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1. 发明授权

US06580006B1 Catalytic process for preparing perfluoroethanesulfonyl fluoride and/or perfluorodiethylsulfone 有权
标题翻译：制备全氟乙磺酰氟和/或全氟二乙基砜的催化方法
公开(公告)号：US06580006B1
公开(公告)日：2003-06-17
申请号：US10137165
申请日：2002-05-02
申请人： William M. Lamanna , Michael D. Barrera , Gerald L. Bauer , Yuri Cheburkov
发明人： William M. Lamanna , Michael D. Barrera , Gerald L. Bauer , Yuri Cheburkov
IPC分类号： C07C30900
CPC分类号： C07C303/02 , C07C315/00 , Y02P20/582 , C07C317/04 , C07C309/80
摘要： The present invention provides a catalytic process for preparing perfluoroethanesulfonyl fluoride and/or perfluorodiethylsulfone using a two-part catalytic process comprising a metal fluoride and a crown ether.
摘要翻译：本发明提供使用包含金属氟化物和冠醚的两部分催化方法制备全氟乙磺酰氟和/或全氟二乙基砜的催化方法。

2. 发明授权

US5723630A Process for preparing fluorinated beta-sultones 失效
标题翻译：制备氟化β-磺内酯的方法
公开(公告)号：US5723630A
公开(公告)日：1998-03-03
申请号：US802193
申请日：1997-02-18
申请人： Yuri Cheburkov , William M. Lamanna
发明人： Yuri Cheburkov , William M. Lamanna
IPC分类号： C07C303/02 , C07C309/06 , C07C309/80 , C07D327/02 , C07D331/04
CPC分类号： C07D327/02
摘要： A process allows the preparation of a fluorinated beta-sultone by reacting a fluorinated olefin with oleum.
摘要翻译：一种方法允许氟化烯烃与发烟硫酸反应来制备氟化β-磺内酯。

3. 发明授权

US5616794A Process for preparing fluorocarboxylic acid halides 失效
标题翻译：氟代羧酸卤化物的制备方法
公开(公告)号：US5616794A
公开(公告)日：1997-04-01
申请号：US558243
申请日：1995-11-17
申请人： Frederick E. Behr , Yuri Cheburkov
发明人： Frederick E. Behr , Yuri Cheburkov
IPC分类号： C07C51/58 , C07C53/50
CPC分类号： C07C51/58
摘要： A process for preparing fluorocarboxylic acid halides comprises the steps of (a) forming a starting composition comprising (i) at least one fluorosulfonic acid halide comprising at least one halosulfonyldifluoromethyl group (--Cf.sub.2 SO.sub.2 X, wherein X is halogen); and (ii) at least one Group III or Group V Lewis acid; and (b) allowing the fluorosulfonic acid halide and the Lewis acid to react to form a product composition comprising at least one fluorocarboxylic acid halide. The process enables the preparation of even higher molecular weight fluorocarboxylic acid halides in good yield.
摘要翻译：制备氟代羧酸卤化物的方法包括以下步骤：（a）形成起始组合物，其包含（i）至少一种含有至少一个卤代磺酰基二氟甲基（-Cf 2 SO 2 X，其中X为卤素）的氟磺酰卤; 和（ii）至少一种III族或V族路易斯酸; 和（b）使氟磺酰卤和路易斯酸反应以形成包含至少一种氟代羧酸卤化物的产物组合物。该方法能够以高产率制备更高分子量的氟代羧酸酰卤。

