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    • 7. 发明授权
    • Negative working resist material, method for the production of the same
and process of forming resist patterns using the same
    • 负性抗蚀剂材料,其制造方法以及使用其形成抗蚀剂图案的工艺
    • US5457003A
    • 1995-10-10
    • US99398
    • 1993-07-30
    • Akinobu TanakaHiroshi BanJiro NakamuraTakao KimuraYoshio Kawai
    • Akinobu TanakaHiroshi BanJiro NakamuraTakao KimuraYoshio Kawai
    • G03F7/075
    • G03F7/0757Y10S430/122Y10S430/123
    • A resist material comprises a polysiloxane obtained by hydrolysis and condensation with dehydration of one or more alkoxysilanes having an oxirane ring, or of a mixture of the alkoxysilane(s) having an oxirane ring and one or more alkoxysilanes having no oxirane ring, and an acid generator. The resist material may contain one or more of a spectral sensitizer, an organic polymer having a hydroxyl group or an epoxy compound. Resist patterns are formed by coating an organic polymer on a substrate and then the resist material on the film of the organic polymer to form a two layer resist having a bottom layer of the organic polymer and top layer of the resist material, prebaking, imagewise exposing high radiation, postbaking, and developing the resist with alkaline solutions to remove an unexposed portion of the top layer, and dry etching the bottom layer using the relic of the resist material as a mask. the temperature of the post baking is preferably lower than that of the prebaking.
    • 抗蚀剂材料包括通过水解和缩合得到的聚硅氧烷,所述聚硅氧烷通过脱水一个或多个具有环氧乙烷环的烷氧基硅烷,或具有环氧乙烷环的烷氧基硅烷和一个或多个不具有环氧乙烷环的烷氧基硅烷的混合物和酸 发电机。 抗蚀剂材料可以含有一种或多种光谱增感剂,具有羟基的有机聚合物或环氧化合物。 通过在有机聚合物的膜上涂覆有机聚合物,然后在有机聚合物的膜上涂覆抗蚀剂材料形成具有有机聚合物的底层和抗蚀剂材料的顶层的双层抗蚀剂,预烘烤,成像曝光 高辐射,后烘烤,并用碱性溶液显影抗蚀剂以除去顶层的未曝光部分,并使用抗蚀剂材料的遗物作为掩模干蚀刻底层。 后烘烤的温度优选低于预烘烤的温度。