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    • 6. 发明授权
    • Mechanochemical fabrication of electroceramics
    • 电瓷机械化学制造
    • US06627104B1
    • 2003-09-30
    • US09720792
    • 2001-03-26
    • John WangDongmei WanJunmin Xue
    • John WangDongmei WanJunmin Xue
    • C04B3526
    • C04B35/64
    • Mechanochemical fabrication produces electroceramics using oxides as starting materials. The fabrication starts with mixing industrial ceramic oxide powders. Electroceramic phases are formed by reacting the oxide powders in a mechanochemical chamber, which is a wear-resistant cylindrical vial with one or more solid balls inside. The formation of electroceramic phases of pervoskite structure and fine crystallinity are activated by mechanical energy or a combination of mechanical energy and thermal energy. Sintered electroceramic materials and components are fabricated when compacts or green bodies made of the resulting ceramic powders are densified at the sintering temperature. The technique can fabricate a wide range of PbO-based ceramics such as Pb(Mg⅓Nb⅔)O3 (PMN), Pb(Mg⅓Nb⅔) O3-PbTiO3 (PMN-PT), Pb(Mg⅓Nb⅔) O3-Pb(Zn⅓Nb⅔)O3-PbTiO3 (PMN-PZN-PT), and other PMN-based relaxor ferroelectrics, Pb(Zr1−xTix)O3 (PZT) and PZT-based piezoelectrics at sintering temperatures as low as 900° C.
    • 机械化学制造生产使用氧化物作为起始材料的电陶瓷。 该制造从混合工业陶瓷氧化物粉末开始。 电陶瓷相通过使机械化学室中的氧化物粉末与内部具有一个或多个固体球的耐磨圆柱形小瓶反应形成。 钙钛矿结构和精细结晶度的电陶瓷相的形成由机械能或机械能和热能的组合激活。 烧结的电陶瓷材料和组件是在由所得陶瓷粉末制成的压块或生坯在烧结温度下致密化时制造的。 该技术可制备Pb(Mg1 / 3Nb2 / 3)O3(PMN),Pb(Mg1 / 3Nb2 / 3)O3-PbTiO3(PMN-PT),Pb(Mg1 / 3Nb2 / 3)O3-Pb(Zn1 / 3Nb2 / 3)O3-PbTiO3(PMN-PZN-PT)和其他PMN基弛豫铁电体,Pb(Zr1-xTix)O3(PZT)和PZT基压电体在烧结温度 低至900℃
    • 9. 发明授权
    • Mn-Zn ferrite and production process thereof
    • 锰锌铁氧体及其制备方法
    • US06468441B1
    • 2002-10-22
    • US09795133
    • 2001-03-01
    • Osamu KobayashiOsamu YamadaKiyoshi Ito
    • Osamu KobayashiOsamu YamadaKiyoshi Ito
    • C04B3526
    • C04B35/2658C04B35/265
    • The present invention provides a Mn—Zn ferrite having an electrical resistivity exceeding 1 &OHgr;m order and a low core loss in a high frequency region exceeding 1 MHz. A basic component composition of the Mn—Zn ferrite includes 44.0 to 49.8 mol % of Fe2O3, 6.0 to 15.0 mol % of ZnO (15.0 mol % is excluded), 0.1 to 3.0 mol % of CoO, 0.02 to 1.20 mol % of Mn2O3, and the remainder of MnO. The Mn—Zn ferrite achieves desired purposes by controlling Fe2O3 content to a range less than 50 mol % that is the stoichiometric composition, adding a proper amount of CoO, restraining amount of Mn2O3 formation to 1.20 mol % or less, and further setting their average grain sizes to less than 10 &mgr;m.
    • 本发明提供一种电阻率超过1欧姆等级的Mn-Zn铁氧体,超高于1MHz的高频区域的低铁损。 Mn-Zn铁氧体的基本成分组成包括Fe2O3为44.0〜49.8mol%,ZnO为6.0〜15.0mol%(不包括15.0mol%),CoO为0.1〜3.0mol%,Mn2O3为0.02〜1.20mol% 和剩余的MnO。 Mn-Zn铁氧体通过将Fe 2 O 3含量控制在化学计量组成小于50摩尔%的范围内,添加适量的CoO,抑制Mn2O3的形成量为1.20摩尔%以下,进一步设定其平均值 粒径小于10um。
    • 10. 发明授权
    • Mn-Zn ferrite and production process thereof
    • 锰锌铁氧体及其制备方法
    • US06461531B2
    • 2002-10-08
    • US09795116
    • 2001-03-01
    • Osamu KobayashiOsamu YamadaKiyoshi Ito
    • Osamu KobayashiOsamu YamadaKiyoshi Ito
    • C04B3526
    • C04B35/2658
    • The present invention provides a Mn—Zn ferrite having an electrical resistivity exceeding 1 &OHgr;m order and having a low core loss in a high frequency region exceeding 1 MHz. The basic component composition of the Mn—Zn ferrite includes 44.0 to 49.8 mol % Fe2O3, 6.0 to 15.0 mol % ZnO (15.0 mol % is excluded), 0.1 to 4.0 mol % at least one of TiO2 and SnO2, and remainder MnO, wherein desired results are obtained by limiting Fe2O3 content to less than 50 mol % that is the stoichiometric composition and adding a proper amount of TiO2 or SnO2 and further controlling its average grain size to less than 10 &mgr;m.
    • 本发明提供一种具有超过1欧姆等级的电阻率并且在超过1MHz的高频区域具有低铁损的Mn-Zn铁氧体。 Mn-Zn系铁氧体的基本成分组成包括Fe2O3为44.0〜49.8mol%,ZnO为6.0〜15.0mol%(不包括15.0mol%),TiO 2和SnO 2中的至少一种为0.1〜4.0mol%,余量为MnO,其中, 通过将Fe 2 O 3含量限制为小于化学计量组成的50mol%并加入适量的TiO 2或SnO 2并进一步控制其平均晶粒尺寸小于10um而得到期望的结果。