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    • 3. 发明申请
    • Amphiphilic Polymer Compositions and their Use
    • 两亲聚合物组合物及其用途
    • US20080287593A1
    • 2008-11-20
    • US11628609
    • 2005-06-07
    • Gunter OetterChristian KrugerHarald KohleMaria SchererNorbert WagnerMatthias BratzRainer BerghausRichard van Gelder
    • Gunter OetterChristian KrugerHarald KohleMaria SchererNorbert WagnerMatthias BratzRainer BerghausRichard van Gelder
    • C08L33/00C08L71/00
    • A01N25/04A01N25/30C08G18/283C08G18/3876C08G18/7831C08L33/06C08L75/04A01N47/24A01N43/653A01N43/40A01N53/00C08L2666/04
    • The present invention relates to amphiphilic polymer compositions, to a process for their preparation and to their use for preparing aqueous active compound compositions of water-insoluble active compounds, in particular active compounds for crop protection.The amphiphilic polymer compositions can be obtained by reacting a) at least one hydrophobic polymer P1 which carries functional groups R1 which are reactive toward isocyanate groups and which is constructed of ethylenically unsaturated monomers M1, comprising: a1) at least 10% by weight, based on the total amount of monomers M1, of monomers M1a of the formula I in which X is oxygen or a group N—R4; R1, R2, R3 and R4 are as defined in the claims and the description; a2) up to 90% by weight, based on the total amount of monomers M1, of neutral monoethylenically unsaturated monomers M1b whose solubility in water at 25° C. is less than 50 g/l and which are different from the monomers M1a; and a3) up to 30% by weight, based on the total amount of monomers M1, of ethylenically unsaturated monomers M1c which are different from the monomers M1a and M1b, b) at least one hydrophilic polymer P2 which carries functional groups R2 which are reactive toward isocyanate groups, c) with at least one compound V which contains isocyanate groups and, with respect to the isocyanate groups, has a functionality of at least 1.5.
    • 本发明涉及两亲聚合物组合物,其制备方法及其用于制备水不溶性活性化合物,特别是用于作物保护的活性化合物的水性活性化合物组合物的用途。 两亲性聚合物组合物可以通过使a)至少一种携带官能团R 1的疏水性聚合物P1与异氰酸酯基团反应,并由烯属不饱和单体M1构成,包括:a1) 至少10重量%,基于单体M1的总量,其中X是氧或NR 4的式I的单体M1a; R 1,R 2,R 3和R 4如权利要求和说明书所定义。 a2)高达90重量%,基于单体M1的总量,在25℃下在水中的溶解度小于50g / l且不同于单体M1a的中性单烯属不饱和单体M1b; 和a3)至多30重量%,基于单体M1的总量,不同于单体M1a和M1b的烯键式不饱和单体M1c,b)至少一种携带官能团R a的亲水性聚合物P2, 其对于异氰酸酯基团是反应性的,c)与至少一种含有异氰酸酯基团的化合物V相对于异氰酸酯基团具有至少1.5的官能度。
    • 10. 发明申请
    • Method of Inducing Tolerance of Plants Against Bacterioses
    • 诱导植物对细菌耐受性的方法
    • US20090143416A1
    • 2009-06-04
    • US12223029
    • 2007-03-06
    • Harald KohleTed R. BardinelliMarco-Antonio Tavares-Rodrigues
