shirao
IPC分类号： H01M452
CPC分类号： H01M10/052 , H01M4/485 , H01M4/525
摘要： A lithium-containing complex metal oxide having a crystal structure of &agr;-NaFeO2 type and represented by a general formula: LiaNiXCoYAlZO2 wherein 0.96≦a≦1.06, 0.70≦X
摘要翻译：一种具有α-NaFeO2型晶体结构并由以下通式表示的含锂复合金属氧化物：其中0.96 <= a <= 1.06,0.70 <= X <0.85,0.05 <= Y <0.20,0.10

5. 发明授权

US06740449B2 Nickel electrode for alkaline storage battery and method of manufacturing the same 有权
标题翻译：碱性蓄电池用镍电极及其制造方法
公开(公告)号：US06740449B2
公开(公告)日：2004-05-25
申请号：US09813998
申请日：2001-03-22
申请人： Chihiro Fujisawa , Takuya Tamagawa , Yoichiro Shibata
发明人： Chihiro Fujisawa , Takuya Tamagawa , Yoichiro Shibata
IPC分类号： H01M452
CPC分类号： H01M4/366 , H01M4/32 , H01M4/38
摘要： A nickel electrode for an alkaline storage battery is made by filling a conductive porous member with an active material including a main active material layer substantially made of nickel hydroxide and containing cobalt in a state of a solid solution, and a compound layer containing at least one element selected from the group consisting of calcium, aluminum, strontium, scandium, yttrium, and lanthanoide series, the compound layer being formed on a surface of the main active material layer. A metal molar ratio of cobalt contained in the main active material layer to nickel contained in the main active material layer is in a range of 0.5% to 3.0%, and a metal molar ratio of the at least one element contained in the compound layer to nickel contained in the active material is in a range of 0.3% to 5.0%.
摘要翻译：用于碱性蓄电池的镍电极是通过用活性材料填充导电性多孔构件制成的，所述活性材料包括基本上由氢氧化镍制成的主要活性物质层，并且以固溶体状态含有钴，以及含有至少一种选自钙，铝，锶，钪，钇和镧系元素的元素，所述化合物层形成在所述主活性物质层的表面上。主活性物质层中所含的钴与包含在主活性物质层中的镍的金属摩尔比在0.5〜3.0％的范围内，化合物层中含有的至少一种元素的金属摩尔比与活性物质中所含的镍为0.3〜5.0％的范围。

6. 发明授权

US06596439B1 Lithium ion battery capable of being discharged to zero volts 有权
标题翻译：能够放电至零伏特的锂离子电池
公开(公告)号：US06596439B1
公开(公告)日：2003-07-22
申请号：US09675287
申请日：2000-09-29
申请人： Hisashi Tsukamoto , Clay Kishiyama , Mikito Nagata , Hiroshi Nakahara , Tiehua Piao
发明人： Hisashi Tsukamoto , Clay Kishiyama , Mikito Nagata , Hiroshi Nakahara , Tiehua Piao
IPC分类号： H01M452
CPC分类号： H01M10/0525 , A61N1/378 , H01M4/13 , H01M4/131 , H01M4/133 , H01M4/485 , H01M4/505 , H01M4/525 , H01M4/587 , H01M4/661 , H01M4/662 , H01M10/0587 , H01M10/42 , H01M2004/021 , Y10T29/49108 , Y10T29/4911
摘要： A lithium ion battery particularly configured to be able to discharge to a very low voltage, e.g. zero volts, without causing permanent damage to the battery. More particularly, the battery is configured to define a Zero Volt Crossing Potential (ZCP) which is lower than a Substrate Dissolution Potential (SDP) to thus avoid low voltage substrate damage. The configuration includes a lithium nickel cobalt oxide positive active material combined with negative electrode comprising a titanium or titamum alloy substrate having a carbon active material formed thereon.
摘要翻译：特别是能够放电到非常低的电压的锂离子电池，例如，零电压，而不会对电池造成永久性损坏。更具体地，电池被配置为定义低于衬底溶出电位（SDP）的零伏交叉电位（ZCP），从而避免低电压衬底损坏。该配置包括与负极组合的锂镍钴氧化物正极活性材料，其包含其上形成有碳活性材料的钛或钛合金基底。

