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    • 5. 发明授权
    • Method and device for determining the total oxygen content and/or the total carbon content in ammonia
    • 用于测定氨中总氧含量和/或总碳含量的方法和装置
    • US07907283B2
    • 2011-03-15
    • US12282996
    • 2007-03-22
    • Karl-Heinz WostbrockWalther Schmid
    • Karl-Heinz WostbrockWalther Schmid
    • G01N31/12G01N21/35
    • G01N31/007G01N21/31
    • The invention relates to a process for determining the total oxygen content and the total carbon content in ammonia, in which ammonia is first split into nitrogen and hydrogen, then the oxygen still present in the ammonia is reacted essentially fully with hydrogen to give water and the carbon still present is reacted essentially fully with hydrogen to give methane. In a next step, the water content and the methane content in the gas are determined. Finally, the total oxygen content is determined from the water content and the total carbon content from the methane content. The invention further relates to an apparatus for performing the process, which comprises a cracker for splitting the ammonia and for converting the oxygen- and/or carbon-comprising compounds, and at least one cavity ring-down spectrometer for detecting the water content and/or carbon content. The cracker and the at least one spectrometer, and also all devices and connecting lines between the cracker and the spectrometer, are surrounded by an inert gas.
    • 本发明涉及一种确定氨中总氧含量和总碳含量的方法,其中氨首先分解成氮和氢,然后氨中仍然存在的氧基本上与氢反应,得到水, 仍然存在的碳基本上与氢反应以产生甲烷。 在下一步骤中,确定气体中的含水量和甲烷含量。 最后,总含氧量由水含量和甲烷含量的总碳含量确定。 本发明还涉及一种用于执行该方法的装置,其包括用于分解氨并用于转化含氧和/或含碳化合物的裂化器,以及用于检测含水量和/或含碳化合物的至少一个空腔下降光谱仪, 或碳含量。 裂化器和至少一个光谱仪以及裂解器和光谱仪之间的所有装置和连接线都被惰性气体包围。