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1. 发明授权

US5869427A Substituted thiophene derivative and plant disease control agent comprising the same as active ingredient 失效
标题翻译：取代噻吩衍生物和植物病害防治剂，其包含与活性成分相同的物质
公开(公告)号：US5869427A
公开(公告)日：1999-02-09
申请号：US962331
申请日：1997-10-31
申请人： Yukihiro Yoshikawa , Kanji Tomiya , Toshio Kitajima , Hiroyuki Katsuta , Osamu Takahashi , Shunichi Inami , Yuji Yanase , Naofumi Tomura , Junro Kishi , Hideo Kawasima
发明人： Yukihiro Yoshikawa , Kanji Tomiya , Toshio Kitajima , Hiroyuki Katsuta , Osamu Takahashi , Shunichi Inami , Yuji Yanase , Naofumi Tomura , Junro Kishi , Hideo Kawasima
IPC分类号： C07D409/12 , C07D417/12 , C04D333/22 , A01N43/10
CPC分类号： C07D409/12 , C07D417/12
摘要： A novel substituted thiophene derivatives represented by the formula (1) in the invention: ##STR1## wherein R is a straight or branched alkyl group having 3-12 carbon atoms, straight or branched halogenoalkyl group having 3-12 carbon atoms, straight or branched alkenyl group having 3-10 carbon atoms, straight or branched halogenoalkenyl group having 3-10 carbon atoms, or cycloalkyl group having 3-10 carbon atoms, the cycloalkyl group being unsubstituted or substituted with an alkyl group having 1-4 carbon atoms, R and --NHCOAr are adjacent to each other, and Ar is a heterocyclic group; have excellent control activity on various plant disease such as Gray mold, Powdery mildew, Blast and Rust, and are useful as a plant disease control agent due to outstanding residual effect on Botrytis cinerea and excellent effect on Gibberella zeae.
摘要翻译：在本发明中由式（1）表示的新型取代噻吩衍生物：其中R是具有3-12个碳原子的直链或支链烷基，具有3-12个碳原子的直链或支链卤代烷基，具有3-10个碳原子的直链或支链烯基，具有3-10个碳原子的直链或支链卤代烯基或具有3-10个碳原子的环烷基，所述环烷基是未取代的或被具有1-4个碳原子的烷基取代原子，R和-NHCOAr彼此相邻，Ar是杂环基; 对灰霉病，白粉病，爆破和锈病等各种植物病害具有优异的防治作用，由于对灰葡萄孢的突出残留效果，对玉米赤霉菌有极好的效果，可用作植物病害防治剂。

2. 发明授权

US5965774A Substituted anilide derivative 有权
标题翻译：取代苯胺衍生物
公开(公告)号：US5965774A
公开(公告)日：1999-10-12
申请号：US150170
申请日：1998-09-09
申请人： Yukihiro Yoshikawa , Kanji Tomiya , Naofumi Tomura , Hiroyuki Katsuta , Osamu Takahashi , Shunichi Inami , Yuji Yanase , Junro Kishi , Hideo Kawashima
发明人： Yukihiro Yoshikawa , Kanji Tomiya , Naofumi Tomura , Hiroyuki Katsuta , Osamu Takahashi , Shunichi Inami , Yuji Yanase , Junro Kishi , Hideo Kawashima
IPC分类号： C07D231/14 , A01N43/26 , A01N43/56 , A01N43/78 , C07C211/45 , C07D213/82 , C07D231/16 , C07D241/14 , C07D263/34 , C07D277/20 , C07D277/30 , C07D277/56 , C07D307/68 , C07D309/28 , C07D327/06 , C07D333/24
CPC分类号： A01N43/56 , A01N43/78 , C07C211/45 , C07D231/14 , C07D277/56
摘要： A substituted anilide derivative represented by the formula (2): ##STR1## wherein A and B are methyl, and X is a hydrogen atom. The substituted anilide can be used to prepare a substituted carboxanilide derivative that exhibits a disease control effect against Botrytis cinerea, Powdery mildew, Pyricularia oryzae of rice plant and other various plant diseases, is excellent in residual effect, has activity against strains that are resistant to conventional chemicals, is safe for crops, and thus is useful as a plant disease control agent.
摘要翻译：由式（2）表示的取代的酰苯胺衍生物：其中A和B是甲基，X是氢原子。取代的酰苯胺可用于制备对灰葡萄孢，白粉病，稻瘟病菌和其他各种植物病害具有疾病防治作用的取代羧酰苯胺衍生物，其残留效果优异，具有抗抗性的菌株的活性常规化学品对作物是安全的，因此可用作植物病害防治剂。

