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1. 发明授权

US6077804A Olefin polymerization catalyst and process for preparing polyolefins 失效
标题翻译：烯烃聚合催化剂和制备聚烯烃的方法
公开(公告)号：US6077804A
公开(公告)日：2000-06-20
申请号：US858120
申请日：1997-05-19
申请人： Yoshio Tajima , Naoki Kataoka , Akira Sano , Kazuo Matsuura
发明人： Yoshio Tajima , Naoki Kataoka , Akira Sano , Kazuo Matsuura
IPC分类号： C08F4/642 , C08F4/60 , C08F4/652 , C08F4/658 , C08F4/659 , C08F4/6592 , C08F10/00
CPC分类号： C08F10/00 , C08F4/65904 , C08F4/65912 , C08F4/65916 , C08F4/6592
摘要： According to the present invention, there are provided a catalyst and a process for the preparation of polyolefins having a relatively wide molecular weight distribution, good particle properties, a narrow composition distribution in copolymerization and a high molecular weight and being less sticky. The catalyst is prepared by contacting the following constituents (1) to (4) with one another:(1) a compound represented by the general formula Me.sup.1 R.sup.1.sub.p (OR.sup.2).sub.q X.sub.4-p-q, where Me.sup.1 is Zr, Ti or Hf, R.sup.1 and R.sup.2 are each independently a hydrocarbon group having 1 to 24 carbon atoms, X is a halogen atom, p and q are each an integer in the ranges of 0.ltoreq.p.ltoreq.4 and 0.ltoreq.q.ltoreq.4 , provided 0.ltoreq.p+q.ltoreq.4;(2) a compound represented by the general formula Me.sup.2 R.sup.3.sub.m (OR.sup.4).sub.n X.sup.2.sub.z-m-n, where Me.sup.2 is a Group I-III element in the Periodic Table, R.sup.3 and R.sup.4 are each independently a hydrocarbon group having 1 to 24 carbon atoms, X.sup.2 is a halogen atom or a hydrogen atom, provided when X.sup.2 is a hydrogen atom, Me.sup.2 is a Group III element in the Periodic Table, z is the valence of Me.sup.2, m and n are each an integer in the ranges of 0.ltoreq.m.ltoreq.z, and 0.ltoreq.n.ltoreq.z, provided 0.ltoreq.m+n.ltoreq.z;(3) an organocyclic compound having conjugated double bonds; and(4) a modified organoaluminum compound containing Al--O--Al bond, and thereafter contacting the resulting contact reaction product with the following component (5):(5) an inorganic carrier and/or a particulate polymer carrier.
摘要翻译：根据本发明，提供了一种催化剂和制备具有较宽分子量分布，良好的颗粒性能，窄的共聚合成分布和高分子量且不易粘的聚烯烃的方法。通过使下述成分（1）〜（4）彼此接触来制备催化剂：（1）由通式Me1R1p（OR2）qX4-pq表示的化合物，其中Me1为Zr，Ti或Hf，R1和R2 各自独立地为具有1〜24个碳原子的烃基，X为卤素原子，p和q各自为0≤p≤4且0≤q≤4的整数，提供0

