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    • 5. 发明专利
    • DE2062293B2
    • 1980-11-20
    • DE2062293
    • 1970-12-17
    • SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V., DEN HAAG (NIEDERLANDE)
    • ZWET, HENRY VAN, AMSTERDAMBAUER, SHERMAN RONALD, ORINDAKEIM, WILHELM, BERKELEY
    • C07C2/30B01J31/00C07B61/00C07C1/00C07C2/34C07C11/02C07C67/00C08F4/00
    • 1285299 Ethylene oligomerisation catalysts SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ NV 17 Dec 1970 [19 Dec 1969] 59948/70 Heading B1E [Also in Divisions C3 and C5] An ethylene oligomerisation catalyst comprises a product of the reaction between an olefin-nickel compound and a fluorine-containing compound selected from trifluoroacetic acid, trifluoroacetylacetone, hexafluoroacetylacetone, hexafluoropropene and 4, 4, 4-trifluoro-3-hydroxy-3-trifluoromethylbutyric acid. The specification lists numerous suitable olefinnickel compounds which are #-allyl nickel salts, bis-#-allyl nickel compounds and zerovalent nickel compounds, for example bis (cyclooctadiene) nickel (O), bis (cyclooctatetraene) nickel (O) and bis (1, 3, 7-octatriene) nickel (O); it is preferred that the or each olefin moiety forming part of the olefin-nickel compound has from 2 to 20 carbon atoms and not more than 4 olefinic linkages and/or not more than 3 carbocyclic rings. In preparing the catalyst it is preferred to use between 0.5 and 12 moles of fluorine-containing compound per mole of olefin-nickel compound. The catalyst may be supported on inorganic carrier material selected from acid-treated clays, kieselguhr crystalline macroreticular aluminosilicates (molecular sieves) and acidic oxides; exemplified acidic oxides are alumina, silica-alumine, silica-magnesia, silica-alumina-magnesia, silica-alumina-titania and silica-alumina-zirconia and silica-titania-zirconia. A composition comprising aforementioned reaction product and carrier material may contain from 0.01 to 70 parts by weight of reaction product per 100 parts by weight of carrier material. Examples relate to unsupported catalysts prepared from bis (1, 5- cyclooctadiene) nickel (O) and one of each of the five specified fluorine-containing compounds (Examples I, II and V to VIII) and to supported catalysts prepared from bis (1, 5-cyclooctadiene) nickel (O), trifluoroacetic acid and esither silica-alumina (Example III) or alumina (Example IV).