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1. 发明授权

KR880000499B1 1:1형 금속 착염 염료로 천연 또는 합성 폴리아미드 섬유물질의 염색방법 失效
公开(公告)号：KR880000499B1
公开(公告)日：1988-04-08
申请号：KR850003739
申请日：1985-05-30
申请人： CIBA GEIGY AG
发明人： BACK GERHARD , MOSIMANN WALTER
IPC分类号： C09B45/02 , C09B45/00 , C09B67/22 , C09B67/24 , D06P1/10 , D06P1/673 , D06P3/06 , D06P3/24

2. 发明授权

US3875139A Heavy metal complexes of azo dyestuffs containing the residue of a 2-amino-3-hydroxypyridine 失效
标题翻译：含有2-氨基-3-羟基吡啶残基的偶氮染料重金属络合物
公开(公告)号：US3875139A
公开(公告)日：1975-04-01
申请号：US27414872
申请日：1972-07-24
申请人： CIBA GEIGY AG
发明人： BACK GERHARD , BUEHLER ARTHUR
IPC分类号： C09B29/42 , C09B45/00 , C09B45/02 , C09B45/34 , D06P3/12 , C09B45/14 , C09B45/16 , C09B45/24
CPC分类号： C09B45/025 , C09B45/00
摘要： Heavy metal complexes of azo compounds of formula

WHERE D is the residue of a heterocyclic diazo component which can form a complex with a heavy metal, such as 8-quinolinyl, and B is hydrogen or halogen, provide dyeings on, for example, natural and synthetic polyamide and polyacrylonitrile which yield level blue and green shades of good general fastness, including resistance to acid, alkali, light and rubbing.
摘要翻译：式WHERE的偶氮化合物的重金属络合物是可以与重金属如8-喹啉基形成络合物的杂环重氮组分的残基，B是氢或卤素，在例如天然和/或合成聚酰胺和聚丙烯腈，其具有良好的通用牢度的蓝色和绿色色调，包括耐酸，碱，光和摩擦。

3. 发明授权

US3869440A Metal-complex azo dyestuffs containing a 5-substituted-2,3-dihydroxypyridine as coupling component 失效
公开(公告)号：US3869440A
公开(公告)日：1975-03-04
申请号：US21704172
申请日：1972-01-11
申请人： CIBA GEIGY AG
发明人： BACK GERHARD , FASCIATI ALFRED
IPC分类号： C09B29/42 , C09B31/153 , C09B39/00 , C09B43/40 , C09B45/02 , C09B62/006 , C09B45/14 , C09B45/18 , C09B45/20
CPC分类号： C09B62/0067 , C09B29/3621 , C09B31/153 , C09B39/00 , C09B43/40 , C09B45/025
摘要： Heavy metal complexes of azo compounds of the formula

