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    • 3. 发明授权
    • Coproducing alumina, iron oxide, and titanium-dioxide from aluminum ore bodies and feedstocks
    • 从铝矿体和原料生产氧化铝,氧化铁和二氧化钛
    • US06447738B1
    • 2002-09-10
    • US09648300
    • 2000-08-24
    • John S. RendallMassoud AhgharJerry V. FoxFred A. Aiken
    • John S. RendallMassoud AhgharJerry V. FoxFred A. Aiken
    • C01F700
    • C22B34/125C01D5/00C01F7/26C01G23/053C01G23/0532C01G49/06C22B3/08C22B21/0015Y02P10/234
    • A process for the extraction of alumina, iron oxide and titanium dioxide from bauxite ore and clays, and other ore bodies and feedstocks. The process starts by sulfuric acid leaching of the feedstocks in pressure autoclaves at about 200° C. and appropriate pressure. A leach liquor of sulfate salts of aluminum, iron and titanium is obtained. Any iron values are converted to a ferrous state. A recycled potassium sulfate helps produce double aluminum alkali sulfate crystals in the reduced leach liquor. The crystals are removed at about 20°-60° C. with the help of SO2 gases that reduce the ferric. Such double salt is hydrolyzed into a basic aluminum alkali precipitated sulfate salt. This is then dried and calcined at about 950° C. Any alkali sulfate is washed out and recycled. The remainder is alumina. The ferrous sulfate is crystallized out at about 10° C. It is dried and calcined at about 450° C. to produce an iron oxide mixed with other sulfate salts that can be washed out and recycled.
    • 从铝土矿和粘土以及其他矿体和原料中提取氧化铝,氧化铁和二氧化钛的方法。 该过程开始于在约200℃的压力高压釜中的原料硫酸浸出和适当的压力。 得到铝,铁和钛的硫酸盐的浸出液。 任何铁价值都转为有色金属。 回收的硫酸钾有助于在还原的浸出液中产生双重碱式硫酸铝晶体。 借助SO2气体,在约20°-60°C下除去晶体,减少三价铁。 这种双盐水解成碱式铝碱析出的硫酸盐。 然后将其干燥并在约950℃下煅烧。任何碱性硫酸盐被洗涤并再循环。 剩余部分是氧化铝。 硫酸亚铁在约10℃下结晶出来。将其干燥并在约450℃下煅烧以产生与其它硫酸盐混合的氧化铁,其可被洗涤和回收。
    • 5. 发明授权
    • Method for producing calcium compounds containing water of crystallization
    • 含有结晶水的钙化合物的制备方法
    • US06814947B1
    • 2004-11-09
    • US09831451
    • 2001-11-29
    • Josef LehmkuhlAnsgar FendelHubert Bings
    • Josef LehmkuhlAnsgar FendelHubert Bings
    • C01F700
    • C09K21/02C01F7/004D21H17/675D21H19/385
    • The invention relates to the production of calcium compounds containing water of crystallization by means of a chemical reaction between an aqueous alkaline sodium aluminate solution and solid or dissolved or suspended calcium (hydr)-oxide in the presence of carbon dioxide or carbonate; and to the use of these compounds. The resulting precipitate is separated by sedimentation, dehydration, drying and/or clacination and/or grinding or suspending the resulting filter cake and reacted with at least one mineral acid and/or at least one salt of the same. The resulting precipitate, which contains water of crystallization, is separated by sedimentation, dehydration, drying and/or grinding. The resulting compounds can be used as fillers or as extra white pigments for producing and surface-treating paper, cardboard or card, for producing paints and lacquers, as a flame-retardant filler for fire-protecting construction materials and as a filler for producing plasterboards or building slabs or as a hydraulically active additive for producing expansive cements, expansive plasters and screeds and as a swelling component for explosion-protected explosives.
    • 本发明涉及通过碱性铝酸钠水溶液与固体或溶解或悬浮的二(二氧化碳)氧化物在二氧化碳或碳酸盐存在下的化学反应来生产含水结晶的钙化合物; 以及这些化合物的使用。 所得沉淀物通过沉淀,脱水,干燥和/或剥离和/或研磨或悬浮所得滤饼并与至少一种无机酸和/或其至少一种盐反应而分离。 含有结晶水的所得沉淀物通过沉降,脱水,干燥和/或研磨分离。所得化合物可用作填料或作为额外的白色颜料用于生产和表面处理纸,纸板或卡片,用于生产 油漆和漆,作为防火建筑材料的阻燃填料,以及用于生产石膏板或建筑板材的填料或作为生产膨胀水泥,膨胀灰泥和砂浆的水硬性添加剂,以及用于防爆材料的膨胀组分 炸药
    • 6. 发明授权
    • Process for the production of alumina
    • 氧化铝生产工艺
    • US06576204B2
    • 2003-06-10
    • US09773561
    • 2001-02-02
    • Keld Johansen
    • Keld Johansen
    • C01F700
    • C01F7/24C01F7/308
    • A process for the production of alumina is performed by dissolving gibbsite Al2O3.3H2O in nitric acid to provide an acid solution containing aluminum nitrate; decomposing the acid solution at 300-700° C. with a free air supply to form alumina and Nox by spraying onto the inner surface of one or more rotary kilns, drying in a fluid bed, or drying in a steel belt conveyor furnace; regenerating the formed NOx into concentrated nitric acid and recycling the nitric acid to be used for the dissolving of gibbsite; and recovering the alumina formed upon decomposing the acid solution.