4. 发明授权

US5427656A Process for preparing branched perfluorochemicals 失效
标题翻译：制备支链全氟化合物的方法
公开(公告)号：US5427656A
公开(公告)日：1995-06-27
申请号：US219119
申请日：1994-03-29
申请人： Fredrick E. Behr , Yuri Cheburkov , John C. Hansen , Dong-Wei Zhu
发明人： Fredrick E. Behr , Yuri Cheburkov , John C. Hansen , Dong-Wei Zhu
IPC分类号： C25B3/08
CPC分类号： C25B3/08
摘要： A process for preparing inert or functional, tertiary carbon-containing perfluorochemicals comprises the step of electrochemically fluorinating, in the presence of anhydrous hydrogen fluoride, a composition comprising at least one starting compound selected from the group consisting of those fluoroalkanes, fluoroalkenes, fluoroalcohols, fluorocarboxylic acids, fluorocarboxylic acid halides, fluorocarboxylic acid esters, and combinations thereof which contain at least one (preferably, only one) --CX.sub.2 --C(R.sub.f).sub.2 -- group, wherein each X is independently selected from the group consisting of hydrogen, fluorine, and CH.sub.2 OH, with the proviso that only one X can be CH.sub.2 OH, and each R.sub.f group is independently perfluoroalkyl. The process enables preservation of the highly-branched structure of the starting compounds resulting in high product yields.
摘要翻译：制备惰性或功能性含叔碳的全氟化合物的方法包括在无水氟化氢存在下电化学氟化包含至少一种起始化合物的组合物的步骤，所述起始化合物选自氟代烷烃，氟代烯烃，氟代醇，氟代羧酸含有至少一个（优选仅一个）-CX 2 -C（R f）2 - 基团的酸，氟代羧酸卤化物，氟代羧酸酯及其组合，其中每个X独立地选自氢，氟，和CH 2 OH，条件是仅一个X可以是CH 2 OH，并且每个R f基团独立地是全氟烷基。该方法可保存起始化合物的高度支化结构，从而产生高产率。

5. 发明授权

US06437202B2 Fluoroalkene-nucleophile adducts for analysis and removal of fluoroalkenes 失效
标题翻译：用于分析和除去氟代烯烃的氟烯烃 - 亲核试剂加合物
公开(公告)号：US06437202B2
公开(公告)日：2002-08-20
申请号：US09880279
申请日：2001-06-13
申请人： Mark Eugene Mueller , Donald Frederick Hagen , Yuri Cheburkov , Fred Lynn DeRoos , Glenn Delmont Johnson , John Stephen Marhevka , Venkateswarlu Pothapragada
发明人： Mark Eugene Mueller , Donald Frederick Hagen , Yuri Cheburkov , Fred Lynn DeRoos , Glenn Delmont Johnson , John Stephen Marhevka , Venkateswarlu Pothapragada
IPC分类号： C07C1738
CPC分类号： C07C21/18 , B01D15/00 , B01J20/3204 , B01J20/3212 , B01J20/3248 , B01J20/3251 , B01J20/3253 , B01J20/3255 , C07B63/02 , C07C17/38 , C07C17/389 , C07C17/395 , Y10T436/19 , Y10T436/193333
摘要： A method for removing one or more fluorinated alkenes from a fluid comprises the step of contacting the fluid with an N-, S-, or P-containing nucleophile for a time sufficient to form an N-, S-, or P-containing nucleophile-fluoroalkene adduct. The nucleophile, and therefore the adduct, can be covalently bonded, coated or sorbed to a particulate support which can be enmeshed in a porous, fibrous web. In a preferred embodiment the fluorinated alkene can have the formula wherein A=F or Rf; X=H, F, Cl, Rf, or YRf; Z=H, F, Cl, or Rf; and Y=O, N, or S; with the proviso that at least one A=F, and at most one of Z and X is H; wherein each Rf is independently selected from the group consisting of highly fluorinated or perfluorinated alkyl groups; and a combination of any two Rf groups can be linked to form a cyclic structure. The Rf alkyl chains may contain from 1-20 carbon atoms, with 1-12 carbon atoms preferred. The Rf alkyl chains may be straight, branched, or cyclic. Preferably, Rf is CF3, C2F5, or C3F7.
摘要翻译：从流体中除去一种或多种氟化烯烃的方法包括使流体与含有N-，S-或P的亲核试剂接触足够时间以形成含有N-，S-或P的亲核试剂的步骤氟烯烃加成物。亲核试剂，因此加合物可以共价键合，涂覆或吸附到可以嵌入多孔纤维网中的颗粒载体上。在优选的实施方案中，氟化烯可以具有式F = F或Rf; X = H，F，Cl，Rf或YRf; Z = H，F，Cl或Rf; 和Y = O，N或S; 条件是至少一个A = F，并且Z和X中至多一个是H; 其中每个Rf独立地选自高氟化或全氟化的烷基; 并且可以连接任何两个Rf基团的组合以形成环状结构.Rf烷基链可以含有1-20个碳原子，优选1-12个碳原子。 Rf烷基链可以是直链，支链或环状的。 Rf优选为CF 3，C 2 F 5或C 3 F 7。

