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1. 发明授权

US08530609B2 Process for removing metal species in the presence of hydrogen and a porous material and polyester polymer containing reduced amounts of metal species 有权
标题翻译：在氢气和多孔材料存在下除去金属物质的方法和含有减少量金属物质的聚酯聚合物的方法
公开(公告)号：US08530609B2
公开(公告)日：2013-09-10
申请号：US12104514
申请日：2008-04-17
申请人： Zhufang Liu , Jeff Scott Howell
发明人： Zhufang Liu , Jeff Scott Howell
IPC分类号： C08G63/00
CPC分类号： C22B23/026 , C08G63/78 , C08G63/82 , C08G63/90 , C08K3/32 , C22B3/24 , Y02P10/224 , Y02P10/234
摘要： A process for removing metal species from a composition comprising contacting: a. an oligomer mixture stream comprising the monomers of a partially aromatic polyester polymer and at least one metal species, or b. a molten polyester polymer stream comprising partially aromatic polyester polymers and at least one metal species, with a non-catalytic porous material in the presence of hydrogen to produce a treated stream containing a reduced amount of at least one metal species. There are provided compositions comprising a partially aromatic polyester polymer having an It.V. of at least 0.50 produced in a direct esterification melt phase process, from greater than 0 to less than 50 ppm antimony, and less than 40 ppm cobalt, or produced in an ester exchange melt phase process, having from greater than zero to less than 5 ppm titanium and less than 10 ppm manganese.
摘要翻译：一种用于从组合物中除去金属物质的方法，包括使a：包含部分芳族聚酯聚合物和至少一种金属物质的单体的低聚物混合物流，或b。包含部分芳族聚酯聚合物和至少一种金属物质的熔融聚酯聚合物流，在氢气存在下具有非催化多孔材料，以产生含有减少量的至少一种金属物质的处理流。提供了包含具有It.V.的部分芳族聚酯聚合物的组合物。在直接酯化熔融相方法中生产的至少0.50，从大于0到小于50ppm的锑和小于40ppm的钴，或者在酯交换熔融相方法中产生，具有大于零至小于5 ppm的钛和小于10ppm的锰。

2. 发明授权

US07067615B1 Hydrotreating polyester precursors 有权
标题翻译：加氢处理聚酯前体
公开(公告)号：US07067615B1
公开(公告)日：2006-06-27
申请号：US11151085
申请日：2005-06-13
申请人： Zhufang Liu , Jeff Scott Howell , Charles Edwan Sumner, Jr.
发明人： Zhufang Liu , Jeff Scott Howell , Charles Edwan Sumner, Jr.
IPC分类号： C08F6/00
CPC分类号： C08G63/78
摘要： A process comprising contacting a liquid polyester stream with hydrogen in the presence of a hydrogenation catalyst comprising a metal supported on the surface of silicon carbide at a metal dispersion of at least 0.5% or graphite at a metal dispersion of at least 10% to produce a treated liquid polyester stream. The treated stream may be polycondensed in the presence of a polycondensation catalyst to produce a polyester polymer having an It.V. of at least 0.55 dL/g. The liquid polyester stream desirably has a composition comprising: a) terephthalic acid residues, isophthalic acid residues, and/or naphthalenedicarboxylic acid residues and b) an average degree of polymerization of 0.5 to 20 and c) an acid number ranging from 5 to 600.
摘要翻译：一种方法包括在氢化催化剂存在下使液体聚酯流与氢气接触，所述氢化催化剂包含以至少0.5％的金属分散体或至少为10％的金属分散体的石墨支撑在碳化硅表面上的金属，以产生至少10％的金属分散体处理液体聚酯流。处理过的物流可以在缩聚催化剂的存在下进行缩聚以制备具有It.V.的聚酯聚合物。至少0.55dL / g。液体聚酯流理想地具有包括：a）对苯二甲酸残基，间苯二甲酸残基和/或萘二甲酸残基的组合物，以及b）平均聚合度为0.5至20，c）酸值为5至600。