3. 发明授权

US5747518A Substituted thiophene derivative and agricultural and horticultural fungicide containing the same as active ingredient 失效
标题翻译：取代噻吩衍生物和含有与活性成分相同的农业和园艺杀真菌剂
公开(公告)号：US5747518A
公开(公告)日：1998-05-05
申请号：US627929
申请日：1996-04-03
申请人： Yukihiro Yoshikawa , Kanji Tomiya , Hiroyuki Katsuta , Hideo Kawashima , Osamu Takahashi , Shunichi Inami , Yuji Yanase , Junro Kishi , Hitoshi Shimotori , Naofumi Tomura
发明人： Yukihiro Yoshikawa , Kanji Tomiya , Hiroyuki Katsuta , Hideo Kawashima , Osamu Takahashi , Shunichi Inami , Yuji Yanase , Junro Kishi , Hitoshi Shimotori , Naofumi Tomura
IPC分类号： A01N43/10 , A01N43/40 , A01N43/56 , A01N43/78 , C07D333/36 , C07D333/42 , C07D333/44 , C07D401/12 , C07D403/12 , C07D409/12 , C07D417/12 , A61K31/415 , A61K31/38 , A61K31/425 , A61K31/44
CPC分类号： C07D401/12 , A01N43/10 , A01N43/40 , A01N43/56 , A01N43/78 , C07D333/36 , C07D333/42 , C07D333/44 , C07D403/12 , C07D409/12 , C07D417/12
摘要： The substituted thiophene derivative of the invention which is represented by the general formula (1) has a broad disease spectrum for a pathogenic fungus of various crops, exhibits an excellent controlling effect on disease such as gray mold, powdery mildew and rust in particular, and is also effective for a resistant fungus of conventional fungicides which has become a serious problem, and consequently is useful for an agricultural and horticultural fungicide. ##STR1##
摘要翻译：由通式（1）表示的本发明的取代噻吩衍生物对各种作物的致病真菌具有广泛的疾病谱，特别是对灰霉病，白粉病和锈病等疾病具有优异的防治效果，对于已经成为严重问题的常规杀真菌剂的抗性真菌也是有效的，因此可用于农业和园艺杀真菌剂。（1）

4. 发明授权

US5914344A Substituted carboxanilide derivative and plant disease control agent comprising same as active ingredient 失效
标题翻译：取代的羧酰苯胺衍生物和包含与活性成分相同的植物病害防治剂
公开(公告)号：US5914344A
公开(公告)日：1999-06-22
申请号：US908187
申请日：1997-08-07
申请人： Yukihiro Yoshikawa , Kanji Tomiya , Naofumi Tomura , Hiroyuki Katsuta , Osamu Takahashi , Shunichi Inami , Yuji Yanase , Junro Kishi , Hideo Kawashima
发明人： Yukihiro Yoshikawa , Kanji Tomiya , Naofumi Tomura , Hiroyuki Katsuta , Osamu Takahashi , Shunichi Inami , Yuji Yanase , Junro Kishi , Hideo Kawashima
IPC分类号： C07D231/14 , A01N43/26 , A01N43/56 , A01N43/78 , C07C211/45 , C07D213/82 , C07D231/16 , C07D241/14 , C07D263/34 , C07D277/20 , C07D277/30 , C07D277/56 , C07D307/68 , C07D309/28 , C07D327/06 , C07D333/24 , A61K31/415
CPC分类号： A01N43/56 , A01N43/78 , C07C211/45 , C07D231/14 , C07D277/56
摘要： A substituted carboxanilide derivative represented by the formula (1): ##STR1## wherein A is a hydrogen atom or methyl, B is a methyl or ethyl, and Het is 1-methyl-3-substituted-4-pyrazolyl or 2-methyl-4-substituted-5-triazoyl group, exhibits a disease control effect against Botrytis cinerea, Powdery mildew, Pyricularia oryzae of rice plant and other various plant diseases, is excellent in residual effect, has also activity against resistant strain for conventional chemicals, particularly exerts control effects against Botrytis cinerea at a lower dosage as compared with a prior art, is also safe for crops, and thus is useful as a plant control agent.
摘要翻译：由式（1）表示的取代的羧酰苯胺衍生物：其中A是氢原子或甲基，B是甲基或乙基，Het是1-甲基-3-取代-4-吡唑基或2-甲基-4-取代的 -5-三唑酰基对植物灰葡萄孢，白粉病，稻瘟病等多种植物病害具有防治效果，残留效果优异，对常规化学品的抗性菌株也具有抗菌活性，特别是对抗与现有技术相比，较低剂量的灰葡萄孢属对于作物也是安全的，因此可用作植物控制剂。