2. 发明授权

US5604170A Solid catalyst components for olefin polemerization and use thereof 失效
标题翻译：用于烯烃聚合的固体催化剂组分及其用途
公开(公告)号：US5604170A
公开(公告)日：1997-02-18
申请号：US199561
申请日：1994-02-22
申请人： Akira Sano , Kunimichi Kubo , Kazuo Matsuura , Yoshio Tajima
发明人： Akira Sano , Kunimichi Kubo , Kazuo Matsuura , Yoshio Tajima
IPC分类号： C08F4/646 , C08F4/659 , C08F4/6592 , C08F10/00 , C08F110/06 , C08F210/16 , C08F4/64
CPC分类号： C08F10/00 , C08F110/06 , C08F210/16 , C08F4/65904 , C08F4/65912 , C08F4/65916 , C08F4/65925
摘要： An effective catalyst carrier for use in the polymerization of olefins is provided.Said carrier comprises particles of silicon oxide or aluminum oxide satisfying the following characteristics (A) to (E):(A) An average particle diameter as measured by the sieving method is in the range of 20 to 150 .mu.m.(B) A specific surface area as measured by the BET method is in the range of 150 to 600 m.sup.2 /g.(C) The volume of pores ranging in pore radius from 18 to 1,000 Angstroms as measured by the mercury penetration method is in the range of 0.3 to 2.0 cm.sup.3 /g.(D) An apparent specific gravity as measured according to JIS K6220-6.8 is not lower than 0.32.(E) After the particles classified in the range of between 53 .mu.m and 75 .mu.m by the sieving method have been subjected to an ultrasonic disintegration treatment at 40 KHz, 35 W, for 20 minutes, the proportion of 50 .mu.m or smaller particles, i.e., degree of ultrasonic disintegration, is not more than 30%.
摘要翻译：提供了一种用于烯烃聚合的有效催化剂载体。所述载体包含满足以下特征（A）至（E）的氧化硅或氧化铝颗粒：（A）通过筛分方法测量的平均粒径为20-150μm。（B）通过BET法测定的比表面积为150〜600m 2 / g的范围。（C）通过水银渗透法测定的孔半径为18〜1000埃的孔的体积在0.3〜2.0cm 3 / g的范围内。（D）根据JIS K6220-6.8测定的表观比重不低于0.32。（E）通过筛分方法将分级在53μm至75μm范围内的颗粒在40KHz，35W，20分钟以上进行超声波分解处理，比例为50μm以上颗粒，即超声崩解度不大于30％。

3. 发明授权

US4923935A Process for producing polyethylene of ultrahigh molecular weight 失效
标题翻译：生产超高分子量聚乙烯的方法
公开(公告)号：US4923935A
公开(公告)日：1990-05-08
申请号：US302564
申请日：1989-01-26
申请人： Akira Sano , Shigeki Yokoyama , Yasunosuke Miyazaki , Tetsujiro Kuroishi , Kazuo Matsuura
发明人： Akira Sano , Shigeki Yokoyama , Yasunosuke Miyazaki , Tetsujiro Kuroishi , Kazuo Matsuura
IPC分类号： C08F10/00 , C08F2/38 , C08F4/00 , C08F4/60 , C08F4/64 , C08F4/654 , C08F8/00 , C08F10/02
CPC分类号： C08F10/02 , C08F10/00
摘要： A process for producing polyethylene of ultrahigh molecular weight having an intrinsic viscosity of 10-30 dl/g at 135.degree. C. in decalin is disclosed which comprises at least the following two stages of polymerization reaction: (a) a first reaction stage where in ethylene is polymerized with use of a catalyst comprising a solid component containing at least Mg, Ti and/or Va and in the absence or presence of hydrogen of reduced concentration to produce 70-99.5 weight parts of polyethylene having an intrinsic viscosity of 12-32 dl/g at 135.degree. C. in decalin; and (b) a second reaction stage wherein a fresh feed of ethylene is polymerized in the presence of hydrogen of higher concentration to produce 30-0.5 weight parts of polyethylene having an intrinsic viscosity of 0.1-5 dl/g at 135.degree. C. in decalin.
摘要翻译：公开了在135℃下在十氢萘中生产特性粘度为10-30dl / g的超高分子量聚乙烯的方法，其至少包括以下两个阶段的聚合反应：（a）第一反应阶段，其中在使用包含至少含有Mg，Ti和/或Va的固体组分的催化剂和在还原浓度不存在或不存在的情况下使乙烯聚合，得到70-99.5重量份的特性粘度为12-32的聚乙烯 dl / g，135℃，十氢化萘; 和（b）第二反应阶段，其中乙烯的新鲜进料在较高浓度的氢气存在下聚合，以在135℃下产生特性粘度为0.1-5dl / g的30至0.5重量份的聚乙烯十氢化萘

