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1. 发明授权

US4798869A Process for the production of thermoplastic compositions and compositions produced thereby 失效
公开(公告)号：US4798869A
公开(公告)日：1989-01-17
申请号：US927985
申请日：1986-11-07
申请人： Harald Sturm , Rolf-Walter Terwonne , Dieter Thunig
发明人： Harald Sturm , Rolf-Walter Terwonne , Dieter Thunig
IPC分类号： C02F11/00 , C02F11/04 , C02F11/14 , C02F103/00 , C08F2/22 , C08F285/00 , C08F265/04 , C08F267/06
CPC分类号： C08F285/00 , Y10S525/902
摘要： A process for the production of a thermoplastic composition for molded parts having improved impact resistance, transparency, surface gloss, and weatherability, and formed of a hard inner core of crosslinked polystyrene, a rubber-elastic intermediate layer of crosslinked polyacrylic ester, and an outer layer of polyvinyl chloride, wherein the inner core thereof is produced by the steps of:(a) forming a mixture, before or after addition of an initiator, under polymerization conditions in the presence of an emulsifier, of 0.01-5.0% by weight of an acrylic acid or methacrylic acid aclkyl ester with a crosslinking component, and thereafter(b) adding to the mixture, 20-70% by weight of a mixture of an aromatic vinyl monomer with a crosslinking component and, simultaneously therewith in a separate stream, a solution of an organic complexing agent and of an emulsifier in water, and optionally a solution of a catalyst, and emulsion polymerizing the resultant mixture;wherein the intermediate layer thereof is produced by adding, to the inner core produced in step (b),(c) 79.99-25% by weight of a mixture of an acrylic acid alkyl ester with a crosslinking component and simultaneouly therewith an aqueous emulsifier solution, under emulsion polymerization conditions; andwherein the outer layer thereof is formed on the thus-produced core/shell polymer by adding, to 50 to 2 parts by weight thereof,(d) 50 to 98 parts by weight of vinyl chloride or a monomer mixture containing predominantly vinyl chloride, with agitation, and in the presence of an initiator, the agitating temperature and period selected so that the conversion, based on the monomer mixture or, respectively, the vinyl chloride, is at most 10% by weight, and thereafter continuing the polymerization by heating to the polymerization temperature, to a vinyl chloride conversion of 65-95%.

2. 发明授权

US4731413A Molding compositions based on linear, high-molecular weight polyesters 失效
标题翻译：基于线性高分子量聚酯的成型组合物
公开(公告)号：US4731413A
公开(公告)日：1988-03-15
申请号：US829254
申请日：1986-02-14
申请人： Michael Droscher , Christian Gerth , Harald Sturm
发明人： Michael Droscher , Christian Gerth , Harald Sturm
IPC分类号： C08L67/00 , C08L7/00 , C08L21/00 , C08L33/00 , C08L33/02 , C08L51/00 , C08L51/02 , C08L67/02 , C08L101/08 , C08L13/02 , C08L21/02
CPC分类号： C08L67/02
摘要： Polyesters are modified by adding an aqueous latex having a solids content of
摘要翻译：通过加入固体含量<50重量％的水性胶乳来改性聚酯。胶乳中含有的合成树脂的玻璃化转变温度为0℃，含有0.1-20摩尔％的官能团。

3. 发明授权

US06316550B2 Process for preparing thermoplastic molding compositions 有权
标题翻译：制备热塑性模塑组合物的方法
公开(公告)号：US06316550B2
公开(公告)日：2001-11-13
申请号：US09730782
申请日：2000-12-07
申请人： Axel Stieneker , Radu Bordeianu , Thomas Neu , Harald Sturm , Wilhelm Friedrich Schmitt
发明人： Axel Stieneker , Radu Bordeianu , Thomas Neu , Harald Sturm , Wilhelm Friedrich Schmitt
IPC分类号： C08F25904
CPC分类号： C08F285/00 , C08F214/06
摘要： One embodiment of the present invention provides a process, which includes: graft polymerizing a vinyl chloride monomer in suspension in the presence of a core-shell impact modifier; wherein the core-shell impact modifier includes: a core including polyvinyl chloride or vinyl chloride copolymers; and a shell including crosslinked alkyl (meth)acrylate homo- or copolymers. Another embodiment of the present invention provides a thermoplastic polyvinyl chloride molding composition modified with an elastomer-containing core-shell modifier, prepared by a process, which includes graft polymerizing a vinyl chloride monomer in suspension in the presence of a core-shell impact modifier; wherein the core-shell impact modifier includes a core including polyvinyl chloride or vinyl chloride copolymers; and a shell including crosslinked alkyl (meth)acrylate homo- or copolymers. Another embodiment of the present invention provides a plastic profile, which includes the above-noted composition. Another embodiment of the present invention provides an article selected from the group including window frame, pipe, film, siding and panel, which includes the above-noted composition. By the present invention, a thermoplastic polyvinyl chloride molding composition is obtained that has improved impact strength, corner strength and optical properties.
摘要翻译：本发明的一个实施方案提供了一种方法，其包括：在核 - 壳抗冲改性剂存在下将悬浮液中的氯乙烯单体接枝聚合;其中核 - 壳抗冲改性剂包括：包含聚氯乙烯或氯乙烯共聚物 ; 包括交联的（甲基）丙烯酸烷基酯均聚物或共聚物。本发明的另一个实施方案提供了一种通过包括含有弹性体的核 - 壳改性剂改性的热塑性聚氯乙烯模塑组合物，其通过包括接枝聚合氯乙烯单体在核 - 壳抗冲改性剂存在下悬浮; 其中所述核 - 壳抗冲改性剂包括包含聚氯乙烯或氯乙烯共聚物的芯; 和包含交联的（甲基）丙烯酸烷基酯均聚物或共聚物的壳。本发明的另一个实施方案提供了一种塑料型材，其包括上述组合物。本发明的另一实施例提供一种选自包括窗框，管，膜，壁板和面板的组件，其包括上述组成。通过本发明，得到具有改善的冲击强度，拐角强度和光学性能的热塑性聚氯乙烯模塑组合物。

