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1. 发明授权

US06506358B1 Process for the preparation of quasi-crystalline boehmites 失效
标题翻译：制备准晶体勃艮第的方法
公开(公告)号：US06506358B1
公开(公告)日：2003-01-14
申请号：US09636694
申请日：2000-08-11
申请人： Dennis Stamires , Paul O'Connor , Gregory Pearson , William Jones
发明人： Dennis Stamires , Paul O'Connor , Gregory Pearson , William Jones
IPC分类号： C01F700
CPC分类号： C01F7/448 , B01J21/04 , C01F7/34 , C01F7/36 , C01P2002/04 , C01P2002/72
摘要： The present invention pertains to an improved process for the preparation of quasi-crystalline boehmite. In this improved process a quasi-crystalline boehmite precursor is aged at a pH below 7, prefereably under hydrothermal conditions. It was found that when conducting the preparation processes for quasi-crystalline aluminas described in the prior art at a pH below 7 and under hydrothermal conditions instead of the high pH and thermal aging used in the prior art, QCBs with higher crystallinity are obtained. In the process according to the invention additives may be added to the quasi-crystalline boehmite precursor. This results in a high quality QCB with additives in a homogeneously dispersed state. Suitable additives are compounds containing elements selected from the group of rare earth metals alkaline earth metals, transition metals, actinides, silicon, gallium, boron, and phosphorus.
摘要翻译：本发明涉及制备准晶状勃姆石的改进方法。在这种改进的方法中，准结晶勃姆石前体在pH低于7的条件下老化，优选在水热条件下。发现在现有技术中描述的准晶体氧化铝的制备方法在pH低于7且在水热条件下代替现有技术中使用的高pH和热老化，获得具有较高结晶度的QCB。在根据本发明的方法中，可以将添加剂加入到准结晶勃姆石前体中。这导致具有均匀分散状态的添加剂的高质量QCB。合适的添加剂是含有选自稀土金属碱土金属，过渡金属，锕系元素，硅，镓，硼和磷的元素的化合物。

2. 发明授权

US06503867B1 Quasi-crystalline boehmites containing additives 失效
标题翻译：准晶体含有添加剂的勃艮第
公开(公告)号：US06503867B1
公开(公告)日：2003-01-07
申请号：US09636690
申请日：2000-08-11
申请人： Dennis Stamires , Paul O'Connor , Gregory Pearson , William Jones
发明人： Dennis Stamires , Paul O'Connor , Gregory Pearson , William Jones
IPC分类号： B01J2300
CPC分类号： C04B35/62605 , B01J21/04 , B01J21/12 , B01J23/02 , B01J23/06 , B01J23/08 , B01J23/10 , B01J23/28 , B01J23/70 , B01J23/75 , B01J23/755 , B01J23/882 , B01J23/883 , B01J35/002 , B01J37/03 , B01J37/036 , B01J37/10 , C01F7/02 , C01P2002/72 , C04B2235/3215 , C04B2235/3218 , C04B2235/3256 , C04B2235/3275 , C04B2235/3279 , C04B2235/3284 , C04B2235/3286
摘要： The present invention pertains to a quasi-crystalline boehmite containing additive in a homogeneously dispersed state. Suitable additives are compounds containing elements selected from the group of alkaline earth metals, alkaline metals, transition metals, actinides, silicon, gallium, boron, titanium, and phosphorus. Said QCBs according to the invention may be prepared in several ways. In general, a quasi-crystalline boehmite precursor and an additive are converted to a quasi-crystalline boehmite containing the additive in a homogeneously dispersed state.
摘要翻译：本发明涉及具有均匀分散状态的含有准结晶勃姆石的添加剂。合适的添加剂是含有选自碱土金属，碱金属，过渡金属，锕系元素，硅，镓，硼，钛和磷中的元素的化合物。根据本发明的所述QCB可以以几种方式制备。通常，将准晶体勃姆石前体和添加剂转化为含有均匀分散状态的添加剂的准晶体勃姆石。

3. 发明授权

US06555496B1 Micro-crystalline boehmites containing additives 失效
标题翻译：含有添加剂的微晶布氏体
公开(公告)号：US06555496B1
公开(公告)日：2003-04-29
申请号：US09636688
申请日：2000-08-11
申请人： Dennis Stamires , Paul O'Connor , Gregory Pearson , William Jones
发明人： Dennis Stamires , Paul O'Connor , Gregory Pearson , William Jones
IPC分类号： B01J2340
CPC分类号： B01J20/08 , B01J21/04 , C01F7/02 , C01P2002/72
摘要： A microcrystalline boehmite containing additive in a homogeneously dispersed state. Suitable additives are compounds containing elements selected from the group consisting of alkaline earth metals, alkaline metals, rare earth metals, transition metals, actinides, silicon, gallium, boron, titanium, and phosphorus. The microcrystalline boehmite according to the invention may be prepared in several ways. In general, a microcrystalline boehmite precursor and an additive are converted to a microcrystalline boehmite containing the additive in a homogeneously dispersed state. The additive does not contain zirconia or magnesia.
摘要翻译：含有均匀分散状态的含微晶勃姆石的添加剂。合适的添加剂是含有选自碱土金属，碱金属，稀土金属，过渡金属，锕系元素，硅，镓，硼，钛和磷的元素的化合物。根据本发明的微晶勃姆石可以以几种方式制备。通常，微晶勃姆石前体和添加剂以均匀分散的状态转化为含有添加剂的微晶勃姆石。添加剂不含氧化锆或氧化镁。

