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    • 3. 发明授权
    • Two-component type developer and image forming method
    • 双组分型显影剂和成像方法
    • US06312862B1
    • 2001-11-06
    • US09434401
    • 1999-11-05
    • Kenji OkadoRyoichi FujitaYushi MikuriyaShinya YachiKazumi Yoshizaki
    • Kenji OkadoRyoichi FujitaYushi MikuriyaShinya YachiKazumi Yoshizaki
    • G03G9113
    • G03G9/097G03G9/0819G03G9/10G03G9/107G03G9/113
    • A two-component type developer has a negatively chargeable toner having toner particles and an external additive and a magnetic-fine-particle-dispersed resin carrier. The magnetic-fine-particle-dispersed resin carrier has composite particles containing at least inorganic compound particles and a binder resin. The inorganic compound particles have been surface-treated with a lipophilic-treating agent having at least one type of functional group (A) selected from the group consisting of an epoxy group, an amino group, a mercapto group, an organic acid group, an ester group, a ketone group, an alkyl halide group and an aldehyde group, or a mixture of the agent. The composite particles have been surface-coated with at least one type of coupling agent having at least one type of functional group (B) different from the functional group (A) the lipophilic-treating agent. The functional group (B) the coupling agent has being a functional group or groups selected from the group consisting of an epoxy group, an amino group and a mercapto group. The negatively chargeable toner has a weight-average particle diameter of from 3 &mgr;m to 9 &mgr;m.
    • 双组分型显影剂具有带负电荷的调色剂,其具有调色剂颗粒和外部添加剂和磁性微粒分散树脂载体。 磁性粒子分散树脂载体具有至少含有无机化合物粒子和粘合剂树脂的复合粒子。 无机化合物颗粒已经用具有至少一种选自环氧基,氨基,巯基,有机酸基,官能团(A)中的至少一种官能团(A)的亲脂性处理剂进行表面处理 酯基,酮基,烷基卤基和醛基,或者该试剂的混合物。 复合颗粒已经用至少一种类型的具有至少一种类型的官能团(B)的不同于亲脂性处理剂的官能团(A)的偶联剂进行表面涂覆。 官能团(B)偶联剂是选自环氧基,氨基和巯基的官能团或基团。 负带电性调色剂的重均粒径为3〜9μm。
    • 4. 发明授权
    • Magnetic carrier, two-component developer and image forming method
    • 磁性载体,双组分显影剂和成像方法
    • US6124067A
    • 2000-09-26
    • US358409
    • 1999-07-22
    • Yushi MikuriyaKenji OkadoKazumi Yoshizaki
    • Yushi MikuriyaKenji OkadoKazumi Yoshizaki
    • G03G9/08G03G9/097G03G9/107G03G9/113G03G15/08
    • G03G9/09708G03G9/09716G03G9/09725G03G9/107G03G9/1075G03G9/1132G03G9/1134G03G9/1135G03G9/1139
    • A magnetic carrier constituting a two-component developer for use in an electrophotographic image forming method is formed of a carrier core comprising a first resin and magnetic fine particles dispersed in the first resin, and a second resin surface-coating the carrier core. (a) The magnetic carrier has a true specific gravity of 2.5-4.5, a magnetization .sigma..sub.1000 as measured in a magnetic field of 1000.times.(10.sup.3 /4.pi.).multidot.A/m (1000 oersted) of 15-60 Am.sup.2 /kg (emu/g), a residual magnetization .sigma..sub.r of 0.1-20 Am.sup.2 /kg (emu/g) and a resistivity of 5.times.10.sup.11 -5.times.10.sup.15 ohm.cm. (b) The first resin has a polymer chain including a methylene unit (--CH.sub.2 --). (c) The second resin has at least a fluoro-alkyl unit, a methylene unit (--CH.sub.2 --) and an ester unit. (d) The carrier core is surface-coated with (i) a mixture of the second resin and a coupling agent having at least an amino group and a methylene unit, or (ii) a coupling agent having at least an amino group and a methylene unit, and then with the second resin.
