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1. 发明授权

US4719037A Piperidine derivatives, production process therefor, and stabilizers for organic substances containing said derivatives as an active component 失效
标题翻译：哌啶衍生物，其制备方法以及含有所述衍生物作为活性成分的有机物的稳定剂
公开(公告)号：US4719037A
公开(公告)日：1988-01-12
申请号：US887813
申请日：1986-07-21
申请人： Yukoh Takahashi , Yuzo Maegawa , Hiroki Yamamoto , Tatsuo Kaneoya , Haruki Okamura , Shinichi Yachigo , Tamaki Ishii
发明人： Yukoh Takahashi , Yuzo Maegawa , Hiroki Yamamoto , Tatsuo Kaneoya , Haruki Okamura , Shinichi Yachigo , Tamaki Ishii
IPC分类号： C08K5/00 , C07D211/46 , C08K5/34 , C08K5/3432 , C08K5/3435 , C08L1/00 , C08L7/00 , C08L21/00 , C08L23/00 , C08L27/00 , C08L33/00 , C08L33/02 , C08L51/00 , C08L51/02 , C08L67/00 , C08L77/00 , C08L101/00 , C07D401/14 , C09D7/06
CPC分类号： C08K5/3435 , C07D211/46
摘要： Piperidine derivatives represented by the general formula (1) ##STR1## (wherein R.sub.1 is a hydrogen atom, an alkyl group of 1 to 3 carbon atoms or an acyl group of 2 to 18 carbon atoms; and k, m and n each are independently an integer of 1 to 3), a process for producing said derivatives, and stabilizers for organic substances containing said derivatives as an active component.
摘要翻译：由通式（1）表示的哌啶衍生物（1）（其中R 1为氢原子，1〜3个碳原子的烷基或2〜18个碳原子的酰基），k，m，n 各自独立地为1〜3的整数），所述衍生物的制造方法和含有所述衍生物作为活性成分的有机物质的稳定剂。

2. 发明授权

US4670489A Piperidine derivatives, their production and use as stabilizers 失效
标题翻译：哌啶衍生物，其生产和用作稳定剂
公开(公告)号：US4670489A
公开(公告)日：1987-06-02
申请号：US805298
申请日：1985-12-05
申请人： Yukoh Takahashi , Tatsuo Kaneoya , Eizo Okino , Yuzo Maegawa , Haruki Okamura , Shinichi Yachigo , Tamaki Ishii
发明人： Yukoh Takahashi , Tatsuo Kaneoya , Eizo Okino , Yuzo Maegawa , Haruki Okamura , Shinichi Yachigo , Tamaki Ishii
IPC分类号： C07D211/46 , C08K5/00 , C08K5/34 , C08K5/3412 , C08K5/3432 , C08K5/3435 , C08L1/00 , C08L7/00 , C08L21/00 , C08L23/00 , C08L27/00 , C08L33/00 , C08L33/02 , C08L51/00 , C08L51/02 , C08L67/00 , C08L77/00 , C08L101/00 , C09K15/30 , C07D401/12
CPC分类号： C07D211/46 , C09K15/30
摘要： The present invention relates to a piperidine derivative represented by the general formula (I), ##STR1## wherein R.sub.1 is a uni- or divalent carboxylic acid residue, R.sub.2 is a hydrogen atom or a C.sub.1 -C.sub.3 alkyl or C.sub.1 -C.sub.18 acyl group, l is an integer of 1 to 3 and n is 1 or 2,its production and a stabilizer for organic substances containing it as an effective ingredient.
摘要翻译：本发明涉及由通式（I）表示的哌啶衍生物，其中R 1为单或二价羧酸残基，R 2为氢原子或C 1 -C 3烷基或C 1 -C 18 酰基，l为1〜3的整数，n为1或2，其生产和含有有机物质的稳定剂作为有效成分。