6. 发明授权

US5573654A Process for making hexafluoropropane and perfluoropropane 失效
标题翻译：制备六氟丙烷和全氟丙烷的方法
公开(公告)号：US5573654A
公开(公告)日：1996-11-12
申请号：US205636
申请日：1994-03-04
申请人： Yuri Cheburkov , John C. Hansen
发明人： Yuri Cheburkov , John C. Hansen
IPC分类号： C07C17/10 , C07C17/361 , C07C17/363 , C07C19/08 , C07C21/18 , C07C41/06 , C07C43/12 , C25B3/08
CPC分类号： C07C17/361 , C07C17/363
摘要： Perfluoroisobutene-MeOH adduct (2H-octafluororisobutyl methyl ether) is converted to hexafluoropropane by reaction with trialkyl amine (eg. triethyl amine) and H.sub.2 O. 1,1,1,3,3-Pentafluoropropene is also produced in lesser amounts. The electrolysis of the reaction product in anhydrous HF (at 10.degree.-50.degree. C., 0-140 kPa, and 50-300 amps/m.sup.2 anode area) yields C.sub.3 F.sub.8 and some CF.sub.3 CFHCF.sub.3 which is condensed out of a gas stream from the electrolysis cell.
摘要翻译：通过与三烷基胺（例如三乙胺）和H 2 O反应将全氟异丁烯-MeOH加合物（2H-八氟异丁基甲基醚）转化成六氟丙烷。 1,1,3-三氟丙烯也以较少的量生产。反应产物在无水HF（10°-50℃，0-140kPa和50-300安培/ m 2阳极区域）中的电解产生C3F8和一些CF 3 CFHCF 3，其从电解气流中冷凝出来细胞。

7. 发明授权

US5318674A Process for preparing perfluoroalkanesulfonyl fluorides 失效
标题翻译：制备全氟烷基磺酰氟的方法
公开(公告)号：US5318674A
公开(公告)日：1994-06-07
申请号：US85540
申请日：1993-06-30
申请人： Fredrick E. Behr , Yuri Cheburkov , John C. Hansen
发明人： Fredrick E. Behr , Yuri Cheburkov , John C. Hansen
IPC分类号： C25B3/06 , C07C303/02 , C07C303/22 , C07C309/80 , C25B3/08 , C25B1/24
CPC分类号： C07C303/02 , C07C303/22 , C25B3/08
摘要： A process for preparing perfluoroalkanesulfonyl fluorides, e.g., perfluoromethanesulfonyl fluoride, comprises electrochemically fluorinating in the presence of anhydrous hydrogen fluoride at least one precursor compound selected from the group consisting of .alpha.,.beta.-difluoroalkane-.beta.-sultones, e.g., 1,1,2,2-tetrafluoroethane sultone, and the corresponding .alpha.-halocarbonylfluoroalkanesulfonyl halides, e.g., fluorocarbonyldifluoromethanesulfonyl fluoride. The process can be used to prepare perfluoroalkanesulfonyl fluorides in good yield and can be, for example, both more electrically-efficient and more fluorine-efficient than the conventional preparative method involving the electrochemical fluorination of hydrocarbon alkanesulfonyl halides.
摘要翻译：一种制备全氟烷基磺酰氟（如全氟甲磺酰氟）的方法包括在无水氟化氢存在下电化学氟化至少一种选自α，β-二氟烷烃-β-磺内酯的前体化合物，例如1,1,2 ，2-四氟乙烷磺内酯和相应的α-卤代羰基氟烷基磺酰卤，例如氟代羰基二氟甲磺酰氟。该方法可用于以高产率制备全氟烷基磺酰基氟化物，并且可以例如比包含烃链烷磺酰卤的电化学氟化的常规制备方法更具有电效率和更高效的氟。

