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1. 发明授权

US08765999B2 Hydrocarboxylation of formaldehyde in the presence of a higher order carboxylic acid and a homogeneous catalyst 有权
标题翻译：在较高级羧酸和均相催化剂存在下甲醛的氢化羧化
公开(公告)号：US08765999B2
公开(公告)日：2014-07-01
申请号：US13431369
申请日：2012-03-27
申请人： Scott Donald Barnicki , Robert Thomas Hembre , Stephen Neal Falling , Andrew James Vetter
发明人： Scott Donald Barnicki , Robert Thomas Hembre , Stephen Neal Falling , Andrew James Vetter
IPC分类号： C07C51/10
CPC分类号： C07C67/58 , C07C51/09 , C07C51/493 , C07C67/00 , C07C67/36 , C07C59/06 , C07C69/675 , C07C69/24
摘要： Disclosed is a process for the production and purification of glycolic acid or glycolic acid derivatives by the carbonylation of formaldehyde in the presence of a homogeneous acid catalyst and a carboxylic acid. This invention discloses hydrocarboxylations and corresponding homogeneous acid catalyst and glycolic acid separations. The homogeneous acid catalyst is readily separated from the hydrocarboxylation reaction effluent and recycled and the carboxylic acid is readily removed from the glycolic acid and the carboxylic acid is recycled.
摘要翻译：公开了一种在均相酸催化剂和羧酸存在下通过甲醛羰基化生产和纯化乙醇酸或乙醇酸衍生物的方法。本发明公开了加氢羧化和相应的均相酸催化剂和乙醇酸分离。均匀的酸催化剂容易从加氢羧化反应流出物中分离并再循环，羧酸容易从乙醇酸中除去，羧酸被再循环。

2. 发明申请

US20130331605A1 HYDROCARBOXYLATION OF AQUEOUS FORMALDEHYDE USING A DEHYDRATING RECYCLE STREAM TO DECREASE WATER CONCENTRATION 有权
标题翻译：使用脱水循环流降低水分浓度的水性甲醛的碳氢化
公开(公告)号：US20130331605A1
公开(公告)日：2013-12-12
申请号：US13491954
申请日：2012-06-08
申请人： Mesfin Ejerssa Janka , Scott Donald Barnicki , Robert Thomas Hembre , Kelley Margaret Moran , Stephen Neal Falling
发明人： Mesfin Ejerssa Janka , Scott Donald Barnicki , Robert Thomas Hembre , Kelley Margaret Moran , Stephen Neal Falling
IPC分类号： C07C51/12 , C07C59/06
CPC分类号： C07C51/12 , C07C29/149 , C07C59/06 , C07C31/202
摘要： Disclosed is a process for the production and purification of glycolic acid or glycolic acid derivatives by the carbonylation of aqueous formaldehyde. The water in the hydrocarboxylation zone is reduced via reaction with the ester bonds in a recycle stream comprising glycolic acid oligomers and/or methyl glycolate oligomers.
摘要翻译：公开了通过甲醛水解羰基化生产和纯化乙醇酸或乙醇酸衍生物的方法。在包含乙醇酸低聚物和/或乙醇酸甲酯低聚物的再循环料流中，通过与酯键的反应来还原加氢羧化区中的水。

3. 发明授权

US08466328B2 Method for recovery and recycle of ruthenium homogeneous catalysts 有权
标题翻译：钌均相催化剂的回收和再循环方法
公开(公告)号：US08466328B2
公开(公告)日：2013-06-18
申请号：US12889065
申请日：2010-09-23
申请人： Scott Donald Barnicki , Jeffrey Scott Kanel , Kenneth Wayne Hampton, Jr.
发明人： Scott Donald Barnicki , Jeffrey Scott Kanel , Kenneth Wayne Hampton, Jr.
IPC分类号： C07C27/04
CPC分类号： B01J31/2404 , B01J31/24 , B01J31/2409 , B01J31/4053 , B01J2531/0238 , B01J2531/821 , C07C29/149 , C07C29/86 , Y02P20/52 , Y02P20/582 , Y02P20/584 , C07C31/202
摘要： Disclosed is a process for the extractive recovery of a homogeneous ruthenium catalyst from the reaction product of the hydrogenation of glycolic acid, glycolate esters, and/or glycolic acid oligomers with an extractant comprising a hydrophobic solvent and an optional hydrophilic solvent. The ruthenium catalyst, which can include 1,1,1-tris(diaryl- or dialkylphosphinomethyl)alkane ligands, can be recovered from the hydrophobic extract phase by back extraction with a hydrophilic solvent and recycled to a process for the preparation of ethylene glycol by the hydrogenation of glycolic acid and glycolic acid derivatives.
摘要翻译：公开了从乙醇酸，乙醇酸酯和/或乙醇酸低聚物的氢化与包含疏水性溶剂和任选的亲水性溶剂的萃取剂的反应产物中提取回收均相钌催化剂的方法。可以通过用亲水性溶剂反萃取从疏水萃取相中回收可包括1,1,1-三（二芳基 - 或二烷基膦基甲基）烷烃配体的钌催化剂，并循环至制备乙二醇的方法乙醇酸和乙醇酸衍生物的氢化。

