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1. 发明公开

EP0066714A3 Reactive dyestuffs 失效
标题翻译：反应性试验
公开(公告)号：EP0066714A3
公开(公告)日：1983-08-03
申请号：EP82103835
申请日：1982-05-05
申请人： BASF Aktiengesellschaft
发明人： Augart, Dietmar, Dr. , Krueger, Heinz, Dr.
IPC分类号： C09B62/008 , D06P03/66
CPC分类号： C09B62/0067
摘要： Die Erfindung betrifft sulfonsäuregruppenhaltige Ver bindungen der allgemeinen Formel I in der
D den Rest einer Diazokomponente,
X einen faserreaktiven Rest,
m die Zahlen 1 oder 2, für m = 1 XB = X und für m = 2 B ein Brückenglied,
p die Zahlen 0 oder 1 und
A einen Rest der Formeln bedeuten, wobei
R¹ Wasserstoff, gegebenenfalls substituiertes Alkyl oder Phenyl,
R² Wasserstoff, gegebenenfalls substituiertes Alkyl oder Phenyl,
R³ gegebenenfalls substituiertes Amino oder Hydroxy,
Y Sauerstoff oder gegebenenfalls substituiertes Imino und
Y¹ Sauerstoff oder gegebenenfalls substituiertes Imino sind und wobei
R¹ und Y¹ oder R¹ und R³ zu einem Ring verknüpft sein können und
A weder der Barbitursäurerest noch ein Triaminopyri midinrest ist.
Die erfindungsgemäßen Verbindungen eignen sich vor züglich zum Färben hydroxylgruppenhaltiger Fasern.
摘要翻译：其中D是重氮组分的基团，X是纤维反应性基团，m是1或2，如果m是1，XB是X，并且如果m是2， B是桥连构件，p是0或1，A是式“IMAGE”或“IMAGE”的基团，其中R 1是氢，取代或未取代的烷基或苯基，R 2是氢，被取代的或未取代的烷基或苯基，R 3是取代或未取代的氨基或羟基，Y是氧或取代或未取代的亚氨基，Y 1是氧或取代或未取代的亚氨基，其中R 1和Y 1和 R 1和R 3可以连接在一起形成环，并且A既不是巴比妥酸根也不是三氨基嘧啶基，高度适合于染色含羟基纤维。

2. 发明公开

EP0066714A2 Reaktivfarbstoffe 失效
标题翻译： Reaktivfarbstoffe。
公开(公告)号：EP0066714A2
公开(公告)日：1982-12-15
申请号：EP82103835.3
申请日：1982-05-05
申请人： BASF Aktiengesellschaft
发明人： Augart, Dietmar, Dr. , Krueger, Heinz, Dr.
IPC分类号： C09B62/006 , D06P3/66
CPC分类号： C09B62/0067
摘要： Die Erfindung betrifft sulfonsäuregruppenhaltige Verbindungen der allgemeinen Formel 1
in der

D den Rest einer Diazokomponente,
X einen faserreaktiven Rest,
m die Zahlen 1 oder 2, für m = 1 X-B = X und für m
= 2 B ein Brückenglied,
p die Zahlen 0 oder 1 und
A einen Rest der Formeln
bedeuten, wobei
R' Wasserstoff, gegebenenfalls substituiertes Alkyl oder Phenyl,
R 2 Wasserstoff, gegebenenfalls substituiertes Alkyl oder Phenyl,
R 3 gegebenenfalls substituiertes Amino oder Hydroxy,
Y Sauerstoff oder gegebenenfalls substituiertes Imino und
Y' Sauerstoff oder gegebenenfalls substituiertes Imino sind und wobei
R' und Y' oder R' und R 3 zu einem Ring verknüpft sein können und
A weder der Barbitursäurerest noch ein Triaminopyrimidinrest ist.