4. 发明申请

US20060096891A1 Quasi-crystalline boehmites containing additives 失效
标题翻译：准晶体含有添加剂的勃艮第
公开(公告)号：US20060096891A1
公开(公告)日：2006-05-11
申请号：US10298734
申请日：2002-11-18
申请人： Dennis Stamires , Paul O'Connor , Gregory Pearson , William Jones
发明人： Dennis Stamires , Paul O'Connor , Gregory Pearson , William Jones
IPC分类号： B01J27/187 , B01J27/182 , C10G11/04 , C10G47/04
CPC分类号： C10G11/02 , B01J21/04 , B01J21/12 , B01J23/02 , B01J23/06 , B01J23/08 , B01J23/10 , B01J23/16 , B01J23/22 , B01J23/28 , B01J23/70 , B01J23/75 , B01J23/755 , B01J23/882 , B01J23/883 , B01J29/0308 , B01J29/041 , B01J29/08 , B01J29/40 , B01J35/002 , B01J37/03 , B01J37/036 , B01J37/10 , C01F7/02 , C01F7/448 , C01P2002/52 , C01P2002/72 , C10G11/04 , C10G11/08 , C10G11/18 , C10G45/04 , C10G45/12 , C10G45/34 , C10G45/46 , C10G45/54 , C10G45/60 , C10G45/64 , C10G47/02 , C10G47/16 , C10G49/02 , C10G49/08
摘要： The present invention pertains to a quasi-crystalline boehmite containing additive in a homogeneously dispersed state. Suitable additives are compounds containing elements selected from the group of alkaline earth metals, alkaline metals, rare earth metals, transition metals, actinides, silicon, gallium, boron, titanium, and phosphorus. Said QCBs according to the invention may be prepared in several ways. In general, a quasi-crystalline boehmite precursor and an additive are converted to a quasi-crystalline boehmite containing the additive in a homogeneously dispersed state.
摘要翻译：本发明涉及具有均匀分散状态的含有准结晶勃姆石的添加剂。合适的添加剂是含有选自碱土金属，碱金属，稀土金属，过渡金属，锕系元素，硅，镓，硼，钛和磷中的元素的化合物。根据本发明的所述QCB可以以几种方式制备。通常，将准晶体勃姆石前体和添加剂转化为含有均匀分散状态的添加剂的准晶体勃姆石。

5. 发明授权

US06689333B1 Process for the preparation of quasi-crystalline boehmites from inexpensive precursors 有权
标题翻译：用于从廉价前驱物制备准晶体波音的方法
公开(公告)号：US06689333B1
公开(公告)日：2004-02-10
申请号：US09636692
申请日：2000-08-11
申请人： Dennis Stamires , Paul O'Connor , Gregory Pearson , William Jones
发明人： Dennis Stamires , Paul O'Connor , Gregory Pearson , William Jones
IPC分类号： C01F700
CPC分类号： C01F7/448 , B01J21/04 , B01J23/10 , B01J37/10 , C01F7/34 , C01P2002/04 , C01P2002/74
摘要： The present invention pertains to cheaper process for the preparation of quasi-crystalline boehmite containing additive in a homogeneously dispersed state. In this cheaper process an inexpensive quasi-crystalline boehmite precursor is and additive are combined and aged to form a quasi-crystalline boehmite containing additive in a homogeneously dispersed state. Suitable inexpensive quasi-crystalline boehmite precursors are aluminum trihydrate and thermally treated forms thereof and inorganic aluminum salts. Suitable additives are compounds containing elements selected from the group of rare earth metals alkaline earth metals, transition metals, actinides, silicon, gallium, boron, and phosphorus.
摘要翻译：本发明涉及制备具有均匀分散状态的含准结晶勃姆石的添加剂的较便宜的方法。在这种更便宜的方法中，廉价的准晶体勃姆石前体和添加剂结合并老化以形成均匀分散状态的含有添加剂的准晶体勃姆石。合适的廉价准晶体勃姆石前体是三水合铝和其热处理形式和无机铝盐。合适的添加剂是含有选自稀土金属碱土金属，过渡金属，锕系元素，硅，镓，硼和磷的元素的化合物。

