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1. 发明授权

US06300444B1 Process for producing butene polymer 失效
标题翻译：生产丁烯聚合物的方法
公开(公告)号：US06300444B1
公开(公告)日：2001-10-09
申请号：US09529511
申请日：2000-04-15
申请人： Yuichi Tokumoto , Koichi Ohashi , Toshio Okada , Tsutomu Takashima
发明人： Yuichi Tokumoto , Koichi Ohashi , Toshio Okada , Tsutomu Takashima
IPC分类号： C08F414
CPC分类号： C08F10/10 , C08F6/001 , C08F6/02 , C08F10/08 , C08F110/10 , C08F210/08 , C08L23/18 , C08F4/14 , C08F2500/02
摘要： It is possible to produce butene polymer at high yield, which polymer contains 80 mol % or more of polymer molecules having terminal vinylidene structure and being low in the content of residual organic fluorine by a process comprising Step (I) to polymerize in liquid phase by adding complex catalyst composed of boron trifluoride, ether and alcohol and/or water in specified ratios to C4 fractions and Step (II) to reduce the content of trimer and lighter components contained in the obtained polymer to 0.2% by weight or less by distillation.
摘要翻译：可以以高收率生产丁烯聚合物，该聚合物含有80mol％或更多具有末端亚乙烯基结构的聚合物分子，并且通过包括步骤（I）的方法，残留的有机氟含量低，由液相聚合，将由三氯化碳，乙醚和醇和/或水组成的复合催化剂以C4馏分和步骤（II）的比例加入，通过蒸馏将所得聚合物中所含的三聚体和较轻组分的含量降低至0.2重量％以下。

2. 发明授权

US06476284B1 Method of dehalogenating hydrocarbon containing carbon-carbon double bond 有权
标题翻译：含碳碳 - 碳双键脱卤的方法
公开(公告)号：US06476284B1
公开(公告)日：2002-11-05
申请号：US09673864
申请日：2000-10-19
申请人： Koichi Ohashi , Tsutomu Takashima , Teruhisa Kuroki , Koji Fujimura , Yuichi Tokumoto
发明人： Koichi Ohashi , Tsutomu Takashima , Teruhisa Kuroki , Koji Fujimura , Yuichi Tokumoto
IPC分类号： C10G4500
CPC分类号： C08F10/10 , C08F8/26 , C08F10/08 , C08F210/08 , C08F10/00 , C08F4/14 , C08F210/10
摘要： An efficient dehalogenation can be carried out by a method which comprises treating an organic compound containing a compound of halogen, such as fluorine or chlorine, as an impurity and having non-conjugated carbon-carbon double bonds, for example, butene polymer produced with a boron trifluoride catalyst, with an inorganic solid treating agent containing aluminum atoms. When the dehalogenation is conducted in the presence of a basic substance such as ammonia or an amine, it can be continued over long while inhibiting the isomerization of the non-conjugated carbon-carbon double bonds.
摘要翻译：有效的脱卤可以通过以下方法进行：将含有卤素的化合物（例如氟或氯）作为杂质杂化并含有非共轭碳 - 碳双键的方法进行，例如，用三氟化硼催化剂，含有铝原子的无机固体处理剂。当在诸如氨或胺等碱性物质的存在下进行脱卤时，可以持续长时间，同时抑制非共轭碳 - 碳双键的异构化。

