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    • 10. 发明专利
    • DE2358499A1
    • 1974-06-06
    • DE2358499
    • 1973-11-23
    • SUN VENTURES INC
    • SCHNEIDER ABRAHAM ISAACMOORE ROBERT EMERY
    • B01J21/00B01J27/00B01J29/00B01J35/10C07B61/00C07C1/00C07C5/27C07C9/16C07C67/00C07C5/24C10G35/06B01J11/78B01J11/40
    • 1406967 Isomerizing paraffins SUN RESEARCH & DEVELOPMENT CO 23 Nov 1973 [24 Nov 1972] 54398/73 Heading C5E C 6+ paraffins, substantially free of unsaturated hydrocarbons, are isomerized in the presence of a catalyst comprising a mixture of AlCl 3 and a partially dehydrated adsorbent comprising Al 2 O 3 , SiO 2 or an aluminosilicate of surface area 50-300 m. 2 /g. and average pore diameter 30- 350 Š, in the liquid phase at 0-130‹ C. in the presence of a side-reaction suppressor comprising an adamantoid hydrocarbon selected from adamantane, C 11 -C 20 alkyl adamantanes having 1-3 alkyl substituents, diamantane and C 15 -C 24 monoalkyl diamantanes in which the alkyl substituent is attached at a bridgehead position through a primary carbon atom. The isomerization is preferably carried out in the presence of a minor amount of HCl, HBr or saturated chloro- or bromo-hydrocarbon as promoter. Preferred suppressors are adamantane or C 11 -C 14 , alkyladamantanes having up to 3 methyl or ethyl groups. Preferred halohydrocarbon promoters are CCl 4 , CHCl 3 , CH 2 Cl 2 , dichlorethane, isopropylchloride and t-butyl chloride. For feedstocks containing C 7 and higher paraffins it is beneficial to carry out the isomerization in the presence of H 2 , e.g. a partial pressure of 20-500 p.s.i. An inert halohydrocarbon solvent, e.g. 1,1,2,2,-tetrachloroethane may be used and is essential when the paraffin feed is normally a solid at the reaction temperature.