WHERE D is the residue of a heterocyclic diazo component and is selected from pyridyl; benzthiazolyl that is unsubstituted or substituted by chloro, nitro or methoxy; indazolyl that is unsubstituted or substituted by chloro, methoxy or nitro; triazolyl; carboxytriazolyl; 4-phenyl-5-methyl-pyrazolyl; 1phenyl-2,3-dimethylpyrazolyl-5-one; benztriazolyl; benzimidazolyl; thiazolyl; methylthiazolyl; thiadiazolyl that is unsubstituted or substituted by phenyl, pyridyl, acetylamino, phenylsulphonyl, chloro, carbomethoxy, methylthio, ethylthio, phenylthio, cyclohexylthio, methylsulphonyl or methyl; quinolyl that is unsubstituted or substituted by sulfo, chloro, bromo, acetylamino, methyl, sulfophenylazo, or sulfophenylazo containing a fibre-reactive acylamino group, where acyl is selected from chloroacetyl, bromoacetyl, Beta chloropropyionyl, Beta -bromopropionyl, Alpha , Beta dichloropropionyl, Alpha , Beta -dibromopropionyl, chloromaleyl, acrylyl, Beta -chloroacrylyl, Beta bromoacrylyl, Alpha -chloroacrylyl, Alpha -bromoacrylyl, Alpha , Beta -dichloroacrylyl, Alpha , Beta -dibromoacrylyl, trichloroacrylyl, chlorocrotonyl and propiolyl; or benzisothiazolyl that is unsubstituted or substituted by methyl, ethyl, methoxy, chloro, bromo, cyano, nitro, Nmethylsulfonamido, N,N-dimethylsulfonamido or methylsulfonyl; or D is phenyl or naphthyl that contains an OH, NH2 or COOH group in the position orthho-to the azo bond, said phenyl or naphthyl being further unsubstituted or substituted by chloro, bromo, nitro, cyano, lower alkyl, lower alkoxy, lower alkylsulphonyl, sulfonic acid, carboxylic acid, sulphonamide, N-lower alkylsulphonamide, N-lower hydroxyalkyl-sulphonamide, N,Ndiethylsulphonamide, N,N-di( Beta -hydroxyethyl)-sulphonamide, phenylazo, naphthylazo, formylamino, acetylamino, benzoylamino, benzenesulphonamide, p-toluenesulphonylamino, methanesulphonylamino, carboxymethoxyamino, carboethoxyamino, dimethylaminosulphonylamino or isopropoxyamino, X is hydroxy, alkoxy of 1 to 4 carbon atoms, phenoxy, naphthoxy, Beta -hydroxyethylamino, gamma -methoxy-n-propylamino, isopropoxy-n-propylamino, N,N-diethylethylenediamine, cyclohexylamino, piperidyl, morpholyl, phenylamino, carboxyphenylamino, sulfonaphthylaminno, mercapto, methylthio, Beta -hydroxyethylthio, phenylthio, carboxyphenylthio, naphthylthio, thiazolylthio, methylsulphonyl, phenylsulphonyl, methyl-phenylsulphonyl, sulfo or fibre-reactive acrylaminno where acyl is selected from the group consisting of chloroacetyl, bromoacetyl, Beta -chloropropionyl, Beta bromopropionyl, Alpha , Beta -dichloropropionyl, Alpha , Beta -dibromopropionyl, chloromaleyl, acrylyl, Beta -chloroacrylyl, Beta -bromoacrylyl, Alpha -chloroacrylyl, Alpha bromoacrylyl, Alpha , Beta -dichloroacrylyl, Alpha , Beta dibromoacrylyl, trichloroacrylyl, chlorocrotonyl and propiolyl ARE USEFUL TO DYE SUCH FIBERS AS WOOL AND NYLON IN SHADES OF GREEN AND BLUE THAT ARE FAST TO ACID, ALKALI, LIGHT AND RUBBING.

4. 发明授权

US3870695A Heavy metal complexes of azo dyestuffs containing a 2-amino-3-hydroxypyridine as coupling component 失效
标题翻译：含有2-氨基-3-羟基吡啶作为偶联成分的偶氮染料的重金属络合物
公开(公告)号：US3870695A
公开(公告)日：1975-03-11
申请号：US27414772
申请日：1972-07-21
申请人： CIBA GEIGY AG
发明人： BACK GERHARD , BUEHLER ARTHUR
IPC分类号： C07D213/73 , C07D213/75 , C07D498/04 , C09B29/22 , C09B29/42 , C09B31/153 , C09B45/02 , C09B62/006 , C09B62/40 , D06P1/10 , D06P3/22 , D06P3/28 , C09B45/14 , C09B45/20 , C09B45/24
CPC分类号： C09B62/006 , C09B29/3621 , C09B31/153 , C09B45/025 , C09B62/40
摘要： WHERE B is hydrogen, chloro or bromo and D is the residue of a diazo component of the benzene or naphthalene series that contains an hydroxyl, carboxyl or amino group in the position ortho to the azo group, are useful to dye substrates, notably wool, in level green and blue shades having good resistance to acid, alkali, light and rubbing.

