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1. 发明申请

WO1992011299A1 METHOD FOR PREPARING AN OLEFIN POLYMERIZATION CATALYST 审中-公开
标题翻译：制备烯烃聚合催化剂的方法
公开(公告)号：WO1992011299A1
公开(公告)日：1992-07-09
申请号：PCT/FR1991001013
申请日：1991-12-16
申请人： ECP-ENICHEM POLYMERES FRANCE S.A. , BUJADOUX, Karel , LEPREVOST, Benoît , MORTREUX, André , PETIT, Francis
发明人： ECP-ENICHEM POLYMERES FRANCE S.A.
IPC分类号： C08F10/02
CPC分类号： C08F10/00 , C08F4/6555 , C08F4/651
摘要： A method for preparing an olefin homopolymerization and copolymerization catalyst by at least partially reducing at least one tetravalent titanium compound, wherein: firstly, at least one α,φ-dihalogenoalkane of general formula X-(CH2)n-X1, wherein X and X1, which are the same or different, are halogen atoms and n is equal to or greater than 2, are contacted with a tetravalent titanium compound and aluminium until said aluminium completely disappears; and secondly, an organomagnesium derivative is added to the solution thereby obtained in an amount sufficient for the molar ratio of Mg/Ti to be of at least 1. The catalyst thereby obtained may be used together with an activator in an olefin polymerization method, and particularly in an ethylene (co)polymerization method.

2. 发明申请

WO1994009044A1 CATALYSTS AND PROCESS FOR THE PREPARATION OF ETHYLENE POLYMERIZATION CATALYSTS 审中-公开
标题翻译：催化剂和乙烯聚合催化剂的制备方法
公开(公告)号：WO1994009044A1
公开(公告)日：1994-04-28
申请号：PCT/FR1993000996
申请日：1993-10-08
申请人： PETIT, Michèle +hf , ECP-ENICHEM POLYMERES FRANCE S.A. , OLONDE, Xavier , BUJADOUX, Karel , MORTREUX, André
发明人： PETIT, Michèle +hf , ECP-ENICHEM POLYMERES FRANCE S.A. , PETIT, Francis +di
IPC分类号： C08F10/00
CPC分类号： C08F10/02 , Y02P20/544 , C08F4/54
摘要： Catalyst consisting of a reaction product with at least one organomagnesium and/or organo lithium-containing compound of formula R Li (R =alkyl) or ArLi (Ar=phenyl or benzyl), of the reaction product of a compound of formula (Cp)2MX2Li(OR2)2(M=lanthanide, scandium, yttrium; (Cp)=optionally substituted cyclopentadienyl; and R=alkyl), with at least one bidentate ligand, such as beta -dicetone or beta -ketone imine of formula CZ3COCHZCDCZ3, Z being selected from halogen, alkyl and H, D=O, NH or NR (R=alkyl or aryl); and phosphorus ylide R 3P=CA-CO-R , R being selected from alkyl and aryl; A=alkyl or H. Advantageously said catalyst can be in solution form containing, at least partially, an aromatic hydrocarbon. The ethylene polymerization process can be carried out at a temperature in the range of 20 DEG -250 DEG C, at a pressure of up to approximately 200 bars, in solution or in suspension in an at least C6 inert hydrocarbon or can be continuously carried out, in at least one autoclave or tubular reactor, at a temperature in the range of 150 DEG -300 DEG C, and at a pressure ranging from 400-2000 bars, the reactional medium being in a hypercritical state.
摘要翻译：催化剂与由式R 1 Li（R 1 =烷基）或ArLi（Ar =苯基或苄基）的至少一种有机镁和/或有机含锂化合物的反应产物组成，式（Cp）2 M 2 Li（OR 2）2（M =镧系元素，钪，钇;（Cp）=任选取代的环戊二烯基; R =烷基）的化合物与至少一个二齿配体如β-二酮或β-酮式CZ3COCHZCDCZ3的亚胺，Z选自卤素，烷基和H，D = O，NH或NR 3（R =烷基或芳基）; 磷叶立德R 2 3 P = CA-CO-R 2，R 2选自烷基和芳基; A =烷基或H.有利地，所述催化剂可以是至少部分地含有芳族烃的溶液形式。乙烯聚合方法可以在20-250℃的温度，至多约200巴的压力下，在溶液中或在至少C6惰性烃中的悬浮液中进行，或者可以连续进行在至少一个高压釜或管式反应器中，在150-300℃的温度和400-2000巴的压力下，反应介质处于超临界状态。

