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    • 1. 再颁专利
    • Lithium cationic single-ion conducting filler-containing composite polymer electrolyte for lithium secondary battery and method of manufacturing the same
    • 锂二次电池用锂阳离子单离子导电填料复合聚合物电解质及其制造方法
    • USRE44264E1
    • 2013-06-04
    • US12837062
    • 2010-07-15
    • Young Gi LeeKwang Man KimKwang Sun RyuSoon Ho Chang
    • Young Gi LeeKwang Man KimKwang Sun RyuSoon Ho Chang
    • H01M10/40H01M2/16
    • H01M10/0565H01M2/145H01M2/166H01M2/1686H01M10/052H01M10/056H01M2300/0025H01M2300/0071H01M2300/0082H01M2300/0091H01M2300/0094
    • Provided are a composite polymer electrolyte for a lithium secondary battery in which a composite polymer matrix multi-layer structure composed of a plurality of polymer matrices with different pore sizes is impregnated with an electrolyte solution, and a method of manufacturing the same. Among the polymer matrices, a microporous polymer matrix with a smaller pore size contains a lithium cationic single-ion conducting inorganic filler, thereby enhancing ionic conductivity, the distribution uniformity of the impregnated electrolyte solution, and maintenance characteristics. The microporous polymer matrix containing the lithium cationic single-ion conducting inorganic filler is coated on a surface of a porous polymer matrix to form the composite polymer matrix multi-layer structure, which is then impregnated with the electrolyte solution, to manufacture the composite polymer electrolyte. The composite polymer electrolyte is used in a unit battery. The composite polymer matrix structure can increase mechanical properties. The introduction of the lithium cationic single-ion conducting inorganic filler can provide excellent ionic conductivity and high rate discharge characteristics.
    • 本发明提供一种锂二次电池用复合高分子电解质及其制造方法,其特征在于,将具有不同孔径的多个聚合物基体构成的复合聚合物基质多层结构体浸渍在电解液中。 在聚合物基质中,具有较小孔径的微孔聚合物基质包含阳离子单离子导电无机填料,从而提高离子电导率,浸渍电解质溶液的分布均匀性和维护特性。 将含有阳离子单离子导电无机填料的微孔聚合物基体涂覆在多孔聚合物基质的表面上以形成复合聚合物基质多层结构,然后用电解质溶液浸渍,制备复合聚合物电解质 。 复合聚合物电解质用于单位电池。 复合聚合物基体结构可增加机械性能。 引入锂阳离子单离子导电无机填料可以提供优异的离子导电性和高速率放电特性。
    • 5. 发明授权
    • Lithium cationic single-ion conducting filler-containing composite polymer electrolyte for lithium secondary battery and method of manufacturing the same
    • 锂二次电池用锂阳离子单离子导电填料复合聚合物电解质及其制造方法
    • US07399556B2
    • 2008-07-15
    • US11097730
    • 2005-04-01
    • Young Gi LeeKwang Man KimKwang Sun RyuSoon Ho Chang
    • Young Gi LeeKwang Man KimKwang Sun RyuSoon Ho Chang
    • H01M10/40H01M2/16
    • H01M10/0565H01M2/145H01M2/166H01M2/1686H01M10/052H01M10/056H01M2300/0025H01M2300/0071H01M2300/0082H01M2300/0091H01M2300/0094
    • Provided are a composite polymer electrolyte for a lithium secondary battery in which a composite polymer matrix multi-layer structure composed of a plurality of polymer matrices with different pore sizes is impregnated with an electrolyte solution, and a method of manufacturing the same. Among the polymer matrices, a microporous polymer matrix with a smaller pore size contains a lithium cationic single-ion conducting inorganic filler, thereby enhancing ionic conductivity, the distribution uniformity of the impregnated electrolyte solution, and maintenance characteristics. The microporous polymer matrix containing the lithium cationic single-ion conducting inorganic filler is coated on a surface of a porous polymer matrix to form the composite polymer matrix multi-layer structure, which is then impregnated with the electrolyte solution, to manufacture the composite polymer electrolyte. The composite polymer electrolyte is used in a unit battery. The composite polymer matrix structure can increase mechanical properties. The introduction of the lithium cationic single-ion conducting inorganic filler can provide excellent ionic conductivity and high rate discharge characteristics.
    • 本发明提供一种锂二次电池用复合高分子电解质及其制造方法,其中将由多个不同孔径的聚合物基体组成的复合聚合物基体多层结构浸渍在电解质溶液中。 在聚合物基质中,具有较小孔径的微孔聚合物基质包含阳离子单离子导电无机填料,从而提高离子电导率,浸渍电解质溶液的分布均匀性和维护特性。 将含有阳离子单离子导电无机填料的微孔聚合物基体涂覆在多孔聚合物基质的表面上以形成复合聚合物基质多层结构,然后用电解质溶液浸渍,制备复合聚合物电解质 。 复合聚合物电解质用于单位电池。 复合聚合物基体结构可增加机械性能。 引入锂阳离子单离子导电无机填料可以提供优异的离子导电性和高速率放电特性。
    • 7. 发明授权
    • Method for manufacturing a conductive polymer film
    • 导电性高分子膜的制造方法
    • US06309694B1
    • 2001-10-30
    • US09498037
    • 2000-02-04
    • Kwang Sun RyuKwang Man KimSeong-Gu KangSoon Ho Chang
    • Kwang Sun RyuKwang Man KimSeong-Gu KangSoon Ho Chang
    • B05D302
    • H01B1/128C08J5/18C08J2300/12
    • A method of manufacturing a conducting polymer film including dissolving a lithium salt in an organic solvent; after the lithium salt is completely dissolved in the organic solvent, dissolving a conducting polymer in the organic solvent by adding the conducting polymer little by little in many separate doses into the organic solvent until obtaining a deep blue colored solution; and leaving the deep blue colored solution as it stands over seven days and coating it on a flat surface; and evaporating the solvent from the coated solution. It is possible to work the conducting polymer film in a very thin membrane and to control the thickness as required, since the polymer film can be formed directly from a solution. Furthermore, it is also possible to control the conductivity of the polymer film by varying the type of salts as used and the concentration thereof, and thus its applicability is very diverse as the purpose of using them, for example in electronic/electric components.
    • 一种制造导电聚合物膜的方法,包括将锂盐溶解在有机溶剂中; 在锂盐完全溶解在有机溶剂中之后,通过以多种不同的剂量将导电聚合物一点一点地添加到有机溶剂中直到获得深蓝色溶液,将导电聚合物溶解在有机溶剂中; 并将深蓝色溶液放置七天,并将其涂布在平坦的表面上; 并从涂布溶液中蒸发溶剂。 可以在非常薄的膜中加工导电聚合物膜并根据需要控制厚度,因为聚合物膜可以直接从溶液形成。 此外,也可以通过改变所使用的盐的类型及其浓度来控制聚合物膜的导电性,因此其应用性作为其使用目的非常多样化,例如在电子/电气部件中。