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    • 4. 发明授权
    • Method for uniformly doping hemispherical grain polycrystalline silicon
    • 均匀掺杂半球状晶粒多晶硅的方法
    • US5885869A
    • 1999-03-23
    • US528183
    • 1995-09-14
    • Charles TurnerRandhir P. S. Thakur
    • Charles TurnerRandhir P. S. Thakur
    • H01L21/22H01L21/02H01L21/3215H01L21/334H01L21/822H01L21/8242H01L27/04H01L27/10H01L27/108H01L21/20
    • H01L28/84H01L21/32155H01L27/10808H01L29/66181Y10S148/014Y10S148/122Y10S148/138
    • A method is disclosed for uniformly doping HSG polycrystalline silicon independent of the other layers of the semiconductor substrate. A semiconductor substrate having a silicon dioxide layer formed superjacent a polysilicon layer is provided in a chamber. A doped rough silicon layer is formed in situ superjacent the silicon dioxide layer. This is accomplished by depositing the silicon layer superjacent the silicon dioxide layer and exposing the silicon layer to a source gas, a dopant gas, and energy, preferably in situ to thereby form uniformly doped silicon layer and roughened polysilicon layer using rapid thermal chemical vapor deposition techniques or low pressure chemical vapor deposition.Alternatively, a uniformly doped roughened polysilicon layer is formed superjacent the silicon dioxide layer in situ. This formation is achieved by depositing an amorphous silicon layer superjacent the silicon dioxide layer and roughening the amorphous silicon layer in situ. The step of roughening is achieved by vacuum annealing the amorphous silicon layer using rapid thermal chemical vapor deposition techniques or low pressure chemical vapor deposition. The roughened amorphous silicon layer is doped by exposing to a source gas, a dopant gas and energy.
    • 公开了与半导体衬底的其他层无关的均匀掺杂HSG多晶硅的方法。 具有在多晶硅层之上形成的二氧化硅层的半导体衬底设置在室中。 掺杂的粗硅层原位形成在二氧化硅层的上方。 这是通过沉积超过二氧化硅层的硅层并将硅层暴露于源气体,掺杂剂气体和能量,优选在原位,由此形成均匀掺杂的硅层和使用快速热化学气相沉积的粗糙多晶硅层 技术或低压化学气相沉积。 或者,原位形成在二氧化硅层之上的均匀掺杂的粗糙多晶硅层。 通过沉积位于二氧化硅层之上的非晶硅层并原位粗化非晶硅层来实现该形成。 通过使用快速热化学气相沉积技术或低压化学气相沉积对非晶硅层进行真空退火来实现粗糙化的步骤。 粗糙化的非晶硅层通过暴露于源气体,掺杂剂气体和能量而被掺杂。
    • 6. 发明授权
    • Semiconductor processing method of providing a conductively doped layer
of hemispherical grain polysilicon
    • 提供半导体晶粒多晶硅的导电掺杂层的半导体加工方法
    • US5639685A
    • 1997-06-17
    • US539851
    • 1995-10-06
    • John K. ZahurakKlaus F. SchuegrafRandhir P. S. Thakur
    • John K. ZahurakKlaus F. SchuegrafRandhir P. S. Thakur
    • H01L21/02H01L21/70
    • H01L28/84Y10S148/138
    • A semiconductor processing method of providing a conductively doped layer of hemispherical grain polysilicon over a substrate includes, a) providing a layer of conductively doped silicon over the substrate to a thickness greater than about 200 Angstroms; b) depositing an undoped layer of non-polycrystalline silicon over the doped silicon layer to a thickness of from 100 Angstroms to about 400 Angstroms; c) positioning the substrate with the doped silicon and undoped non-polycrystalline silicon layers within a chemical vapor deposition reactor; d) with the substrate therein, lowering pressure within the chemical vapor deposition reactor to a first pressure at or below about 200 mTorr; e) with the substrate therein, raising pressure within the chemical vapor deposition reactor from the first pressure and flushing the reactor with a purging gas; f) with the substrate therein ceasing flow of the purging gas and lowering pressure within the chemical vapor deposition reactor to a second pressure at or below about 200 mTorr; and g) annealing the substrate having the deposited non-polycrystalline silicon layer in the presence of a conductivity enhancing impurity gas at an annealing temperature of from about 350.degree. C. to about 600.degree. C. and at an annealing pressure of from about 10.sup.-4 Torr to about 80 Torr to in situ both diffuse conductivity enhancing impurity into the non-polycrystalline silicon layer and transform the non-polycrystalline silicon layer into a conductively doped hemispherical grain polysilicon layer.