3. 发明授权

US07126037B2 Butene oligomer derivatives having terminal 1,4-butanediol functional groups 有权
标题翻译：具有末端1,4-丁二醇官能团的丁烯低聚物衍生物
公开(公告)号：US07126037B2
公开(公告)日：2006-10-24
申请号：US10204232
申请日：2000-12-19
申请人： Tsutomu Takashima , Koji Fujimura , Yuichi Tokumoto
发明人： Tsutomu Takashima , Koji Fujimura , Yuichi Tokumoto
IPC分类号： C07C2/30
CPC分类号： C08F290/042 , C07C31/20 , C07C33/035 , C08F8/04 , C08F8/44 , C08F10/08 , C08F16/04 , C08F110/10 , C08F2810/40 , C08F2500/02 , C08F2500/03 , C08F8/46
摘要： Butene oligomer derivatives having tert-butyl groups as one of the terminal groups, having a repeating unit of the main hydrocarbon chain consisting of 80% by mole or more of —CH2C(CH3)2—, and carrying the other terminal group consisting of 60% by mole or more of 1,4-butanediol type functional groups. These derivatives are useful as macromonomers which can be subjected to polycondensation, polyaddition, etc.
摘要翻译：具有叔丁基作为端基之一的丁烯低聚物衍生物，其具有由80质量％以上的-CH 2 CO 2（CH 3）构成的主烃链的重复单元＆lt; / 2＆gt; 2＆gt;中，并且携带由60摩尔％以上的1,4-丁二醇型官能团构成的另一个末端基。这些衍生物可用作可进行缩聚，加聚等的大分子单体。

4. 发明授权

US06462151B1 Method of removing and recovering boron trifluoride with metal fluoride and process for polyolefin production using the same 有权
标题翻译：用金属氟化物除去和回收三氟化硼的方法及使用该方法的聚烯烃生产方法
公开(公告)号：US06462151B1
公开(公告)日：2002-10-08
申请号：US09582242
申请日：2000-06-22
申请人： Tsutomu Takashima , Yuichi Tokumoto , Koji Fujimura
发明人： Tsutomu Takashima , Yuichi Tokumoto , Koji Fujimura
IPC分类号： C08F200
CPC分类号： B01D15/00 , B01J20/046 , C08F6/02 , C08F110/10 , C08F110/14 , C08F4/14 , C08L23/22
摘要： Boron trifluoride can be recovered in a reusable state by a method that is economical and does not cause environmental pollution, which method comprises the steps of bringing a fluid containing boron trifluoride or its complex into contact with metal fluoride so as to selectively adsorb and remove boron trifluoride in the complex and heating the resultant metal tetrafluoroborate at a temperature in the range of 100 to 600° C. to separate it into boron trifluoride and metal fluoride. By applying the method to a process for producing polybutene or olefin oligomer using boron trifluoride complex catalyst, the catalyst can be recovered with retaining its activity and reused effectively.
摘要翻译：三氟化硼可以通过经济且不引起环境污染的方法在可再利用状态下回收，该方法包括使含有三氟化硼或其配合物的流体与金属氟化物接触以选择性吸附和除去硼并在100〜600℃的温度范围内加热得到的四氟硼酸金属盐，将其分离成三氟化硼和金属氟化物。通过将该方法应用于使用三氟化硼配合物催化剂制备聚丁烯或烯烃低聚物的方法，可以保持其活性并有效地再利用来回收催化剂。

5. 发明授权

US6084144A Method of recovering boron trifluoride complex and process for producing olefin oligomer using the same 失效
标题翻译：回收三氟化硼配合物的方法及使用其制备烯烃低聚物的方法
公开(公告)号：US6084144A
公开(公告)日：2000-07-04
申请号：US171343
申请日：1998-10-15
申请人： Tsutomu Takashima , Yoshisuke Kakuyama , Shigeru Nishikida , Yuichi Tokumoto , Kouji Fujimura
发明人： Tsutomu Takashima , Yoshisuke Kakuyama , Shigeru Nishikida , Yuichi Tokumoto , Kouji Fujimura
IPC分类号： B01J27/32 , B01J37/34 , B01J38/68 , C07C2/20 , C08F4/14 , C08F6/02 , C08F10/00 , C08F10/10 , C08F110/10 , C07C2/08 , C07C2/22
CPC分类号： C08F10/00 , B01J27/32 , B01J37/348 , B01J38/68 , C07C2/20 , C08F10/10 , C08F4/14 , C08F6/02 , C07C2527/1213 , C08F110/10 , Y02P20/584
摘要： A boron trifluoride complex can be recovered without changing its molar coordination ratio, by applying a direct and/or alternating voltage to an electrically-nonconductive fluid in which at least a part of boron trifluoride complex is dispersed and/or dissolved, and separating the boron trifluoride complex by settling from the electrically-nonconductive fluid. By utilizing this method for the preparation of olefin oligomer using a boron trifluoride complex catalyst, it is possible to reuse the recovered catalyst as it stands for the reaction.
摘要翻译： PCT No.PCT / JP98 / 00783 Sec。 371日期：1998年10月15日 102（e）1998年10月15日日期PCT提交1998年2月26日PCT公布。第WO98 / 38225号公报日期1998年3月9日可以通过向其中至少一部分三氟化硼配合物分散和/或溶解的非导电流体施加直接和/或交流电压而不改变其摩尔配位比来回收三氟化硼配合物，并且通过从非导电流体沉降来分离三氟化硼配合物。通过利用这种使用三氟化硼配合物催化剂制备烯烃低聚物的方法，可以如反应那样重新使用回收的催化剂。