8. 发明授权

US06521461B2 Fluoroalkene-nucleophile adducts for analysis and removal of fluoroalkenes 失效
标题翻译：用于分析和除去氟代烯烃的氟烯烃 - 亲核试剂加合物
公开(公告)号：US06521461B2
公开(公告)日：2003-02-18
申请号：US09881494
申请日：2001-06-14
申请人： Mark Eugene Mueller , Donald Frederick Hagen , Yuri Cheburkov , Fred Lynn DeRoos , Glenn Delmont Johnson , John Stephen Marhevka , Venkateswarlu Pothapragada
发明人： Mark Eugene Mueller , Donald Frederick Hagen , Yuri Cheburkov , Fred Lynn DeRoos , Glenn Delmont Johnson , John Stephen Marhevka , Venkateswarlu Pothapragada
IPC分类号： G01N3300
CPC分类号： C07C21/18 , B01D15/00 , B01J20/3204 , B01J20/3212 , B01J20/3248 , B01J20/3251 , B01J20/3253 , B01J20/3255 , C07B63/02 , C07C17/38 , C07C17/389 , C07C17/395 , Y10T436/19 , Y10T436/193333
摘要： A method for removing one or more fluorinated alkenes from a fluid comprises the step of contacting the fluid with an N-, S-, or P-containing nucleophile for a time sufficient to form an N-, S-, or P-containing nucleophile-fluoroalkene adduct. The nucleophile, and therefore the adduct, can be covalently bonded, coated or sorbed to a particulate support which can be enmeshed in a porous, fibrous web. In a preferred embodiment the fluorinated alkene can have the formula wherein A=F or Rf; X=H, F, Cl, Rf, or YRf; Z= H, F, Cl, or Rf; and Y=O, N, or S; with the proviso that at least one A=F, and at most one of Z and X is H; wherein each Rf is independently selected from the group consisting of highly fluorinated or perfluorinated alkyl groups; and a combination of any two Rf groups can be linked to form a cyclic structure. The Rf alkyl chains may contain from 1-20 carbon atoms, with 1-12 carbon atoms preferred. The Rf alkyl chains may be straight, branched, or cyclic. Preferably, Rf is CF3, C2F5, or C3F7.
摘要翻译：从流体中除去一种或多种氟化烯烃的方法包括使流体与含有N-，S-或P的亲核试剂接触足够时间以形成含有N-，S-或P的亲核试剂的步骤氟烯烃加成物。亲核试剂，因此加合物可以共价键合，涂覆或吸附到可以嵌入多孔纤维网中的颗粒载体上。在优选的实施方案中，氟化烯可以具有式F = F或Rf; X = H，F，Cl，Rf或YRf; Z = H，F，Cl或Rf; 和Y = O，N或S; 条件是至少一个A = F，并且Z和X中至多一个是H; 其中每个Rf独立地选自高氟化或全氟化的烷基; 并且可以连接任何两个Rf基团的组合以形成环状结构.Rf烷基链可以含有1-20个碳原子，优选1-12个碳原子。 Rf烷基链可以是直链，支链或环状的。 Rf优选为CF 3，C 2 F 5或C 3 F 7。

