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    • 3. 发明申请
    • Processes for producing cycloolefin addition polymer
    • 生产环烯加成聚合物的方法
    • US20040063873A1
    • 2004-04-01
    • US10466429
    • 2003-07-16
    • Kenzo OhkitaNoboru OshimaTakashi ImamuraTakashi Tsubouchi
    • C08F004/06
    • C08F32/00Y10S526/903
    • A cyclic olefin having a specific polar group is polymerized by addition polymerization in a hydrocarbon solvent, using a polymerization catalyst component containing (i) a specific transition metal compound, (ii) a Lewis acid compound and (iii) an alkyl aluminoxane, or the cyclic olefin is polymerized by addition polymerization in the hydrocarbon solvent, using the polymerization catalyst component, by further adding at least one aromatic vinyl compound and at least one cyclic nonconjugated polyene compound, or either one of them as a molecular weight modifier, thereby obtaining a cyclic olefinic addition polymer.
    • 使用含有(i)特定的过渡金属化合物,(ii)路易斯酸化合物和(iii)烷基铝氧烷的聚合催化剂组分的聚合催化剂组分,通过在烃溶剂中进行加成聚合来聚合具有特定极性基团的环状烯烃,或 通过进一步添加至少一种芳族乙烯基化合物和至少一种环状非共轭多烯化合物或其中任一种作为分子量调节剂,通过在烃溶剂中的加成聚合使用聚合催化剂组分使环烯烃聚合,得到 环烯烃加成聚合物。
    • 7. 发明申请
    • (Meth) acrylic acid (salt) polymer and its production process
    • (Meth)丙烯酸(盐)聚合物及其生产工艺
    • US20030149206A1
    • 2003-08-07
    • US10281971
    • 2002-10-29
    • Takashi TomitaTsutomu YuasaHirokatsu Kawakami
    • C08F004/06C08F004/28
    • C08F290/061C04B24/2647C04B2103/408C08F220/04C08F220/28C08F290/06C08F290/062
    • There is provided: a (meth)acrylic acid (salt) polymer which has high properties and is little colored; and a process which can produce this polymer with a high polymerization conversion without causing the corrosion of the reaction vessel. When a (meth)acrylic acid (salt) polymer is obtained by carrying out polymerization of an unsaturated monocarboxylic monomer (a) and an unsaturated polyalkylene glycolic monomer (b) with a polymerization initiator, either a redox polymerization initiator including hydrogen peroxide and a reducing agent is used as the polymerization initiator in a specific amount, or the unsaturated polyalkylene glycolic monomer is subjected to the polymerization in the form of an esterification reaction product as obtained by a process including the steps of: esterifying the unsaturated monocarboxylic monomer and a polyalkylene glycol in a specific charging ratio in the presence of an acid catalyst in a manner for a portion of the residual unsaturated monocarboxylic monomer as a starting raw material to remain; and then neutralizing the acid catalyst and the residual unsaturated monocarboxylic monomer (a) with a basic substance after the esterification; and the polymerization is carried out under conditions where the pH during the polymerization is in the range of 3.2 to 7.0.
    • 提供:具有高性能并且着色少的(甲基)丙烯酸(盐)聚合物; 以及可以在不引起反应容器的腐蚀的情况下以高聚合转化率生产该聚合物的方法。 当通过用聚合引发剂进行不饱和单羧酸单体(a)和不饱和聚亚烷基二醇单体(b)的聚合获得(甲基)丙烯酸(盐))聚合物时,可以使用包含过氧化氢的还原性氧化还原聚合引发剂 作为聚合引发剂使用,或不饱和聚亚烷基二醇单体以酯化反应产物的形式进行聚合,所述酯化反应产物通过包括以下步骤的方法得到:不饱和单羧酸单体和聚亚烷基二醇的酯化 在酸催化剂存在下,以残留不饱和单羧酸单体的一部分作为起始原料保留的方式,以特定的带电比例; 然后在酯化后用碱性物质中和酸催化剂和残余不饱和单羧酸单体(a); 聚合反应在聚合反应中的pH在3.2〜7.0的条件下进行。