6. 发明授权

US07208446B2 Quasi-crystalline boehmites containing additives 失效
标题翻译：准晶体含有添加剂的勃艮第
公开(公告)号：US07208446B2
公开(公告)日：2007-04-24
申请号：US10298734
申请日：2002-11-18
申请人： Dennis Stamires , Paul O'Connor , Gregory Pearson , William Jones
发明人： Dennis Stamires , Paul O'Connor , Gregory Pearson , William Jones
IPC分类号： B01J23/00 , B01J21/02 , B01J27/14 , C04B35/10 , C01F7/02
CPC分类号： C10G11/02 , B01J21/04 , B01J21/12 , B01J23/02 , B01J23/06 , B01J23/08 , B01J23/10 , B01J23/16 , B01J23/22 , B01J23/28 , B01J23/70 , B01J23/75 , B01J23/755 , B01J23/882 , B01J23/883 , B01J29/0308 , B01J29/041 , B01J29/08 , B01J29/40 , B01J35/002 , B01J37/03 , B01J37/036 , B01J37/10 , C01F7/02 , C01F7/448 , C01P2002/52 , C01P2002/72 , C10G11/04 , C10G11/08 , C10G11/18 , C10G45/04 , C10G45/12 , C10G45/34 , C10G45/46 , C10G45/54 , C10G45/60 , C10G45/64 , C10G47/02 , C10G47/16 , C10G49/02 , C10G49/08
摘要： The present invention pertains to a quasi-crystalline boehmite containing additive in a homogeneously dispersed state. Suitable additives are compounds containing elements selected from the group of alkaline earth metals, alkaline metals, rare earth metals, transition metals, actinides, silicon, gallium, boron, titanium, and phosphorus. Said QCBs according to the invention may be prepared in several ways. In general, a quasi-crystalline boehmite precursor and an additive are converted to a quasi-crystalline boehmite containing the additive in a homogeneously dispersed state.
摘要翻译：本发明涉及具有均匀分散状态的含有准结晶勃姆石的添加剂。合适的添加剂是含有选自碱土金属，碱金属，稀土金属，过渡金属，锕系元素，硅，镓，硼，钛和磷中的元素的化合物。根据本发明的所述QCB可以以几种方式制备。通常，将准晶体勃姆石前体和添加剂转化为含有均匀分散状态的添加剂的准晶体勃姆石。

7. 发明申请

US20080032884A1 Process for the Preparation of an Additive-Containing Anionic Clay 审中-公开
标题翻译：制备含添加剂的阴离子粘土的方法
公开(公告)号：US20080032884A1
公开(公告)日：2008-02-07
申请号：US11587395
申请日：2005-04-26
申请人： William Jones , Dennis Stamires , Paul O'Connor , Michael Brady
发明人： William Jones , Dennis Stamires , Paul O'Connor , Michael Brady
IPC分类号： B01J21/16
CPC分类号： B01J21/16 , B01J23/007 , B01J23/10 , B01J37/0036
摘要： Process for the preparation of an additive-containing anionic clay comprising the steps of (a) milling a physical mixture of a divalent metal compound and a trivalent metal compound, (b) calcining the physical mixture at a temperature in the range 200-800° C., and (c) rehydrating the calcined mixture in aqueous suspension, wherein an additive is present in the physical mixture and/or the aqueous suspension of step (c). With this process additive-containing anionic clays with a homogeneous additive distribution can be prepared.
摘要翻译：制备含添加剂的阴离子粘土的方法包括以下步骤：（a）研磨二价金属化合物和三价金属化合物的物理混合物，（b）在200-800℃的温度下煅烧该物理混合物和（c）在水悬浮液中再水化煅烧的混合物，其中添加剂存在于步骤（c）的物理混合物和/或水悬浮液中。使用该方法可以制备具有均匀添加剂分布的含添加剂的阴离子粘土。

8. 发明授权

US07022304B2 Doped anionic clays 有权
公开(公告)号：US07022304B2
公开(公告)日：2006-04-04
申请号：US10072630
申请日：2002-02-07
申请人： Dennis Stamires , William Jones , Paul O'Connor
发明人： Dennis Stamires , William Jones , Paul O'Connor
IPC分类号： C01F7/00
CPC分类号： C01B13/363 , B01J21/005 , B01J21/16 , B01J23/007 , C01B13/322 , C01B13/366 , C01F7/005 , C01F7/162 , C01F17/0043 , C01P2002/22 , C01P2002/50 , C01P2002/52 , C04B35/44 , C09C1/42
摘要： The present invention is directed to a process for the preparation of a doped anionic clay. In said process a trivalent metal source is reacted with a divalent metal source, at least one of the metal sources being either doped boehmite, doped MgO or doped brucite, to obtain a doped anionic clay. Suitable dopants are compounds containing elements selected from the group of alkaline earth metals (for instance Ca and Ba), alkaline metals, transition metals (for example Co, Mn, Fe, Ti, Zr, Cu, Ni, Zn, Mo, W, V, Sn), actinides, rare earth metals such as La, Ce, and Nd, noble metals such as Pt and Pd, silicon, gallium, boron, titanium, and phosphorus.

