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    • 3. 发明授权
    • Electrophotographic photoreceptor with porous anodized Al layer and
process for producing the same
    • 具有多孔阳极氧化Al层的电子照相感光体及其制造方法
    • US5132200A
    • 1992-07-21
    • US586160
    • 1990-09-21
    • Yuzuru FukudaShigeru YagiKen EbiharaYasunobu Iwata
    • Yuzuru FukudaShigeru YagiKen EbiharaYasunobu Iwata
    • G03G5/08G03G5/043G03G5/047G03G5/082
    • G03G5/0433G03G5/047G03G5/082
    • An electrophotographic photoreceptor is disclosed, comprising at least a substrate having thereon a charge transporting layer and a charge generating layer, wherein said charge transporting layer is a porous anodized aluminum film which is formed by anodizing a substrate at least a surface of which comprises aluminum or an aluminum alloy by using an alternating current having an effective voltage of from 3 to 40 V or an electrical current of alternating waveform having substantially the equal action. And the electrophotographic photoreceptor can be produced by a process comprising subjecting a substrate at least a surface of which comprises aluminum or an aluminum alloy to anodic oxidation in an electrolytic solution by using an alternating current having an effective voltage of from 3 to 40 V or an electrical current of alternating waveform having substantially the equal action to form as a charge transporting layer a porous anodized aluminum film on the substrate and then forming a charge generating layer thereon. The porous anodized aluminum film has sufficient softness to be freed from heat cracks and exhibits satisfactory adhesion to a charge generating layer and excellent mechanical strength.
    • 公开了一种电子照相感光体,其至少包括其上具有电荷传输层和电荷产生层的基底,其中所述电荷输送层是多孔阳极氧化铝膜,其通过阳极氧化底物而形成,所述基底的至少表面包括铝或 通过使用具有3至40V的有效电压的交流电或具有基本上相同作用的交变波形的电流来获得铝合金。 并且电子照相感光体可以通过以下方法制造,该方法包括使至少其表面包含铝或铝合金的基材在电解液中进行阳极氧化,方法是使用有效电压为3-40V的交流电或 交替波形的电流具有基本上相同的作用,以在电荷输送层上形成多孔阳极氧化铝膜,然后在其上形成电荷产生层。 多孔阳极氧化铝膜具有足够的柔软度以免除热裂纹,并且对电荷产生层表现出令人满意的粘附性和优异的机械强度。
    • 4. 发明授权
    • Electrophotographic photoreceptor having an anodized Al-Mg or Al-Mn
alloy substrate and process for producing the same
    • 具有阳极化Al-Mg或Al-Mn合金基底的电子照相感光体及其制造方法
    • US5120626A
    • 1992-06-09
    • US586083
    • 1990-09-21
    • Yuzuru FukudaShigeru YagiKen EbiharaYasunobu Iwata
    • Yuzuru FukudaShigeru YagiKen EbiharaYasunobu Iwata
    • G03G5/08G03G5/047G03G5/082
    • G03G5/082G03G5/047
    • An electrophotographic photoreceptor is disclosed, comprising at least a substrate having thereon a charge transporting layer and a charge generating layer, wherein the charge transporting layer is a porous anodized film which is formed by anodizing a substrate comprising an Al-Mg alloy containing from 2.2 to 5.6% by weight of magnesium and, as impurities, at least one of Mn, Cu, Fe, Si, Cr, and Zn or an Al-Mn alloy containing from 1.0 to 1.5% by weight of manganese and, as impurities, at least one of Cu, Fe, Si, and Zn. And the electrophotographic photoreceptor can be produced by a process comprising subjecting a substrate comprising an Al-Mg alloy containing from 2.2 to 5.6% by weight of magnesium and, as impurities, at least one of Mn, Cu, Fe, Si, Cr, and Zn or an Al-Mn alloy containing from 1.0 to 1.5% by weight of manganese and, as impurities, at least one of Cu, Fe, Si, and Zn to anodic oxidation to form a charge transporting layer comprising a porous anodized film and then forming a charge generating layer on the charge transporting layer. The electrophotographic photoreceptor exhibits excellent physical properties and electrophotographic properties, and satisfactory adhesion between a charge transporting layer and a charge generating layer.