5. 发明授权

US5240951A Isothiazolecarboxylic acid derivatives, rice blast control agents containing the same as active ingredients, and rice blast control method applying the control agents 失效
标题翻译：异噻唑羧酸衍生物，含有与活性成分相同的稻瘟病控制剂，以及应用控制剂的稻瘟病控制方法
公开(公告)号：US5240951A
公开(公告)日：1993-08-31
申请号：US761217
申请日：1991-09-19
申请人： Hitoshi Shimotori , Yuji Yanase , Takeshi Sekino , Katsutoshi Ishikawa , Toshiaki Kuwatsuka , Hiroharu Tanikawa , Hideo Kawashima , Naofumi Tomura , Yoshiro Kanemoto
发明人： Hitoshi Shimotori , Yuji Yanase , Takeshi Sekino , Katsutoshi Ishikawa , Toshiaki Kuwatsuka , Hiroharu Tanikawa , Hideo Kawashima , Naofumi Tomura , Yoshiro Kanemoto
IPC分类号： A01N43/80 , C07D275/02 , C07D275/03
CPC分类号： C07D275/03 , A01N43/80
摘要： Application of a rice blast control agent containing an isothiazolecarboxylic acid derivative of the below-described formula, which shows excellent activity against rice blast (Pyricularia oryzae) in rice cultivation, to the water surface of a paddy rice field results in the absorption of the derivative through roots of rice plants, so that the resistance of the rice plants can be enhanced. ##STR1## wherein R.sup.1 and R.sup.2 independently mean a hydrogen or halogen atom or a particular group, and Y stands for an OR.sub.3 group (R.sup.3 being a hydrogen or alkali metal atom or a particular group), an NHR.sup.4 group (R.sup.4 being a hydrogen atom or a particular group), or a morpholino group.
摘要翻译：在水稻栽培中将含有对稻瘟病稻瘟病（Pyricularia oryzae）具有优异活性的下述式的异噻唑羧酸衍生物的稻瘟病控制剂施用于水稻田的水面，导致衍生物的吸收通过水稻根系，可以提高水稻的抗性。其中R1和R2独立地表示氢或卤素原子或特定基团，Y表示OR3基团（R3表示氢或碱金属原子或特定基团），NHR4基团（R4表示氢原子或特定组）或吗啉基。