    • 构成用于电子照相成像方法的双组分显影剂的磁性载体由包含分散在第一树脂中的第一树脂和磁性细颗粒的载体芯和表面涂覆载体芯的第二树脂形成。 (a)磁性载体的真比重为2.5-4.5,在1000×(103/4 pi)×A / m(1000奥斯特)为15-60Am 2 / kg(emu)的磁场中测量的磁化σ1000 / g),剩余磁化σr为0.1-20Am 2 / kg(emu / g),电阻率为5×10 11 -5×10 15欧姆·厘米。 (b)第一树脂具有包含亚甲基单元(-CH 2 - )的聚合物链。 (c)第二树脂具有至少氟烷基单元,亚甲基单元(-CH 2 - )和酯单元。 (d)载体芯表面涂覆有(i)第二树脂和至少具有氨基和亚甲基单元的偶联剂的混合物,或(ii)至少具有氨基的偶联剂和 亚甲基单元,然后与第二树脂。
    • 7. 发明授权
    • Image forming apparatus
    • 图像形成装置
    • US07016630B2
    • 2006-03-21
    • US10836278
    • 2004-05-03
    • Kazumi YoshizakiKenji OkadoMasashige TamuraNaotaka Ikeda
    • Kazumi YoshizakiKenji OkadoMasashige TamuraNaotaka Ikeda
    • G03G15/08
    • G03G15/0808G03G15/09G03G2215/0177
    • In an image forming apparatus having a powder transport mechanism including a powder container and a powder transport means which rotates relative to the powder container, the powder transport means has the rotation center substantially on the axis of the powder container, and the space between the inner wall surface of the powder container and the powder transport means is sealed with magnetic particles held by a magnetic-filed generation means. The magnetic particles have a specific saturation magnetization σs and a specific value of A×σA where the residual magnetic flux density of the magnetic-field generation means is represented by A in a specific range and the magnetization intencity of the magnetic particles in a magnetic field with the residual magnetic flux density A is represented by σA.
    • 在具有粉末输送机构的图像形成装置中,粉末输送机构包括粉末容器和相对于粉末容器旋转的粉末输送装置,粉末输送装置具有大致在粉末容器的轴线上的旋转中心, 粉末容器的壁表面和粉末输送装置用磁场产生装置保持的磁性颗粒密封。 磁性颗粒具有特定的饱和磁化信号和Axsigma的特定值,其中磁场产生装置的剩余磁通密度由特定范围内的A表示,并且磁场强度 具有剩余磁通密度A的磁场中的磁性颗粒由σA表示。
    • 8. 发明授权
    • Image forming method
    • 图像形成方法
    • US5994019A
    • 1999-11-30
    • US979960
    • 1997-11-26
    • Kenji OkadoToshiyuki UgaiRyoichi FujitaKazumi Yoshizaki
    • Kenji OkadoToshiyuki UgaiRyoichi FujitaKazumi Yoshizaki
    • G03G13/02G03G15/02G03G9/083
    • G03G13/025G03G15/0241G03G2215/022
    • An image forming method is disclosed in which a contact charging means is brought into contact with a latent image bearing member to electrostatically charge the latent image bearing member on which electrostatic latent images are formed and developed with a one component type or two component type developer to form toner images, using a developing assembly provided with a developing container and a developer carrying member. The one component developer is comprised of toner particles. The two component type developer is comprised of toner particles and a magnetic carrier. The toner particles of the one component type and two component type developers contains fine particles as an external additive.The latent image bearing member has a surface layer having a volume resistivity A of from 10.sup.8 to 10.sup.15 .OMEGA..multidot.cm; the contact charging means comprises an assembly for electrostatically charging the latent image bearing member by applying a voltage to a charging member having a volume resistivity B of from 10.sup.4 to 10.sup.9 .OMEGA..multidot.cm; the toner has, as an external additive, fine particles having a volume resistivity C of from 10.sup.7 to 10.sup.11 .OMEGA..multidot.cm; the magnetic carrier has a volume resistivity D1 of from 10.sup.9 to 10.sup.15 .OMEGA..multidot.cm; and the developer carrying member has a surface layer having a volume resistivity D2 of from 10.sup.9 to 10.sup.15 .OMEGA..multidot.cm. The resistivities A, B, C, D1 and D2 stasisfy the following conditions: B
