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    • 3. 发明授权
    • Methacrylate and acrylate polymers and processes for making same
    • 甲基丙烯酸酯和丙烯酸酯聚合物及其制备方法
    • US06221991B1
    • 2001-04-24
    • US09109210
    • 1998-06-30
    • Robert J. LetchfordJames A. SchwindemanConrad W. KamienskiRoderic P. Quirk
    • Robert J. LetchfordJames A. SchwindemanConrad W. KamienskiRoderic P. Quirk
    • C08F2054
    • C08F20/56C08F4/46C08F4/72C08F8/00C08F20/14C08F20/18C08F20/42C08F2810/40C08G81/021C08F120/14
    • Polar polymers having the following formula: FG-(Q)d-Rn-Z-J-[A(R1R2R3)]x   (I) wherein FG is H or a protected or non-protected functional group; Q is a polar hydrocarbyl group derived by incorporation of a polar compound selected from group consisting of esters, amides, and nitrites of acrylic and methacrylic acid, and mixtures thereof; d is an integer from 10 to 2000; R is a saturated or unsaturated hydrocarbyl group derived by incorporation of a compound selected from the group consisting of conjugated diene hydrocarbons, alkenylsubstituted aromatic hydrocarbons, and mixtures thereof; n is an integer from 0 to 5; Z is a branched or straight chain hydrocarbon group which contains 3-25 carbon atoms, optionally containing aryl or substituted aryl groups; J is oxygen, sulfur, or nitrogen; [A(R1R2R3)]x is a protecting group, in which A is an element selected from Group IVa of the Periodic Table of Elements; R1, R2, and R3 are each independently selected from the group consisting of hydrogen, alkyl, substituted alkyl groups containing lower alkyl, lower alkylthio, and lower dialkylamino groups, aryl or substituted aryl groups containing lower alkyl, lower alkylthio, and lower dialkylamino groups, and cycloalkyl and substituted cycloalkyl containing 5 to 12 carbon atoms; and x is dependent on the valence of J and varies from one when J is oxygen or sulfur to two when J is nitrogen, and living anionic polymerization processes for preparing the same.
    • 具有下式的极性聚合物:其中FG是H或被保护或未被保护的官能团; Q是通过掺入选自丙烯酸和甲基丙烯酸的酯,酰胺和亚硝酸盐的极性化合物及其混合物衍生的极性烃基; d为10〜2000的整数, R是通过引入选自共轭二烯烃,烯基取代的芳族烃及其混合物的化合物衍生的饱和或不饱和烃基; n为0〜5的整数, Z是含有3-25个碳原子的支链或直链烃基,任选含有芳基或取代的芳基; J是氧,硫或氮; [A(R 1 R 2 R 3)] x是保护基,其中A是选自元素周期表Ⅳa族的元素; R 1,R 2和R 3各自独立地选自氢,烷基,含有低级烷基,低级烷硫基和低级二烷基氨基的取代烷基,含有低级烷基,低级烷硫基和低级二烷基氨基的芳基或取代芳基 和含有5至12个碳原子的环烷基和取代的环烷基; 并且x取决于J的化合价,并且当J为氮时J为氧或硫时为2,并且当用于制备其的活性阴离子聚合方法时,其为不同的。