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1. 发明授权

US06307067B1 Palladium and boron co-catalyzed addition of oxygen nucleophiles to vinyl epoxides 有权
标题翻译：钯和硼共催化加成氧亲核试剂到乙烯基环氧化物
公开(公告)号：US06307067B1
公开(公告)日：2001-10-23
申请号：US09390828
申请日：1999-09-07
申请人： Ernest John McEachern , Francisco Dean Toste , Barry Martin Trost
发明人： Ernest John McEachern , Francisco Dean Toste , Barry Martin Trost
IPC分类号： C07D31712
CPC分类号： C07D317/12 , C07B53/00 , C07C41/03 , C07D307/28 , C07D309/24 , C07D313/04 , C07D317/38 , C07C43/178 , C07C43/23 , C07C43/1787
摘要： Nucleophilic oxygen species, such as primary alcohols, carboxylates, and water, are added to vinyl epoxides in a highly regioselective and enantioselective manner, providing a convenient route to enantiomerically enriched 1,2-diols and oxygen-containing heterocycles. The reaction employs a chiral Pd(0) complex and a borane or borate as co-catalysts Also described are similar additions of nitrogen nucleophiles, and the addition of carbonates to vinyl epoxides using a chiral Pd(0) catalyst.
摘要翻译：将亲核氧，如伯醇，羧酸盐和水以高度区域选择性和对映选择性的方式加入到乙烯基环氧化物中，为对映体富集的1,2-二醇和含氧杂环提供了方便的途径。该反应采用手性Pd（0）络合物和硼烷或硼酸盐作为助催化剂。还描述了氮亲核试剂的相似添加剂，以及使用手性Pd（0）催化剂向碳酸酯环氧化物中加入碳酸酯。

2. 发明授权

US06670489B2 Process for producing cyclic formal 有权
公开(公告)号：US06670489B2
公开(公告)日：2003-12-30
申请号：US10221487
申请日：2002-09-13
申请人： Atsushi Koyama , Rikio Fujiwara , Hiroshi Nakatsui
发明人： Atsushi Koyama , Rikio Fujiwara , Hiroshi Nakatsui
IPC分类号： C07D31712
CPC分类号： C07D317/12
摘要： In producing a cyclic formal by feeding an alkylene glycol and a formaldehyde derivative as starting materials to a reaction vessel and reacting them in the presence of a catalyst, the value of amount of alkylene glycol (mole)/amount of formaldehyde derivative in terms of formaldehyde (mole) is kept at 0.02-0.95 at the time of feeding of the starting materials and at 1.05-50 at the time of reaction of the starting materials. According to this process, the amount of by-product impurities at the reaction step can be reduced, and an additional purification step of the cyclic formal is not needed or can be easily performed.

3. 发明授权

US06515145B2 Process for the production of carbonates that melt at a high temperature 失效
标题翻译：用于生产在高温下熔化的碳酸酯的方法
公开(公告)号：US06515145B2
公开(公告)日：2003-02-04
申请号：US09752118
申请日：2000-12-29
申请人： James R. Machac, Jr. , Edward T. Marquis , Howard P. Klein
发明人： James R. Machac, Jr. , Edward T. Marquis , Howard P. Klein
IPC分类号： C07D31712
CPC分类号： C07C68/04 , Y02P20/142 , C07C69/96
摘要： A method for preparing carbonates includes reacting an alkylene oxide with carbon dioxide in the presence of a catalyst and a non-protic solvent. The method further includes having the boiling point of the solvent greater than about 70 ° C., and removing the solvent from the reaction product. The solvent used in the various forms of the present invention can be glyme, diglyme, tetraglyme, cumene, toluene, tetrahydofuran, cyclohexanone, ethylbenzene, aromatic hydrocarbons, or ethers. The catalyst used can be a tetraalkyl ammonium halide, such as tetraethyl ammonium bromide. The alkylene oxide that can be used in the invention can include Bisphenol A, Bisphenol B, Bisphenol F, alkylene oxides that have alkyl substituent groups, alkylene oxides that have aryl substituent groups, and alkylene oxides that contain both alkyl and aryl substituent groups. An essentially solvent free carbonate can be prepared by flash removal of the solvent.
摘要翻译：制备碳酸酯的方法包括在催化剂和非质子溶剂的存在下使烯化氧与二氧化碳反应。该方法还包括使溶剂的沸点大于约70℃，并从反应产物中除去溶剂。用于本发明各种形式的溶剂可以是甘醇二甲醚，二甘醇二甲醚，四甘醇二甲醚，枯烯，甲苯，四氢呋喃，环己酮，乙苯，芳烃或醚。所使用的催化剂可以是四烷基卤化铵，例如四乙基溴化铵。可用于本发明的环氧烷可以包括双酚A，双酚B，双酚F，具有烷基取代基的烯化氧，具有芳基取代基的烯化氧和含有烷基和芳基取代基的烯化氧。可以通过快速除去溶剂来制备基本上无溶剂的碳酸盐。

