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1. 发明授权

US06699939B2 Hetero-telechelic polymers and processes for making same 失效
公开(公告)号：US06699939B2
公开(公告)日：2004-03-02
申请号：US10176723
申请日：2002-06-21
申请人： James A. Schwindeman , Robert J. Letchford , Conrad W. Kamienski , Roderic P. Quirk
发明人： James A. Schwindeman , Robert J. Letchford , Conrad W. Kamienski , Roderic P. Quirk
IPC分类号： C08F29704
CPC分类号： C08F36/04 , C08C19/44 , C08F4/46 , C08F4/48 , C08F4/72 , C08F8/34 , C08F12/04 , C08F2810/40 , C08F112/08
摘要： Hetero-telechelic polymers having the formula: FG—(Q)d—Z—J—[A(R1R2R3)]x (I) wherein FG is a protected or non-protected functional group; Q is a saturated or unsaturated hydrocarbyl group derived by incorporation of a compound selected from the group consisting of conjugated diene hydrocarbons, alkenylsubstituted aromatic hydrocarbons, and mixtures thereof; d is an integer from 10 to 200; Z is a branched or straight chain hydrocarbon group which contains 3-25 carbon atoms, optionally containing aryl or substituted aryl groups; J is oxygen, sulfur, or nitrogen; [A(R1R2R3)]x is a protecting group, wherein A is an element selected from Group IVa of the Periodic Table of Elements; R1, R2, and R3 are each independently selected from the group consisting of hydrogen, alkyl, substituted alkyl groups containing lower alkyl, lower alkylthio, and lower dialkylamino groups, aryl or substituted aryl groups containing lower alkyl, lower alkylthio, and lower dialkylamino groups, and cycloalkyl and substituted cycloalkyl containing 5 to 12 carbon atoms; and x is dependent on the valence of J and varies from one when J is oxygen or sulfur to two when J is nitrogen, with the proviso J and FG are not the same, and processes for making the same.

2. 发明授权

US06221991B1 Methacrylate and acrylate polymers and processes for making same 失效
标题翻译：甲基丙烯酸酯和丙烯酸酯聚合物及其制备方法
公开(公告)号：US06221991B1
公开(公告)日：2001-04-24
申请号：US09109210
申请日：1998-06-30
申请人： Robert J. Letchford , James A. Schwindeman , Conrad W. Kamienski , Roderic P. Quirk
发明人： Robert J. Letchford , James A. Schwindeman , Conrad W. Kamienski , Roderic P. Quirk
IPC分类号： C08F2054
CPC分类号： C08F20/56 , C08F4/46 , C08F4/72 , C08F8/00 , C08F20/14 , C08F20/18 , C08F20/42 , C08F2810/40 , C08G81/021 , C08F120/14
摘要： Polar polymers having the following formula: FG-(Q)d-Rn-Z-J-[A(R1R2R3)]x (I) wherein FG is H or a protected or non-protected functional group; Q is a polar hydrocarbyl group derived by incorporation of a polar compound selected from group consisting of esters, amides, and nitrites of acrylic and methacrylic acid, and mixtures thereof; d is an integer from 10 to 2000; R is a saturated or unsaturated hydrocarbyl group derived by incorporation of a compound selected from the group consisting of conjugated diene hydrocarbons, alkenylsubstituted aromatic hydrocarbons, and mixtures thereof; n is an integer from 0 to 5; Z is a branched or straight chain hydrocarbon group which contains 3-25 carbon atoms, optionally containing aryl or substituted aryl groups; J is oxygen, sulfur, or nitrogen; [A(R1R2R3)]x is a protecting group, in which A is an element selected from Group IVa of the Periodic Table of Elements; R1, R2, and R3 are each independently selected from the group consisting of hydrogen, alkyl, substituted alkyl groups containing lower alkyl, lower alkylthio, and lower dialkylamino groups, aryl or substituted aryl groups containing lower alkyl, lower alkylthio, and lower dialkylamino groups, and cycloalkyl and substituted cycloalkyl containing 5 to 12 carbon atoms; and x is dependent on the valence of J and varies from one when J is oxygen or sulfur to two when J is nitrogen, and living anionic polymerization processes for preparing the same.
摘要翻译：具有下式的极性聚合物：其中FG是H或被保护或未被保护的官能团; Q是通过掺入选自丙烯酸和甲基丙烯酸的酯，酰胺和亚硝酸盐的极性化合物及其混合物衍生的极性烃基; d为10〜2000的整数， R是通过引入选自共轭二烯烃，烯基取代的芳族烃及其混合物的化合物衍生的饱和或不饱和烃基; n为0〜5的整数， Z是含有3-25个碳原子的支链或直链烃基，任选含有芳基或取代的芳基; J是氧，硫或氮; [A（R 1 R 2 R 3）] x是保护基，其中A是选自元素周期表Ⅳa族的元素; R 1，R 2和R 3各自独立地选自氢，烷基，含有低级烷基，低级烷硫基和低级二烷基氨基的取代烷基，含有低级烷基，低级烷硫基和低级二烷基氨基的芳基或取代芳基和含有5至12个碳原子的环烷基和取代的环烷基; 并且x取决于J的化合价，并且当J为氮时J为氧或硫时为2，并且当用于制备其的活性阴离子聚合方法时，其为不同的。