6. 发明授权

US4980363A Novel amide derivatives, processes for production thereof, and agricultural-horticultural fungicide containing them 失效
标题翻译：新型酰胺衍生物，其制备方法和含有它们的农业园艺杀真菌剂
公开(公告)号：US4980363A
公开(公告)日：1990-12-25
申请号：US259817
申请日：1988-10-19
申请人： Hitoshi Shimotori , Yoshiro Kanemoto , Hideo Yamazaki , Tsutomu Ishii , Shuji Ozawa , Yuji Yanase , Toshiaki Kuwatsuka , Yoshinori Tanaka , Takeshi Sekine , Keiko Shinada
发明人： Hitoshi Shimotori , Yoshiro Kanemoto , Hideo Yamazaki , Tsutomu Ishii , Shuji Ozawa , Yuji Yanase , Toshiaki Kuwatsuka , Yoshinori Tanaka , Takeshi Sekine , Keiko Shinada
IPC分类号： A01N43/74 , A01N43/78 , A01N43/80 , C07D275/02 , C07D275/03 , C07D277/56 , C07D417/12 , C07D521/00
CPC分类号： C07D275/03 , A01N43/74 , A01N43/78 , A01N43/80 , C07D231/12 , C07D233/56 , C07D249/08 , C07D277/56 , C07D417/12
摘要： An amide derivative represented by the following general formula (I) ##STR1## wherein one of X and Y represents a sulfur atom and the other represents a carbon atom, Z represents a nitrile or thioamide group, each of R.sup.1 and R.sup.2 represents a hydrogen atom, a halogen atom, an alkyl group having 1 to 6 carbon atoms, a halomethyl group or a phenyl group, and R.sup.3 represents an alkenyl group having 2 to 6 carbon atoms, a haloalkenyl group having 2 to 4 carbon atoms, a furyl group, a thienyl group, an alkoxy group having 1 to 4 carbon atoms, an alkylthio group having 1 to 4 carbon atoms, an alkynyloxy group having 3 to 5 carbon atoms, an alkynylthio group having 3 to 5 carbon atoms, a pyrazolyl group, or an unsubstituted or halo-substituted phenyl group; processes for producing the amide derivative; an agricultural-horicultural fungicide comprising the amide derivative as an active ingredient; and to an agricultural-horicultural fungicidal composition comprising the amide derivative of general formula (I) as an active ingredient.

7. 发明申请

US20080312184A1 Composition for Preventing Plant Diseases and Method for Preventing the Diseases 有权
标题翻译：防治植物病害的组合物和预防疾病的方法
公开(公告)号：US20080312184A1
公开(公告)日：2008-12-18
申请号：US11883352
申请日：2006-01-20
申请人： Syunichi Inami , Yuji Yanase
发明人： Syunichi Inami , Yuji Yanase
IPC分类号： A01N43/56 , A01N43/653 , A01N55/10 , A01N57/16 , A01N43/78 , A01P3/00 , A01N43/36 , A01N43/54 , A01N43/76 , A01N43/88
CPC分类号： A01N43/54 , A01N43/56 , A01N43/653 , A01N43/30 , A01N47/14 , A01N47/44 , A01N43/66 , A01N43/76 , A01N43/32 , A01N43/78 , A01N37/46 , A01N57/16 , A01N43/36 , A01N37/24 , A01N43/50 , A01N37/20 , A01N43/40 , A01N47/12 , A01N43/88 , A01N37/50 , A01N37/32 , A01N37/22 , A01N37/52 , A01N47/24 , A01N2300/00
摘要： The present invention is to provide a composition for preventing plant diseases which comprises at least Component I and Component II, is capable of obtaining a synergic effect that cannot be expected with each single component, is capable of markedly increasing a control effect in a much smaller amount of chemicals against various plant pathogens, and causes no phytotoxicity suffering.A composition for preventing plant diseases comprises Components I and II as active ingredients. The Component I is (RS)—N—[2-(1,3-dimethylbutyl)thiophen-3-yl]-1-methyl-3-tri fluoromethyl-1H-pyrazole-4-carboxamide. As the Component II, there can be exemplified, for example, tetraconazole, flutriafol, imibenconazole, triadimefon, simeconazole, oxpoconazole fumarate, prothioconazole, bupirimate, spiroxamine, metiram, dodine, anilazine, chlozolinate, oxycarboxin, ethaboxam, iprovalicarb, pyrazophos, fluoroimide, diflumetorim, fenhexamid, famoxadone, fenamidone, cyazofamid, zoxamide, cyflufenamid, boscalid, benthiavalicarb-isopropyl, picoxystrobin, pyraclostrobin, fluoxastrobin or dimoxystrobin.
摘要翻译：本发明提供一种用于预防植物病害的组合物，其至少包含组分I和组分II，能够获得对于每种单一组分不能预期的协同作用，能够显着增加小得多的控制效果对各种植物病原体的化学物质的量，并且不会产生植物毒性。用于预防植物病害的组合物包含组分I和II作为活性成分。组分I是（RS）-N- [2-（1,3-二甲基丁基）噻吩-3-基] -1-甲基-3-三氟甲基-1H-吡唑-4-甲酰胺。作为组分II，可以列举例如四唑唑，氟利多醇，阿米芬唑，三唑酮，西康唑，富马酸氧唑考唑，丙硫菌唑，泛酸，螺噻胺，甲霉唑，十二烷，苯那嗪，氯洛他定，氧卡卡林，依巴唑星，异恶唑，吡唑磷，氟代酰亚胺，二氟吗啉，芬己酰胺，恶唑酮，甲酰胺，环唑酰胺，唑酰胺，环丙沙芬，布洛沙利多，苦草酸，异丙基，吡肟菌酯，嘧菌酯，氟西汀或二恶灵。

