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    • 10. 发明申请
    • High chloride emulsion doped with combination of metal complexes
    • 掺有金属络合物的高氯化物乳液
    • US20030077549A1
    • 2003-04-24
    • US09919118
    • 2001-07-31
    • Eastman Kodak Company
    • Jerzy Z. MydlarzEric L. Bell
    • G03C001/035
    • G03C1/035G03C1/08G03C5/04G03C2001/03517G03C2001/03535G03C2001/03594
    • A radiation-sensitive emulsion comprised of silver halide grains (a) containing greater than 50 mole percent chloride, based on silver, (b) having greater than 50 percent of their surface area provided by null100null crystal faces, and (c) having a central portion accounting for up to 99 percent of total silver and containing a first dopant of Formula (I) and a second dopant of Formula (II): nullML6nullnnullnull(I) wherein n is zero, null1, null2, null3 or null4; M is a filled frontier orbital polyvalent metal ion, other than iridium; and L6 represents bridging ligands which can be independently selected, provided that at least four of the ligands are anionic ligands, and at least one of the ligands is a cyano ligand or a ligand more electronegative than a cyano ligand; nullTE4(NZ)Enullnullrnullnull(II) wherein T is Os or Ru; E4 represents bridging ligands which can be independently selected; Enull is E or NZ; r is zero, null1, null2 or null3; and Z is oxygen or sulfur; wherein the silver halide grains have an average equivalent spherical diameter of less than 0.9 micrometer, the dopant of Formula (II) is located within an inner core of the grains comprising up to 60 percent of the total silver, and the dopant of Formula (I) is located in an outer dopant band which is separated from the inner core by at least 10 percent of the total silver. Significantly improved latent image keeping performance can be obtained for optical and digital exposed elements which comprise silver halide grains in an emulsion layer doped with a dopant of Formula (I) and a dopant of Formula (II) as described above, while substantially maintaining other desired photographic parameters.
    • 由卤化银颗粒(a)组成的辐射敏感性乳液(a),其含有大于50摩尔%的氯化物,基于银,(b)具有由{100}晶面提供的其表面积的50%以上,和(c) 占总银总量的99%以上且含有式(I)的第一掺杂剂和式(II)的第二掺杂剂的中心部分:[ML6] n(I)其中n为0,-1,-2, -3或-4; M是除铱之外的填充边界轨道多价金属离子; 并且L6表示可以独立选择的桥连配体,条件是至少四个配体是阴离子配体,并且至少一个配体是氰基配体或者比氰基配体更具有负电性的配体; [TE4(NZ)E'] r(II)其中T是Os或Ru; E4表示可独立选择的桥连配体; E'是E或NZ; r为零,-1,-2或-3; Z是氧或硫; 其中卤化银颗粒具有小于0.9微米的平均当量球形直径,式(II)的掺杂剂位于包含至多总银的60%的晶粒的内核内,并且式(I )位于外部掺杂剂带中,其从内芯分离总银的至少10%。 在如上所述掺杂有式(I)的掺杂剂和式(II)的掺杂剂的乳剂层中包含卤化银颗粒的光学和数字暴露元件可以获得显着改善的潜像保持性能,同时基本上保持其它所需的 摄影参数。