3. 发明授权

US5900464A Processes for making methacrylate and acrylate polymers 失效
标题翻译：制备甲基丙烯酸酯和丙烯酸酯聚合物的方法
公开(公告)号：US5900464A
公开(公告)日：1999-05-04
申请号：US677793
申请日：1996-07-10
申请人： Robert J. Letchford , James A. Schwindeman , Conrad W. Kamienski , Roderic P. Quirk
发明人： Robert J. Letchford , James A. Schwindeman , Conrad W. Kamienski , Roderic P. Quirk
IPC分类号： C08F4/46 , C08F4/72 , C08F8/00 , C08F20/14 , C08F20/18 , C08F20/42 , C08F20/56 , C08G81/02 , C08L31/02 , C08F297/02
CPC分类号： C08F20/56 , C08F20/14 , C08F20/18 , C08F20/42 , C08F4/46 , C08F4/72 , C08F8/00 , C08G81/021 , C08F2810/40
摘要： Polar polymers having the following formula:FG--(Q).sub.d --R.sub.n --Z--J--�A(R.sup.1 R.sup.2 R.sup.3)!.sub.x(I)wherein FG is H or a protected or non-protected functional group; Q is a polar hydrocarbyl group derived by incorporation of a polar compound selected from group consisting of esters, amides, and nitriles of acrylic and methacrylic acid, and mixtures thereof; d is an integer from 10 to 2000; R is a saturated or unsaturated hydrocarbyl group derived by incorporation of a compound selected from the group consisting of conjugated diene hydrocarbons, alkenylsubstituted aromatic hydrocarbons, and mixtures thereof; n is an integer from 0 to 5; Z is a branched or straight chain hydrocarbon group which contains 3-25 carbon atoms, optionally containing aryl or substituted aryl groups; J is oxygen, sulfur, or nitrogen; �A(R.sup.1 R.sup.2 R.sup.3)!.sub.x is a protecting group, in which A is an element selected from Group IVa of the Periodic Table of Elements; R.sup.1, R.sup.2, and R.sup.3 are each independently selected from the group consisting of hydrogen, alkyl, substituted alkyl groups containing lower alkyl, lower alkylthio, and lower dialkylamino groups, aryl or substituted aryl groups containing lower alkyl, lower alkylthio, and lower dialkylamino groups, and cycloalkyl and substituted cycloalkyl containing 5 to 12 carbon atoms; and x is dependent on the valence of J and varies from one when J is oxygen or sulfur to two when J is nitrogen, and living anionic polymerization processes for preparing the same.
摘要翻译：具有下式的极性聚合物：FG-（Q）d-Rn-Z-J- [A（R1R2R3）] x（I）其中FG是H或被保护或未被保护的官能团; Q是通过掺入选自丙烯酸和甲基丙烯酸的酯，酰胺和腈的极性化合物及其混合物衍生的极性烃基; d为10〜2000的整数， R是通过引入选自共轭二烯烃，烯基取代的芳族烃及其混合物的化合物衍生的饱和或不饱和烃基; n为0〜5的整数， Z是含有3-25个碳原子的支链或直链烃基，任选含有芳基或取代的芳基; J是氧，硫或氮; [A（R 1 R 2 R 3）] x是保护基，其中A是选自元素周期表Ⅳa族的元素; R 1，R 2和R 3各自独立地选自氢，烷基，含有低级烷基，低级烷硫基和低级二烷基氨基的取代烷基，含有低级烷基，低级烷硫基和低级二烷基氨基的芳基或取代芳基和含有5至12个碳原子的环烷基和取代的环烷基; 并且x取决于J的化合价，并且当J为氮时J为氧或硫时为2，并且当用于制备其的活性阴离子聚合方法时，其为不同的。