7. 发明授权

US06479189B1 Sealed alkaline storage battery with a manganese containing NiOH electrode 有权
标题翻译：密封碱性蓄电池，含锰锰电极
公开(公告)号：US06479189B1
公开(公告)日：2002-11-12
申请号：US09630458
申请日：2000-08-02
申请人： Takeshi Ogasawara , Yoshifumi Magari , Nobuyuki Higashiyama , Mamoru Kimoto , Yasuhiko Itoh
发明人： Takeshi Ogasawara , Yoshifumi Magari , Nobuyuki Higashiyama , Mamoru Kimoto , Yasuhiko Itoh
IPC分类号： H01M452
CPC分类号： H01M4/362 , H01M4/32 , H01M4/50 , H01M4/52 , H01M10/30 , H01M10/34 , H01M2010/4292 , H01M2300/0014 , Y02E60/124
摘要： The sealed alkaline storage battery of this invention includes a nonsintered nickel positive electrode using, as an active material, manganese-containing &agr;-nickel hydroxide including, as a solid-solution element, 15 through 50 wt % of manganese on the basis of a total amount of nickel and manganese; a negative electrode; and an alkaline electrolyte including 0.55 through 0.80 g of water per gram of the manganese-containing &agr;-nickel hydroxide. In this manner, the invention provides an alkaline storage battery exhibiting high positive electrode active material utilization for a large number of charge-discharge cycles.
摘要翻译：本发明的密封碱性蓄电池包括非烧结镍正极，其使用含锰的α-氢氧化镍作为活性材料，其包含作为固溶体元素的基于总量的15至50重量％的锰镍和锰的量; 负极; 以及每克含锰的α-氢氧化镍含有0.55〜0.80g水的碱性电解液。以这种方式，本发明提供了一种在大量充放电循环中具有高正极活性物质利用率的碱性蓄电池。

8. 发明授权

US06270535B1 Method of forming CoOOH and NiOOH in a NiMH electrochemical cell and an electrochemical cell formed thereby 失效
标题翻译：在NiMH电化学电池中形成CoOOH和NiOOH的方法以及由此形成的电化学电池
公开(公告)号：US06270535B1
公开(公告)日：2001-08-07
申请号：US09148176
申请日：1998-09-04
申请人： Deepika B. Singh
发明人： Deepika B. Singh
IPC分类号： H01M452
CPC分类号： H01M4/0447 , H01M4/52 , H01M10/288 , H01M10/345 , H01M10/44 , H01M10/446 , H02J7/0075 , Y10T29/49108
摘要： A formation procedure for a NiMH electrochemical cell is disclosed that significantly shortens the time required to fully form such a cell. The formation procedure includes a first step during which the cell is charged at a constant voltage of preferably 1.0 volt for approximately three hours. A second charging step is performed by applying either a constant charge current at a predetermined rate of C/3 for five hours or applying a constant voltage of 1.45 to 1.5 volts for five to nine hours. A third step may optionally be used whereby the cell is charged at a constant current of C/10 for about two hours. NiMH cells subjected to this formation procedure have a much greater percentage of the starting cobalt material in the positive electrode converted to CoOOH thereby improving the conductive matrix formed about the Ni(OH)2/NiOOH particles, which constitute the active material of the positive electrode. The disclosed inventive formation procedures result in higher utilization, higher cell capacities following long-term storage, or storage at high temperatures as well as improved capacity recovery following deep discharge.
摘要翻译：公开了一种NiMH电化学电池的形成方法，其显着缩短了完全形成这种电池所需的时间。形成步骤包括第一步骤，在该步骤中，电池以优选1.0伏的恒定电压充电大约三个小时。通过以C / 3的预定速率施加恒定充电电流5小时或施加1.45至1.5伏的恒定电压进行5至9小时来执行第二充电步骤。可以任选地使用第三步骤，由此电池以C / 10的恒定电流充电约2小时。经过这种形成过程的NiMH电池具有比正转化成CoOOH的起始钴材料的百分比大得多，从而改善了构成正极活性材料的Ni（OH）2 / NiOOH颗粒周围形成的导电基体。所公开的本发明形成方法导致更高的利用率，长期储存后的更高的电池容量或在高温下的储存以及在深度放电之后改进的容量恢复。