3. 发明授权

US4670488A Piperidine derivatives, their production and use as stabilizers 失效
标题翻译：哌啶衍生物，其生产和用作稳定剂
公开(公告)号：US4670488A
公开(公告)日：1987-06-02
申请号：US805380
申请日：1985-12-04
申请人： Yuzo Maegawa , Yukoh Takahashi , Eizo Okino , Tatsuo Kaneoya , Haruki Okamura , Shinichi Yachigo , Tamaki Ishii
发明人： Yuzo Maegawa , Yukoh Takahashi , Eizo Okino , Tatsuo Kaneoya , Haruki Okamura , Shinichi Yachigo , Tamaki Ishii
IPC分类号： C07D211/58 , C08K5/00 , C08K5/34 , C08K5/3412 , C08K5/3435 , C08L1/00 , C08L7/00 , C08L21/00 , C08L23/00 , C08L23/12 , C08L27/00 , C08L33/00 , C08L33/02 , C08L51/00 , C08L51/02 , C08L55/00 , C08L55/02 , C08L67/00 , C08L77/00 , C08L101/00 , C07D401/12
CPC分类号： C07D211/58 , C08K5/3435
摘要： The present invention relates to a piperidine derivative represented by the general formula (I), ##STR1## wherein R.sub.1 and R.sub.2 independently represent a hydrogen atom or a C.sub.1 -C.sub.3 alkyl or C.sub.2 -C.sub.20 acyl group, R.sub.3 represents a hydrogen atom or a C.sub.1 -C.sub.20 alkyl, C.sub.6 -C.sub.20 aryl, C.sub.7 -C.sub.20 aralkyl or C.sub.2 -C.sub.20 acyl group, and l represents 1 to 3, and a stabilizer for organic substances containing said piperidine derivative as an effective ingredient.
摘要翻译：本发明涉及由通式（I）表示的哌啶衍生物，其中R 1和R 2独立地表示氢原子或C 1 -C 3烷基或C 2 -C 20酰基，R 3表示氢原子或C 1 -C 20烷基，C 6 -C 20芳基，C 7 -C 20芳烷基或C 2 -C 20酰基，l表示1-3，以及含有所述哌啶衍生物作为有效成分的有机物的稳定剂。

4. 发明授权

US5049604A Process for producing piperidine derivative and stabilized resin composition containing said derivative 失效
标题翻译：制备含有所述衍生物的哌啶衍生物和稳定化树脂组合物的方法
公开(公告)号：US5049604A
公开(公告)日：1991-09-17
申请号：US600160
申请日：1990-10-19
申请人： Takeo Fujii , Tamaki Ishii , Shinichi Yachigo , Tatsuo Kaneoya , Yukoh Takahashi , Yuzo Maegawa , Haruki Okamura , Eizo Okino
发明人： Takeo Fujii , Tamaki Ishii , Shinichi Yachigo , Tatsuo Kaneoya , Yukoh Takahashi , Yuzo Maegawa , Haruki Okamura , Eizo Okino
IPC分类号： C07D211/58 , C08K5/13 , C08K5/3435 , C08K5/375
CPC分类号： C08K5/13 , C07D211/58 , C08K5/3435 , C08K5/375
摘要： A stabilized resin composition comprising a resin, a piperidine derivative represented by the formula (III) ##STR1## wherein R.sub.1 is a hydrogen atom or an alkyl group having 1 to 3 carbom atoms; R.sub.2 is a hydrogen atom or an alkyl group having from 1 to 2 carbon atoms; and R.sub.3 and R.sub.4 are each independently an alkyl group having 1 to 12 carbon atoms, a phenol-type antioxidant and a sulfur-containing antioxidant. The composition simultaneously meets heat resistance, oxidation resistance and light resistance requirements.
摘要翻译：一种稳定的树脂组合物，其包含树脂，由式（III）表示的哌啶衍生物（III），其中R 1是氢原子或具有1至3个碳原子的烷基; R2是氢原子或具有1至2个碳原子的烷基; R 3和R 4各自独立地为具有1〜12个碳原子的烷基，酚型抗氧化剂和含硫抗氧化剂。该组合物同时满足耐热性，抗氧化性和耐光性要求。

