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    • 4. 发明申请
    • Comb Polymers and Use Thereof for the Production of Active or Effective Ingredient Formulations
    • 梳形聚合物及其用途来生产活性或有效成分配方
    • US20100048655A1
    • 2010-02-25
    • US12443921
    • 2007-10-04
    • Sebastian KoltzenburgPeter DomboGünter OetterMatthias Bratz
    • Sebastian KoltzenburgPeter DomboGünter OetterMatthias Bratz
    • A01N25/00A01P3/00A01N37/10A01N43/50A01N43/653
    • C08F220/26A01N25/10A01N25/30A61K8/86A61Q19/00C08F220/14C08F226/10C08F265/00C08F265/04C08F283/06C08F290/00C08F290/06C08F290/062C08F2220/1883C08L51/003C08L53/00A01N43/653A01N37/50A01N43/56A01N43/90A01N43/40C08L2666/02
    • The present invention relates to novel comb polymers, to a process for their manufacture and to the use thereof in the stabilization in an aqueous phase of active or effect substances which are insoluble or sparingly soluble in water. The invention furthermore relates to the use of the comb polymers in the manufacture of active substance formulations or active substance preparations of water-insoluble active or effect substances, in particular of active substances for plant protection.The comb polymers can be obtained by copolymerization of monoethylenically unsaturated monomers M, the monomers M comprising: a) at least one monoethylenically unsaturated monomer Ma chosen from esters of monoethylenically unsaturated C3-C8-monocarboxylic acids with C1-C20-alkanols, C5-C10-cycloalkanols, phenyl-C1-C4-alkanols or phenoxy-C1-C4-alkanols and the diesters of monoethylenically unsaturated C4-C8-dicarboxylic acids with C1-C20-alkanols, C5-C10-cycloalkanols, phenyl-C1-C4-alkanols or phenoxy-C1-C4-alkanols; and b) at least one monoethylenically unsaturated monomer Mb chosen from the esters of monoethylenically unsaturated C3-C8-monocarboxylic acids and the mono- and diesters of monoethylenically unsaturated C4-C8-dicarboxylic acids with poly(C2-C4-alkylene ether)ols; and the total amount of the monomers Ma and Mb making up at least 60% by weight of the monomers M constituting the comb polymer.
    • 本发明涉及新颖的梳状聚合物,其制备方法及其在稳定水相中不溶或微溶于水的活性或有效物质中的用途。 本发明还涉及梳状聚合物在制备活性物质制剂或水不溶性活性或有效物质的活性物质制剂中的用途,特别是用于植物保护的活性物质。 梳状聚合物可以通过单烯属不饱和单体M的共聚获得,单体M包含:a)至少一种单烯属不饱和单体Ma,其选自单烯属不饱和C3-C8-一元羧酸与C1-C20-链烷醇的酯,C5-C10 环烷醇,苯基-C 1 -C 4 - 链烷醇或苯氧基-C 1 -C 4 - 链烷醇和单烯属不饱和C 4 -C 8 - 二羧酸与C 1 -C 20链烷醇,C 5 -C 10 - 环烷醇,苯基-C 1 -C 4 - 链烷醇 或苯氧基-C 1 -C 4 - 链烷醇; 和b)选自单烯属不饱和C 3 -C 8 - 单羧酸的酯和单烯属不饱和C4-C8-二羧酸与聚(C 2 -C 4 - 亚烷基醚)醚的单酯和二酯的至少一种单烯属不饱和单体Mb; 并且构成组成聚合物的单体M的至少60重量%的单体Ma和Mb的总量。
    • 5. 发明申请
    • Preparation Comprising at Least One Conazole Fungicide
    • 包括最少一种针唑杀真菌剂的制备
    • US20080318785A1
    • 2008-12-25
    • US11918522
    • 2006-04-13
    • Sebastian KoltzenburgPeter DomboGunter OetterChristian KrugerWolfgang SchrofMatthias Bratz
    • Sebastian KoltzenburgPeter DomboGunter OetterChristian KrugerWolfgang SchrofMatthias Bratz
    • A01N43/653C08F228/02A01P3/00C08F26/06
    • C08F220/60A01N25/10A01N25/14A01N43/653C08F220/18C08F220/38A01N2300/00
    • The invention relates to preparations, in particular plant-protective preparations which contain a mixture of at least two different active plant-protective substances, wherein a) at least one active substance is selected from a conazole group (active substance 1) and b) another active plant-protective substance (active substance 2) whose water solubility at a temperature of 20° C. is less than 20 g/l, c) at least one type of copolymer CP consisting of M monomers comprising α) at least one type of monoethylenically unsaturated monomer M1 comprising at least one sulphonic acid group and β) at least one type of neutral monoethylenically unsaturated monomer M2, wherein the quantitative ratio between the active substance 1 and the other active plant-protective substance 2 ranges from 1:10 to 10:1. Said invention also relates to novel copolymers CP which are embodied in the form of polymers consisting of at least three types of different monoethylenically unsaturated monomers M and comprise, in the polymerisation incorporated form, α) at least one type of monoethylenically unsaturated monomer M1 comprising at least one sulphonic acid group, β1) at least one type of neutral monoethylenically unsaturated monomer M2 whose water solubility at a temperature of 20° C. is less than 30 g/l and β2) at least one type of neutral monoethylenically unsaturated monomer M2b whose water solubility at a temperature of 20° C. is greater than 50 g/l.