3. 发明申请

WO1993012149A1 METHOD AND CATALYST FOR THE (CO)POLYMERIZATION OF ALPHA-OLEFINS, METHOD FOR THE PREPARATION OF SUCH CATALYST 审中-公开
标题翻译： ALPHA-OLEFIN的（CO）聚合方法和催化剂，制备这种催化剂的方法
公开(公告)号：WO1993012149A1
公开(公告)日：1993-06-24
申请号：PCT/FR1992001204
申请日：1992-12-17
申请人： ECP-ENICHEM POLYMERES FRANCE S.A. , ADISSON, Emmanuel , BUJADOUX, Karel , FONTANILLE, Michel , DEFFIEUX, Alain
发明人： ECP-ENICHEM POLYMERES FRANCE S.A.
IPC分类号： C08F10/00
CPC分类号： C08F10/00 , C08F4/635
摘要： Said catalyst has the general formula VX3, mAlX3, nZ, with X = halogen atom; Z = at least one saturated, branched or not, at least partially halogenated hydrocarbon; m is comprised between 0,1 and 10; and n is comprised between 1 and 300. In order to prepare said catalyst, the cogrinding of a vanadium halogenide VX2 and/or VX3 ( X = Hal), is carried out, with an aluminium halogenide AlX3, and there is added at least one halogenated hydrocarbon Z to the mixture obtained in proportions corresponding to the selected values of m and n. The invention also relates to the (co)polymerization of alpha-olefins, at 20-350 °C, in the presence of a catalytic system comprising at least one catalyst as defined hereabove and at least one organometallic activator.

4. 发明申请

WO1993000401A1 COMPOSITIONS CONTAINING ETHYLENE COPOLYMERS AND FILMS OBTAINED 审中-公开
标题翻译：含有乙烯共聚物和薄膜的组合物
公开(公告)号：WO1993000401A1
公开(公告)日：1993-01-07
申请号：PCT/FR1992000567
申请日：1992-06-19
申请人： ECP-ENICHEM POLYMERES FRANCE S.A. , VALLIGNY, Dominique , PIECUCH, Edouard
发明人： ECP-ENICHEM POLYMERES FRANCE S.A.
IPC分类号： C08L23/10
CPC分类号： C08L23/0815 , C08J5/18 , C08J2323/08 , C08J2323/14 , C08L23/14 , C08L2666/06
摘要： Compositions which can be transformed into films comprise 50 to 93 % by weight of at least one ethylene copolymer (E) and at least one alpha-olefin with a relative density from 0.880 to 0.940, and 7 to 50 % by weight of at least one propylene and ethylene crystalline copolymer (P) having a content of propylene-derived units of at least 80 % mol and a fluidity index (at 230 °C, 2.16 kg) from 1 to 20 dg/mn. The films having a thickness from 20 to 200 micrometres, characterized in that they contain at least one composition as defined above, are also disclosed.

5. 发明申请

WO1993007180A1 CATALYSTS AND PROCESS FOR THE PREPARATION OF SAME FOR USE IN THE POLYMERISATION OF ETHYLENE 审中-公开
标题翻译：用于乙烯聚合反应的催化剂及其制备方法
公开(公告)号：WO1993007180A1
公开(公告)日：1993-04-15
申请号：PCT/FR1992000917
申请日：1992-09-30
申请人： ECP-ENICHEM POLYMERES FRANCE S.A.
发明人： ECP-ENICHEM POLYMERES FRANCE S.A. , OLONDE, Xavier , BUJADOUX, Karel , MORTREUX, André , PETIT, Francis
IPC分类号： C08F04/42
CPC分类号： C08F10/02 , C08F4/52
摘要： The catalyst consists of the reaction product of the compound of formula Cp*2NdC12Li(OEt2)2, (Cp* = pentamethylcyclopentadienyl and Et = ethyl), with at least one reagent chosen from the organomagnesium compounds and RLi organolithium compounds in which R is alkyl having at most 12 carbon atoms or ArLi in which Ar is a phenyl nucleus or a C6H5-CH2- benzyl radical. It is advantageously produced in the form of a solution containing, at least partially, an aromatic hydrocarbon. The catalyst in solution has, in particular, a Nd concentration of 0.1-100 mmoles/1. The process for the polymerization of ethylene using said catalyst can be carried out at between 20 °C and 250 °C, under pressure which can attain approximately 200 bars, in solution or in suspension in an at least C6 inert hydrocarbon (C10C12 saturated aliphatic hydrocarbon fraction) or it can be carried out in continuous mode, in at least one autoclave or tubular reactor, at 150 °C - 300 °C, under a pressure of 400 - 2000 bars, the reactional medium being in a hypercritical state.