3. 发明授权

US08921509B2 Process for removing metal species in the presence of hydrogen and a porous material and polyester polymer containing reduced amounts of metal species 有权
标题翻译：在氢气和多孔材料存在下除去金属物质的方法和含有减少量金属物质的聚酯聚合物的方法
公开(公告)号：US08921509B2
公开(公告)日：2014-12-30
申请号：US13525872
申请日：2012-06-18
申请人： Zhufang Liu , Jeff Scott Howell
发明人： Zhufang Liu , Jeff Scott Howell
IPC分类号： C08G63/00 , C08G63/78 , C22B23/02 , C08G63/90 , C08G63/82 , C22B3/24 , C08K3/32
CPC分类号： C22B23/026 , C08G63/78 , C08G63/82 , C08G63/90 , C08K3/32 , C22B3/24 , Y02P10/224 , Y02P10/234
摘要： Provided is a composition with partially aromatic polyester polymers having an It.V. of at least 0.50 dL/g, produced in an ester exchange melt phase process, having from zero or greater than zero to less than 5 ppm titanium, from zero or greater than zero to less then 10 ppm germanium, and from zero or greater than zero to less than 20 ppm manganese.
摘要翻译：提供了具有部分芳族聚酯聚合物的组合物，其具有It.V. 在酯交换熔融相方法中产生的至少0.50dL / g，具有零或大于零至小于5ppm的钛，从零至大于零至小于10ppm的锗，并且从零或大于零至小于20ppm锰。

4. 发明申请

US20080194750A1 PROCESS FOR REMOVING METAL SPECIES IN THE PRESENCE OF HYDROGEN AND A POROUS MATERIAL AND POLYESTER POLYMER CONTAINING REDUCED AMOUNTS OF METAL SPECIES 有权
标题翻译：在氢和多孔材料存在下去除金属物质的过程和含金属物质减少量的聚酯聚合物
公开(公告)号：US20080194750A1
公开(公告)日：2008-08-14
申请号：US12104514
申请日：2008-04-17
申请人： Zhufang Liu , Jeff Scott Howell
发明人： Zhufang Liu , Jeff Scott Howell
IPC分类号： C08K3/00 , C08K3/10
CPC分类号： C22B23/026 , C08G63/78 , C08G63/82 , C08G63/90 , C08K3/32 , C22B3/24 , Y02P10/224 , Y02P10/234
摘要： A process for removing metal species from a composition comprising contacting: a. an oligomer mixture stream comprising the monomers of a partially aromatic polyester polymer and at least one metal species, or b. a molten polyester polymer stream comprising partially aromatic polyester polymers and at least one metal species, with a non-catalytic porous material in the presence of hydrogen to produce a treated stream containing a reduced amount of at least one metal species. There is also provided a composition comprising a partially aromatic polyester polymer having an It.V. of at least 0.50 produced in a direct esterification melt phase process, from greater than 0 to less than 50 ppm antimony, and less than 40 ppm cobalt. There is also provided a composition comprising partially aromatic polyester polymers having an It.V. of at least 0.50 produced in an ester exchange melt phase process, from greater than zero to less than 5 ppm titanium, and less than 10 ppm manganese.
摘要翻译：一种用于从组合物中除去金属物质的方法，包括使a：包含部分芳族聚酯聚合物和至少一种金属物质的单体的低聚物混合物流，或b。包含部分芳族聚酯聚合物和至少一种金属物质的熔融聚酯聚合物流，在氢气存在下具有非催化多孔材料，以产生含有减少量的至少一种金属物质的处理流。还提供了一种组合物，其包含具有It.V.的部分芳族聚酯聚合物。在直接酯化熔融相方法中产生的至少为0.50，大于0至小于50ppm的锑和小于40ppm的钴。还提供了包含部分芳族聚酯聚合物的组合物，其具有It.V. 在酯交换熔融相方法中产生的至少为0.50，从大于零至小于5ppm的钛和小于10ppm的锰。

5. 发明授权

US07390869B2 Process for removing metal species in the presence of hydrogen and a porous material and polyester polymer containing reduced amounts of metal species 有权
标题翻译：在氢气和多孔材料存在下除去金属物质的方法和含有减少量金属物质的聚酯聚合物的方法
公开(公告)号：US07390869B2
公开(公告)日：2008-06-24
申请号：US11151084
申请日：2005-06-13
申请人： Zhufang Liu , Jeff Scott Howell
发明人： Zhufang Liu , Jeff Scott Howell
IPC分类号： C08F6/00
CPC分类号： C22B23/026 , C08G63/78 , C08G63/82 , C08G63/90 , C08K3/32 , C22B3/24 , Y02P10/224 , Y02P10/234
摘要： A process for removing metal species from a composition comprising contacting: a. an oligomer mixture stream comprising the monomers of a partially aromatic polyester polymer and at least one metal species, or b. a molten polyester polymer stream comprising partially aromatic polyester polymers and at least one metal species, with a non-catalytic porous material in the presence of hydrogen to produce a treated stream containing a reduced amount of at least one metal species. There is also provided a composition comprising a partially aromatic polyester polymer having an It.V. of at least 0.50 produced in a direct esterification melt phase process, from greater than 0 to less than 50 ppm antimony, and less than 40 ppm cobalt. There is also provided a composition comprising partially aromatic polyester polymers having an It.V. of at least 0.50 produced in an ester exchange melt phase process, from greater than zero to less than 5 ppm titanium, and less than 10 ppm manganese.
摘要翻译：一种用于从组合物中除去金属物质的方法，包括使a：包含部分芳族聚酯聚合物和至少一种金属物质的单体的低聚物混合物流，或b。包含部分芳族聚酯聚合物和至少一种金属物质的熔融聚酯聚合物流，在氢气存在下具有非催化多孔材料，以产生含有减少量的至少一种金属物质的处理流。还提供了一种组合物，其包含具有It.V.的部分芳族聚酯聚合物。在直接酯化熔融相方法中产生的至少为0.50，大于0至小于50ppm的锑和小于40ppm的钴。还提供了包含部分芳族聚酯聚合物的组合物，其具有It.V. 在酯交换熔融相方法中产生的至少为0.50，从大于零至小于5ppm的钛和小于10ppm的锰。