    • 本发明涉及制剂,特别是含有至少两种不同的活性植物保护物质的混合物的植物保护制剂,其中a)至少一种活性物质选自唑类(活性物质1)和b)另一种 在20℃温度下的水溶性小于20g / l的活性植物保护物质(活性物质2),c)由M单体组成的至少一种共聚物CP,包括α)至少一种类型的 包含至少一个磺酸基团的单烯属不饱和单体M1和β)至少一种中性单烯属不饱和单体M2,其中活性物质1与另一种活性植物保护物质2的定量比范围为1:10至10 :1。 所述发明还涉及新型共聚物CP,其以由至少三种不同单烯属不饱和单体M组成的聚合物的形式体现并且以聚合形式包含α)至少一种类型的单烯属不饱和单体M1,其包含在 至少一种磺酸基团,β1)至少一种类型的中和单烯属不饱和单体M2b,其在20℃温度下的水溶性小于30g / l和β2)至少一种中性单烯属不饱和单体M2b,其中 在20℃的温度下的水溶解度大于50g / l。
    • 6. 发明申请
    • Use Of Menadione
    • US20080039320A1
    • 2008-02-14
    • US11791464
    • 2005-11-24
    • Harald KohleReinhard StierlRandall GoldFelix GorthJohn-Bryan SpeakmanPeter DomboMartin SemarDieter StrobelMatthias NiedenbruckHans Bestman
    • Harald KohleReinhard StierlRandall GoldFelix GorthJohn-Bryan SpeakmanPeter DomboMartin SemarDieter StrobelMatthias NiedenbruckHans Bestman
    • A01N35/06A01C1/06A01N43/40A01N43/56A01N43/84A01P3/00A01N43/653A01N43/50A01N25/00
    • A01N35/06A01N2300/00
    • The use of menadione or one of its plant-compatible acid addition salts for enhancing the activity of agrochemicals against phytopathogenic fungi, mixtures of menadione and at least one active compound selected from the following groups: A) azoles, such as cyproconazole, difenoconazole, epoxiconazole, fluquinconazole, flusilazole, hexaconazole, imazalil, metconazole, myclobutanil, penconazole, prochloraz, prothioconazole, tebuconazole, triadimefon, triadimenol, triflumizole; B) strobilurins, such as azoxystrobin, dimoxystrobin, fluoxastrobin, kresoxim-methyl, metominostrobin, orysastrobin, picoxystrobin, pyraclostrobin or trifloxystrobin; C) acylalanines, such as benalaxyl, metalaxyl, mefenoxam, ofurace, oxadixyl; D) amine derivatives, such as spiroxamine; E) anilinopyrimidines, such as pyrimethanil, mepanipyrim or cyprodinil; F) dicarboximides, such as iprodione, procymidone, vinclozolin; G) cinnamides and analogs, such as dimethomorph, flumetover or flumorph; H) dithiocarbamates, such as ferbam, nabam, maneb, metam, metiram, propineb, polycarbamate, thiram, ziram, zineb; I) heterocylic compounds, such as benomyl, boscalid, carbendazim, dithianon, famoxadone, fenamidone, picobenzamid, proquinazid, quinoxyfen, thiophanate-methyl, triforine, 5-chloro-7-(4-methylpiperidin-1-yl)-6-(2,4,6-trifluorophenyl)-[1,2,4]triazolo[1,5-a]pyrimidine, N,N-dimethyl-3-(3-bromo-6-fluoro-2-methylindole-1-sulfonyl)-[1,2,4]triazole-1-sulfonamide or thiophene derivatives of the formula II; K) sulfur and copper fungicides, such as Bordeaux mixture, copper acetate, copper oxychloride, basic copper sulfate; L) nitrophenyl derivatives, such as dinocap; M) phenylpyrroles, such as fenpiclonil or fludioxonil; N) sulfenic acid derivatives, such as captafol, dichlofluanid, tolylfluanid; 0) other fungicides selected from the group consisting of benthiavalicarb, chlorothalonil, cyflufenamid, diclofluanid, diethofencarb, ethaboxam, fenhexamid, fluazinam, iprovalicarb, metrafenone, zoxamide; oxime ether derivatives of the formula III, phenylamidine derivatives of the formula IV, compounds of the formula V, where in the formulae III to V the substituents are defined according to the description; in a synergistically effective amount, methods for controlling harmful fungi using mixtures of menadione with active compounds from groups A) to O) and compositions comprising these mixtures.