6. 发明授权

US5585447A Catalyst for the (co)polymerization of alpha-olefins, a process for its preparation and (co)polymerization process making use thereof 失效
标题翻译：用于（共）聚合α-烯烃的催化剂，其制备方法和（共）聚合方法
公开(公告)号：US5585447A
公开(公告)日：1996-12-17
申请号：US514717
申请日：1995-08-14
申请人： Emmanuel Adisson , Karel Bujadoux , Michel Fontanille , Alain Deffieux
发明人： Emmanuel Adisson , Karel Bujadoux , Michel Fontanille , Alain Deffieux
IPC分类号： C08F10/00 , C08F4/68
CPC分类号： C08F10/00
摘要： This catalyst has the general formula VX.sub.3, mAIX.sub.3, nZ, wherein X is a halogen atom, Z is at least one at least partially halogenated, branched or unbranched, saturated hydrocarbon, m is between 0.1 and 10, and n is between 1 and 300. To prepare it, a vanadium halide VX.sub.2 and/or VX.sub.3 is coground with an aluminum halide AlX.sub.3, and then at least one halogenated hydrocarbon Z is added to the mixture obtained in proportions corresponding to the chosen values of m and n. The invention also relates to the (co)polymerization of alpha-olefins at 20.degree.-350.degree. C. in the presence of a catalyst system comprising at least one catalyst as defined above and at least one organometallic activator.
摘要翻译：该催化剂具有通式VX3，mAIX3，nZ，其中X为卤素原子，Z为至少一个至少部分卤化的，支链或非支链的饱和烃，m为0.1至10，n为1至300 为了制备它，卤化钒VX2和/或VX3与卤化铝AlX 3共同接触，然后将至少一种卤代烃Z加入到与选择的m和n值相对应的比例中获得的混合物中。本发明还涉及在包含至少一种如上定义的催化剂和至少一种有机金属活化剂的催化剂体系存在下，在20-350℃下（α-共聚）α-烯烃的聚合。

7. 发明授权

US5334663A Thermoplastic compositions, process for preparing them and their application in the production of industrial articles 失效
标题翻译：热塑性组合物，其制备方法及其在工业制品生产中的应用
公开(公告)号：US5334663A
公开(公告)日：1994-08-02
申请号：US24244
申请日：1993-03-01
申请人： Joel Audureau , Vincent Crenna
发明人： Joel Audureau , Vincent Crenna
IPC分类号： C08J3/20 , C08F8/50 , C08L23/04 , C08L23/08 , C08L23/10 , C08L23/14 , C08L23/18 , C08L23/26 , C08J5/00 , C08L23/36
CPC分类号： C08L23/04 , B29C47/92 , C08F8/50 , C08L23/0815 , C08L23/10 , B29C2947/92704 , B29C47/0004 , B29C47/38 , B29C47/805 , C08F2800/10 , C08F2810/10 , C08L2023/42 , C08L2205/03 , C08L23/142
摘要： The compositions contain a) less than 90% and at least 2% by weight of at least one ethylene polymer (A), and optionally, at least one .alpha.-olefin having from 3 to 12 carbon atoms, said polymer containing at least 70% in moles of patterns derived from ethylene, and b) more than 10% and up to 98% by weight of at least one polymer (B) containing at least 85% in moles of patterns derived from at least one .alpha.-olefin having from 3 to 12 carbon atoms and at the most 15% in moles of patterns derived from ethylene, and are characterized in that the polymer (A) is a modified polymer of which the measured limit viscosity is comprised between 1.3 and 100 times its limit viscosity calculated from the distribution of molecular masses. The compositions are obtained by a process consisting in providing a polymer of ethylene and, optionally, of at least one .alpha.-olefin having from 3 to 12 carbon atoms in the presence, on the one hand, of at least one initiator of free radicals in a quantity comprised between 0.001 and 0.3 parts by weight of the initiator for one hundred parts by weight of said polymer at a temperature higher than the melting temperature of said polymer during a time at least equal to one tenth of the half life time of the initiator at the temperature considered, and, on the other hand, of at least one polymer (B). Application to the production of industrial articles by extrusion-blowing of sheaths or hollow bodies, extrusion of films by means of flat dies, roto-moulding, injection or coating.
摘要翻译：组合物含有a）小于90％和至少2重量％的至少一种乙烯聚合物（A）和任选的至少一种具有3至12个碳原子的α-烯烃，所述聚合物含有至少70％来自乙烯的图案的摩尔数，以及b）大于10重量％至多98重量％的至少一种含至少85摩尔的至少一种具有3个以上的α-烯烃的图案的聚合物（B）至12个碳原子和最多15％（摩尔）衍生自乙烯的图案，其特征在于聚合物（A）是经测定的极限粘度为其极限粘度的1.3至100倍的改性聚合物，其极限粘度由分子量的分布。通过包括提供乙烯和任选的至少一种具有3至12个碳原子的α-烯烃的聚合物在一方面存在至少一种自由基引发剂的方法获得组合物对于100重量份所述聚合物，在比所述聚合物的熔融温度高至少等于所述引发剂半衰期的十分之一的时间内的温度下，所述引发剂的量为0.001至0.3重量份在所考虑的温度下，另一方面由至少一种聚合物（B）。通过挤压吹塑护套或中空体来生产工业制品的应用，通过平面模具挤出膜，旋转成型，注射或涂覆。