    • 在衬底上提供半球形晶粒多晶硅的导电掺杂层的半导体处理方法包括:a)在衬底上提供厚度大于约200埃的导电掺杂硅层; b)在掺杂硅层上沉积未掺杂的非多晶硅层至厚度为100埃至约400埃; c)将衬底与掺杂的硅和未掺杂的非多晶硅层定位在化学气相沉积反应器内; d)与其中的基底,将化学气相沉积反应器内的压力降低到等于或低于约200mTorr的第一压力; e)与其中的基板,从第一压力升高化学气相沉积反应器内的压力并用净化气体冲洗反应器; f)其中衬底在其中停止清洗气体的流动并且将化学气相沉积反应器内的压力降低至等于或低于约200mTorr的第二压力; 以及g)在约350℃至约600℃的退火温度和约10℃的退火温度下,在导电性增强杂质气体存在下退火具有沉积的非多晶硅层的衬底, 4乇至约80乇原位扩散导电性增强杂质进入非多晶硅层,并将非多晶硅层转变为导电掺杂半球形晶粒多晶硅层。
    • 10. 发明专利
    • Manufacture of semiconductor device
    • 半导体器件的制造
    • JPS60189971A
    • 1985-09-27
    • JP4521684
    • 1984-03-09
    • Toshiba Corp
    • USAMI TOSHIROUMIKATA YUUICHISHINADA KAZUYOSHI
    • H01L29/78H01L21/28
    • H01L21/28273Y10S148/053Y10S148/138Y10S148/169
    • PURPOSE: To contrive the improvement in characteristic of withstand voltage of the oxide film on an amorphous single crystal Si film and in leakage characteristic by a method wherein an amorphous single crystal Si film serving as the first gate electrode is deposited on a semiconductor substrate and an insulation film is then formed thereon, through which an impurity is ion-implanted to the amorphous single crystal Si film, and the insulation film is removed; thereafter, the second gate oxide film is formed on the surface of the amorphous single crystal Si film.
      CONSTITUTION: A field oxide film 22 is formed on the surface of the P
      - type Si substrate 21 having a crystal orientation of (100); thereafter, the first gate oxide film 23 is formed on the surface of the substrate 21 surrounded by the oxide film 22 by heat treatment. Next, the first polycrystalline Si film 24 of no doping is deposited over the entire surface. Phosphorus is ion-implanted to the polycrystalline Si film 24 through a CVD oxide film 25. After annealing in a nitrogen atmosphere, the oxide film 25 is removed. Then, the second gate oxide film 26 is formed on the surface of the polycrystalline Si film 24. The second polycrystalline Si film 27, second gate oxide film 26, first polycrystalline film 24, and first gate oxide film 23 are successively removed by etching.
      COPYRIGHT: (C)1985,JPO&Japio
    • 目的:通过在半导体衬底上沉积作为第一栅电极的非晶单晶Si膜而将半导体衬底上的氧化物膜的耐电压特性提高到非晶单晶硅膜的漏电特性, 然后在其上形成绝缘膜,将杂质离子注入到非晶单晶Si膜中,并除去绝缘膜; 此后,在非晶单晶Si膜的表面上形成第二栅氧化膜。 构成:在具有(100)晶体取向的P型Si衬底21的表面上形成场氧化膜22。 此后,通过热处理在由氧化物膜22包围的基板21的表面上形成第一栅极氧化膜23。 接下来,在整个表面上沉积无掺杂的第一多晶Si膜24。 通过CVD氧化膜25将磷离子注入到多晶硅膜24中。在氮气气氛中退火后,除去氧化膜25。 然后,在多晶硅膜24的表面上形成第二栅极氧化膜26.通过蚀刻,依次除去第二多晶Si膜27,第二栅极氧化膜26,第一多晶膜24和第一栅极氧化膜23。