    • 公开了一种电子照相感光体,其至少包括其上具有电荷输送层和电荷产生层的基底,其中所述电荷输送层是多孔阳极氧化膜,其通过阳极氧化包含Al-Mg合金的基底而形成,所述Al-Mg合金含有2.2〜 5.6重量%的镁,作为杂质,含有1.0〜1.5重量%的锰和作为杂质的至少一种Mn,Cu,Fe,Si,Cr和Zn中的至少一种或Al-Mn合金 Cu,Fe,Si和Zn之一。 并且电子照相感光体可以通过以下方法制造,该方法包括使包含含有2.2-5.6重量%镁的Al-Mg合金的基材和作为杂质的至少一种Mn,Cu,Fe,Si,Cr和 Zn或Al-Mn合金,其含有1.0至1.5重量%的锰,并且作为杂质,将Cu,Fe,Si和Zn中的至少一种用于阳极氧化以形成包含多孔阳极氧化膜的电荷输送层,然后 在电荷输送层上形成电荷产生层。 电子照相感光体表现出优异的物理性能和电子照相性能,以及电荷输送层与电荷产生层之间的良好粘附性。
    • 6. 发明授权
    • Electrophotographic photoreceptor
    • 电子照相感光体
    • US5166020A
    • 1992-11-24
    • US584640
    • 1990-09-19
    • Yuzuru FukudaShigeru Yagi
    • Yuzuru FukudaShigeru Yagi
    • G03G5/08G03G5/043G03G5/082G03G5/10
    • G03G5/082G03G5/0433G03G5/102G03G5/104
    • An electrophotographic photoreceptor is disclosed, comprising at least a substrate having thereon a charge transporting layer and a charge generating layer, wherein the charge transporting layer is a porous anodized aluminum film which is formed by anodic oxidation of a substrate at least a surface of which comprises aluminum or an aluminum alloy, with the pores thereof being filled with a metal. The electrophotographic photoreceptor can be produced by a process comprising subjecting a substrate at least a surface of which comprises aluminum or an aluminum alloy to anodic oxidation in a 1 to 30% by weight acid aqueous solution containing at least one inorganic polybasic acid selected from the group consisting of sulfuric acid, phosphoric acid, chromic acid, etc. or at least one organic polybasic acid selected from the group consisting of oxalic acid, malonic acid, tartaric acid, etc. by a direct current at a current density of from 0.1 to 10 A.multidot.dm.sup.-2 or a substantially equal electrical current to form a porous anodized aluminum film on the substrate, filling a metal in the pores of said porous anodized aluminum film by electrolysis in an aqueous solution containing a salt of the metal to form a charge transporting layer comprising the metal-filled porous anodized aluminum film, and then forming a charge generating layer on the charge transporting layer. The metal-filled porous anodized aluminum film is free from defects and exhibits satisfactory adhesion to a charge generating layer and excellent mechanical strength.
    • 公开了一种电子照相感光体,其至少包括其上具有电荷输送层和电荷产生层的基底,其中所述电荷输送层是通过基底的阳极氧化形成的多孔阳极氧化铝膜,其至少表面包括 铝或铝合金,其孔被金属填充。 电子照相感光体可以通过以下方法制备,该方法包括使至少包含铝或铝合金的表面的基底在含有至少一种选自下组的无机多元酸的1至30重量%的酸水溶液中进行阳极氧化 由硫酸,磷酸,铬酸等组成的至少一种有机多元酸或选自草酸,丙二酸,酒石酸等的至少一种有机多元酸,其电流密度为0.1〜10 Axdm-2或基本上相等的电流以在基底上形成多孔阳极氧化铝膜,通过在含有金属盐的水溶液中电解,在所述多孔阳极氧化铝膜的孔中填充金属,以形成电荷输送层 包括金属填充的多孔阳极氧化铝膜,然后在电荷输送层上形成电荷产生层。 金属填充的多孔阳极氧化铝膜没有缺陷,并且对电荷产生层表现出令人满意的粘附力和优异的机械强度。
    • 7. 发明授权
    • Negatively chargeable electrophotographic photoreceptor
    • 可负电荷的电子照相感光体
    • US5556729A
    • 1996-09-17
    • US464466
    • 1995-06-05
    • Yuzuru FukudaTsuyoshi OhtaMasato OnoTaketoshi HigashiShigeru Yagi
    • Yuzuru FukudaTsuyoshi OhtaMasato OnoTaketoshi HigashiShigeru Yagi
    • G03G5/08G03G5/082G03G5/147
    • G03G5/08235G03G5/08278
    • An electrophotographic photoreceptor comprising: an electrically conductive substrate, a charge injection blocking layer formed on said electrically conductive substrate, a photoconductive layer comprising a single layer formed on said charge injection blocking layer, said photoconductive layer comprising amorphous silicon containing boron, a positive hole capturing layer formed on said photoconductive layer, said positive hole capturing layer being selected from the group comprising amorphous silicon containing less than 50 ppm boron and amorphous silicon being substantially composed of hydrogen and silicon atoms, and a surface layer formed on said positive hole capturing layer. The boron concentration contained in said photoconductive layer is 0.01-1000 ppm. The surface layer is formed by amorphous silicon nitride, amorphous silicon oxide, amorphous silicon carbide or amorphous carbon as a main body. The charge injection blocking layer has amorphous silicon as a main body and contains a group V element. The electrophotographic photoreceptor is excellent in the dark attenuation, the sensitivity and electrification capacity and does not cause image flow or image fogging on copied images obtained by using the photoreceptor.
    • 一种电子照相感光体,其特征在于,具有:导电性基板,形成在所述导电性基板上的电荷注入阻挡层,含有形成于所述电荷注入阻挡层上的单层的光电导层,所述光电导层含有含硼的非晶硅, 所述空穴捕获层选自含有小于50ppm硼的非晶硅和基本上由氢和硅原子组成的非晶硅,以及形成在所述正空穴捕获层上的表面层。 所述光电导层中含有的硼浓度为0.01〜1000ppm。 表面层由非晶氮化硅,非晶氧化硅,非晶碳化硅或无定形碳作为主体形成。 电荷注入阻挡层以非晶硅为主体,含有V族元素。 电子照相感光体在黑暗衰减,灵敏度和带电能力方面优异,并且不会对通过使用感光体获得的复印图像上的图像流动或图像起雾。