9. 发明授权

US07576024B2 Catalyst composition comprising anionic clay and rare earth metals, its preparation and use in FCC 有权
标题翻译：包含阴离子粘土和稀土金属的催化剂组合物，其制备和用于FCC
公开(公告)号：US07576024B2
公开(公告)日：2009-08-18
申请号：US10582177
申请日：2004-12-06
申请人： William Jones , Dennis Stamires , Paul O'Connor , Michael F. Brady
发明人： William Jones , Dennis Stamires , Paul O'Connor , Michael F. Brady
IPC分类号： B01J29/06
CPC分类号： B01J21/16 , B01J23/10 , B01J37/03 , C10G11/04 , C10G11/18
摘要： The invention relates to a composition comprising anionic clay and rare earth metal hydroxy carbonate. This composition can suitably be used in FCC for the reduction of NOx and/or SOx emissions, the reduction of the S and/or N-content in fuels, and as a metal trap.The composition can be prepared by precipitating a divalent metal salt, a trivalent metal salt, and a rare earth metal salt to form a precipitate, calcining the precipitate at 200-800° C., and rehydrating the precipitate in the presence of a carbonate source to form a composition comprising anionic clay and a rare earth metal hydroxy carbonate.
摘要翻译：本发明涉及包含阴离子粘土和稀土金属羟基碳酸酯的组合物。该组合物可以适当地用于FCC中用于还原NOx和/或SO x排放，降低燃料中的S和/或N含量，以及作为金属阱。该组合物可以通过沉淀二价金属盐，三价金属盐和稀土金属盐来制备，以形成沉淀物，在200-800℃下煅烧沉淀物，并在碳酸盐源存在下再沉淀沉淀物以形成包含阴离子粘土和稀土金属羟基碳酸酯的组合物。

10. 发明申请

US20070191213A1 Metal-containing compositions and their use as catalyst composition 审中-公开
标题翻译：含金属的组合物及其作为催化剂组合物的用途
公开(公告)号：US20070191213A1
公开(公告)日：2007-08-16
申请号：US10557921
申请日：2004-05-19
申请人： William Jones , Paul O'Connor , Dennis Stamires
发明人： William Jones , Paul O'Connor , Dennis Stamires
IPC分类号： B01J38/00 , B01J29/06
CPC分类号： B01D53/508 , B01D53/565 , B01D53/8609 , B01D53/8628 , B01D2255/2047 , B01D2255/20723 , B01D2255/20761 , B01D2255/20769 , B01D2255/20776 , B01D2255/9202 , B01D2257/2045 , B01D2257/2064 , B01D2257/406 , B01D2257/408 , B01J23/002 , B01J23/007 , B01J23/06 , B01J23/22 , B01J23/30 , B01J23/72 , B01J23/83 , B01J23/8472 , B01J23/885 , B01J29/0308 , B01J29/041 , B01J37/04 , B01J37/30 , B01J2523/00 , C01B13/145 , C01G1/02 , C01G31/00 , C01G39/00 , C01G41/00 , C01P2002/22 , C01P2004/62 , C10G2/33 , C10G11/182 , C10G29/06 , C10G29/16 , C10G45/04 , C10G45/58 , Y02P20/154 , B01J2523/12 , B01J2523/27 , B01J2523/31 , B01J2523/69 , B01J2523/55 , B01J2523/68 , B01J2523/17 , B01J2523/3712 , B01J2523/22
摘要： Metal-containing composition and use thereof in catalytic reactions, which metal-containing composition is obtainable by contacting a metal hydroxy salt with a solution comprising one or more pH-dependent anions selected from the group consisting of pH-dependent boron-containing anions, vanadium-containing anions, tungsten-containing anions, molybdenum-containing anions, iron-containing anions, niobium-containing anions, tantalum-containing anions, aluminium-containing anions, and gallium-containing anions.
摘要翻译：含金属组合物及其在催化反应中的用途，该含金属组合物可通过使金属羟基盐与包含一种或多种pH依赖性阴离子的溶液接触而获得，所述pH依赖性阴离子选自pH依赖性含硼阴离子，钒含阴离子，含钼阴离子，含铁阴离子，含铌阴离子，含钽阴离子，含铝阴离子和含镓阴离子。

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