    • Harald KohleTed R. BardinelliMarco-Antonio Tavares-Rodrigues
    • A61K31/4152A61K31/4196A61P37/04A61K31/505
    • A01N47/24A01N37/50A01N43/40A01N43/54A01N43/76A01N43/88A01N47/14A01N47/34A01N55/00A01N59/20A01N63/04A01N2300/00
    • A method of inducing tolerance of plants against bacterioses which comprises treating the plants, the soil or seeds with an effective amount of a combination of a compound of the formula I in which X is halogen, alkyl or trifluoromethyl; m is 0 or 1; Q is C(═CH—CH3)—COOCH3, C(═CH—OCH3)—COOCH3, C(═N—OCH3)—CONHCH3, C(═N—OCH3)—COOCH3, N(—OCH3)—COOCH3, or a group Q1  wherein # denotes the bond to the phenyl ring; A is —O—B, —CH2O—B, —OCH2—B, —CH2S—B, —CH═CH—B, —C≡C—B, —CH2O—N═C(R1)—B, —CH2S—N═C(R1)—B, —CH2O—N═C(R1)—CH═CH—B, or —CH2O—N═C(R1)—C(R2)═N—OR3, where B is phenyl, naphthyl, 5- or 6-membered hetaryl or 5- or 6-membered heterocyclyl, containing one to three N atoms and/or one O or S atom or one or two O and/or S atoms, the ring systems being unsubstituted or substituted as defined in the description; R1 is hydrogen, cyano, alkyl, haloalkyl, cycloalkyl, alkoxy, or alkylthio; R2 is phenyl, phenylcarbonyl, phenylsulfonyl, 5- or 6-membered hetaryl, 5- or 6-membered hetarylcarbonyl or 5- or 6-membered hetarylsulfonyl, the ring systems being unsubstituted or substituted by one to three radicals Ra, C1-C10-alkyl, C3-C6-cycloalkyl, C2-C10-alkenyl, C2-C10-alkynyl, C1-C10-alkyl-carbonyl, C2-C10-alkenylcarbonyl, C3-C10-alkynylcarbonyl, C1-C10-alkyl-sulfonyl, or C(═NORA)—RB, the hydrocarbon radicals of these groups being unsubstituted or substituted as defined in the description; R3 is hydrogen, C1-C6-alkyl, C2-C6-alkenyl, C2-C6-alkynyl, the hydrocarbon radicals of these groups being unsubstituted or substituted as defined in the description; and a second active compound as defined in the description; which is taken up by the plants or seeds.
    • 诱导植物对细菌的耐受性的方法,其包括用有效量的式I化合物(其中X为卤素,烷基或三氟甲基)的化合物处理植物,土壤或种子; m为0或1; C(-CH-CH 3)-COOCH 3,C(-CH-OCH 3)-COOCH 3,C(-N-OCH 3)-CONHCH 3,C(-N-OCH 3)-COOCH 3,N(-OCH 3) 或其中#表示与苯环的键的基团Q1; A是-OB,-CH2O-B,-OCH2-B,-CH2S-B,-CH-CH-B,-C≡CB,-CH2O-NC(R1)-B,-CH2S-NC(R1) B,-CH2O-NC(R1)-CH-CH-B或-CH2O-NC(R1)-C(R2)-N-OR3,其中B是苯基,萘基,5-或6-元杂芳基或5 - 或6-元杂环基,其含有一至三个N原子和/或一个O或S原子或一个或两个O和/或S原子,所述环系是未被描述的或如说明书中所定义的取代; R 1是氢,氰基,烷基,卤代烷基,环烷基,烷氧基或烷硫基; R 2是苯基,苯基羰基,苯基磺酰基,5-或6-元杂芳基,5-或6-元杂芳基羰基或5-或6-元杂芳基磺酰基,该环系是未被取代的或被1-3个基团取代, 烷基,C 3 -C 6 - 环烷基,C 2 -C 10 - 烯基,C 2 -C 10 - 炔基,C 1 -C 10 - 烷基 - 羰基,C 2 -C 10 - 烯基羰基,C 3 -C 10 - 炔基羰基,C 1 -C 10 - 烷基磺酰基或C (-NORA)-RB,这些基团的烃基是未被描述的或如说明书中所定义的取代基; R 3是氢,C 1 -C 6 - 烷基,C 2 -C 6 - 烯基,C 2 -C 6 - 炔基,这些基团的烃基是未被取代或如说明书中所定义的取代; 和如说明书中定义的第二活性化合物; 这被植物或种子摄取。