5. 发明授权

US4774274A Thermally stabilized butadiene resins containing a hindered phenolic acrylate or methacrylate 失效
标题翻译：含有受阻酚丙烯酸酯或甲基丙烯酸酯的热稳定丁二烯树脂
公开(公告)号：US4774274A
公开(公告)日：1988-09-27
申请号：US64461
申请日：1987-06-22
申请人： Takeshi Takata , Shin-ichi Yachigo , Tatsuo Kaneoya , Haruki Okamura , Yukoh Takahashi
发明人： Takeshi Takata , Shin-ichi Yachigo , Tatsuo Kaneoya , Haruki Okamura , Yukoh Takahashi
IPC分类号： C08K5/134 , C08K5/10
CPC分类号： C08K5/134
摘要： A process for producing a bisphenol compound useful as deterioration preventor capable of stabilizing organic substances against the decompositions caused by heat, light and oxygen, represented by the following general formula: ##STR1## wherein R.sub.1 represents alkyl group having 1 to 3 carbon atoms, alkenyl group having 2 to 4 carbon atoms, phenyl group or 2-phenylethenyl group; R.sub.2 represents alkyl group having 1 to 5 carbon atoms, or cyclohexyl group; R.sub.3 represents alkyl group having 1 to 9 carbon atoms, cyclohexyl group or phenyl group; and R.sub.4 represents alkyl group having 1 to 11 carbon atoms or phenyl group, which comprises reacting a carboxylic acid represented by the following general formula: ##STR2## wherein R.sub.1 is as defined above, with a bisphenol compound represented by the following general formula: ##STR3## wherein R.sub.2, R.sub.3 and R.sub.4 are as defined above, by the use of a halogenating agent in the presence of a dehydrohalogenating agent, as well as butadiene polymer compositions containing said bisphenol compounds.
摘要翻译：一种生产双酚化合物的方法，该双酚化合物可用作能够稳定有机物质以抵抗由热，光和氧引起的分解引起的降解防止剂，由以下通式表示：其中R 1表示具有1至3个碳原子的烷基，烯基具有2至4个碳原子的基团，苯基或2-苯基乙烯基; R2表示具有1至5个碳原子的烷基或环己基; R3表示具有1至9个碳原子的烷基，环己基或苯基; R 4表示具有1〜11个碳原子的烷基或苯基，其包括使由以下通式表示的羧酸与下述通式表示的双酚化合物反应：其中R 1如上定义。其中R2，R3和R4如上定义，在脱卤化氢剂存在下使用卤化剂，以及含有所述双酚化合物的丁二烯聚合物组合物。

6. 发明授权

US4695407A Method for purifying 1-aminoanthraquinone 失效
标题翻译： 1-氨基蒽醌的纯化方法
公开(公告)号：US4695407A
公开(公告)日：1987-09-22
申请号：US466568
申请日：1983-02-15
申请人： Norio Kotera , Masatoshi Uegaki , Masakatsu Yoshimura , Shinzaburo Masaki , Tatsuo Kaneoya , Takashi Miyaoka , Yuzo Maegawa , Akira Fukasawa
发明人： Norio Kotera , Masatoshi Uegaki , Masakatsu Yoshimura , Shinzaburo Masaki , Tatsuo Kaneoya , Takashi Miyaoka , Yuzo Maegawa , Akira Fukasawa
IPC分类号： C09B1/22 , C07C221/00 , C07C225/34 , C09B1/16 , C07C97/24
CPC分类号： C07C221/00 , C07C225/34
摘要： A method for purifying 1-aminoanthraquinone which comprises previously subjecting a crude 1-aminoanthraquinone to a removal treatment of inorganic impurities so that their content is reduced to not more than 4 wt. % as converted to ash basis or to a removal treatment of iodine-consuming reductive inorganic impurities so that their content is reduced to not more than 2 wt. % as converted to consumed iodine basis, and then rectifying the 1-aminoanthraquinone.
摘要翻译：一种纯化1-氨基蒽醌的方法，其包括先将粗制的1-氨基蒽醌处理无机杂质，使其含量降至不超过4重量％。％转化为灰分或去除处理碘消耗的还原性无机杂质，使其含量降低至不超过2重量％。％转化为消耗碘，然后精馏1-氨基蒽醌。

