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    • 9. 发明申请
    • PREPARATION OF SECONDARY ETHER FATTY ACIDS AND ESTERS FROM THEIR HYDROXY FATTY ACID EQUIVALENTS
    • 从其羟基脂肪酸等量物质制备二级脂肪酸和酯
    • WO1997045505A1
    • 1997-12-04
    • PCT/US1997009213
    • 1997-05-29
    • THE UNITED STATES OF AMERICA, as represented by THE SECRETARY OF AGRICULTURE
    • THE UNITED STATES OF AMERICA, as represented by THE SECRETARY OF AGRICULTUREISBELL, Terry, A.MUND, Melissa, S.
    • C10C01/00
    • C07C69/708C07C59/125C07C59/60C07C67/29
    • The fatty ether compounds possess low viscosity and low temperature melting point properties and may be used as viscosity modifiers in cosmetics and vegetable oil based biodegradable hydraulic fluids and dielectric fluids. The fatty ethers are of formula (I) wherein R is selected from C7-C17 aliphatic hydrocarbons saturated or unsaturated, linear or branched, and optionally substituted, with one or more hydroxy groups; R is selected from linear or branched C1-C24 hydrocarbons saturated or unsaturated, linear or branched, aliphatic or aromatic, and optionally substituted by one or more hydroxyl, halo, or amine groups; with the proviso that when R is aromatic, it is limited to an optionally substituted six member carbon ring; and R2 is selected from hydrogen or from linear or branched C1-C24 hydrocarbons saturated or unsaturated, linear or branched, aliphatic or aromatic, and optionally substituted by one ore more hydroxyl, halo, or amine groups; with the proviso that when R2 is aromatic, it is limited to an optionally substituted six member carbon ring; and x is an integer from 2 to 4. These fatty ester ether compounds are produced by reaction of the hydroxy fatty acid or lactone with an alcohol in the presence of an acid catalyst. The fatty ether esters are recovered, or hydrolyzed to fatty ether acids, or transesterified with a different alcohol in the presence of an acid catalyst to alternate ester variants.
    • 脂肪醚化合物具有低粘度和低温熔点性质,可用作化妆品和植物油基生物降解液压油和介电流体中的粘度调节剂。 脂肪醚具有式(I),其中R选自具有一个或多个羟基的饱和或不饱和,直链或支链并任选取代的C 7 -C 17脂族烃; R 1选自饱和或不饱和的,直链或支链的脂族或芳族直链或支链C 1 -C 24烃,并任选被一个或多个羟基,卤素或胺基取代; 条件是当R 1是芳族时,它限于任选取代的六元碳环; R 2选自氢或直链或支链C 1 -C 24烃饱和或不饱和,直链或支链,脂族或芳族,任选被一个或多个羟基,卤素或胺基取代; 条件是当R 2是芳族时,它限于任选取代的六元碳环; x为2-4的整数。这些脂肪酯醚化合物是通过羟基脂肪酸或内酯与醇在酸催化剂存在下反应生成的。 脂肪醚酯被回收或水解成脂肪醚酸,或在酸催化剂存在下用不同的醇进行酯交换,以替代酯变体。