9. 发明授权

US06225009B1 Electrochemical cell with a non-liquid electrolyte 失效
标题翻译：具有非液体电解质的电化学电池
公开(公告)号：US06225009B1
公开(公告)日：2001-05-01
申请号：US09068864
申请日：1998-05-19
申请人： Niles A Fleischer , Joost Manassen , Joel Lang , Eli Rosh Chodesh , Marvin S. Antelman
发明人： Niles A Fleischer , Joost Manassen , Joel Lang , Eli Rosh Chodesh , Marvin S. Antelman
IPC分类号： H01M452
CPC分类号： H01G9/025 , H01M4/13 , H01M4/36 , H01M4/383 , H01M4/48 , H01M4/5825 , H01M4/60 , H01M6/18 , H01M6/181 , H01M6/185 , H01M6/40 , H01M6/48 , H01M10/056 , H01M10/0562 , H01M10/0564 , H01M10/0565 , H01M2004/029 , H01M2300/0005 , H01M2300/0082 , Y02T10/7022
摘要： A non-liquid electrolyte containing electrochemical cell which operates efficiently at room temperature. The cell includes (a) a non-liquid electrolyte in which protons are mobile, (b) an anode active material based on an organic compound which is a source of protons during cell discharge, or an anode active material including a metal whose cation can assume at least two different non-zero oxidation numbers and (c) a solid cathode including a compound which forms an electrochemical couple with the anode. Anode and cathode active materials can be chosen so that the cell has the feature that the electrochemical reactions at the anode and cathode are at least partially reversible. An important feature of the cell is that no thermal activation is required for its operation, therefore, the cell efficiently operates under ambient temperatures.
摘要翻译：含有电化学电池的非液体电解质在室温下有效运行。电池包括（a）其中质子是可移动的非液体电解质，（b）基于作为电池放电期间质子源的有机化合物的负极活性材料或包含阳离子可以假设至少两个不同的非零氧化数字和（c）包括与阳极形成电化学耦合的化合物的固体阴极。可以选择阳极和阴极活性材料，使得电池具有阳极和阴极上的电化学反应至少部分可逆的特征。电池的一个重要特征是其操作不需要热激活，因此，电池在环境温度下有效地工作。

10. 发明授权

US06756155B1 Positive active material for rechargeable lithium batteries and method of preparing same 有权
标题翻译：可充电锂电池的正极活性物质及其制备方法
公开(公告)号：US06756155B1
公开(公告)日：2004-06-29
申请号：US09505389
申请日：2000-02-16
申请人： Ho-Jin Kweon , Seung-Kee Kim , Sang-Moon Hwang , Young-Bae Roh
发明人： Ho-Jin Kweon , Seung-Kee Kim , Sang-Moon Hwang , Young-Bae Roh
IPC分类号： H01M452
CPC分类号： H01M4/13 , C01G51/42 , C01G51/50 , C01P2002/52 , C01P2002/54 , C01P2002/88 , C01P2004/03 , C01P2004/61 , C01P2004/62 , C01P2004/84 , C01P2006/32 , C01P2006/40 , H01M4/131 , H01M4/136 , H01M4/485 , H01M4/525 , H01M4/58 , H01M4/5815 , H01M4/582 , H01M10/052 , H01M2004/021
摘要： Disclosed is a positive active material for a rechargeable lithium battery. The active material includes a cobalt-based compound selected from the group consisting of the compounds represented by the formulas 1 to 4. The active material has a structure of secondary particles with a size of 10 to 30 &mgr;m and the secondary particle is gathered with primary particles with a size of 1 to 5 &mgr;m. The active material includes a metallic oxide coated on the cobalt-based compound. LiCoA2 (1) LiCoO2-xBx (2) LiCo1-xMxA2 (3) LiCo1-xMxO2-yBy (4) where A is selected from the group consisting of O, S, F and P, B is selected from the group consisting of S, F and P, M is a transition metal selected from Al, Mg, Cr or Mn; Sr; or lanthanide metal selected from La or Ce; 0
摘要翻译：公开了用于可再充电锂电池的正极活性材料。活性物质包括选自由式1〜4表示的化合物的钴系化合物。活性物质具有尺寸为10〜30μm的二次粒子的结构，二次粒子聚集为初级粒径为1〜5μm的粒子。活性材料包括涂覆在钴基化合物上的金属氧化物，其中A选自O，S，F和P，B选自S，F和P，M是过渡选自Al，Mg，Cr或Mn的金属; 锶或选自La或Ce的镧系金属; 0

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