Die erfindungsgemäßen Verbindungen eignen sich vorzüglich zum Färben hydroxylgruppenhaltiger Fasern.
摘要翻译：其中D是重氮组分的基团，X是纤维反应性基团，m是1或2，如果m是1，XB是X，并且如果m是2， B是桥连构件，p是0或1，A是式“IMAGE”或“IMAGE”的基团，其中R 1是氢，取代或未取代的烷基或苯基，R 2是氢，被取代的或未取代的烷基或苯基，R 3是取代或未取代的氨基或羟基，Y是氧或取代或未取代的亚氨基，Y 1是氧或取代或未取代的亚氨基，其中R 1和Y 1和 R 1和R 3可以连接在一起形成环，并且A既不是巴比妥酸根也不是三氨基嘧啶基，高度适合于染色含羟基纤维。

3. 发明授权

US3905950A Reactive disazo dyestuffs containing 1-aminoalkyl-6-hydroxypyrid-6-one and monochlorotriazinyl groupings 失效
标题翻译：含有1-氨基烷基-6-羟基吡啶-6-酮和一氯三嗪基的活性双偶氮染料
公开(公告)号：US3905950A
公开(公告)日：1975-09-16
申请号：US36668673
申请日：1973-06-04
申请人： ICI LTD
发明人： CRABTREE ALLEN
IPC分类号： C09B62/006 , C09B62/04 , C09B62/09 , C09B62/08 , D06P1/38 , D06P3/60
CPC分类号： C09B62/043 , C09B62/0067 , C09B62/09
摘要： Disazo dyestuffs of the formula:

wherein N IS 0, 1 OR 2 P IS 0, 1 OR 2 Q IS 2 OR 3 AND Q is a member of the group consisting of 4,6-disulpho-1,3phenylene, 2,5-disulpho-1,4-phenylene,

D R A W I N G
in which Q1 is a direct link or -CH CH-, -NH-CONH-, -S-, OCH2CH2O-, -CH2- or -CH2CH2- . These dyestuffs are greenish-yellow cellulose-reactive dyes of good fastness to washing, light, hypochlorite bleaching and to acid and alkali treatments. Mixtures with phthalocyanine dyes exhibit better resistance to catalytic wet fading than similar dyes based on pyrazolone coupling components.
摘要翻译：下式的二重唑染料：SO3H | |（HO3S）n CH3 | N = N |（CH2）pH | CqH2qNHNCl角度角CC | PARALLEL NN ANGLE C | NH | Q | NH | C ANGLE NN | PARALLEL CC | PARALLEL | | CqH2qNHNCl | N = N|（CH2）pH | CH3（HO3S）n | | SO3H其中N IS 0，1 OR 2 P IS 0,1或2 Q IS 2 OR 3，Q是由 4,6-二磺基-1,3-亚苯基，2,5-二磺基-1,4-亚苯基，SO 3 HHO 3 S || NHCONH-和（2）SO 3 H | -Q1-- | HO 3 S（3）其中Q1是直链或-CH = CH-，-NH-CONH-，-S-，-OCH 2 CH 2 O-，-CH 2 - 或-CH 2 CH 2 - 。

4. 发明授权

US3725383A 2-hydroxy-pyrid-6-one azo dyestuffs containing a cellulose fiber reactive substituent 失效
标题翻译：含有纤维素纤维反应性替代物的2-羟基 - 吡啶-6-酮AZO脱水酶
公开(公告)号：US3725383A
公开(公告)日：1973-04-03
申请号：US3725383D
申请日：1971-05-20
申请人： ICI LTD
发明人： AUSTIN P , YOUNG E , LENG J , RIDYARD D
IPC分类号： C09B29/15 , C09B29/42 , C09B31/153 , C09B45/02 , C09B62/006 , C09B29/36 , C09B62/08 , C09B62/24
CPC分类号： C09B62/0067 , C09B29/10 , C09B29/3621 , C09B31/153 , C09B45/025
摘要： Azo dyestuffs of the general formula:

D R A W I N G
WHEREIN R represents an aromatic radical which may contain one or more further azo groups, M represents H or a metal atom forming part of a metal-complex system in the dyestuff, R1 represents an alkyl group or a phenyl radical which may be substituted, e.g., by lower alkyl, lower alkoxy or chlorine, R2 represents a hydrogen atom, an alkyl, aralkyl or cycloalkyl group or a phenyl radical which may be substituted, e.g., by lower alkyl, lower alkoxy or halogen, and R3 represents a hydrogen atom, a heterocyclic radical containing a cellulose-reactive substituent, or the acyl radical of an organic carboxylic or sulphonic acid which may or may not contain a cellulose-reactive substituent are valuable dyestuffs for a variety of substrates. For example those containing SO3H groups and a fiber-reactive group are valuable for dyeing and printing of cellulose polyamide and wool textile materials while those which are free from complex metal groups and sulphonic acid groups may be used as disperse dyestuffs.
摘要翻译：偶氮染料的通式如下：

5. 发明授权

US3668211A Certain 6-hydroxy 2-(1h) pyridones 失效
标题翻译：某些6-羟基2-（1H）吡啶
公开(公告)号：US3668211A
公开(公告)日：1972-06-06
申请号：US3668211D
申请日：1969-10-30
申请人： ICI LTD
发明人： CRABTREE ALLEN
IPC分类号： C07D213/81 , C09B62/006 , C09B62/08 , C07D31/46
CPC分类号： C07D213/81 , C09B62/0067 , C09B62/08
摘要： Compounds of the formula

WHEREIN T1 represents a hydrogen atom or a group of the formula -COOR1 or CONR1R2, or an aliphatic, araliphatic, homocyclic or heterocyclic radical, T2 represents a group of the formula -CN, -COOR1 or CONR1R2, R1 and R2 each independently represents a hydrogen atom or an aliphatic, araliphatic, homocyclic or heterocyclic radical or NR1R2 represents a heterocyclic radical, and Z represents an aliphatic radical having a primary or secondary amono group substituted therein, are valuable dyestuff intermediates being useful as coupling components for the manufacture of a wide variety of azo compounds.
摘要翻译：式WHEREIN T1的化合物表示氢原子或式-COOR1或CONR1R2的基团，或脂族，芳脂族，双环或杂环基团，T2表示式-CN，-COOR1或CONR1R2，R1和R2的基团每个独立地表示氢原子或脂族，芳脂族，双环或杂环基，或-NR 1 R 2表示杂环基，Z表示其中被取代的伯或仲氨基的脂族基团，是有价值的染料中间体，可用作偶联组分制造各种各样的偶氮化合物。

6. 发明授权

US4067864A Fiber-reactive 2-hydroxy-pyrid-6-on-(3)-yl azo dyestuffs 失效
标题翻译：纤维反应性2-羟基 - 吡啶-6-酮（3） - 基偶氮染料
公开(公告)号：US4067864A
公开(公告)日：1978-01-10
申请号：US635205
申请日：1975-11-25
申请人： Fritz Oesterlein , Gert Hegar , Karl Seitz
发明人： Fritz Oesterlein , Gert Hegar , Karl Seitz
IPC分类号： C09B29/42 , C09B39/00 , C09B45/02 , C09B62/006 , C09B62/08 , C09B62/24 , C09B62/44 , D06P1/38
CPC分类号： C09B62/0067 , C09B29/3626 , C09B39/00 , C09B45/025
摘要： Azo dyestuffs which contain an acid substituent which confers solubility in water of the formula ##STR1## wherein D is the radical of a sulfo substituted benzene or naphthalene diazo component;R' is alkyl of 1 to 4 carbon atoms;Z is a fiber reactive group; andN is an integer of 1 to 4 are disclosed and are useful in dyeing nitrogen containing fibers such as polyamides, polyurethanes, silk, leather and wool as well as cellulose materials, in particular cotton.
摘要翻译：含有赋予式的水中的溶解度的酸取代基的偶氮染料，其中D是磺基取代的苯或萘重氮组分的基团; R'是1至4个碳原子的烷基; Z是纤维反应性基团; 并且N是1至4的整数，并且用于含有氮素的纤维素如聚氨酯，聚氨酯，丝绸，皮革和羊毛中的含氮纤维素材料，特别是棉。