8. 发明授权

US4792565A Pyrazolecarbonylamine derivatives and agricultural and horticultural fungicides containing said compounds 失效
标题翻译：吡唑羰胺衍生物和含有所述化合物的农业和园艺杀真菌剂
公开(公告)号：US4792565A
公开(公告)日：1988-12-20
申请号：US38971
申请日：1987-04-16
申请人： Hitoshi Shimotori , Tutomu Ishii , Hideo Yamazaki , Toshiaki Kuwatsuka , Yuji Yanase , Yoshinori Tanaka
发明人： Hitoshi Shimotori , Tutomu Ishii , Hideo Yamazaki , Toshiaki Kuwatsuka , Yuji Yanase , Yoshinori Tanaka
IPC分类号： C07D231/12 , A01N25/02 , A01N43/56 , C07D231/14 , C07D403/12 , C07D405/12 , C07D409/12 , C07D231/16
CPC分类号： C07D403/12 , A01N43/56 , C07D231/14 , C07D405/12 , C07D409/12
摘要： Novel pyrazole derivatives of the general formula (I) ##STR1## wherein R.sup.1 represents an alkyl, haloalkyl, alkenyl, haloalkenyl or phenyl group, R.sup.2 and R.sup.3 each represent a hydrogen or halogen atom, or an alkyl, haloalkyl, alkoxy, alkoxyalkyl or phenyl group, and R.sup.4 represents an alkyl, alkenyl, haloalkenyl or phenyl group, or a heterocyclic aromatic group which contains at least one of oxygen, nitrogen and sulfur atoms and may be unsubstituted or substituted,which are useful as agricultural and horticultural fungicides. The pyrazole derivatives can be produced by reacting compounds of the general formula (III) ##STR2## wherein R.sup.1, R.sup.2 and R.sup.3 are as defined above, and X represents a halogen atom,with aminoacetonitriles of the general formula (IV) ##STR3## wherein R.sup.4 is as defined above, or salts thereof.
摘要翻译：通式（I）的新型吡唑衍生物其中R 1表示烷基，卤代烷基，烯基，卤代烯基或苯基，R 2和R 3各自表示氢或卤素原子，或烷基，卤代烷基，烷氧基，烷氧基烷基或苯基，R4表示烷基，链烯基，卤代烯基或苯基，或含有氧，氮和硫原子中的至少一个的杂环芳基，可以是未取代或取代的，可用作农业和园艺杀真菌剂。吡唑衍生物可以通过使通式（III）的化合物（III）（其中R1，R2和R3如上定义，X代表卤素原子）与通式（IV）的氨基乙腈反应，（IV）其中R 4如上所定义，或其盐。

