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    • 1. 发明申请
    • Method for killing organicsms in the course of conveying ballast water in ships and apparatus thereof
    • 在船舶运送压载水过程中杀死有机物的方法及其装置
    • US20040251215A1
    • 2004-12-16
    • US10864966
    • 2004-06-10
    • Mindong BaiXiyao BaiXiaojian ZhouZhitao ZhangMindi BaiBo YangChengwu Yi
    • C02F001/72
    • C02F1/4608C02F2001/46185C02F2103/008C02F2303/04C02F2305/023
    • The present invention relates to gaseous discharge and applied biotechnology. In particularly, the present invention relates to a method for killing organisms in the course of conveying ballast water in ship, comprising applying a voltage with frequency of 400-40000 Hz between the anode electrode and the cathode electrode of the free radical generator, thereby forming strong ionization discharge of electric field strength of 250-600 Td between the anode electrode and the cathode electrode, ionizing, dissociating, and exciting O2 and H2O, or O2, processing into active particles comprising O3, OHnulland HO2, dissolving excitately to obtain free radical solution mainly consisted of OHnull, adding the free radical solution to conveying pipeline of ballast water, conveying for 2-20 s in the pipeline, thereby obtaining killing organisms of ballast water selected from the group consisted of bacteria, single cell alga, and protozoan. It is capable to kill harmful invading microorganisms in the course of transporting ballast water without leaving any residual chemical reagent. The bacteria, single cell alga, protozoan, spore and vibrio, are eliminated and decomposed into H2O, O2, and small inorganic salt. It has no pollution and discharge, therefore, it can solve the problem of environmental pollution. The apparatus of carrying out above method comprises medium-high frequency electric source, ejector, gas liquid dissolution separator, liquid-liquid mixer, residual free radical treater, wherein a free radical generator is installed between the said ejector and the input raw material gas. The present method is capable of improving the quality of ballast water and is simple in operation and inexpensive.
    • 本发明涉及气体排放和应用生物技术。 特别地,本发明涉及在船舶运送压载水的过程中杀死生物体的方法,包括在自由基发生器的阳极和阴极之间施加400-40000Hz频率的电压,从而形成 强电离放电的阳极电极和阴极之间的电场强度为250-600Td,电离,离解和激发O 2和H 2 O或O 2,加工成包含O 3,OH +和HO 2的活性粒子,兴奋地溶解 得到主要由OH +组成的自由基溶液,将压载水输送管道添加自由基溶液,在管道中输送2-20秒,从而获得选自细菌, 单细胞藻和原生动物。 在运输压载水的过程中能够杀死有害入侵的微生物,而不会留下任何残留的化学试剂。 细菌,单细胞藻,原生动物,孢子和弧菌被消除并分解成H 2 O,O 2和小无机盐。 没有污染排放,因此可以解决环境污染问题。 实施上述方法的装置包括中高频电源,喷射器,气液分离器,液 - 液混合器,残余自由基处理器,其中在所述喷射器和输入原料气体之间安装有自由基发生器。 本方法能够提高压载水的质量,操作简单,成本低廉。
    • 2. 发明申请
    • Apparatus for purification of industrial wastewater with thin film fixed bed TiO2 photocatalyst
    • 用薄膜固定床TiO2光催化剂净化工业废水的设备
    • US20040182792A1
    • 2004-09-23
    • US10392386
    • 2003-03-20
    • Machiraju SubrahmanyamPierre BouleDurga Kumari ValluriMaddigapu Pratap ReddyMohammed NoorjahanKondapuram Vijaya Raghavan
    • C02F001/72
    • C02F1/725B01J21/063B01J35/004B01J37/0232C02F1/32C02F2305/10Y02W10/37
    • An apparatus for the photocatalyitc oxidation of common industrial effluent contaminants in aqueous solution includes a reactor and a thin film photocatalyst fixed to a support material like Cuddapah stone. The support material is preferably an inert material. The TiO2 preformed does not contain any adsorbent for making the thin film photocatalyst, The catalytic runs were carried out over TiO2 thin film fixed bed reactor. The study is extended to the immobilization of preformed TiO2 with a binder for making thin film using a simple spray technique on inert Cuddapah stone. This method of immobilization require no thermal treatment of the catalyst at high temperatures. The method is applicable for the photocatalytic treatment of industrial effluents at a higher scale. Also it is a method for preparing a photocatalyst adopted for the oxidation of industrial common effluent by simple spray technique. Also it is a method and apparatus for destroying industrial common effluent contaminants in aqueous solution
