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    • 1. 发明授权
    • Process for recovery of nitric acid from nitrates
    • 从硝酸盐回收硝酸的方法
    • US4205054A
    • 1980-05-27
    • US890910
    • 1978-03-28
    • Yujiro SugaharaHiroyuki NaitoKiyoshi TakaiTatuya Kondo
    • Yujiro SugaharaHiroyuki NaitoKiyoshi TakaiTatuya Kondo
    • C01B21/42C01F11/38
    • C01B21/42
    • A process for recovery of nitric acid comprising incorporating or absorbing waste nitric acid and/or a nitrate in an oil-absorbing inorganic carrier and forming a nitrate-carrier granule containing water in the form of a hydroxide, a hydrate or adsorption moisture in an amount sufficient to generate a vapor of nitric acid stably and being substantially non-sticky at a decomposition temperature of the nitrate; heating the formed granule while keeping the substantially non-sticky state in the granule to decompose the nitrate in the granule to a vapor of nitric acid; and recovering the generated vapor of nitric acid is disclosed. According to this process, nitric acid can be directly recovered from waste nitric acid or a nitrate in the form of a vapor of nitric acid without substantial generation of nitrogen oxide gases by using a cheap and easily available inorganic carrier.
    • 一种回收硝酸的方法,包括在吸油无机载体中并入或吸收废硝酸和/或硝酸盐,并形成含有氢氧化物,水合物或吸附水分形式的水的硝酸盐载体颗粒,其量为 足以在硝酸盐的分解温度下稳定地产生硝酸蒸气并基本上不粘; 加热形成的颗粒,同时保持颗粒中基本上不粘的状态,将颗粒中的硝酸盐分解成硝酸蒸气; 并回收所产生的硝酸蒸汽。 根据该方法,通过使用便宜且容易获得的无机载体,硝酸可以从硝酸的硝酸盐或硝酸盐的形式直接回收而不会产生大量的氮氧化物气体。
    • 3. 发明授权
    • Treating raw materials containing titanium components
    • 处理含钛成分的原料
    • US4069295A
    • 1978-01-17
    • US682058
    • 1976-04-30
    • Yujiro SugaharaYoshibumi NoshiHiroyuki NaitoKiyoshi TakaiNoboru Maruyama
    • Yujiro SugaharaYoshibumi NoshiHiroyuki NaitoKiyoshi TakaiNoboru Maruyama
    • C22B1/00C01G45/00C01G23/08C01G31/00C01G37/14
    • C22B1/00
    • A method of treating raw materials containing components of metals of the group IVb of the Periodic Table, which comprises heat-treating a raw material of a component of a metal of the group IVb of the Periodic Table containing coloring poisonous metal components such as Mn, V and Cr components in the presence of a flux composed mainly of an alkali metal nitrate or an alkali metal peroxide which is a thermal decomposition product of the alkali metal nitrate in an amount 2 to 5 times the amount of the raw material on the weight basis in a non-reducing atmosphere to thereby effect fluxing reaction, and subjecting the resulting fluxing reaction product to a leaching treatment of at least one stage in an aqueous medium to separate the fluxing reaction product into said coloring metal components and a concentrate of the component of the group IVb of the Periodic Table which is acid-soluble and substantially free of said coloring poisonous metal components. In practising this treating method, if a residue left after the above leaching step is incorporated into a mixture of the raw material and the flux, the composition is granulated and the granulated composition is heat-treated, the fluxing reaction of the raw material can be accomplished while keeping the granulated composition in the substantially non-sticky granular state throughout the fluxing heat treatment.
