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1. 发明授权

US4923935A Process for producing polyethylene of ultrahigh molecular weight 失效
标题翻译：生产超高分子量聚乙烯的方法
公开(公告)号：US4923935A
公开(公告)日：1990-05-08
申请号：US302564
申请日：1989-01-26
申请人： Akira Sano , Shigeki Yokoyama , Yasunosuke Miyazaki , Tetsujiro Kuroishi , Kazuo Matsuura
发明人： Akira Sano , Shigeki Yokoyama , Yasunosuke Miyazaki , Tetsujiro Kuroishi , Kazuo Matsuura
IPC分类号： C08F10/00 , C08F2/38 , C08F4/00 , C08F4/60 , C08F4/64 , C08F4/654 , C08F8/00 , C08F10/02
CPC分类号： C08F10/02 , C08F10/00
摘要： A process for producing polyethylene of ultrahigh molecular weight having an intrinsic viscosity of 10-30 dl/g at 135.degree. C. in decalin is disclosed which comprises at least the following two stages of polymerization reaction: (a) a first reaction stage where in ethylene is polymerized with use of a catalyst comprising a solid component containing at least Mg, Ti and/or Va and in the absence or presence of hydrogen of reduced concentration to produce 70-99.5 weight parts of polyethylene having an intrinsic viscosity of 12-32 dl/g at 135.degree. C. in decalin; and (b) a second reaction stage wherein a fresh feed of ethylene is polymerized in the presence of hydrogen of higher concentration to produce 30-0.5 weight parts of polyethylene having an intrinsic viscosity of 0.1-5 dl/g at 135.degree. C. in decalin.
摘要翻译：公开了在135℃下在十氢萘中生产特性粘度为10-30dl / g的超高分子量聚乙烯的方法，其至少包括以下两个阶段的聚合反应：（a）第一反应阶段，其中在使用包含至少含有Mg，Ti和/或Va的固体组分的催化剂和在还原浓度不存在或不存在的情况下使乙烯聚合，得到70-99.5重量份的特性粘度为12-32的聚乙烯 dl / g，135℃，十氢化萘; 和（b）第二反应阶段，其中乙烯的新鲜进料在较高浓度的氢气存在下聚合，以在135℃下产生特性粘度为0.1-5dl / g的30至0.5重量份的聚乙烯十氢化萘

2. 发明授权

US4760120A Easily soluble polyethylene powder for the preparation of fibers or films having high strength and high elastic modulus 失效
标题翻译：用于制备具有高强度和高弹性模量的纤维或薄膜的易溶性聚乙烯粉末
公开(公告)号：US4760120A
公开(公告)日：1988-07-26
申请号：US941858
申请日：1986-12-15
申请人： Akira Sano , Tetsujirou Kuroishi , Yasunosuke Miyazaki , Shigeki Yokoyama , Kazuo Matsuura
发明人： Akira Sano , Tetsujirou Kuroishi , Yasunosuke Miyazaki , Shigeki Yokoyama , Kazuo Matsuura
IPC分类号： C08L23/06 , C08F2/38 , C08F4/60 , C08F4/634 , C08F4/64 , C08F8/00 , C08F10/02 , C08J3/09 , C08J5/18 , C08L23/00 , C08L101/00 , D01F6/04
CPC分类号： C08F10/02 , Y10S526/904 , Y10S526/905 , Y10T428/2982
摘要： An ultra-high molecular weight polyethylene powder easily soluble in organic solvents and suitable for use in the preparation of fibers or films having a high strength and a high elastic modulus, said polyethylene powder having an intrinsic viscosity in the range of 5 to 30 dl/g in decalin at 135.degree. C. and being obtained by at least two-step polymerization reactions which are:a first step of polymerizing ethylene in the absence of hydrogen or at a reduced hydrogen concentration, using a catalyst containing a solid catalyst component and an organometallic compound, said solid catalyst component containing at least magnesium and titanium and/or vanadium, to produce 50-99.5 parts by weight, based on 100 parts by weight of a final polyethylene product, of polyethylene having an intrinsic viscosity of 12 to 32 dl/g in decalin at 135.degree. C.; anda second step of polymerizing ethylene at a higher hydrogen concentration that in said first step to produce 50-0.5 parts by weight of polyethylene.
摘要翻译：该超高分子量聚乙烯粉末容易溶于有机溶剂，适用于制备具有高强度和高弹性模量的纤维或薄膜，所述聚乙烯粉末的特性粘度在5-30dl / g，在135℃的十氢化萘中，并通过至少两步聚合反应获得，所述反应为：在不存在氢气或在降低的氢浓度下使乙烯聚合的第一步骤，使用含有固体催化剂组分和有机金属化合物，所述固体催化剂组分至少含有镁和钛和/或钒，基于100重量份的最终聚乙烯产品，产生50-99.5重量份的特性粘度为12至32dl的聚乙烯 / g，在135℃的萘烷中。以及在较高氢浓度下聚合乙烯的第二步骤，在第一步骤中制备50至0.5重量份的聚乙烯。