4. 发明申请

US20120078010A1 PROCESS FOR RECOVERING AND RECYCLING AN ACID CATALYST 有权
标题翻译：回收和回收酸催化剂的方法
公开(公告)号：US20120078010A1
公开(公告)日：2012-03-29
申请号：US12889045
申请日：2010-09-23
申请人： Scott Donald Barnicki , Stephen Neal Falling , Jeffrey Scott Kanel , Robert Sterling Kline , Peter Borden Mackenzie
发明人： Scott Donald Barnicki , Stephen Neal Falling , Jeffrey Scott Kanel , Robert Sterling Kline , Peter Borden Mackenzie
IPC分类号： C07C51/10
CPC分类号： B01D11/0492 , B01J31/0225 , B01J31/0227 , B01J31/4092 , C07C51/48 , C07C303/44 , C07C315/06 , Y02P20/584 , C07C59/06 , C07C309/06 , C07C309/05 , C07C317/04
摘要： Disclosed is a process for the extractive recovery of an acid catalyst from an aqueous mixture of glycolic acid with an extraction solvent comprising a tertiary amine or an onium carboxylate compound, a modifier, and a diluent. The acid catalyst, which can comprise strong acids such as sulfuric acid, alkyl sulfonic acids, and fluoroalkyl sulfonic acids, can be recovered by back extraction with aqueous formaldehyde and recycled to a process for the preparation of glycolic acid by the acid-catalyzed carbonylation of formaldehyde.
摘要翻译：公开了一种从乙醇酸的水性混合物与包含叔胺或羧酸铝化合物，改性剂和稀释剂的萃取溶剂萃取回收酸催化剂的方法。可以包含强酸如硫酸，烷基磺酸和氟代烷基磺酸的酸催化剂可以通过用甲醛水溶液反萃取回收，并循环至通过酸催化的羰基化反应制备乙醇酸的方法甲醛。

5. 发明授权

US06960694B2 Processes for preparing β-hydroxy-ketones and α,β-unsaturated ketones 有权
标题翻译：制备β-羟基酮和α，β-不饱和酮的方法
公开(公告)号：US06960694B2
公开(公告)日：2005-11-01
申请号：US10611394
申请日：2003-07-01
申请人： Scott Donald Barnicki , Jennifer Ellen McCusker-Orth , Jerry Lynn Miller
发明人： Scott Donald Barnicki , Jennifer Ellen McCusker-Orth , Jerry Lynn Miller
IPC分类号： C07C45/72 , C07C45/74 , C07C49/17 , C07C49/203 , C07C49/235 , C07C49/245 , C07C49/807
CPC分类号： C07C49/807 , C07C45/72 , C07C45/74 , C07C47/19 , C07C49/17 , C07C49/21 , C07C49/203 , C07C47/21
摘要： Processes for producing β-hydroxy-ketones and α,β-unsaturated ketones are disclosed which comprise the crossed condensation of an aldehyde with a ketone in the presence of a hydroxide or alkoxide of alkali metal or an alkaline earth metal as catalyst. The products of the process, β-hydroxy-ketones and α,β-unsaturated ketones, are useful for the preparation of many commercially important products in the chemical process industries including solvents, drug intermediates, flavors and fragrances, other specialty chemical intermediates.
摘要翻译：公开了用于生产β-羟基酮和α，β-不饱和酮的方法，其包括在碱金属或碱土金属的氢氧化物或醇盐作为催化剂存在下，醛与酮的交叉缩合。该方法的产物β-羟基酮和α，β-不饱和酮可用于在化学工业行业中制备许多商业上重要的产品，包括溶剂，药物中间体，香料和香料，以及其他特种化学中间体。