9. 发明授权

US6147268A Fluoroalkene-nucleophile adducts for analysis and removal of fluoroalkenes 失效
标题翻译：用于分析和除去氟代烯烃的氟烯烃 - 亲核试剂加合物
公开(公告)号：US6147268A
公开(公告)日：2000-11-14
申请号：US154350
申请日：1998-09-16
申请人： Mark Eugene Mueller , Donald Frederick Hagen , Yuri Cheburkov , Fred Lynn DeRoos , Glenn Delmont Johnson , John Stephen Marhevka , Venkateswarlu Pothapragada
发明人： Mark Eugene Mueller , Donald Frederick Hagen , Yuri Cheburkov , Fred Lynn DeRoos , Glenn Delmont Johnson , John Stephen Marhevka , Venkateswarlu Pothapragada
IPC分类号： B01D15/00 , B01J20/32 , C07B63/02 , C07C17/38 , C07C17/389 , C07C17/395 , C07C19/08 , C07C21/18 , B01D24/00 , B01D39/00
CPC分类号： C07C21/18 , B01D15/00 , B01J20/3204 , B01J20/3212 , B01J20/3248 , B01J20/3251 , B01J20/3253 , B01J20/3255 , C07B63/02 , C07C17/38 , C07C17/389 , C07C17/395 , Y10T436/19 , Y10T436/193333
摘要： A method for removing one or more fluorinated alkenes from a fluid comprises the step of contacting the fluid with an N-, S-, or P-containing nucleophile for a time sufficient to form an N-, S-, or P-containing nucleophile-fluoroalkene adduct. The nucleophile, and therefore the adduct, can be covalently bonded, coated or sorbed to a particulate support which can be enmeshed in a porous, fibrous web. In a preferred embodiment the fluorinated alkene can have the formula ##STR1## wherein A=F or R.sub.f ; X=H, F, Cl, R.sub.f, or YR.sub.f ; Z=H, F, Cl, or R.sub.f ; and Y=O, N, or S; with the proviso that at least one A=F, and at most one of Z and X is H; wherein each R.sub.f is independently selected from the group consisting of highly fluorinated or perfluorinated alkyl groups; and a combination of any two R.sub.f groups can be linked to form a cyclic structure. The R.sub.f alkyl chains may contain from 1-20 carbon atoms, with 1-12 carbon atoms preferred. The R.sub.f alkyl chains may be straight, branched, or cyclic. Preferably, R.sub.f is CF.sub.3, C.sub.2 F.sub.5, or C.sub.3 F.sub.7.
摘要翻译：从流体中除去一种或多种氟化烯烃的方法包括使流体与含有N-，S-或P的亲核试剂接触足够时间以形成含有N-，S-或P的亲核试剂的步骤氟烯烃加成物。亲核试剂，因此加合物可以共价键合，涂覆或吸附到可以嵌入多孔纤维网中的颗粒载体上。在优选的实施方案中，氟化烯可以具有下式：其中A = F或Rf; X = H，F，Cl，Rf或YRf; Z = H，F，Cl或Rf; 和Y = O，N或S; 条件是至少一个A = F，并且Z和X中至多一个是H; 其中每个Rf独立地选自高氟化或全氟化的烷基; 并且任何两个Rf基团的组合可以连接形成环状结构。 Rf烷基链可以含1-20个碳原子，优选1-12个碳原子。 Rf烷基链可以是直链，支链或环状的。 Rf优选为CF 3，C 2 F 5或C 3 F 7。

10. 发明授权

US6023002A Process for preparing hydrofluoroethers 失效
标题翻译：制备氢氟醚的方法
公开(公告)号：US6023002A
公开(公告)日：2000-02-08
申请号：US12959
申请日：1998-01-26
申请人： Frederick E. Behr , Yuri Cheburkov
发明人： Frederick E. Behr , Yuri Cheburkov
IPC分类号： C07C41/01 , C07C41/14 , C07C43/12 , C07C45/42 , C07C49/167 , C07C49/457 , C07C41/05 , C07C41/22 , C07C51/60
CPC分类号： C07C43/12 , C07C41/01 , C07C41/14
摘要： Described is a reaction of a fluorinated alkoxide with an alkyl fluorovinylalkyl ether, the alkyl fluorovinylalkyl ether having alpha-beta carbon-carbon unsaturation relative to the ether oxygen, to produce a hydrofluoroether.
摘要翻译：描述了氟化烷氧基与烷基氟乙烯基烷基醚的反应，烷基氟乙烯基烷基醚相对于醚氧具有α-β碳 - 碳不饱和度，以产生氢氟醚。

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