6. 发明申请

US20070255070A1 Hydrogenation process and catalysts 失效
标题翻译：氢化工艺和催化剂
公开(公告)号：US20070255070A1
公开(公告)日：2007-11-01
申请号：US11787496
申请日：2007-04-17
申请人： Zhufang Liu
发明人： Zhufang Liu
IPC分类号： C07C69/74
CPC分类号： C07C67/303 , C07C2601/14 , C07C69/75
摘要： Disclosed is a process for the preparation of dimethyl cyclohexanedicarboxylates by the hydrogenation of the corresponding dimethyl benzenedicarboxylate ester in the presence of supported catalysts comprising (i) a Group VIII metal and (ii) a catalyst support material selected from graphite and silicon carbide.
摘要翻译：公开了通过在负载催化剂的氢化下相应的二苯基二羧酸酯的制备来制备环己烷二羧酸二甲酯的方法，所述载体催化剂包含（ⅰ）第Ⅷ族金属和（ⅱ）选自石墨和碳化硅的催化剂载体材料。

7. 发明申请

US20070088181A1 Catalyst for the preparation of ketones from carboxylic acids 审中-公开
标题翻译：用于由羧酸制备酮的催化剂
公开(公告)号：US20070088181A1
公开(公告)日：2007-04-19
申请号：US11525105
申请日：2006-09-22
申请人： Alexey Ignatchenko , Michelle King , Zhufang Liu
发明人： Alexey Ignatchenko , Michelle King , Zhufang Liu
IPC分类号： C07C45/45 , B01J23/00
CPC分类号： B01J23/02 , B01J21/063 , B01J21/066 , B01J23/04 , C07C45/48 , C07C49/04 , C07C49/10
摘要： A catalyst for the preparation of ketones from carboxylic acids is described. The catalyst comprises a mixture of zirconium dioxide, titanium dioxide, and one or more metal oxides from Group 1 or 2 of the Periodic Table of Elements. The catalyst can operate at a lower temperature, reduce coke formation, and provide longer lifetime.
摘要翻译：描述了用于由羧酸制备酮的催化剂。催化剂包含二氧化锆，二氧化钛和元素周期表第1或2族中的一种或多种金属氧化物的混合物。催化剂可以在较低温度下运行，减少焦炭形成，并提供更长的使用寿命。

8. 发明授权

US07538060B2 Palladium-copper chromite hydrogenation catalysts 失效
标题翻译：钯 - 亚铬酸铜加氢催化剂
公开(公告)号：US07538060B2
公开(公告)日：2009-05-26
申请号：US11674831
申请日：2007-02-14
申请人： Scott Donald Barnicki , Bruce LeRoy Gustafson , Zhufang Liu , Steven Thomas Perri , Paul Randolph Worsham
发明人： Scott Donald Barnicki , Bruce LeRoy Gustafson , Zhufang Liu , Steven Thomas Perri , Paul Randolph Worsham
IPC分类号： B01J35/00 , B01J37/00 , C07C29/132 , C07C29/149
CPC分类号： C07C29/149 , B01J23/868 , B01J23/8993 , B01J37/0201 , B01J37/0205 , B01J37/03 , C07C29/157 , C07C2601/14 , Y02P20/52 , C07C31/202 , C07C31/276 , C07C31/04
摘要： Disclosed are catalysts comprising copper chromite, palladium and lanthanum having hydrogenation activity. The combination of copper chromite with palladium and lanthanum enhances catalyst activity more than the presence of either palladium alone or palladium in combination with alkali or alkaline earth metals. The catalysts are useful for the preparation of methanol from carbon monoxide and hydrogen and for the hydrogenation of carbonyl compounds such as, for example, aldehydes, ketones, and esters, to their corresponding alcohols. The catalysts may be used for the preparation of cyclohexanedimethanols from dialkyl cyclohexanedicarboxylates or of ethylene glycol from alkyl glycolates.
摘要翻译：公开了包含具有氢化活性的亚铬酸铜，钯和镧的催化剂。亚铬酸铜与钯和镧的组合比单独的钯或钯与碱金属或碱土金属组合的存在提高了催化剂活性。催化剂可用于从一氧化碳和氢气制备甲醇，并将羰基化合物（例如醛，酮和酯）氢化成其相应的醇。催化剂可用于从环己烷二羧酸二烷基酯或乙二醇由烷基乙醇酸制备环己烷二甲醇。