7. 发明授权

US4851551A Ultraviolet ray absorbing agent 失效
标题翻译：紫外线吸收剂
公开(公告)号：US4851551A
公开(公告)日：1989-07-25
申请号：US155699
申请日：1988-02-16
申请人： Tatsuo Kaneoya , Haruki Okamura
发明人： Tatsuo Kaneoya , Haruki Okamura
IPC分类号： C08K5/34 , C07D493/10 , C07D519/00 , C08K5/00 , C08K5/1575 , C08K5/3467 , C08K5/3472 , C08K5/3475 , C08L1/00 , C08L7/00 , C08L21/00 , C08L23/00 , C08L27/00 , C08L33/00 , C08L33/02 , C08L51/00 , C08L51/02 , C08L67/00 , C08L77/00 , C08L101/00 , C09K3/00
CPC分类号： C07D493/10 , C08K5/1575 , C08K5/3475
摘要： An ultraviolet ray absorbing agent comprising as an active ingredient a spiro compound having a spiro ring structure in the molecule, said spiro compound being represented by the general formula ##STR1## wherein, Y is ##STR2## A is ##STR3## R.sub.1 is hydrogen, halogen, lower alkyl of 1 to 4 carbon atoms, lower alkoxyl of 1 to 4 carbon atoms, carboxyl, or sulfo, R.sub.2 is hydrogen or alkyl of 1 to 12 carbon atoms, R.sub.3 and R.sub.4 are alkyls of 1 to 12 carbon atoms, X is methylene, oxygen, imino, sulfur, sulfinyl, or sulfonyl, and n is an integer of 1 to 12.
摘要翻译：一种紫外线吸收剂，其包含作为活性成分的分子中具有螺环结构的螺环化合物，所述螺环化合物由通式“IMAGE”表示，其中，Y为<！ - SIPO

8. 发明授权

US4745195A Ultraviolet ray absorbing agent 失效
标题翻译：紫外线吸收剂
公开(公告)号：US4745195A
公开(公告)日：1988-05-17
申请号：US856334
申请日：1986-04-28
申请人： Tatsuo Kaneoya , Haruki Okamura
发明人： Tatsuo Kaneoya , Haruki Okamura
IPC分类号： C08K5/34 , C07D493/10 , C07D519/00 , C08K5/00 , C08K5/1575 , C08K5/3467 , C08K5/3472 , C08K5/3475 , C08L1/00 , C08L7/00 , C08L21/00 , C08L23/00 , C08L27/00 , C08L33/00 , C08L33/02 , C08L51/00 , C08L51/02 , C08L67/00 , C08L77/00 , C08L101/00 , C09K3/00 , C07D249/20
CPC分类号： C07D493/10 , C08K5/1575 , C08K5/3475
摘要： An ultraviolet ray absorbing agent comprising as an active ingredient a spiro compound having a spiro ring structure in the molecule, said spiro compound being represented by the general formula ##STR1## wherein, Y is ##STR2## A is ##STR3## R.sub.1 is hydrogen, halogen, lower alkyl of 1 to 4 carbon atoms, lower alkoxyl of 1 to 4 carbon atoms, carboxyl, or sulfo, R.sub.2 is hydrogen or alkyl of 1 to 12 carbon atoms, R.sub.3 and R.sub.4 are alkyls of 1 to 12 carbon atoms, X is methylene, oxygen, imino, sulfur, sulfinyl, or sulfonyl, and n is an integer of 1 to 12.
摘要翻译：一种紫外线吸收剂，其包含作为活性成分的分子中具有螺环结构的螺环化合物，所述螺环化合物由通式“IMAGE”表示，其中，Y为<！ - SIPO