6. 发明授权

US5384426A Process for the preparation of isopropyl acetate 失效
标题翻译：乙酸异丙酯的制备方法
公开(公告)号：US5384426A
公开(公告)日：1995-01-24
申请号：US163304
申请日：1993-12-07
申请人： Kyuichi Ohyama , Giichi Shimada , Yuichi Tokumoto , Kazuo Sakamoto
发明人： Kyuichi Ohyama , Giichi Shimada , Yuichi Tokumoto , Kazuo Sakamoto
IPC分类号： C07C67/54 , C07C67/04
CPC分类号： C07C67/54
摘要： Disclosed is an improved process for the refinement of isopropyl acetate, whereby there can be effectively prepared isopropyl acetate having a high purity of, for example, approximately 99.9%, in which a distillate fraction having a carbon number of 3 obtained by catalytically cracking petroleums such as naphtha or a crude propylene by-produced in a process for the preparation of isobutene by the dehydrogenation of isobutane.
摘要翻译：公开了一种用于精制乙酸异丙酯的改进方法，由此可以有效制备具有例如约99.9％的高纯度的乙酸异丙酯，其中通过催化裂化石油得到的具有碳数3的馏出物馏分作为通过异丁烷脱氢制备异丁烯的方法中产生的石脑油或粗丙烯。

7. 发明授权

US5457228A Method for producing lower alkyl acetate 失效
标题翻译：低级烷基乙酸酯的制备方法
公开(公告)号：US5457228A
公开(公告)日：1995-10-10
申请号：US330115
申请日：1994-10-27
申请人： Yuichi Tokumoto , Kazuo Sakamoto , Kikuo Sasaki , Isoo Shimizu
发明人： Yuichi Tokumoto , Kazuo Sakamoto , Kikuo Sasaki , Isoo Shimizu
IPC分类号： C07C67/04
CPC分类号： C07C67/04 , Y02P20/584
摘要： A method for producing a lower alkyl acetate in which undesirable polymerization of the starting material of olefin and deterioration of catalyst can be avoided, a higher catalytic efficiency and a higher reaction rate are attained, the installation of reaction equipment is inexpensive and the operation of the reaction can be carried out without difficulty. The method of the invention comprises the steps of feeding acetic acid and an olefin both in a liquid state and in cocurrent through a continuous flow type fixed bed reactor containing an acidic ion exchange resin catalyst(s) under the conditions that the molar ratio of acetic acid to the olefin in a feed current is in the range of 1.0 to 2.0 and an LHSV of acetic acid relative to the catalyst layer is 0.1 to 10.0 with maintaining the inlet of the catalyst bed at 70.degree. C. to 120.degree. C.; cooling the obtained reaction mixture to a temperature not lower than 70.degree. C.; and recycling it to the catalyst bed.
摘要翻译：一种生产低级烷基乙酸酯的方法，其中可以避免烯烃原料的不期望的聚合和催化剂的劣化，更高的催化效率和更高的反应速率，反应设备的安装便宜，反应可以毫无困难地进行。本发明的方法包括以下步骤：将乙酸和烯烃以液体状态并通过包含酸性离子交换树脂催化剂的连续流式固定床反应器在乙酸的摩尔比在进料电流中酸与烯烃的摩尔比在1.0至2.0的范围内，乙酸的相对于催化剂层的LHSV为0.1至10.0，同时保持催化剂床的入口在70℃至120℃。将得到的反应混合物冷却至不低于70℃的温度。并将其再循环到催化剂床上。