7. 发明授权

US3994906A 3-Sulphoalkyl-6-hydroxy-pyrid-(2)-ones 失效
标题翻译： 3-磺基烷基-6-羟基 - 吡啶并 - （2） - 酮
公开(公告)号：US3994906A
公开(公告)日：1976-11-30
申请号：US590784
申请日：1975-06-26
申请人： Gert Hegar
发明人： Gert Hegar
IPC分类号： C07D213/69 , C07D213/82 , C09B29/42 , C09B45/02 , C09B62/006 , C09B62/008 , C07D213/52
CPC分类号： C07D213/69 , C07D213/82 , C09B29/3626 , C09B45/025 , C09B62/0067 , C09B62/0088
摘要： A compound of the formula ##SPC1##Wherein R and R' each represent a hydrogen atom, an alkyl or aryl radical or a heterocyclic radical and X represents a sulphoalkyl group. These compounds are useful as coupling components for the manufacture of dyestuffs which are distinguished by high tinctorial strength.
摘要翻译：式WHEREIN R和R'的化合物各自表示氢原子，烷基或芳基或杂环基，X表示磺基烷基。这些化合物可用作用于制造以高着色强度区分的染料的偶联组分。

8. 发明授权

US3926944A Water-soluble cellulose reactive azo dyestuffs containing 3-azo-2-hydroxy-N-subnstituted pyrid-6-one radical 失效
标题翻译：含有3-偶氮-2-羟基-N-取代的吡啶-6-酮基的水溶性纤维素反应性偶氮染料
公开(公告)号：US3926944A
公开(公告)日：1975-12-16
申请号：US38733473
申请日：1973-08-10
申请人： ICI LTD
发明人： BERRIE ALISTAIR HOWARD , BUDZIAREK RICHARD
IPC分类号： C09B62/006 , C09B62/04 , C09B29/36 , D06P1/38 , D06P3/66
CPC分类号： C09B62/0067 , C09B62/043
摘要： IN WHICH T1 is H, phenyl, anisyl, NH2, or lower alkyl, T2 is H, CN, lower alkyl, CONH2 or substituted aminocarbonyl, Z is R, HOR''-, ROR''-, R2NR''-, phenyl or anisyl, (R and R'' are lower alkyl and lower alkylene) the diazo component carrying a cellulosereactive group. Also included are dyes in which the reactive group also contains an anthraquinone or phthalocyanine residue or where two moles of the dye are linked through a diamine radical. Cr and Co complexes of dyes in which the diazo component is a oaminophenol are included.

D R A W I N G
A new class of cellulose reactive dyes have a sulphonated benzene, naphthalene or azobenzene diazo component coupled on to a class of coupling components of the formula:
摘要翻译：一类新的纤维素活性染料具有磺化苯，萘或偶氮苯重氮组分，其结合一类下式的偶合组分：

9. 发明授权

US3869440A Metal-complex azo dyestuffs containing a 5-substituted-2,3-dihydroxypyridine as coupling component 失效
公开(公告)号：US3869440A
公开(公告)日：1975-03-04
申请号：US21704172
申请日：1972-01-11
申请人： CIBA GEIGY AG
发明人： BACK GERHARD , FASCIATI ALFRED
IPC分类号： C09B29/42 , C09B31/153 , C09B39/00 , C09B43/40 , C09B45/02 , C09B62/006 , C09B45/14 , C09B45/18 , C09B45/20
CPC分类号： C09B62/0067 , C09B29/3621 , C09B31/153 , C09B39/00 , C09B43/40 , C09B45/025
摘要： Heavy metal complexes of azo compounds of the formula