9. 发明授权

US4407756A Process for producing aminoanthraquinone 失效
标题翻译：生产氨基蒽醌的方法
公开(公告)号：US4407756A
公开(公告)日：1983-10-04
申请号：US39606
申请日：1979-05-16
申请人： Akira Fukasawa , Masakatsu Yoshimura , Tatsuo Kaneoya , Kenji Takahashi
发明人： Akira Fukasawa , Masakatsu Yoshimura , Tatsuo Kaneoya , Kenji Takahashi
IPC分类号： C07C225/34 , C09B1/22 , C07C97/24
CPC分类号： C09B1/22
摘要： A process for producing an aminoanthraquinone, which comprises feeding of a nitroanthraquinone and an alkali sulfide continuously into a reaction zone kept at a temperature of from 80.degree. to 140.degree. C., the alkali sulfide being used in an amount of 1.6 or more times the mole number of the nitro group, and withdrawing the reaction product continuously or intermittently from the reaction zone; and an aminoanthraquinone obtained by the above process which is one of the most important intermediates of anthraquinone dyes.
摘要翻译：一种制备氨基蒽醌的方法，其包括将硝基蒽醌和碱金属硫化物连续加入到保持温度为80-140℃的反应区中，碱金属硫化物的用量为1.6或更多倍硝基的摩尔数，连续或间歇地从反应区取出反应产物; 和通过上述方法获得的氨基蒽醌，其是蒽醌染料的最重要的中间体之一。

10. 发明授权

US4612394A Process for producing aminophenyl-.beta.-hydroxyethylsulfone 失效
标题翻译：制备氨基苯基-β-羟乙基砜的方法
公开(公告)号：US4612394A
公开(公告)日：1986-09-16
申请号：US477443
申请日：1983-03-21
申请人： Norio Kotera , Kazuhiro Tada , Shinzaburo Masaki , Kunihisa Goto , Tatsuo Kaneoya
发明人： Norio Kotera , Kazuhiro Tada , Shinzaburo Masaki , Kunihisa Goto , Tatsuo Kaneoya
IPC分类号： B01J23/74 , B01J25/02 , B01J27/20 , C07C317/36 , C07C85/11
CPC分类号： C07C323/00 , C07C317/00
摘要： A process for producing aminophenyl-.beta.-hydroxyethylsulfone of the formula (I), ##STR1## which comprises the following steps: (1) condensing nitrohalobenzene with mercaptoethanol in the presence of an alkali hydroxide and at least one reaction medium selected from N-alkyl-substituted amides and sulfoxides to produce mononitrophenyl-.beta.-hydroxyethylsulfide of the formula (II): ##STR2## (2) oxidizing the mononitrophenyl-.beta.-hydroxyethylsulfide (II) to produce mononitrophenyl-.beta.-hydroxyethylsulfone of the formula (III): ##STR3## and (3) reducing the mononitrophenyl-.beta.-hydroxyethylsulfone to produce the aminophenyl-.beta.-hydroxyethylsulfone of the formula (I). This compound is useful as an intermediate for aminophenyl-.beta.-sulfatoethylsulfone represented by the following formula: ##STR4## which is an important intermediate for vinyl sulfone type reactive dyes largely used for dyeing cellulose fiber materials.
摘要翻译：（I）的氨基苯基-β-羟基乙基砜的制备方法，其包括以下步骤：（1）在碱金属氢氧化物和至少一种选自以下的反应介质的存在下将硝基卤苯与巯基乙醇缩合 N-烷基取代的酰胺和亚砜，以制备式（II）的单硝基苯基-β-羟乙基硫化物：（II）（2）（2）氧化单硝基苯基-β-羟乙基硫醚（II）以制备单硝基苯基-β-羟乙基硫醚式（III）：（III）和（3）还原单硝基苯基-β-羟基乙基砜以制备式（I）的氨基苯基-β-羟基乙基砜。该化合物可用作由下式表示的氨基苯基-β-磺基乙基砜的中间体：作为主要用于染色纤维素纤维材料的乙烯基砜型活性染料的重要中间体的“IMAGE”。

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