9. 发明授权

US07524994B2 Process for the preparation of a tetraalkylcyclobutane-1,3-diol using an iridium-promoted cobalt-based catalyst 失效
标题翻译：使用铱促进的钴基催化剂制备四烷基环丁烷-1,3-二醇的方法
公开(公告)号：US07524994B2
公开(公告)日：2009-04-28
申请号：US11947941
申请日：2007-11-30
申请人： Jennifer Ellen McCusker-Orth , Jerome Leonard Stavinoha, Jr. , Anthony Dominick Messina , Steven Thomas Perri , Zhufang Liu , Philip Conrad Heidt , Brent Alan Tennant
发明人： Jennifer Ellen McCusker-Orth , Jerome Leonard Stavinoha, Jr. , Anthony Dominick Messina , Steven Thomas Perri , Zhufang Liu , Philip Conrad Heidt , Brent Alan Tennant
IPC分类号： C07C35/04 , C07C31/18 , C07C29/143
CPC分类号： C07C29/145 , C07B2200/09 , C07C45/72 , C07C45/89 , C07C45/90 , C07C49/88 , C07C2601/04 , C07C49/39 , C07C35/045
摘要： The present disclosure relates to the production of a 2,2,4,4-tetraalkylcyclobutane-1,3-diol. In one embodiment, the present invention relates to the production of a 2,2,4,4-tetraalkylcyclobutane-1,3-diol by hydrogenation of a 2,2,4,4-tetraalkylcyclobutane-1,3-dione in the presence of an iridium-promoted cobalt-based catalyst.
摘要翻译：本公开涉及制备2,2,4,4-四烷基环丁烷-1,3-二醇。在一个实施方案中，本发明涉及在存在下通过氢化2,2,4,4-四烷基环丁烷-1,3-二酮制备2,2,4,4-四烷基环丁烷-1,3-二醇的铱促进的钴基催化剂。

10. 发明申请

US20080132737A1 PROCESS FOR THE PREPARATION OF A TETRAALKYLCYCLOBUTANE-1,3-DIOL USING AN IRIDIUM-PROMOTED COBALT-BASED CATALYST 失效
标题翻译：使用二氧化钛促进的基于钴的催化剂制备四烯丙基-1,3-丁二醇的方法
公开(公告)号：US20080132737A1
公开(公告)日：2008-06-05
申请号：US11947941
申请日：2007-11-30
申请人： Jennifer Ellen McCusker-Orth , Jerome Leonard Stavinoha , Anthony Dominick Messina , Steven Thomas Perri , Zhufang Liu , Philip Conrad Heidt , Brent Alan Tennant
发明人： Jennifer Ellen McCusker-Orth , Jerome Leonard Stavinoha , Anthony Dominick Messina , Steven Thomas Perri , Zhufang Liu , Philip Conrad Heidt , Brent Alan Tennant
IPC分类号： C07C35/04
CPC分类号： C07C29/145 , C07B2200/09 , C07C45/72 , C07C45/89 , C07C45/90 , C07C49/88 , C07C2601/04 , C07C49/39 , C07C35/045
摘要： The present disclosure relates to the production of a 2,2,4,4-tetraalkylcyclobutane-1,3-diol. In one embodiment, the present invention relates to the production of a 2,2,4,4-tetraalkylcyclobutane-1,3-diol by hydrogenation of a 2,2,4,4-tetraalkylcyclobutane-1,3-dione in the presence of an iridium-promoted cobalt-based catalyst.
摘要翻译：本公开涉及制备2,2,4,4-四烷基环丁烷-1,3-二醇。在一个实施方案中，本发明涉及在存在下通过氢化2,2,4,4-四烷基环丁烷-1,3-二酮制备2,2,4,4-四烷基环丁烷-1,3-二醇的铱促进的钴基催化剂。

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