    • 一种处理包含元素周期表IVb族金属组分的原料的方法,该方法包括对含有着色有毒金属组分如Mn的周期表IVb族金属组分的原料进行热处理, V和Cr组分在主要由碱金属硝酸盐或碱金属过氧化物组成的助熔剂存在下,碱金属硝酸盐或碱金属过氧化物是碱金属硝酸盐的热分解产物,其量为原料重量的2至5倍 在非还原性气氛中进行助熔反应,并将得到的助熔反应产物在水性介质中进行至少一个阶段的浸出处理,将助熔反应产物分离成所述着色金属组分,并将组分的浓缩物 周期表的IVb组是酸溶性的并且基本上不含所述着色有毒金属组分。 在实施该处理方法时,如果将上述浸出工序后残留的残留物并入原料与助熔剂的混合物中,则将其组成进行造粒,对该粒状组合物进行热处理,可以使原料的助熔反应 在整个助熔热处理过程中将颗粒状组合物保持在基本上不粘的颗粒状态。
    • 5. 发明授权
    • Scrap preheating system for an electric furnace
    • 电炉废料预热系统
    • US4478574A
    • 1984-10-23
    • US410890
    • 1982-08-24
    • Ryuzo OkunoKeio ToyodaMasahiro SaraiKiyoshi Takai
    • Ryuzo OkunoKeio ToyodaMasahiro SaraiKiyoshi Takai
    • C21C5/56F27D13/00F27D17/00
    • F27D13/002C21C5/527C21C5/565Y02P10/216
    • This disclosure relates to a system for preheating scrap before charging in an electric furnace and for preventing the release of malodorous or noxious gas. The system includes a first duct leading from the furnace exhaust gas outlet to a chimney; a branching duct is connected in the first line for passing part of the gas to the chimney and for diverting the remainder of the gas to a scrap preheater. After preheating the scrap, the diverted gas is recirculated back to the first line at a junction which is adjacent the furnace outlet. The system further includes gas combustion means connected in the first line between the junction and the branching duct, and a heat equalizer-accumulator in the first line between the combustion means and the chimney. The system may further include a heat exchanger connected in the first line downstream of the branching duct and a second line for passing the diverted gas through the heat exchanger after it leaves the scrap preheater. A temperature responsive device may be connected in the first line for adjusting the amount of the diverted gas.
    • 本公开涉及一种用于在电炉中充电之前预热废料并用于防止恶臭或有害气体的释放的系统。 该系统包括从炉废气出口通向烟囱的第一管道; 分支管道连接在第一管线中,用于使气体的一部分通到烟囱,并将剩余的气体转移到废料预热器。 在预热废料之后,转移的气体在与炉出口相邻的连接处再循环回到第一管线。 该系统还包括连接在接头和分支管道之间的第一管线中的气体燃烧装置,以及在燃烧装置和烟囱之间的第一管线中的热均衡器 - 蓄能器。 该系统还可以包括连接在分支管道下游的第一管线中的热交换器和用于使转向的气体在离开废料预热器之后通过热交换器的第二管线。 温度响应装置可以连接在第一行中,用于调节转向气体的量。
    • 10. 发明授权
    • System using electric furnace exhaust gas to preheat scrap for
steelmaking
    • 系统采用电炉废气预热废钢,用于炼钢
    • US4692113A
    • 1987-09-08
    • US906120
    • 1986-09-10
    • Kiyoshi TakaiKiyoshi Iwasaki
    • Kiyoshi TakaiKiyoshi Iwasaki
    • C21C5/56F27D13/00F27D17/00C21B3/04F23J15/00
    • F27D17/008C21C5/527C21C5/565F27D13/002Y02P10/216Y10S261/09Y10S266/901
    • Dust containing high-temperature gas exhausted from an electric steelmaking furnace is directed through scrap preheaters, wherein scrap that is to be charged into said electric furnace is preheated. The absorption of some of the heat from the exhaust leaving the electric furnace by the scrap, therefore, decreases the amount of electric power required for melting the steel scrap and also shortens the time required for steelmaking. Exhaust gas after preheating of the scrap is contaminated with incidental malodorous materials, e.g., paint and oil fumes, and is directed through a gas scrubber followed by a wet-type electric precipitator to remove these contaminants before release of cleaned exhaust gas into the atmosphere. A flow of alkaline aqueous solution of a deodorant solvent in the gas scrubber removes malodorous substances from the exhaust gas, simultaneously causing a drop in the gas temperature to a predetermined controlled value while generating a constant supply of saturated water vapor. Exhaust gas mixed with the saturated water vapor then flows through a wet-type electrostatic precipitator which collects oil mist attached to the water vapor and any small water droplets entrained therein. This purging of dust and malodorous constituents from the exhaust gas facilitates preheating of scrap for electric steelmaking processes, providing benefits of improved economy and reduced environmental air pollution.
    • 含有从电炼钢炉排出的高温气体的粉尘被引导通过废料预热器,其中将要加入到所述电炉中的废料被预热。 因此,通过废料从排出电炉的排气中吸收一些热量,减少了熔炼钢渣所需的电力量,并缩短了炼钢所需的时间。 废料预热后的废气被偶然的恶臭物质(例如油漆和油烟雾)污染,并且被引导通过气体洗涤器,随后是湿式电除尘器以除去这些污染物,然后将净化的废气释放到大气中。 气体洗涤器中除臭溶剂的碱性水溶液流从废气中除去恶臭物质,同时使气体温度下降到预定的受控值,同时产生恒定的饱和水蒸气。 与饱和水蒸气混合的废气然后流过湿式静电除尘器,其收集附着在水蒸汽上的油雾和夹在其中的任何小水滴。 从排气中清除灰尘和恶臭成分有助于预热电炼炼工艺废料,提供经济改善和减少环境空气污染的好处。