4. 发明授权

US4849390A Catalysts for polymerization of olefins 失效
标题翻译：用于烯烃聚合的催化剂
公开(公告)号：US4849390A
公开(公告)日：1989-07-18
申请号：US38949
申请日：1987-04-16
申请人： Akira Sano , Kunimichi Kubo , Kazuo Matsuura
发明人： Akira Sano , Kunimichi Kubo , Kazuo Matsuura
IPC分类号： C08F10/00 , C08F4/02 , C08F4/60 , C08F4/64
CPC分类号： C08F4/025 , Y10S526/901 , Y10S526/909
摘要： A catalyst for polymerization of olefins is disclosed which comprises a titanium and/or vanadium compound supported on a silicon and/or aluminum oxide carrier. This carrier has peculiar characteristics including a specified proportion of highly spherical oxide particles, a selected average pore size and a specified proportion of a selected particle size range before and after ultrasonic treatment, whereby there is obtained a catalyst having increased bulk density, narrow particle size distribution and high fluidity.

5. 发明授权

US4767819A Ultra-high-molecular-weight polyethylene solution 失效
标题翻译：超高分子量聚乙烯溶液
公开(公告)号：US4767819A
公开(公告)日：1988-08-30
申请号：US70545
申请日：1987-07-07
申请人： Shigeki Yokoyama , Michiaki Torii , Kazuo Matsuura , Akira Sano
发明人： Shigeki Yokoyama , Michiaki Torii , Kazuo Matsuura , Akira Sano
IPC分类号： C08L23/04 , C08J3/09 , C08L23/00 , C08L91/00 , C10G67/06 , D01F6/04 , C08L23/06
CPC分类号： D01D1/02 , C08J3/092 , C10G67/06 , D01F6/04 , C08J2323/06
摘要： The present invention provides an ultra-high-molecular-weight polyethylene solution which is produced by the steps of subjecting a kerosene fraction having a boiling point of 160.degree. to 300.degree. C. to a nucleus hydrogenation treatment at a pressure of 30 to 100 kg/cm.sup.2 at a temperature of 100.degree. to 300.degree. C. in the presence of a metallic catalyst for nucleus hydrogenation of aromatic nuclei; separating and removing at least a part of n-paraffins present in the kerosene therefrom by the use of a molecular sieve made up of a synthesized zeolite in order to obtain a residual oil; fractionating the latter by a rectification apparatus to obtain a hydrocarbon mixture fraction which has a boiling point of 180.degree. to 250.degree. C. and which is substantially free from naphthalene and biphenyl; and dissolving, in the hydrocarbon mixture fraction, an ultra-high-molecular-weight polyethylene having an intrinsic viscosity of 8 or more in decalin at 135.degree. C.
摘要翻译：本发明提供了一种超高分子量聚乙烯溶液，其通过以下步骤制备：使沸点为160〜300℃的煤油馏分在30〜100kg的压力下进行核氢化处理在金属催化剂存在下，在100〜300℃的温度下，芳族核的核氢化; 通过使用由合成沸石构成的分子筛分离和除去存在于煤油中的至少一部分正链烷烃，以获得残油; 通过精馏装置对后者进行分馏，得到沸点为180-250℃，基本上不含萘和联苯的烃混合物馏分; 并在烃混合物馏分中，在135℃下在十氢化萘中溶解特性粘度为8以上的超高分子量聚乙烯。

6. 发明授权

US06486275B2 Process for preparing polyolefins 失效
公开(公告)号：US06486275B2
公开(公告)日：2002-11-26
申请号：US09844902
申请日：2001-04-27
申请人： Akira Sano , Takeichi Shiraishi , Kunihiro Suzuki , Hiroyuki Shimizu , Kazuo Matsuura
发明人： Akira Sano , Takeichi Shiraishi , Kunihiro Suzuki , Hiroyuki Shimizu , Kazuo Matsuura
IPC分类号： C08F4656
CPC分类号： C08F10/00 , C08F4/6567 , C08F4/6578 , C08F4/6465
摘要： A process for preparing polyolefins by polymerizing or coploymerizing an olefin or olefins in the presence of a catalyst comprising a solid catalyst component and an organometallic compound is provided.