    • 用于水溶液中常见工业污水污染物的光催化氧化的装置包括固定到诸如Cuddapah石之类的载体材料的反应器和薄膜光催化剂。 载体材料优选为惰性材料。 预制的TiO2不含用于制备薄膜光催化剂的任何吸附剂。催化运行在TiO2薄膜固定床反应器上进行。 该研究扩展到使用简单的喷雾技术在惰性Cuddapah石上制备薄膜的预制TiO 2的固定化。 这种固定方法不需要在高温下对催化剂进行热处理。 该方法适用于较高规模的工业废水的光催化处理。 也是通过简单喷涂技术制备用于工业普通流出物氧化的光催化剂的方法。 还有一种破坏水溶液中工业常见污染物的方法和装置
    • 5. 发明申请
    • Method for treating waste by hydrothermal oxidation
    • 通过水热氧化处理废物的方法
    • US20030189012A1
    • 2003-10-09
    • US10362675
    • 2003-02-24
    • Francois Cansell
    • C02F001/72
    • C02F1/72B01J3/008B01J3/042B01J19/2415B01J2219/0009B01J2219/00135B01J2219/00162C02F1/722C02F1/78C02F11/086Y02P20/544
    • The invention concerns a method for oxidising organic matter contained in an aqueous effluent and an installation for implementing said method. Said method comprises the following steps: injecting into a tubular body said aqueous effluent; bringing said aqueous effluent to a pressure P1, corresponding to the critical pressure of said aqueous effluent; bringing said aqueous effluent to a temperature T1; and injecting into said tubular body at n points spaced apart from one another, n fractions of at least an oxidising composition, so that a portion of the thermal energy produced by the oxidation reaction increases the temperature of the reaction mixture from said temperature T1 to temperature T2>T1 according to an increasing curve, whereby said organic matter is oxidised, said reaction mixture continuously developing from a sub-critical liquid state to the supercritical domain.
    • 本发明涉及用于氧化含水流出物中含有的有机物质的方法和用于实施所述方法的装置。 所述方法包括以下步骤:将管状体注入所述含水流出物; 使所述含水流出物达到对应于所述含水流出物的临界压力的压力P1; 使所述含水流出物达到温度T1; 并且在彼此间隔开的n个点处注入所述管状体,至少一个氧化组合物的n个部分,使得由氧化反应产生的热能的一部分将反应混合物的温度从所述温度T1升高到温度 T2> T1,其中所述有机物质被氧化,所述反应混合物从亚临界液体状态连续发展到超临界域。
    • 7. 发明申请
    • Process and system for the self-regulated remediation of groundwater
    • 地下水自主调节的过程和系统
    • US20030155309A1
    • 2003-08-21
    • US10366966
    • 2003-02-14
    • A. Russell Schindler
    • C02F001/72
    • C02F1/008B09C1/002C02F1/72C02F1/722C02F2103/06C02F2209/001C02F2209/03C02F2209/22C02F2209/24
    • A process and system for the self-regulated remediation of groundwater situated beneath the surface of a contaminated ground site is herein proposed. The process includes the steps of selecting a ground site to be tested for potential contamination, extracting soil gas samples from interspersed locations within an underground soil layer, gleaning information from the extracted soil gas samples to both determine the extent of any contamination and delimit any specific area of contamination at the selected ground site, determining both an appropriate concentration of a preselected oxidant or oxygen-releasing agent within a solution and an appropriate flow rate of injection according to the determined extent of contamination, determining both an appropriate number of groundwater injection points and an appropriate spacing between the groundwater injection points according to the delimited specific area of contamination, and delivering the determined preselected oxidant solution under pressure into the groundwater within the delimited specific area of contamination via the groundwater injection points at the determined injection flow rate.