4. 发明授权

US06515149B2 Acetal compound, polymer, resist composition and patterning response 有权
公开(公告)号：US06515149B2
公开(公告)日：2003-02-04
申请号：US09922635
申请日：2001-08-07
申请人： Takeru Watanabe , Takeshi Kinsho , Koji Hasegawa , Tsunehiro Nishi , Mutsuo Nakashima , Seiichiro Tachibana , Jun Hatakeyama
发明人： Takeru Watanabe , Takeshi Kinsho , Koji Hasegawa , Tsunehiro Nishi , Mutsuo Nakashima , Seiichiro Tachibana , Jun Hatakeyama
IPC分类号： C07D31712
CPC分类号： C08G61/08 , C08G61/02 , Y10S430/106 , Y10S430/111
摘要： Acetal compounds in which a 5- or 6-membered ring acetal structure is connected to a norbornene structure through a linker represented by —(CH2)m— in which one hydrogen atom may be substituted with a hydroxyl or acetoxy group, and m is from 1 to 8 are novel. Using the acetal compounds as a monomer, polymers are obtained. A resist composition comprising the polymer as a base resin is sensitive to high-energy radiation and has excellent sensitivity, resolution, and etching resistance.

5. 发明授权

US06388104B1 4-methylene-1,3-dioxolanes having functional groups 失效
标题翻译：具有官能团的4-亚甲基-1,3-二氧戊环
公开(公告)号：US06388104B1
公开(公告)日：2002-05-14
申请号：US09679066
申请日：2000-10-05
申请人： Helmut Hartl , Rainer B. Frings , Gerwald F. Grahe
发明人： Helmut Hartl , Rainer B. Frings , Gerwald F. Grahe
IPC分类号： C07D31712
CPC分类号： C08G65/331 , C07D317/12 , C07D317/16 , C07D317/24
摘要： Novel 4-methylene-1,3-dioxolanes of the general formula I in which R1 denotes hydrogen or alkyl, X denotes a single bond, C1-C18 alkylene, cycloalkylene, arylalkylene, —CH2(OCH2CH2)n— or —CH2(OCH(CH3)CH2)n—, in which n is an integer from 1 to 100, and Z means a functional group selected from among —OH, —COOR′ or —OCOR′, in which R′ denotes hydrogen or C1-C8 alkyl, are described, as are a process for the production thereof and the intermediates used in this process.
摘要翻译：具有通式Iin的新型4-亚甲基-1,3-二氧戊环，其中R 1表示氢或烷基，X表示单键，C 1 -C 18亚烷基，亚环烷基，芳基亚烷基，-CH 2（OCH 2 CH 2）n - 或-CH 2（OCH（ CH 3）CH 2）n - ，其中n是1至100的整数，Z表示选自-OH，-COOR'或-OCOR'的官能团，其中R'表示氢或C 1 -C 8烷基，以及其制备方法以及在该方法中使用的中间体。

6. 发明授权

US06699998B2 Non-aqueous electrolyte and lithium secondary battery using the same 有权
标题翻译：非水电解质和锂二次电池使用相同
公开(公告)号：US06699998B2
公开(公告)日：2004-03-02
申请号：US10109943
申请日：2002-03-29
申请人： Toshikazu Hamamoto , Koji Abe , Tsutomu Takai , Yasuo Matsumori
发明人： Toshikazu Hamamoto , Koji Abe , Tsutomu Takai , Yasuo Matsumori
IPC分类号： C07D31712
CPC分类号： H01M10/052 , H01M4/587 , H01M10/0525 , H01M10/0567 , H01M10/0569 , H01M2300/0025 , H01M2300/0037
摘要： A non-aqueous electrolyte comprising a non-aqueous solvent and a lithium salt dissolved therein, and a cyclic carbonate, linear carbonate, and vinylene carbonate having a chlorine content of 100 ppm or less, and a lithium secondary battery using the same.
摘要翻译：包含溶解在其中的非水溶剂和锂盐的非水电解质和氯含量为100ppm以下的环状碳酸酯，直链碳酸酯和碳酸亚乙烯酯，以及使用该非水电解质的锂二次电池。

7. 发明授权

US06395911B1 Process for cis-1{2-[4-(6-methoxy-2-phenyl-1,2,3,4-tetrahydronaphthalen-1-yl)phenoxy] ethyl}pyrrolidine 有权
公开(公告)号：US06395911B1
公开(公告)日：2002-05-28
申请号：US09974309
申请日：2001-10-09
申请人： Charles K. F. Chiu
发明人： Charles K. F. Chiu
IPC分类号： C07D31712
CPC分类号： C07D295/088 , C07C43/215 , C07C45/48 , C07C45/59 , C07C49/84 , C07C2602/10 , C07D317/22 , C07D317/26
摘要： This invention provides an improved process for cis-1-{2-[4-(6-methoxy-2-phenyl-1,2,3,4-tetrahydronaphthalen-1-yl)phenoxy]ethyl}pyrrolidine which is an intermediate for the preparation of (−)cis-6-phenyl-5-[4-(2-pyrrolidin-1-yl-ethoxy)-phenyl]-5,6,7,8-tetrahydronaphthalene-2-ol which is useful for the treatment of osteoporosis.

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