4. 发明授权

US06703446B2 Hetero-telechelic polymers and processes for making same 失效
标题翻译：杂环聚合物和制备相同的方法
公开(公告)号：US06703446B2
公开(公告)日：2004-03-09
申请号：US10176816
申请日：2002-06-21
申请人： James A. Schwindeman , Robert J. Letchford , Conrad W. Kamienski , Roderic P. Quirk
发明人： James A. Schwindeman , Robert J. Letchford , Conrad W. Kamienski , Roderic P. Quirk
IPC分类号： C08F29704
CPC分类号： C08F36/04 , C08C19/44 , C08F4/46 , C08F4/48 , C08F4/72 , C08F8/34 , C08F12/04 , C08F2810/40 , C08F112/08
摘要： Hetero-telechelic polymers having the formula: FG—(Q)d—Z—J—[A(R1R2R3)]x (I) wherein FG is a protected or non-protected functional group; Q is a saturated or unsaturated hydrocarbyl group derived by incorporation of a compound selected from the group consisting of conjugated diene hydrocarbons, alkenylsubstituted aromatic hydrocarbons, and mixtures thereof; d is an integer from 10 to 200; Z is a branched or straight chain hydrocarbon group which contains 3-25 carbon atoms, optionally containing aryl or substituted aryl groups; J is oxygen, sulfur, or nitrogen; [A(R1R2R3)]x is a protecting group, wherein A is an element selected from Group IVa of the Periodic Table of Elements; R1, R2, and R3 are each independently selected from the group consisting of hydrogen, alkyl, substituted alkyl groups containing lower alkyl, lower alkylthio, and lower dialkylamino groups, aryl or substituted aryl groups containing lower alkyl, lower alkylthio, and lower dialkylamino groups, and cycloalkyl and substituted cycloalkyl containing 5 to 12 carbon atoms; and x is dependent on the valence of J and varies from one when J is oxygen or sulfur to two when J is nitrogen, with the proviso J and FG are not the same, and processes for making the same.
摘要翻译：具有下式的异烟酰基聚合物：其中FG是被保护或未被保护的官能团; Q是通过引入选自共轭二烯烃，烯基取代的芳族烃及其混合物的化合物衍生的饱和或不饱和烃基; d为10〜200的整数; Z是含有3-25个碳原子的支链或直链烃基，任选含有芳基或取代的芳基; J是氧，硫或氮; [A（R 1 R 2 R 3）] x是保护基，其中A是选自元素周期表Ⅳa族的元素; R 1，R 2和R 3各自独立地选自氢，烷基，含有低级烷基，低级烷硫基和低级二烷基氨基的取代烷基，含低级烷基的低级烷基烷基，低级烷硫基和低级二烷基氨基，环烷基和取代环烷基，含有5至12个碳原子; 并且x取决于J的化合价，并且当J是氮时，当J是氧或硫时，J的值是不同的，条件是J和FG不相同，并且其制备方法。

5. 发明授权

US06812295B2 Functionalized initiators for anionic polymerization, protected functionalized polymers, deprotected analogues thereof, and methods of making the same 失效
标题翻译：用于阴离子聚合的官能化引发剂，保护的官能化聚合物，其去保护的类似物及其制备方法
公开(公告)号：US06812295B2
公开(公告)日：2004-11-02
申请号：US10801367
申请日：2004-03-16
申请人： James Anthony Schwindeman , Robert J. Letchford , Eric John Granger , Roderic P. Quirk
发明人： James Anthony Schwindeman , Robert J. Letchford , Eric John Granger , Roderic P. Quirk
IPC分类号： C08F818
CPC分类号： C08C19/44 , C07F1/02 , C08F36/04 , C08F4/48
摘要： The present invention provides functionalized electrophiles, their analogous initiators, and processes for preparing these compounds. The present invention also relates to homotelechelic, heteroelechelic, and radial functional polydiene polymers, polyarylene polymers and polydiene/polyarylene copolymers, their optionally hydrogenated analogues, their optionally deprotected analogs, and process for preparing these functionalized polymers.
摘要翻译：本发明提供功能化的亲电子试剂，它们的类似的引发剂，以及制备这些化合物的方法。本发明还涉及同基亚类，异亚烯基和径向功能性聚二烯聚合物，聚亚芳基聚合物和聚二烯/聚亚芳基共聚物，它们任选氢化的类似物，它们任选脱保护的类似物，以及制备这些官能化聚合物的方法。