    • 氧化铝的制造方法是将三水铝矿Al 2 O 3·3H 2 O溶解在硝酸中,得到含有硝酸铝的酸溶液; 用自由空气供应在300-700℃下分解酸溶液,通过喷洒到一个或多个旋转窑的内表面上,在流化床中干燥或在钢带输送机炉中干燥来形成氧化铝和Nox; 将形成的NOx再生成浓硝酸并再循环用于三水铝矿溶解的硝酸; 并回收在分解酸溶液时形成的氧化铝。
    • 9. 发明授权
    • Bauxite ore digestion in the bayer process
    • 铝土矿矿石在拜耳过程中消化
    • US06555076B1
    • 2003-04-29
    • US09601854
    • 2000-09-22
    • Bernard DroyDany Michaux
    • Bernard DroyDany Michaux
    • C01F700
    • C01F7/062
    • The process according to the invention to raise simultaneously to an optimum level the temperature and concentration of an aqueous medium intended for use in bauxite ore digestion in an alumina production plant according to the Bayer process, which includes successive phases (a) to (f) in which: a) the aqueous medium coming from digestion containing pregnant liquor is cooled and evaporated in a multiple staged flash evaporation zone; b) the sterile residue is separated, the aluminium trihydroxide is precipitated and the aqueous medium, consisting of spent liquor, intended for use in digestion is recovered; c) if need be, the required quantity of water, additional to that already evaporated in phase (a) is eliminated by evaporation in a specific evaporation section; d) the aqueous medium intended for use in digestion is heated in several stages; e) the flash vapour generated in each of the stages of the evaporation phase (a) is used in each of the stages of the heating phase (d); f) the aqueous medium intended for use in digestion coming from the heating phase (d) is heated by live steam. is characterised in that, in addition to all these phases, a simultaneous heating and evaporation phase is carried out on the aqueous medium intended for use in digestion.
    • 根据本发明的方法同时提高根据拜耳方法在氧化铝生产设备中用于铝土矿矿石消解的水性介质的温度和浓度的最佳水平,其包括连续阶段(a)至(f) 其中:a)来自含有怀疑液体的消化的水性介质被冷却并在多级闪蒸蒸发区中蒸发; b)分离无菌残余物,沉淀出三氢氧化铝,并将由废液组成的含水介质 回收用于消化的用途; c)如果需要,在特定蒸发段中通过蒸发消除在相(a)中已蒸发的所需量的水,d)用于消化的水性介质为 在几个阶段加热; e)在加热阶段(d)的每个阶段中使用在蒸发阶段(a)的每个阶段中产生的闪蒸蒸气; f)水中 我们用于来自加热阶段(d)的消化的培养基通过活蒸汽加热。其特征在于,除了所有这些相之外,在用于以下的水性介质中进行同时加热和蒸发阶段 消化。
    • 10. 发明授权
    • Zeolite beta and its use in aromatic alkylation
    • 沸石β及其在芳族烷基化中的应用
    • US06440886B1
    • 2002-08-27
    • US09705615
    • 2000-11-03
    • Gregory J. GajdaRichard T. Gajek
    • Gregory J. GajdaRichard T. Gajek
    • C01F700
    • B01J29/7007B01J29/7415B01J2229/26B01J2229/42C07C2/66C07C6/126C07C2529/70Y02P20/52Y10S423/27C07C15/085
    • There is disclosed a new form of zeolite beta which shows substantially greater stability and greater catalyst lifetime when used in the alkylation and transalkylation of aromatic compounds. The new, surface-modified zeolite beta is characterized by having surface aluminum 2p binding energies, as measured by X-ray photoelectron spectroscopy, of at least 74.8 electron volts. This surface-modified zeolite beta is prepared by treating an as synthesized and templated zeolite beta with an acid at a pH between about 0 and about 2 at a temperature up to about 125° C. for a time sufficient to modify the chemical environment of the surface aluminum atom without bringing about dealumination of the zeolite beta, then calcining the acid-treated templated material at 550-700° C. to remove the template.
    • 公开了一种新型沸石β,当用于芳族化合物的烷基化和烷基转移时,其表现出显着更大的稳定性和更大的催化剂寿命。 新的表面改性沸石β的特征在于具有至少74.8电子伏特的通过X射线光电子能谱测量的表面铝2p结合能。 该表面改性沸石β通过在约至约125℃的温度下用pH在约0和约2之间的酸处理合成的和模板化的沸石β来制备,时间足以改变化合物的化学环境 表面铝原子,而不会使β沸石脱铝,然后在550-700℃煅烧酸处理的模板材料以除去模板。