6. 发明授权

US06200624B1 Enteral formula or nutritional supplement containing arachidonic and docosahexaenoic acids 失效
标题翻译：含有花生四烯酸和二十二碳六烯酸的肠内配方或营养补充剂
公开(公告)号：US06200624B1
公开(公告)日：2001-03-13
申请号：US08592832
申请日：1996-01-26
申请人： Terrence Bruce Mazer , Robert Alan Miller , Charles Allan McCombs , Scott Donald Barnicki , James Cecil Phillips , Charles Edwan Sumner, Jr.
发明人： Terrence Bruce Mazer , Robert Alan Miller , Charles Allan McCombs , Scott Donald Barnicki , James Cecil Phillips , Charles Edwan Sumner, Jr.
IPC分类号： A23L200
CPC分类号： A23L33/17 , A23L33/12 , A23L33/40 , Y10S426/80 , Y10S426/801
摘要： This invention is directed to the use of triglycerides containing fatty ester moieties that include arachidonic acid (AA) and docosahexaenoic acid (DHA) in enteral nutritionals or nutritional supplements. These triglycerides are derived from lipid mixtures which have high levels of sterols and phosphorous. A preferred embodiment of the invention comprises an infant or enteral nutritional, or nutritional supplement, that comprises a lipid source derived from egg yolk. The lipid source derived from egg yolk is prepared by transesterification or hydrolysis, subjecting the mixture to distillation, and esterification with glycerin to result in a triglyceride containing the desired fatty acids of AA and DHA and little or no sterols and phosphorus.
摘要翻译：本发明涉及含有花生四烯酸（AA）和二十二碳六烯酸（DHA）的脂肪酸酯部分的甘油三酯在肠内营养或营养补充剂中的用途。这些甘油三酯衍生自具有高水平的甾醇和磷的脂质混合物。本发明的优选实施方案包括婴儿或肠内营养或营养补充剂，其包含源自蛋黄的脂质源。来自蛋黄的脂质源通过酯交换或水解制备，使混合物蒸馏，并用甘油进行酯化，得到含有所需的AA和DHA脂肪酸的甘油三酯，很少或没有固醇和磷。

7. 发明授权

US5945550A Gas phase process for the epoxidation of non-allylic olefins 失效
标题翻译：用于非烯丙烯烯烃环氧化的气相方法
公开(公告)号：US5945550A
公开(公告)日：1999-08-31
申请号：US122027
申请日：1998-07-24
申请人： Scott Donald Barnicki , John Robert Monnier , Kimberly Thornton Peters
发明人： Scott Donald Barnicki , John Robert Monnier , Kimberly Thornton Peters
IPC分类号： B01J23/54 , C07B61/00 , C07D301/10 , C07D303/04 , C07D303/06
CPC分类号： C07D301/10
摘要： This invention provides an improved gas phase feed process using heterogeneous catalysis for the selective epoxidation of non-allylic olefins wherein the epoxidation is carried out in the presence of branched-chain alkane or cyclic aliphatic hydrocarbons with high autoignition temperatures and high Research Octane Numbers. The hydrocarbons useful in the present invention possess higher heat capacities as compared to other non-oxidizable materials, e.g., nitrogen, argon, helium, and other straight-chain hydrocarbons, e.g., methane, ethane, and n-butane, as well as smaller flammability (cool flame and explosive) regions than the above-stated hydrocarbons typically used as diluents or ballast gases in olefin epoxidations. The process is particularly useful for the continuous preparation of 3,4-epoxy-1-butene from 1,3-butadiene.
摘要翻译：本发明提供了使用非均相催化用于非烯丙烯选择性环氧化的改进的气相进料方法，其中环氧化在具有高自燃温度和高研究辛烷值的支链烷烃或环脂族烃存在下进行。与其它不可氧化的材料（例如氮气，氩气，氦气和其它直链烃，例如甲烷，乙烷和正丁烷）以及较小的碳氢化合物相比，本发明中有用的烃具有更高的热容量。可燃性（冷却火焰和爆炸性）区域比通常用作烯烃环氧化物中的稀释剂或压载气体的上述烃类。该方法特别适用于从1,3-丁二烯连续制备3,4-环氧-1-丁烯。