6. 发明授权

US06706821B1 Michael addition products of amine terminated polyolefins and polyfunctional acrylates 失效
标题翻译：胺封端的聚烯烃和多官能丙烯酸酯的迈克尔加成产物
公开(公告)号：US06706821B1
公开(公告)日：2004-03-16
申请号：US09908485
申请日：2001-07-18
申请人： Robert J. Letchford
发明人： Robert J. Letchford
IPC分类号： C08G6100
CPC分类号： C08G18/672 , C08C19/02 , C08C19/28 , C08F222/1006 , C08F255/00 , C08F285/00 , C08F290/00 , C08F290/06 , C08F290/14 , C08L71/02 , C08L2205/05 , C08L2666/04
摘要： Adducts of polyfunctional acrylates and amine terminated polyolefins are provided. The adducts are prepared via a Michael addition reaction of the acrylate and the amine terminated polyolefin. The resultant adducts can be further polymerized with acrylic monomers via free radical or radiation curing mechanisms or quaternized to improve dispersion in aqueous systems.
摘要翻译：提供多官能丙烯酸酯和胺封端的聚烯烃的加合物。通过丙烯酸酯和胺封端的聚烯烃的迈克尔加成反应制备加合物。所得到的加合物可以通过自由基或辐射固化机理与丙烯酸单体进一步聚合或季铵化以改进含水体系中的分散体。

7. 发明授权

US06184338B2 Anionic polymerization initiators containing tertiary amine functionality, their chain extended analogues, and processes for using the same 失效
标题翻译：含有叔胺官能团的阴离子聚合引发剂，其扩链类似物及其使用方法
公开(公告)号：US06184338B2
公开(公告)日：2001-02-06
申请号：US09139222
申请日：1998-08-24
申请人： James A. Schwindeman , Robert J. Letchford
发明人： James A. Schwindeman , Robert J. Letchford
IPC分类号： C08G1200
CPC分类号： C08F36/04 , C08F4/46
摘要： The present invention provides novel anionic polymerization amine initiators having a tertiary amine group pendant to the polymer chain and processes for making the same. The initiators can be useful in the preparation of tertiary amine containing polymers, including linear, homotelechelic, heterotelechelic and radial polymers.
摘要翻译：本发明提供了具有与聚合物链相连的叔胺基团的新的阴离子聚合胺引发剂及其制备方法。引发剂可用于制备含叔胺的聚合物，包括线性，均酮，超远距离和径向聚合物。

8. 发明授权

US06720391B2 Functionalized initiators for anionic polymerization, protected functionalized polymers, deprotected analogues thereof, and methods of making the same 失效
标题翻译：用于阴离子聚合的官能化引发剂，保护的官能化聚合物，其去保护的类似物及其制备方法
公开(公告)号：US06720391B2
公开(公告)日：2004-04-13
申请号：US10062331
申请日：2002-02-01
申请人： James Anthony Schwindeman , Robert J. Letchford , Eric John Granger , Roderic P. Quirk
发明人： James Anthony Schwindeman , Robert J. Letchford , Eric John Granger , Roderic P. Quirk
IPC分类号： C08F818
CPC分类号： C08C19/44 , C07F1/02 , C08F36/04 , C08F4/48
摘要： The present invention provides functionalized electrophiles, their analogous initiators, and processes for preparing these compounds. The present invention also relates to homotelechelic, heterotelechelic, and radial functional polydiene polymers, polyarylene polymers and polydiene/polyarylene copolymers, their optionally hydrogenated analogues, their optionally deprotected analogues, and processes for preparing these functionalized polymers.
摘要翻译：本发明提供功能化的亲电子试剂，它们的类似的引发剂，以及制备这些化合物的方法。本发明还涉及同基亚类，异触耳和径向功能聚二烯聚合物，聚亚芳基聚合物和聚二烯/聚亚芳基共聚物，它们任选氢化的类似物，它们任选脱保护的类似物，以及制备这些官能化聚合物的方法。