9. 发明授权

US09185911B2 Composition for preventing plant diseases and method for preventing the diseases 有权
标题翻译：用于预防植物疾病的组合物和用于预防疾病的方法
公开(公告)号：US09185911B2
公开(公告)日：2015-11-17
申请号：US11883352
申请日：2006-01-20
申请人： Syunichi Inami , Yuji Yanase
发明人： Syunichi Inami , Yuji Yanase
IPC分类号： A01N43/56 , A01N43/653 , A01N55/10 , A01N43/54
CPC分类号： A01N43/54 , A01N43/56 , A01N43/653 , A01N43/30 , A01N47/14 , A01N47/44 , A01N43/66 , A01N43/76 , A01N43/32 , A01N43/78 , A01N37/46 , A01N57/16 , A01N43/36 , A01N37/24 , A01N43/50 , A01N37/20 , A01N43/40 , A01N47/12 , A01N43/88 , A01N37/50 , A01N37/32 , A01N37/22 , A01N37/52 , A01N47/24 , A01N2300/00
摘要： The present invention is to provide a composition for preventing plant diseases which comprises at least Component I and Component II, is capable of obtaining a synergic effect that cannot be expected with each single component, is capable of markedly increasing a control effect in a much smaller amount of chemicals against various plant pathogens, and causes no phytotoxicity suffering.A composition for preventing plant diseases comprises Components I and II as active ingredients. The Component I is (RS)—N-[2-(1,3-dimethylbutyl)thiophen-3-yl]-1-methyl-3-tri fluoromethyl-1H-pyrazole-4-carboxamide. As the Component II, there can be exemplified, for example, tetraconazole, flutriafol, imibenconazole, triadimefon, simeconazole, oxpoconazole fumarate, prothioconazole, bupirimate, spiroxamine, metiram, dodine, anilazine, chlozolinate, oxycarboxin, ethaboxam, iprovalicarb, pyrazophos, fluoroimide, diflumetorim, fenhexamid, famoxadone, fenamidone, cyazofamid, zoxamide, cyflufenamid, boscalid, benthiavalicarb-isopropyl, picoxystrobin, pyraclostrobin, fluoxastrobin or dimoxystrobin.
摘要翻译：本发明提供一种用于预防植物病害的组合物，其至少包含组分I和组分II，能够获得对于每种单一组分不能预期的协同作用，能够显着增加小得多的控制效果对各种植物病原体的化学物质的量，并且不会产生植物毒性。用于预防植物病害的组合物包含组分I和II作为活性成分。组分I是（RS）-N- [2-（1,3-二甲基丁基）噻吩-3-基] -1-甲基-3-三氟甲基-1H-吡唑-4-甲酰胺。作为组分II，可以列举例如四唑唑，氟利多醇，阿米芬唑，三唑酮，西康唑，富马酸氧唑考唑，丙硫菌唑，泛酸，螺噻胺，甲霉唑，十二烷，苯那嗪，氯洛他定，氧卡卡林，依巴唑星，异恶唑，吡唑磷，氟代酰亚胺，二氟吗啉，芬己酰胺，恶唑酮，甲酰胺，环唑酰胺，唑酰胺，环丙沙芬，布洛沙利多，苦草酸，异丙基，吡肟菌酯，嘧菌酯，氟西汀或二恶灵。

10. 发明申请

US20060235066A1 Aqueous suspension preparation of bactericide for folieage application 有权
标题翻译：杀虫剂水性悬浮液制备方法
公开(公告)号：US20060235066A1
公开(公告)日：2006-10-19
申请号：US10564851
申请日：2004-07-07
申请人： Koichi Morinaga , Yuji Yanase , Kanemitsu Miyama , Hideo Kawashima
发明人： Koichi Morinaga , Yuji Yanase , Kanemitsu Miyama , Hideo Kawashima
IPC分类号： A01N43/56
CPC分类号： A01N43/56 , A01N25/24 , A01N25/30 , A01N25/04 , A01N2300/00
摘要： The present invention provides an aqueous suspension formulation containing (RS)—N-[2-(1,3-dimethylbutyl)thiophene-3-yl]-1-methyl-3-trifluoromethyl-1H-pyrazole-4-carboxamide and having high rain resistance and stable residual effectiveness. A aqueous suspension formulation for foliar application fungicide of the present invention contains a fungicidal active ingredient, (RS)—N-[2-(1,3-dimethylbutyl)thiophene-3-yl]-1-methyl-3-trifluoromethyl-1H-pyrazole-4-carboxamide, and a polyoxyalkylene rosin acid ester or liquid paraffin, and has improved rain resistance on plant leaves and excellent residual effectiveness.
摘要翻译：本发明提供含有（RS）-N- [2-（1,3-二甲基丁基）噻吩-3-基] -1-甲基-3-三氟甲基-1H-吡唑-4-甲酰胺并含有高耐雨性和稳定的残留效果。本发明的叶面施用杀真菌剂的水性悬浮液制剂含有杀真菌活性成分（RS）-N- [2-（1,3-二甲基丁基）噻吩-3-基] -1-甲基-3-三氟甲基-1H- - 吡唑-4-甲酰胺和聚氧化烯松香酸酯或液体石蜡，并且具有改善植物叶子的耐雨性和优异的残留效果。

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