    • 本文提出了一种用于对受污染地面的地表下方进行自我调节的地下水修复的方法和系统。 该过程包括以下步骤:选择要测试潜在污染的地面现场,从地下土壤层内的散布位置提取土壤气体样品,从提取的土壤气体样品中清除信息,以确定任何污染的程度,并界定任何特定 在选定的场地的污染区域,根据确定的污染程度确定溶液中预选的氧化剂或释氧剂的合适浓度和适当的注射流速,确定适当数量的地下水注入点 以及根据划定的污染特定区域的地下水注入点之间的适当间距,以及在确定的注射流程下经由地下水注入点将确定的预选氧化剂溶液在压力下输送到限定的特定污染区域内的地下水中 te。
    • 8. 发明申请
    • Synergistic combination of metal ions with an oxidizing agent and algaecide to reduce both required oxidizing agent and microbial sensitivity to fluctuations in oxidizing agent concentration, particularly for swimming pools
    • 金属离子与氧化剂和除藻剂的协同组合以减少所需的氧化剂和微生物对氧化剂浓度波动的敏感性,特别是对于游泳池
    • US20020144958A1
    • 2002-10-10
    • US09828566
    • 2001-04-05
    • Jonathan Sherman
    • C02F001/72C02F001/50
    • C02F1/72C02F1/505C02F2103/42Y10S210/908
    • A water purification system and method suitable for use in swimming pools, spas, hot tubs, water storage tanks, wells and water cooling towers adds (i) an oxidizing agent, preferably granulated or caked chlorine, (ii) metal ions, preferably silver from a galvanic cell having a silver anode electrically connected to a cathode made from a metal of still higher electrochemical potential, normally platinum, and, optionally (iii) an algaecide, preferably chelated copper and/or phosphate-removing compound, and/or (iv) a phosphate-reducing compound, all in synergistic combination. The galvanic cell is preferably some tens of square centimeters in size and some tens of grams in weight, thereby liberating sufficient silver or copper ions so as to aid in treating a multi-thousand liter body of water, such as a swimming pool, for, typically under normal contamination, some weeks to months until the anode is consumed. Copper and/or silver ions liberated from the galvanic cell cooperate with oxidizing agent to suppress bacterial, fungal and/or algae growth, particularly when new supply of oxidizing agent ceases for a prolonged time, normally >2 days. The (i) amount of chlorine, bromine or other chemicals needed to maintain water quality is thus significantly reduced to the greatly enhanced comfort of bathers while the (ii) time during which recovery can graciously be made from an exhausted supply of oxidizing agent is usefully extended.
    • 适用于游泳池,水疗中心,热水浴缸​​,储水罐,水井和水冷却塔的净水系统和方法,添加了(i)氧化剂,优选颗粒状或结块的氯,(ii)金属离子,优选为银 具有银阳极的电池电连接到由更高电化学电位的金属制成的阴极,通常为铂,和任选地(iii)除藻剂,优选螯合的铜和/或磷酸盐去除化合物,和/或 )磷酸盐还原化合物,全部具有协同组合。 原电池的尺寸优选为几十平方厘米,重量为几十克,从而释放足够的银或铜离子,以帮助处理诸如游泳池的数千升体积的水, 通常在正常污染下,几周到几个月直到阳极消耗。 从原电池释放的铜离子和/或银离子与氧化剂配合以抑制细菌,真菌和/或藻类的生长,特别是当新的氧化剂供应长时间停止时,通常> 2天。 因此,(i)维持水质所需的氯,溴或其他化学物质的量因此显着降低到大大增加了泳客的舒适度,而(ii)可以从耗尽的氧化剂供应中慷慨地恢复的时间是有用的 延长
    • 9. 发明申请
    • Feeder and method for preparing aqueous solutions containing high concentrations of solid oxidizers
    • 用于制备含有高浓度固体氧化剂的水溶液的进料器和方法
    • US20020084228A1
    • 2002-07-04
    • US10025194
    • 2001-12-19
    • LONZA, INC.
    • Philip Gerdon SweenyJames Howard Harvey
    • C02F001/72
    • B01F1/0022B01F15/00123B01F15/00422B01F15/026B01F15/0292B01F15/0441B01F15/0479C02F1/72C02F2209/03C02F2209/42
    • A continuous method is provided for dissolving a solid oxidizer into an aqueous solution which yields a stream of the aqueous solution having a constant or near constant concentration of solid oxidizer. The method of the present invention includes (a) disposing a bed of solid oxidizer into a container; (b) introducing an aqueous solution below the top surface of the bed; and (c) removing any solution above the top surface of the bed while maintaining a constant or near constant level of aqueous solution above the bed. Preferably, step (c) is performed at about atmospheric pressure. This method can be achieved with a feeder that includes a tank for containing a bed of solid oxidizer and a disperser for introducing the aqueous solution into the tank. A sensor/control unit is provided for sensing a combined bed and aqueous solution volume within the tank and maintaining the combined volume within a predetermined range.
    • 提供了将固体氧化剂溶解在水溶液中的连续方法,其产生具有恒定或接近恒定浓度的固体氧化剂的水溶液流。 本发明的方法包括(a)将固体氧化剂床放入容器中; (b)在床的顶表面下方引入水溶液; 和(c)在床的顶表面上除去任何溶液,同时保持在床上方恒定或接近恒定水平的水溶液。 优选地,步骤(c)在约大气压下进行。 该方法可以通过包括用于容纳固体氧化剂床的罐和用于将水溶液引入罐中的分散器的进料器来实现。 提供传感器/控制单元,用于感测罐内的组合床和水溶液体积,并将组合体积保持在预定范围内。