3. 发明授权

US4767819A Ultra-high-molecular-weight polyethylene solution 失效
标题翻译：超高分子量聚乙烯溶液
公开(公告)号：US4767819A
公开(公告)日：1988-08-30
申请号：US70545
申请日：1987-07-07
申请人： Shigeki Yokoyama , Michiaki Torii , Kazuo Matsuura , Akira Sano
发明人： Shigeki Yokoyama , Michiaki Torii , Kazuo Matsuura , Akira Sano
IPC分类号： C08L23/04 , C08J3/09 , C08L23/00 , C08L91/00 , C10G67/06 , D01F6/04 , C08L23/06
CPC分类号： D01D1/02 , C08J3/092 , C10G67/06 , D01F6/04 , C08J2323/06
摘要： The present invention provides an ultra-high-molecular-weight polyethylene solution which is produced by the steps of subjecting a kerosene fraction having a boiling point of 160.degree. to 300.degree. C. to a nucleus hydrogenation treatment at a pressure of 30 to 100 kg/cm.sup.2 at a temperature of 100.degree. to 300.degree. C. in the presence of a metallic catalyst for nucleus hydrogenation of aromatic nuclei; separating and removing at least a part of n-paraffins present in the kerosene therefrom by the use of a molecular sieve made up of a synthesized zeolite in order to obtain a residual oil; fractionating the latter by a rectification apparatus to obtain a hydrocarbon mixture fraction which has a boiling point of 180.degree. to 250.degree. C. and which is substantially free from naphthalene and biphenyl; and dissolving, in the hydrocarbon mixture fraction, an ultra-high-molecular-weight polyethylene having an intrinsic viscosity of 8 or more in decalin at 135.degree. C.
摘要翻译：本发明提供了一种超高分子量聚乙烯溶液，其通过以下步骤制备：使沸点为160〜300℃的煤油馏分在30〜100kg的压力下进行核氢化处理在金属催化剂存在下，在100〜300℃的温度下，芳族核的核氢化; 通过使用由合成沸石构成的分子筛分离和除去存在于煤油中的至少一部分正链烷烃，以获得残油; 通过精馏装置对后者进行分馏，得到沸点为180-250℃，基本上不含萘和联苯的烃混合物馏分; 并在烃混合物馏分中，在135℃下在十氢化萘中溶解特性粘度为8以上的超高分子量聚乙烯。

4. 发明授权

US5002714A Process for producing highly oriented polyethylene material 失效
标题翻译：生产高取向聚乙烯材料的方法
公开(公告)号：US5002714A
公开(公告)日：1991-03-26
申请号：US453708
申请日：1989-12-20
申请人： Akira Sano , Hirofumi Kamiishi , Yoshimu Iwanami , Shigeki Yokoyama , Kazuo Matsuura
发明人： Akira Sano , Hirofumi Kamiishi , Yoshimu Iwanami , Shigeki Yokoyama , Kazuo Matsuura
IPC分类号： B29C47/00 , B29C55/00 , B29C55/04 , B29C55/18 , B29C69/02 , B29K23/00
CPC分类号： B29C47/0004 , B29C55/04 , B29C55/18 , B29C47/0009 , B29K2023/06 , B29K2223/06
摘要： A process for the production of polyethylene materials oriented at a high level is disclosed in which a selected ethylene polymer as produced is extruded or rolled at a temperature lower than its melting point and subsequently subjected to stretching. The polymer is from 5 to 50 dl/g at 135.degree. C. in decalin in intrinsic viscosity and smaller than 60 .ANG. in crystal size on a plane (110) in the diffraction pattern.