8. 发明授权

US5591410A Process for the on-line grafting of carboxylic acid and carboxylic acid anhydrides containing an ethylenic unsaturation onto ethylene homopolymers or copolymers and installation for the implementation of this process 失效
标题翻译：在乙烯均聚物或共聚物上含有烯属不饱和键的羧酸和羧酸酐的在线接枝方法，以及用于实施该方法的设备
公开(公告)号：US5591410A
公开(公告)日：1997-01-07
申请号：US478849
申请日：1995-06-07
申请人： Joel Audureau , Hacene Mehalla , Thierry Pellerin
发明人： Joel Audureau , Hacene Mehalla , Thierry Pellerin
IPC分类号： C08F2/00 , C08F8/00 , C08F8/46 , C08F255/00 , C08F255/02
CPC分类号： C08F8/46 , C08F255/02 , C08F8/00
摘要： (I) The (co)polymerisation of ethylene is carried out in at least one reaction zone (R) under high pressure, at 150.degree.-320.degree. C.; (II) the reaction product is routed into a zone (S), under an intermediate pressure P, for separation of the (co)polymer, in the molten state, from the unreacted (co)monomer(s), or the reaction product is routed into a first separation zone (S1), under an intermediate pressure (P1); the (co)polymer issuing from (S1) is then routed into a second separation zone (S2), under a pressure P2
摘要翻译：（I）乙烯的（共）聚合在150-320℃的高压下在至少一个反应区（R）中进行。（II），在中间压力P下将反应产物引入一个区域（S），以使熔融状态的（共）聚合物与未反应的（共）单体或反应产物在中间压力（P1）下被路由到第一分离区（S1）中; 然后在压力P2

9. 发明授权

US5583181A Process for the on-line grafting of carboxylic acids and carboxylic acid anhydrides containing an ethylenic unsaturation onto ethylene homopolymers or copolymers and installation for the implementation of this process 失效
标题翻译：在乙烯均聚物或共聚物上在线接枝含有烯属不饱和键的羧酸和羧酸酐的方法和用于实施该方法的装置
公开(公告)号：US5583181A
公开(公告)日：1996-12-10
申请号：US371575
申请日：1995-01-12
申请人： Jo el Audureau , Hacene Mehalla , Thierry Pellerin
发明人： Jo el Audureau , Hacene Mehalla , Thierry Pellerin
IPC分类号： C08F2/00 , C08F8/00 , C08F8/46 , C08F255/00 , C08F255/02
CPC分类号： C08F8/46 , C08F255/02 , C08F8/00
摘要： (I) The (co)polymerisation of ethylene is carried out in at least one reaction zone (R) under high pressure, at 150.degree.-320.degree. C.; (II) the reaction product is routed into a zone (S), under an intermediate pressure P, for separation of the (co)polymer, in the molten state, from the unreacted (co)monomer(s), or the reaction product is routed into a first separation zone (S1), under an intermediate pressure (P1); the (co)polymer issuing from (S1) is then routed into a second separation zone (S2), under a pressure P2
摘要翻译：（I）乙烯的（共）聚合在150-320℃的高压下在至少一个反应区（R）中进行。（II），在中间压力P下将反应产物引入一个区域（S），以使熔融状态的（共）聚合物与未反应的（共）单体或反应产物在中间压力（P1）下被路由到第一分离区（S1）中; 然后在压力P2

10. 发明专利

ES2032842T3 未知
公开(公告)号：ES2032842T3
公开(公告)日：1993-03-01
申请号：ES87400679
申请日：1987-03-26
申请人： ECP-ENICHEM POLYMERES FRANCE S.A.
发明人： CRENNA, VINCENT
IPC分类号： C08L7/00 , C08L21/00 , C08L23/00 , C08L23/02 , C08L23/08 , C08L23/12 , C08L23/16 , C08L101/00
摘要： Polyolefin composition comprising, as first constituent (A) at least one highly isotactic propylene polymer and, as second constituent (B), at least one linear copolymer with a density of between 0.914 and 0.945, of ethylene and of at least one alpha -olefin containing from 3 to 12 carbon atoms. It comprises, per 100 parts by weight, from 30 to 40 parts by weight of the polymer (A), from 40 to 67 parts by weight of the polymer (B) and additionally from 3 to 25 parts by weight of at least one terpolymer (C) which has a density of between 0.865 and 0.912, containing from 70 to 94 mol% of ethylene, from 4 to 20 mol% of propylene and from 2 to 10 mol% of at least one alpha -olefin containing from 4 to 12 carbon atoms. Application to conversion into industrial articles.

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