4. 发明授权

US5232991A Preparation of an impact-resistant polyacrylate/vinyl chloride graft copolymer 失效
标题翻译：耐冲击聚丙烯酸酯/氯乙烯共聚物的制备
公开(公告)号：US5232991A
公开(公告)日：1993-08-03
申请号：US753163
申请日：1991-08-30
申请人： Harald Sturm , Armin Boebel , Karl-Heinz Prell
发明人： Harald Sturm , Armin Boebel , Karl-Heinz Prell
IPC分类号： C08F265/06 , C08F2/18 , C08F2/20 , C08F214/06 , C08F265/00 , C08F265/04
CPC分类号： C08F265/04
摘要： For the preparation of thermoplastic materials based on (a) homopolymers or copolymers of vinyl chloride and (b) polyacrylates having a glass transition temperature of less than -20.degree. C., firstly the acrylate is polymerized in aqueous emulsion in the presence of crosslinking compounds copolymerizable with the acrylates and having at least two nonconjugated double bonds. Secondly, the vinyl chloride or vinyl chloride with up to 20% by weight of copolymerizable monomers is heated with an initiator, a suspension agent system and optionally additives in an aqueous suspension to a temperature of about .gtoreq.30.degree. C. The polyacrylate is subsequently added and polymerization carried out at temperatures of about >30.degree. C. to the desired conversion. The resulting polymers exhibit improved particle size distribution, good reproducibility of the bulk density and in particular caked deposits on the wall are dramatically reduced during polymerization.
摘要翻译：为了制备基于（a）氯乙烯的均聚物或共聚物和（b）玻璃化转变温度低于-20℃的聚丙烯酸酯的热塑性材料，首先将丙烯酸酯在水性乳液中在交联化合物存在下聚合可与丙烯酸酯共聚并具有至少两个非共轭双键。其次，将高达20重量％可共聚单体的氯乙烯或氯乙烯与引发剂，悬浮剂体系和任选的添加剂一起加热至约> 30℃的温度。聚丙烯酸酯是随后加入并在约> 30℃的温度下进行聚合至所需的转化率。所得聚合物显示出改善的粒度分布，在聚合过程中体积密度的良好重现性，特别是壁上的结块沉积物显着降低。

5. 发明授权

US4251303A Method and apparatus for making a fillet-seam closure on a folding carton, particularly a peaked-top carton 失效
标题翻译：用于在折叠纸箱上制作圆角缝缝合的方法和装置，特别是顶顶纸箱
公开(公告)号：US4251303A
公开(公告)日：1981-02-17
申请号：US22007
申请日：1979-03-19
申请人： Gerhard Deimel , Paul Schmidt , Harald Sturm
发明人： Gerhard Deimel , Paul Schmidt , Harald Sturm
IPC分类号： B29C53/00 , B29C65/00 , B29C65/08 , B65B51/22 , B30B15/34 , B32B31/20 , B65B7/18
CPC分类号： B29C66/326 , B29C65/08 , B29C65/7841 , B29C66/1122 , B29C66/43122 , B29C66/73921 , B29C66/81422 , B29C66/81427 , B29C66/81431 , B29C66/9241 , B65B51/225 , B29C66/71 , B29C66/832 , B29K2023/06 , B29K2305/02 , B29L2009/003 , Y10S53/02
摘要： A method and an apparatus for making a fillet seam closure on folding boxes fabricated from box-board internally lined with aluminum foil and coated with a thermal plastic resin includes folding the fillet seam along a fold line, holding the areas of the fillet seam to be welded together by applying compressive forces along a line parallel to the desired weld seam and slightly spaced therefrom between the weld seam and the fold line and ultrasonically welding the fillet seam with a simultaneous application of pressure in the weld seam which gradually decreases from the weld seam center line to the edge facing the fold line to effect the displacement of the thermal plastic resin from the center line towards the edge in the formation of a V-joint. The weld is allowed to cool off and the compressor forces are maintained during the welding and the cooling operations.
摘要翻译：在内部由铝箔内衬铝箔并由热塑性树脂涂覆的盒子板上制作折叠盒的方法和装置包括沿着折线折叠圆角缝，将圆角缝的区域保持为通过沿着平行于期望的焊缝的线施加压缩力并在焊缝和折叠线之间略微间隔开来焊接在一起，并且在焊缝中同时施加压力并从焊缝逐渐减小而超声焊接焊缝中心线到面向折叠线的边缘，以在形成V形接头时实现热塑性树脂从中心线朝向边缘的位移。允许焊接冷却，在焊接和冷却操作期间保持压缩机的力。

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