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    • 1. 发明授权
    • Process for preparing thermoplastic molding compositions
    • 制备热塑性模塑组合物的方法
    • US06316550B2
    • 2001-11-13
    • US09730782
    • 2000-12-07
    • Axel StienekerRadu BordeianuThomas NeuHarald SturmWilhelm Friedrich Schmitt
    • Axel StienekerRadu BordeianuThomas NeuHarald SturmWilhelm Friedrich Schmitt
    • C08F25904
    • C08F285/00C08F214/06
    • One embodiment of the present invention provides a process, which includes: graft polymerizing a vinyl chloride monomer in suspension in the presence of a core-shell impact modifier; wherein the core-shell impact modifier includes: a core including polyvinyl chloride or vinyl chloride copolymers; and a shell including crosslinked alkyl (meth)acrylate homo- or copolymers. Another embodiment of the present invention provides a thermoplastic polyvinyl chloride molding composition modified with an elastomer-containing core-shell modifier, prepared by a process, which includes graft polymerizing a vinyl chloride monomer in suspension in the presence of a core-shell impact modifier; wherein the core-shell impact modifier includes a core including polyvinyl chloride or vinyl chloride copolymers; and a shell including crosslinked alkyl (meth)acrylate homo- or copolymers. Another embodiment of the present invention provides a plastic profile, which includes the above-noted composition. Another embodiment of the present invention provides an article selected from the group including window frame, pipe, film, siding and panel, which includes the above-noted composition. By the present invention, a thermoplastic polyvinyl chloride molding composition is obtained that has improved impact strength, corner strength and optical properties.
    • 本发明的一个实施方案提供了一种方法,其包括:在核 - 壳抗冲改性剂存在下将悬浮液中的氯乙烯单体接枝聚合;其中核 - 壳抗冲改性剂包括:包含聚氯乙烯或氯乙烯共聚物 ; 包括交联的(甲基)丙烯酸烷基酯均聚物或共聚物。本发明的另一个实施方案提供了一种通过包括含有弹性体的核 - 壳改性剂改性的热塑性聚氯乙烯模塑组合物,其通过包括接枝聚合氯乙烯 单体在核 - 壳抗冲改性剂存在下悬浮; 其中所述核 - 壳抗冲改性剂包括包含聚氯乙烯或氯乙烯共聚物的芯; 和包含交联的(甲基)丙烯酸烷基酯均聚物或共聚物的壳。 本发明的另一个实施方案提供了一种塑料型材,其包括上述组合物。 本发明的另一实施例提供一种选自包括窗框,管,膜,壁板和面板的组件,其包括上述组成。 通过本发明,得到具有改善的冲击强度,拐角强度和光学性能的热塑性聚氯乙烯模塑组合物。