8. 发明授权

US5436402A Method for preparing p-isobutylstyrene 失效
标题翻译：对异丁基苯乙烯的制备方法
公开(公告)号：US5436402A
公开(公告)日：1995-07-25
申请号：US323600
申请日：1994-10-17
申请人： Isoo Shimizu , Yasuo Matsumura , Yuichi Tokumoto , Kazumichi Uchida
发明人： Isoo Shimizu , Yasuo Matsumura , Yuichi Tokumoto , Kazumichi Uchida
IPC分类号： C07B61/00 , C07C5/27 , C07C5/333 , C07C7/04 , C07C7/148 , C07C15/02 , C07C15/46
CPC分类号： C07C15/46 , C07C5/277 , C07C5/3335 , C07C5/3337
摘要： A method for preparing a high-purity p-isobutylstyrene is here disclosed which comprises the first step of reacting o- and/or m-isobutylethylbenzene, if necessary, together with isobutylbenzene, in the presence of an acid catalyst in a liquid phase at a reaction temperature of -10.degree. to 600.degree. C. so that the production of sec-butylethylbenzene in butylethylbenzene may not exceed 20% by weight, in order to form a mixture of p-isobutylethylbenzene and sec-butylethylbenzene; and the second step of bringing the mixture of p-isobutylethylbenzene and sec-butylethylbenzene recovered from the first step into contact with a dehydrogenation metal catalyst containing at least one metal selected from the groups Ib, IIb, VIa, VIIa and VIII of the periodic table at a reaction temperature of 300.degree. to 650.degree. C. under a reaction pressure of 50 kg/cm.sup.2 or less in a gaseous phase.
摘要翻译：这里公开了一种制备高纯度对异丁基苯乙烯的方法，该方法包括如下情况的第一步：在必要时，在酸催化剂存在下，在液相中，在反应温度为-10℃至600℃，从而在丁基乙基苯中产生仲丁基乙基苯不得超过20重量％，以便形成对异丁基乙基苯和仲丁基乙基苯的混合物; 并且使从第一步骤回收的对异丁基乙基苯和仲丁基乙基的混合物与含有选自元素周期表中的Ib，IIb，VIa，VIIa和VIII族的至少一种金属的脱氢金属催化剂接触的第二步骤在反应温度为300〜650℃，反应压力为50kg / cm 2以下的气相中。

9. 发明授权

US5260477A Method for preparing alpha-(4-isobutylphenyl)propionic acid or its precursor 失效
标题翻译：制备α-（4-异丁基苯基）丙酸或其前体的方法
公开(公告)号：US5260477A
公开(公告)日：1993-11-09
申请号：US452804
申请日：1989-12-18
申请人： Isoo Shimizu , Yasuo Matsumura , Yuichi Tokumoto , Kazumichi Uchida
发明人： Isoo Shimizu , Yasuo Matsumura , Yuichi Tokumoto , Kazumichi Uchida
IPC分类号： C07C5/333 , C07C45/50 , C07C45/62 , C07C51/14 , C07C51/255 , C07C69/76
CPC分类号： C07C51/14 , C07C45/50 , C07C45/62 , C07C5/3332 , C07C51/255
摘要： A method for preparing .alpha.-(4-isobutylphenyl)propionic acid or its precursor is here disclosed which comprises a step (I) of dehydrogenating p-isobutylethylbenzene in a gaseous phase in the presence of a dehydrogenating metal catalyst to form p-isobutylstyrene and at least one unsaturated hydrocarbon compound selected from a group A defined in Claim 1; a step (II) of reacting p-isobutylstyrene obtained in the step (I) with carbon monoxide and hydrogen or with carbon monoxide and water or a lower alcohol in the presence of a transition metal complex carbonylating catalyst to form .alpha.-(4-isobutylphenyl)propionic acid or its precursor; and a step (III) of hydrogenating at least one unsaturated hydrocarbon compound selected from the group A obtained in the dehydrogenation step (I) to form p-isobutylethylbenzene, and recycling the thus formed p-isobutylethylbenzene through the step (I) as the raw material of the step (I).

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