8. 发明授权

US5660691A Process for the production of tocotrienol/tocopherol blend concentrates 失效
标题翻译：生育三烯酚/生育酚共混物浓缩物的方法
公开(公告)号：US5660691A
公开(公告)日：1997-08-26
申请号：US558073
申请日：1995-11-13
申请人： Scott Donald Barnicki , Charles Edwan Sumner, Jr. , Hampton Loyd Chip Williams, III
发明人： Scott Donald Barnicki , Charles Edwan Sumner, Jr. , Hampton Loyd Chip Williams, III
IPC分类号： C07D311/72 , C07D311/76
CPC分类号： C07D311/72
摘要： Disclosed is an improved process for the preparation of tocotrienol/tocopherol blend concentrates from vegetable oil distillates which are enriched in tocotrienols. Tocotrienol/tocopherol blend concentrates are obtained containing 20-80% tocotrienols/tocopherols by weight, with an overall recovery of tocotrienols/tocopherols of 72% to 97%. The process is comprised first of an esterification reaction where the more volatile alcohols are converted to their less volatile fatty acid esters, followed by a series of distillation steps where components boiling higher and lower than the tocotrienols/tocopherols are separated from tocotrienols/tocopherols and other like boiling substances. Advantages of the process are that tocotrienol/tocopherol blend concentrates are produced efficiently and economically in a minimum number of steps without the use of solvents and with a relatively small capital investment.
摘要翻译：公开了一种用于从富含生育三烯酚的植物油馏出物制备生育三烯酚/生育酚共混物浓缩物的改进方法。获得含有20-80％生育三烯醇/生育酚的生育三烯酚/生育酚共混物浓缩物，其中生育三烯酚/生育酚的总回收率为72％至97％。该方法首先包括酯化反应，其中挥发性较高的醇转化成其挥发性较小的脂肪酸酯，然后进行一系列蒸馏步骤，其中沸点高于和低于生育三烯酚/生育酚的组分与生育三烯酚/生育酚等分离像沸腾物质。该方法的优点是生育三烯酚/生育酚共混物浓缩物在不使用溶剂和相对小的资本投资的情况下以最少数量的步骤有效且经济地生产。

9. 发明授权

US09040748B2 Hydrocarboxylation of aqueous formaldehyde using a dehydrating recycle stream to decrease water concentration 有权
标题翻译：使用脱水再循环流使甲醛水解氢化以降低水的浓度
公开(公告)号：US09040748B2
公开(公告)日：2015-05-26
申请号：US13491954
申请日：2012-06-08
申请人： Mesfin Ejerssa Janka , Scott Donald Barnicki , Robert Thomas Hembre , Kelley Margaret Moran , Stephen Neal Falling
发明人： Mesfin Ejerssa Janka , Scott Donald Barnicki , Robert Thomas Hembre , Kelley Margaret Moran , Stephen Neal Falling
IPC分类号： C07C51/12 , C07C27/04 , C07C29/149
CPC分类号： C07C51/12 , C07C29/149 , C07C59/06 , C07C31/202
摘要： Disclosed is a process for the production and purification of glycolic acid or glycolic acid derivatives by the carbonylation of aqueous formaldehyde. The water in the hydrocarboxylation zone is reduced via reaction with the ester bonds in a recycle stream comprising glycolic acid oligomers and/or methyl glycolate oligomers.
摘要翻译：公开了通过甲醛水解羰基化生产和纯化乙醇酸或乙醇酸衍生物的方法。在包含乙醇酸低聚物和/或乙醇酸甲酯低聚物的再循环料流中，通过与酯键的反应来还原加氢羧化区中的水。

10. 发明授权

US08927766B2 Hydrocarboxylation of methylene dipropionate in the presence of a propionic acid and a homogeneous catalyst 有权
标题翻译：在丙酸和均相催化剂存在下，将二丙酸亚丙基酯加氢羧化
公开(公告)号：US08927766B2
公开(公告)日：2015-01-06
申请号：US13431402
申请日：2012-03-27
申请人： Scott Donald Barnicki , Robert Thomas Hembre , Stephen Neal Falling
发明人： Scott Donald Barnicki , Robert Thomas Hembre , Stephen Neal Falling
IPC分类号： C07C51/12 , C07C59/06
CPC分类号： C07C51/12 , C07C29/149 , C07C51/09 , C07C67/08 , C07C67/36 , C07C59/06 , C07C69/24 , C07C69/675 , C07C31/202
摘要： Disclosed is a process for the production and purification of glycolic acid or glycolic acid derivatives by the carbonylation of methylene dipropionate in the presence of a homogeneous acid catalyst and propionic acid. This invention discloses hydrocarboxylations and corresponding homogeneous acid catalyst and glycolic acid separations. The homogeneous acid catalyst is readily separated from the hydrocarboxylation reaction effluent and recycled and the propionic acid is readily removed from the glycolic acid and the propionic acid is recycled.
摘要翻译：公开了一种在均相酸催化剂和丙酸存在下通过二丙酸亚甲酯的羰基化生产和纯化乙醇酸或乙醇酸衍生物的方法。本发明公开了加氢羧化和相应的均相酸催化剂和乙醇酸分离。均匀的酸催化剂容易从加氢羧化反应流出物中分离并再循环，丙酸容易从乙醇酸中除去，丙酸被再循环。

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