The heavy metal complexes of azo dyestuffs of formula
摘要翻译：式WHERE B的偶氮染料的重金属络合物是氢，氯或溴，D是在偶氮基的邻位含有羟基，羧基或氨基的苯或萘系的重氮组分的残基，对于具有良好的抗酸，碱，光和摩擦性能的级别的绿色和蓝色色调染色基质，特别是羊毛是有用的。

5. 发明授权

US3692463A Dyeing silk and wool fibers in aqueous bath of metallizable fiber-reactive azo dyes and nitrogen-containing polyglycols with after-treatment using metal releasing agent 失效
标题翻译：在使用金属释放剂进行后处理的金属化纤维反应性AZO染料和含氮的聚合物的水浴中染色丝和羊毛纤维
公开(公告)号：US3692463A
公开(公告)日：1972-09-19
申请号：US3692463D
申请日：1970-03-03
申请人： CIBA GEIGY AG
发明人： BACK GERHARD , ABEL HEINZ , BUEHLER ARTHUR , LITZLER ALFRED
IPC分类号： C09B62/012 , D06P1/607 , D06P3/10 , D06P3/20 , C09B45/04
CPC分类号： C09B62/012 , D06P1/6076 , D06P3/10 , D06P3/20 , Y10S8/907 , Y10S8/917
摘要： THE PRESENT INVENTION RELATES TO A PROCESS FOR DYEING NATURAL PROTEIN FIBRES, PREFERABLY WOOL, WITH METALLIZABLE FIBER-REACTIVE MONOAZO DYESTUFFS IN TE PRESENCE OF A NITROGEN-CONTAINING POLYGLYCOL COMPOUND. UPON AFTER-TREATMENT WITH METAL-YIELDING AGENTS DYEINGS OF EXCELLENT WET AND LIGHT FASTNESS ARE OBTAINED.

6. 发明授权

US3692462A Dyeing silk and wool with chromable fiber-reactive azo dyestuffs and polyglycol-ether amines 失效
标题翻译：染色丝绸和羊毛与可变色纤维反应AZO DYESTUFFS和聚乙烯醇醚
公开(公告)号：US3692462A
公开(公告)日：1972-09-19
申请号：US3692462D
申请日：1970-03-04
申请人： CIBA GEIGY AG
发明人： BACK GERHARD , ABEL HEINZ , BUEHLER ARTHUR , LITZLER ALFRED
IPC分类号： C09B62/012 , D06P1/607 , D06P3/10 , D06P3/20 , C09B62/50 , D06P1/38
CPC分类号： C09B62/012 , D06P1/6076 , D06P3/10 , D06P3/20 , Y10S8/907 , Y10S8/917
摘要： A PROCESS FOR DYEING NATURAL PROTEIN FIBRES WHEREIN DYEING IS PERFORMED AT 80 TO 110*C. IN THE PRESENCE OF A NITROGEN-CONTAINING POLYGLYCOL DERIVATIVE OF AN ALIPHATIC COMPOUND OF HIGH MOLECULAR WEIGHT, A CHROMIUM-RELEASING AGENT AND A WATER-SOLUBLE FIBRE-REACTIVE, CHROMABLE MONO-OR DISAZO DYESTUFF CONTAINING GROUPS CAPABLE OF COMPLEX FORMATION, AT LEAST ONE SULFONIC ACID GROUP IMPARTING SOLUBILITY IN WATER, AND A FIBRE-REACTIVE ACYLAMINO GROUP.