9. 发明授权

US6160054A Hetero-telechelic polymers and processes for making same 失效
标题翻译：杂环聚合物和制备相同的方法
公开(公告)号：US6160054A
公开(公告)日：2000-12-12
申请号：US687111
申请日：1996-07-18
申请人： James A. Schwindeman , Robert J. Letchford , Conrad W. Kamienski , Roderic P. Quirk
发明人： James A. Schwindeman , Robert J. Letchford , Conrad W. Kamienski , Roderic P. Quirk
IPC分类号： C08C19/44 , C08F4/46 , C08F4/48 , C08F4/72 , C08F8/00 , C08F12/04 , C08F36/04 , C08F297/04 , C08F8/30 , C08F8/46
CPC分类号： C08F36/04 , C08C19/44 , C08F4/46 , C08F4/48 , C08F4/72 , C08F8/34 , C08F12/04 , C08F2810/40 , C08F112/08
摘要： Hetero-telechelic polymers having the formula:FG--(Q).sub.d --Z--J--[A(R.sup.1 R.sup.2 R.sup.3)].sub.x (I)wherein FG is a protected or non-protected functional group; Q is a saturated or unsaturated hydrocarbyl group derived by incorporation of a compound selected from the group consisting of conjugated diene hydrocarbons, alkenylsubstituted aromatic hydrocarbons, and mixtures thereof; d is an integer from 10 to 200; Z is a branched or straight chain hydrocarbon group which contains 3-25 carbon atoms, optionally containing aryl or substituted aryl groups; J is oxygen, sulfur, or nitrogen; [A(R.sup.1 R.sup.2 R.sup.3)].sub.x is a protecting group, wherein A is an element selected from Group IVa of the Periodic Table of Elements; R.sup.1, R.sup.2, and R.sup.3 are each independently selected from the group consisting of hydrogen, alkyl, substituted alkyl groups containing lower alkyl, lower alkylthio, and lower dialkylamino groups, aryl or substituted aryl groups containing lower alkyl, lower alkylthio, and lower dialkylamino groups, and cycloalkyl and substituted cycloalkyl containing 5 to 12 carbon atoms; and x is dependent on the valence of J and varies from one when J is oxygen or sulfur to two when J is nitrogen, with the proviso J and FG are not the same, and processes for making the same.
摘要翻译：具有式FG-（Q）d-Z-J- [A（R 1 R 2 R 3）] x（I）的异烟酰基聚合物，其中FG是受保护或未被保护的官能团; Q是通过引入选自共轭二烯烃，烯基取代的芳族烃及其混合物的化合物衍生的饱和或不饱和烃基; d为10〜200的整数; Z是含有3-25个碳原子的支链或直链烃基，任选含有芳基或取代的芳基; J是氧，硫或氮; [A（R1R2R3）] x为保护基，其中A为选自元素周期表第Ⅳa族的元素; R 1，R 2和R 3各自独立地选自氢，烷基，含有低级烷基，低级烷硫基和低级二烷基氨基的取代烷基，含有低级烷基，低级烷硫基和低级二烷基氨基的芳基或取代芳基和含有5至12个碳原子的环烷基和取代的环烷基; 并且x取决于J的化合价，并且当J是氮时，当J是氧或硫时，J的值是不同的，条件是J和FG不相同，并且其制备方法。

10. 发明授权

US5919870A Functional telechelic star polymers 失效
标题翻译：功能遥爪星形聚合物
公开(公告)号：US5919870A
公开(公告)日：1999-07-06
申请号：US660658
申请日：1996-06-05
申请人： Robert J. Letchford , Conrad W. Kamienski , James A. Schwindeman
发明人： Robert J. Letchford , Conrad W. Kamienski , James A. Schwindeman
IPC分类号： C08C19/44 , C08F4/46 , C08F4/72 , C08F8/00 , C08F36/04 , C08F4/08 , C08F36/06
CPC分类号： C08F36/04 , C08C19/44 , C08F4/46 , C08F4/72
摘要： Protected functional initiators have been demonstrated to polymerize dienes and alkenyl substituted aromatics. The resultant living anions were linked with a coupling agent, such as divinylbenzene or tin tetrachloride, to afford a protected functionalized star polymer. Subsequent deprotection afforded a star polymer, with functional groups on the end of each arm of the star. The star polymer could be hydrogenated before or after removal of the protecting groups. The newly liberated functional groups can participate in further polymerization chemistry.
摘要翻译：已经证明保护的官能引发剂聚合二烯和烯基取代的芳族化合物。所得活性阴离子与偶联剂如二乙烯基苯或四氯化锡连接，得到受保护的官能化星形聚合物。随后的脱保护得到星形聚合物，其中每个臂的末端具有官能团。星形聚合物可以在除去保护基团之前或之后被氢化。新释放的官能团可以参与进一步的聚合化学。

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