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    • 7. 发明授权
    • Liquid crystal device
    • 液晶装置
    • US5510159A
    • 1996-04-23
    • US214428
    • 1994-03-18
    • Masanobu AsaokaHideaki TakaoYukio HanyuMakoto Kojima
    • Masanobu AsaokaHideaki TakaoYukio HanyuMakoto Kojima
    • C08G73/10G02F1/1337
    • C08G73/105G02F1/133723Y10T428/1023Y10T428/31721
    • A liquid crystal device is constituted by a pair of substrates each provided with a transparent electrode, and a liquid crystal disposed between the substrates; at least one of said pair of substrates having thereon an alignment film comprising (i) a polyimide including principally a recurring unit of the following structural formula (I): ##STR1## wherein R.sub.11 denotes a tetravalent organic group, and R.sub.12 and R.sub.13 denote the same or different alkyl or perfluoroalkyl groups having 1-10 carbon atoms, and also at most 20 mol. % of a recurring monoamine unit of the following structural formula (II): ##STR2## wherein R.sub.21 and R.sub.22 denote the same or different alkyl or perfluoroalkyl groups having 1-10 carbon atoms, and X denotes an aromatic group, a heterocyclic group or a derivative group thereof; or (ii) a polyimide obtained through a reaction of at least two species of tetracarboxylic anhydrides of the following formula (III): ##STR3## wherein R.sub.31 denotes a tetravalent organic group, and a diamine of the following formula (IV): ##STR4## wherein R.sub.41 and R.sub.42 denote the same or different alkyl or perfluoroalkyl groups having 1-10 carbon atoms.
    • 液晶装置由分别设置有透明电极的一对基板和设置在基板之间的液晶构成, 所述一对衬底中的至少一个具有取向膜,所述取向膜包含(i)主要包含以下结构式(I)的重复单元的聚酰亚胺:其中R 11表示四价有机基团,R 12和 R13表示相同或不同的具有1-10个碳原子,最多20mol的烷基或全氟烷基。 %结构式(II)的重复单胺单元:其中R 21和R 22表示具有1-10个碳原子的相同或不同的烷基或全氟烷基,X表示芳族基团,杂环基 基团或其衍生基团; 或(ii)通过至少两种下列通式(III)的四羧酸酐的有机基团反应获得的聚酰亚胺和下式(Ⅳ)的二胺:其中R41和 R42表示具有1-10个碳原子的相同或不同的烷基或全氟烷基。
    • 8. 发明授权
    • Liquid crystal device
    • 液晶装置
    • US5320883A
    • 1994-06-14
    • US964061
    • 1992-10-21
    • Masanobu AsaokaHideaki TakaoYukio HanyuMakoto Kojima
    • Masanobu AsaokaHideaki TakaoYukio HanyuMakoto Kojima
    • C08G73/10G02F1/1337
    • C08G73/105G02F1/133723Y10T428/1023Y10T428/31721
    • A liquid crystal device is constituted by a pair of substrates each provided with a transparent electrode, and a liquid crystal disposed between the substrates; at least one of said pair of substrates having thereon an alignment film comprising (i) a polyimide including principally a recurring unit of the following structural formula (I): ##STR1## wherein R.sub.11 denotes a tetravalent organic group, and R.sub.12 and R.sub.13 denote the same or different alkyl or perfluoroalkyl groups having 1 - 10 carbon atoms, and also at most 10 mol. % of a recurring monoamine unit of the following structural formula (II): ##STR2## wherein R.sub.21 and R.sub.22 denote the same or different alkyl or perfluoroalkyl groups having 1 - 10 carbon atoms, and X denotes an aromatic group, a heterocyclic group or a derivative group thereof; or (ii) a polyimide obtained through a reaction of at least two species of tetracarboxylic anhydrides of the following formula (III): ##STR3## wherein R.sub.31 denotes a tetravalent organic group, and a diamine of the following formula (IV): ##STR4## wherein R.sub.41 and R.sub.42 denote the same or different alkyl or perfluoroalkyl groups having 1 - 10 carbon atoms.
    • 液晶装置由分别设置有透明电极的一对基板和设置在基板之间的液晶构成, 所述一对衬底中的至少一个具有取向膜,所述取向膜包含(i)主要包含以下结构式(I)的重复单元的聚酰亚胺:其中R 11表示四价有机基团,R 12和 R13表示相同或不同的具有1-10个碳原子的烷基或全氟烷基,并且最多为10摩尔。 %结构式(II)的重复单胺单元:其中R 21和R 22表示相同或不同的具有1-10个碳原子的烷基或全氟烷基,X表示芳族基团,杂环基 基团或其衍生基团; 或(ii)通过至少两种下式(III)的四羧酸酐反应获得的聚酰亚胺:其中R31表示四价有机基团的下式的四羧酸酐和下式(Ⅳ)的二胺: (IV)其中R41和R42表示具有1-10个碳原子的相同或不同的烷基或全氟烷基。