7. 发明专利

FR2562553A1 COMPLEXES DU CHROME OU DU COBALT, LEUR PREPARATION ET LEUR UTILISATION 未知
公开(公告)号：FR2562553A1
公开(公告)日：1985-10-11
申请号：FR8505165
申请日：1985-04-04
申请人： CIBA GEIGY AG , CIBA GEIGY AG
发明人： BACK GERHARD , GERHARD BACK
IPC分类号： C09B45/16 , C09B45/20 , C09B55/00 , C09B45/14 , C09B45/48 , D06P1/10 , D06P3/24
摘要： L'INVENTION CONCERNE DES COMPLEXES DE CHROME OU DE COBALT REPONDANT A LA FORMULE: (CF DESSIN DANS BOPI) DANS LAQUELLE A DESIGNE LE RADICAL D'UN COLORANT AZOIQUE OU AZOMETHINIQUE DICYCLIQUEMENT METALLISABLE; B LE RADICAL D'UN COMPOSE ORGANIQUE TRIDENTE, DIANIONIQUE, FORMANT DES COMPLEXES, QUI CONTIENT UN GROUPE CNC PARTICIPANT AU COMPLEXE DE CHROME OU DE COBALT; ME EST UN ATOME DE CHROME OU DE COBALT, ET KA UN CATION, UN PROCEDE POUR LA PREPARATION DES COMPLEXES DE COBALT OU DE CHROME REPONDANT A LA FORMULE I. UTILISATION DE CES COMPLEXES POUR LA TEINTURE DE MATIERES CONTENANT DES GROUPES AZOTES OU DES GROUPES HYDROXY.

8. 发明专利

FR2592054A1 COLORANTS A COMPLEXE DE CHROME 1:1 ASYMETRIQUES, LEUR PROCEDE DE PREPARATION ET LEUR UTILISATION 未知
公开(公告)号：FR2592054A1
公开(公告)日：1987-06-26
申请号：FR8617977
申请日：1986-12-22
申请人： CIBA GEIGY AG , CIBA GEIGY AG
发明人： BACK GERHARD , GERHARD BACK FABIO BEFFA ULRICH SCHLESINGER ET ALOIS PUNTENER , BEFFA FABIO , SCHLESINGER ULRICH , PUNTENER ALOIS
IPC分类号： D06P1/10 , D06P3/32 , C09B45/26 , C09B45/16 , C09B45/40 , D06P3/14
摘要： Colorants à complexe de chrome 1:1 asymétrique, leur procédé de préparation et leur utilisation. Colorants à complexe de chrome 1:2, de formule (CF DESSIN DANS BOPI) dans laquelle A et D, indépendamment l'un de l'autre, sont chacun le résidu d'un composant diazo de la série du benzène ou du naphtalène, qui porte en position ortho par rapport au groupe azo le groupe hydroxy ou carboxy, B est le résidu d'un composant de copulation qui porte le groupe X en position voisine du groupe azo, X est un oxygène ou un radical -NR-, R étant un hydrogène ou un radical alkyle en C1-C4, Y désigne certains radicaux aminés, m vaut 0 ou 1, n est un nombre entier de 1 à 7, et Ka(anion) est un cation, pour la ceinture de la laine, du polyamide et du cuir en des nuances orangé, brun ou brun olive. L'invention trouve son application principale dans la teinture de la laine, du polyamide et du cuir.

9. 发明专利

MX168486B 未知
公开(公告)号：MX168486B
公开(公告)日：1993-05-27
申请号：MX56985
申请日：1985-11-11
申请人： CIBA GEIGY AG
发明人： PUNTENER ALOIS , BACK GERHARD , KOLLER JOSEF
IPC分类号： D06P1/642 , D06P1/673 , D06P3/32 , D06P5/00 , D06P5/10 , C14C11/00
摘要： For improving the light-fastness of leather dyed with anionic dyes, the leather is treated, before, during or after dyeing, with a compound of copper.

10. 发明专利

ZA8603825B PROCESS FOR DYEING NATURAL OR SYNTHETIC POLYAMIDE FIBRE MATERIALS WITH MIXTURES OF DYES 未知
公开(公告)号：ZA8603825B
公开(公告)日：1987-01-28
申请号：ZA8603825
申请日：1986-05-22
申请人： CIBA GEIGY AG
发明人： BACK GERHARD , MOSIMANN WALTER
IPC分类号： D06P3/14 , C09B67/22 , D06P1/673 , D06P3/06 , D06P3/24 , D06P , C09B
CPC分类号： D06P1/6735 , C09B67/0041 , D06P3/06

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