    • 公开了一种图像形成方法,其中接触充电装置与潜像承载部件接触,以静电潜像形成和显影的潜像承载部件用单组分型或双组分型显影剂静电充电 使用具有显影容器和显影剂承载构件的显影组件形成调色剂图像。 单组分显影剂由调色剂颗粒组成。 双组分型显影剂由调色剂颗粒和磁性载体构成。 单组分型和二组分型显影剂的调色剂颗粒含有作为外部添加剂的细颗粒。 潜像承载部件具有体积电阻率A为108至1015欧米伽×厘米的表面层; 接触充电装置包括用于通过向体积电阻率B为104至109欧姆×xcm的充电部件施加电压来静电充电潜像承载部件的组件; 作为外部添加剂,调色剂具有体积电阻率C为107至1011欧米伽×厘米的细小颗粒; 磁性载体的体积电阻率D1为109〜1015ΩEGEG×cm; 并且显影剂承载构件具有体积电阻率D2为109至1015欧姆×xcm的表面层。 电阻率A,B,C,D1和D2停留在以下条件下:B
    • 9. 发明授权
    • Image forming apparatus, and replenishing developer kit
    • 成像设备和补充开发套件
    • US07024138B2
    • 2006-04-04
    • US10765033
    • 2004-01-28
    • Naotaka IkedaKenji OkadoKazumi YoshizakiHironori Minagawa
    • Naotaka IkedaKenji OkadoKazumi YoshizakiHironori Minagawa
    • G03G15/01
    • G03G15/08G03G15/01G03G15/0865G03G2215/0607G03G2215/066
    • In an image forming apparatus having at least one single electrostatic latent image bearing member and a plurality of image forming units each having a replenishing developer cartridge and a developing assembly, at least one of the image forming units is a special-color image forming unit having a special-color replenishing developer cartridge containing a special-color replenishing developer, and at least one of the other image forming unit is a non-special-color image forming unit having a non-special-color replenishing developer cartridge containing a non-special-color replenishing developer. The special-color replenishing developer cartridge has a volume larger than the volume of the non-special-color replenishing developer cartridge, and the special-color replenishing developer contains a toner and a carrier.
    • 在具有至少一个单一静电潜像承载部件和多个图像形成单元的图像形成装置中,每个图像形成单元均具有补充显影剂盒和显影组件,至少一个图像形成单元是特殊颜色图像形成单元,其具有 包含特殊颜色补充显影剂的特殊颜色补充显影剂盒,并且至少其中一个图像形成单元是非特殊颜色图像形成单元,其具有包含非特殊颜色补充显影剂盒的非特殊颜色补充显影剂盒 彩色补充开发者。 特殊颜色补充显影剂盒的体积大于非特殊颜色补充显影剂盒的体积,并且特殊颜色补充显影剂含有调色剂和载体。
    • 10. 发明授权
    • Toner, two-component developer and image forming method
    • 调色剂,双组分显影剂和成像方法
    • US6077635A
    • 2000-06-20
    • US99527
    • 1998-06-18
    • Kenji OkadoRyoichi FujitaWakashi IidaYuji MorikiKazumi YoshizakiMichihisa Magome
    • Kenji OkadoRyoichi FujitaWakashi IidaYuji MorikiKazumi YoshizakiMichihisa Magome
    • G03G9/08G03G9/097G03G13/01
    • G03G9/0827G03G9/0819G03G9/09708
    • A toner is disclosed which has toner particles and an external additive. The toner has (a) in circularity distribution of particles measured with a flow type particle image analyzer, an average circularity of from 0.920 to 0.995, containing particles with a circularity of less than 0.950 in an amount of from 2% by number to 40% by number; and (b) a weight-average particle diameter of from 2.0 .mu.m to 9.0 .mu.m as measured by Coulter method. The external additive has, on the toner particles, at least (i) an inorganic fine powder (A) present in the state of primary particles or secondary particles and having an average particle length of from 10 m.mu.m to 400 m.mu.m and a shape factor SF-1 of from 100 to 130 and (ii) a non-spherical inorganic fine powder (B) formed by coalescence of a plurality of particles and having a shape factor SF-1 of greater than 150. Also, a two-component developer and an image forming method, using the toner, are disclosed.
    • 公开了一种具有调色剂颗粒和外部添加剂的调色剂。 调色剂具有(a)以流动型颗粒图像分析仪测量的颗粒的圆形分布,平均圆形度为0.920至0.995,其中圆形度小于0.950的颗粒的量为2%至40% 按数量 (b)通过Coulter法测定的重均粒径为2.0μm〜9.0μm。 外部添加剂在调色剂颗粒上至少存在(i)以一次粒子或二次粒子状态存在的平均粒子长度为10μm〜400μm的无机细粉末(A), 100〜130的形状因子SF-1和(ii)通过多个粒子的聚结而形成的非球形的无机细粉末(B),并且具有大于150的形状因子SF-1。另外, - 组分显影剂和使用调色剂的图像形成方法。