7. 发明授权

US5916982A Process for the production of polyolefins 失效
标题翻译：生产聚烯烃的方法
公开(公告)号：US5916982A
公开(公告)日：1999-06-29
申请号：US722516
申请日：1996-09-27
申请人： Osamu Nakazawa , Akira Sano , Kazuo Matsuura
发明人： Osamu Nakazawa , Akira Sano , Kazuo Matsuura
IPC分类号： C08F4/619 , C08F4/6192 , C08F4/64 , C08F10/00
CPC分类号： C08F10/00 , C08F4/61912 , C08F4/61916 , C08F4/61922 , Y10S526/943
摘要： A process for the production of polyolefins is provided which comprises polymerizing or copolymerizing olefins in the presence of a catalyst composition which includes a catalyst component (I) resulting from mutual contact of sub-components (A) and (B), and a catalyst component (II). Sub-component (A) is of the formulaR.sup.1.sub.p Me.sup.1 X.sup.1.sub.4-p and/or R.sup.1.sub.2 Me.sup.1 X.sup.1'and sub-component (B) is a modified organoaluminum compound having Al--O--Al bonds. Catalyst component (II) is an admixture of sub-component (C), which is a transition metal elemental compound of Groups VII-VIII, and one or more of triethylaluminum, triisobutylaluminum, diethyl zinc, n-butyllithium, and butylmagnesiumchloride. The catalyst components (I) and/or (II) are contacted with a carrier during or after the preparation of the components (I) and/or (II).
摘要翻译：提供了一种生产聚烯烃的方法，其包括在催化剂组合物存在下聚合或共聚烯烃，所述催化剂组合物包括由副组分（A）和（B）的相互接触产生的催化剂组分（I）和催化剂组分（二）。亚组分（A）为式R1pMe1X14-p和/或R12Me1X1'，亚组分（B）为具有Al-O-Al键的改性有机铝化合物。催化剂组分（II）是次级组分（C）的混合物，其为第VII-VIII族的过渡金属元素化合物和三乙基铝，三异丁基铝，二乙基锌，正丁基锂和丁基氯化镁中的一种或多种。在组分（I）和/或（II）的制备期间或之后，催化剂组分（I）和/或（II）与载体接触。

8. 发明授权

US5026511A Process for the production of polyethylene materials 失效
标题翻译：聚乙烯材料生产工艺
公开(公告)号：US5026511A
公开(公告)日：1991-06-25
申请号：US485248
申请日：1990-02-26
申请人： Akira Sano , Hirofumi Kamiishi , Seizo Kobayashi , Kazuo Matsuura , Shigeki Yokoyama
发明人： Akira Sano , Hirofumi Kamiishi , Seizo Kobayashi , Kazuo Matsuura , Shigeki Yokoyama
IPC分类号： C08F4/64 , B29C55/00 , B29C55/18 , C08F4/60 , C08F4/685 , C08F110/00 , C08F110/02 , C08J5/18 , C08L23/06 , D01F6/04
CPC分类号： C08J5/18 , B29C55/005 , B29C55/18 , C08L23/06 , D01F6/04 , B29K2023/06 , C08J2323/06
摘要： A process for producing a polyethylene material for use in products requiring high mechanical strength and high elastic modulus is disclosed. The process involves the use of a specific class of particulate polyethylenes having an intrinsic viscosity of 5-50 dl/g in decalin at 135.degree. C. and the steps of compression molding, solvent immersing, solid-phase extruding or rolling and finally drawing the material in that order.