WHERE D is the residue of a heterocyclic diazo component and is selected from pyridyl; benzthiazolyl that is unsubstituted or substituted by chloro, nitro or methoxy; indazolyl that is unsubstituted or substituted by chloro, methoxy or nitro; triazolyl; carboxytriazolyl; 4-phenyl-5-methyl-pyrazolyl; 1phenyl-2,3-dimethylpyrazolyl-5-one; benztriazolyl; benzimidazolyl; thiazolyl; methylthiazolyl; thiadiazolyl that is unsubstituted or substituted by phenyl, pyridyl, acetylamino, phenylsulphonyl, chloro, carbomethoxy, methylthio, ethylthio, phenylthio, cyclohexylthio, methylsulphonyl or methyl; quinolyl that is unsubstituted or substituted by sulfo, chloro, bromo, acetylamino, methyl, sulfophenylazo, or sulfophenylazo containing a fibre-reactive acylamino group, where acyl is selected from chloroacetyl, bromoacetyl, Beta chloropropyionyl, Beta -bromopropionyl, Alpha , Beta dichloropropionyl, Alpha , Beta -dibromopropionyl, chloromaleyl, acrylyl, Beta -chloroacrylyl, Beta bromoacrylyl, Alpha -chloroacrylyl, Alpha -bromoacrylyl, Alpha , Beta -dichloroacrylyl, Alpha , Beta -dibromoacrylyl, trichloroacrylyl, chlorocrotonyl and propiolyl; or benzisothiazolyl that is unsubstituted or substituted by methyl, ethyl, methoxy, chloro, bromo, cyano, nitro, Nmethylsulfonamido, N,N-dimethylsulfonamido or methylsulfonyl; or D is phenyl or naphthyl that contains an OH, NH2 or COOH group in the position orthho-to the azo bond, said phenyl or naphthyl being further unsubstituted or substituted by chloro, bromo, nitro, cyano, lower alkyl, lower alkoxy, lower alkylsulphonyl, sulfonic acid, carboxylic acid, sulphonamide, N-lower alkylsulphonamide, N-lower hydroxyalkyl-sulphonamide, N,Ndiethylsulphonamide, N,N-di( Beta -hydroxyethyl)-sulphonamide, phenylazo, naphthylazo, formylamino, acetylamino, benzoylamino, benzenesulphonamide, p-toluenesulphonylamino, methanesulphonylamino, carboxymethoxyamino, carboethoxyamino, dimethylaminosulphonylamino or isopropoxyamino, X is hydroxy, alkoxy of 1 to 4 carbon atoms, phenoxy, naphthoxy, Beta -hydroxyethylamino, gamma -methoxy-n-propylamino, isopropoxy-n-propylamino, N,N-diethylethylenediamine, cyclohexylamino, piperidyl, morpholyl, phenylamino, carboxyphenylamino, sulfonaphthylaminno, mercapto, methylthio, Beta -hydroxyethylthio, phenylthio, carboxyphenylthio, naphthylthio, thiazolylthio, methylsulphonyl, phenylsulphonyl, methyl-phenylsulphonyl, sulfo or fibre-reactive acrylaminno where acyl is selected from the group consisting of chloroacetyl, bromoacetyl, Beta -chloropropionyl, Beta bromopropionyl, Alpha , Beta -dichloropropionyl, Alpha , Beta -dibromopropionyl, chloromaleyl, acrylyl, Beta -chloroacrylyl, Beta -bromoacrylyl, Alpha -chloroacrylyl, Alpha bromoacrylyl, Alpha , Beta -dichloroacrylyl, Alpha , Beta dibromoacrylyl, trichloroacrylyl, chlorocrotonyl and propiolyl ARE USEFUL TO DYE SUCH FIBERS AS WOOL AND NYLON IN SHADES OF GREEN AND BLUE THAT ARE FAST TO ACID, ALKALI, LIGHT AND RUBBING.

10. 发明授权

US4001205A Water-soluble, fiber-reactive phenylazodihydroxy, methyl, cyanopyridine dyestuffs 失效
标题翻译：水溶性，纤维反应性苯并二唑，甲基，氰基吡啶衍生物
公开(公告)号：US4001205A
公开(公告)日：1977-01-04
申请号：US411624
申请日：1973-11-01
申请人： Arthur Buehler , Alfred Fasciati , Gerd Hoelzle
发明人： Arthur Buehler , Alfred Fasciati , Gerd Hoelzle
IPC分类号： C09B29/42 , C09B31/02 , C09B45/02 , C09B62/006 , C09B62/08 , C09B62/24 , C09B62/50 , D06P3/58
CPC分类号： C09B62/0067 , C09B29/3626 , C09B31/02 , C09B45/025 , C09B62/0068
摘要： Azo dyestuffs containing at least one acidic group imparting solubility in water and the grouping of the formula ##SPC1##

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