9. 发明授权

US06111040A Process for the production of olefinic polymers 失效
标题翻译：制备烯烃聚合物的方法
公开(公告)号：US06111040A
公开(公告)日：2000-08-29
申请号：US17780
申请日：1998-02-03
申请人： Hiroyuki Shimizu , Akira Sano , Kazuo Matsuura
发明人： Hiroyuki Shimizu , Akira Sano , Kazuo Matsuura
IPC分类号： C08F4/658 , C08F4/659 , C08F4/6592 , C08F210/16 , C08F4/44
CPC分类号： C08F210/16 , C08F4/65912 , C08F4/6592 , C08F4/65922 , Y10S526/943
摘要： A catalyst comprises a composition resulting from mutual contact of the following Components. (A), (B), (C) and (D):said Component (A) being a reaction product resulting from mutual contact of components (a), (b) and (c);said component (a) being represented by the formulaMe.sup.1 R.sup.1.sub.p (OR.sup.2).sub.q X.sup.1.sub.4-p-q Iwherein R.sup.1 and R.sup.2 each are a C.sub.1 -C.sub.24 hydrocarbon moieties, X.sup.1 is a hydrogen atom or a halogen atom, Me.sup.1 is titanium, zirconium or hafnium, p and q are 0.ltoreq.p.ltoreq.4, 0.ltoreq.q.ltoreq.4 and 0.ltoreq.p+q.ltoreq.4,said component (b) being represented by the formulaMe.sup.2 R.sup.3.sub.m (OR.sup.4).sub.n X.sup.2.sub.z-m-n IIwherein R.sup.3 and R.sup.4 each are a C.sub.1 -C.sub.2 4 hydrocarbon moieties, X.sup.2 is a hydrogen atom or a halogen atom, Me.sup.2 is an element of Groups I to III in the Periodic Table, z is a valence of Me.sup.2, and m and n are 0.ltoreq.m.ltoreq.z, 0.ltoreq.n.ltoreq.z and 0.ltoreq.m+n.ltoreq.z, and said component (c) being an organocyclic compound having two or more conjugated double bonds;said Component (B) being a modified organoaluminum compound having Al-O-Al bonds;said Component (C) being an organocyclic compound having two or more conjugated double bonds which is different from component (c); andsaid Component (D) being an inorganic carrier or particulate polymer carrier. The disclosed catalyst find extensive use in the manufacture of olefinic polymers having a relatively high molecular weight and a relatively wide molecular weight distribution as well as olefinic copolymers having a relatively narrow composition distribution.
摘要翻译：催化剂包含由以下组分的相互接触产生的组合物。（A），（B），（C）和（D）：所述组分（A）是由组分（a），（b）和（c）相互接触而产生的反应产物。所述组分（a）由式Me1R1p（OR2）qX14-pq I表示，其中R1和R2各自为C1-C24烃部分，X1为氢原子或卤素原子，Me1为钛，锆或铪，p 并且q是0 = p

10. 发明授权

US6034188A Process for preparing polyolefins 失效
标题翻译：聚烯烃的制备方法
公开(公告)号：US6034188A
公开(公告)日：2000-03-07
申请号：US579893
申请日：1995-12-28
申请人： Akira Sano , Hiroyuki Shimizu , Kazuo Matsuura
发明人： Akira Sano , Hiroyuki Shimizu , Kazuo Matsuura
IPC分类号： C08F4/658 , C08F4/42 , C08F4/60 , C08F4/642 , C08F10/00 , C08F10/02 , C08F110/02 , C08F4/16
CPC分类号： C08F10/00 , C08F10/02 , C08F110/02
摘要： An olefin polymerization is conducted in the presence of a catalyst comprising a solid catalyst component and an organometallic compound, said solid catalyst component being prepared by reacting the following components [I], [II] and [III] with one another:[I] a reaction product obtained by reacting the following components (1), (2) and (3) with one another:(1) a silicon oxide and/or an aluminum oxide;(2) a reaction product obtained by the reaction of a magnesium halide and a compound represented by the general formula Me(OR).sub.n X.sub.z-n where Me represents an element of Groups I to IV in the Periodic Table, z represents the valence of the element Me, n is 0
摘要翻译：在包含固体催化剂组分和有机金属化合物的催化剂的存在下进行烯烃聚合，所述固体催化剂组分通过使以下组分[I]，[II]和[III]彼此反应制备：[I] 通过使以下组分（1），（2）和（3）彼此反应获得的反应产物：（1）氧化硅和/或氧化铝; （2）通过卤化镁与通式Me（OR）n X z-n表示的化合物反应得到的反应产物，其中Me表示周期表中第Ⅳ至Ⅳ组元素，z表示元素Me，n为0

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