5. 发明授权

US5026511A Process for the production of polyethylene materials 失效
标题翻译：聚乙烯材料生产工艺
公开(公告)号：US5026511A
公开(公告)日：1991-06-25
申请号：US485248
申请日：1990-02-26
申请人： Akira Sano , Hirofumi Kamiishi , Seizo Kobayashi , Kazuo Matsuura , Shigeki Yokoyama
发明人： Akira Sano , Hirofumi Kamiishi , Seizo Kobayashi , Kazuo Matsuura , Shigeki Yokoyama
IPC分类号： C08F4/64 , B29C55/00 , B29C55/18 , C08F4/60 , C08F4/685 , C08F110/00 , C08F110/02 , C08J5/18 , C08L23/06 , D01F6/04
CPC分类号： C08J5/18 , B29C55/005 , B29C55/18 , C08L23/06 , D01F6/04 , B29K2023/06 , C08J2323/06
摘要： A process for producing a polyethylene material for use in products requiring high mechanical strength and high elastic modulus is disclosed. The process involves the use of a specific class of particulate polyethylenes having an intrinsic viscosity of 5-50 dl/g in decalin at 135.degree. C. and the steps of compression molding, solvent immersing, solid-phase extruding or rolling and finally drawing the material in that order.

6. 发明授权

US4879076A Process for the production of polyethylene materials 失效
标题翻译：聚乙烯材料生产工艺
公开(公告)号：US4879076A
公开(公告)日：1989-11-07
申请号：US061226
申请日：1987-06-12
申请人： Akira Sano , Seizo Kobayashi , Kazuo Matsuura , Shigeki Yokoyama , Takeshi Kamiya
发明人： Akira Sano , Seizo Kobayashi , Kazuo Matsuura , Shigeki Yokoyama , Takeshi Kamiya
IPC分类号： B29C55/30 , C08F110/02 , C08F297/08 , C08J5/18 , C08L23/06 , D01F6/04
CPC分类号： C08J5/18 , B29C55/30 , C08F110/02 , C08F297/083 , C08L23/06 , D01F6/04 , B29K2023/06 , C08J2323/06
摘要： A process for producing polyethylene materials is disclosed in which particulate polyethylene is drawn at lower temperatures than its melting point, the polymer having an intrinsic viscosity of 5-50 dl/g at 135.degree. C. in decalin and resulting from the polymerization of ethylene at temperatures below the above melting point and with use of a selected catalyst. The polyethylene materials excel in mechanical strength and elastic modulus.
摘要翻译：公开了一种生产聚乙烯材料的方法，其中颗粒聚乙烯在比其熔点低的温度下被拉伸，该聚合物在135℃下在十氢化萘中的特性粘度为5-50dl / g，并且由乙烯在温度低于上述熔点，并使用选定的催化剂。聚乙烯材料的机械强度和弹性模量优异。

7. 发明授权

US4704439A Chlorinated linear ultra low density polyethylene 失效
标题翻译：氯化线性超低密度聚乙烯
公开(公告)号：US4704439A
公开(公告)日：1987-11-03
申请号：US838373
申请日：1986-03-11
申请人： Noboru Yamaoka , Shigeki Yokoyama , Kazuo Matsuura , Kozo Misumi , Junichi Watanabe , Seiji Kadomatsu
发明人： Noboru Yamaoka , Shigeki Yokoyama , Kazuo Matsuura , Kozo Misumi , Junichi Watanabe , Seiji Kadomatsu
IPC分类号： C08F8/00 , C08F4/64 , C08F8/20 , C08F8/22 , C08F210/00 , C08F210/16
CPC分类号： C08F8/22
摘要： Chlorinated linear ultra low density polyethylene containing 3-40% by weight of chlorine produced by chlorinating a linear ultra low density polyethylene having the properties (i)-(iv) cited below, said polyethylene being produced by copolymerizing ethylene and an .alpha.-olefin having 3-12 carbon atoms in the presence of a catalyst comprising a solid catalyst component containing at least magnesium and titanium and an organic aluminum compound.______________________________________ (i) Melt index 0.01-100 g/10 min (ii) Density 0.860-0.910 g/cm.sup.3 (iii) Maximum peak temperature not lower than 100.degree. C. (Tm) by the differential scanning calorimetry (iv) Boiling n-hexane not less than 10% by insolubles weight ______________________________________
摘要翻译：氯化线性超低密度聚乙烯，其含有3-40重量％的氯，其通过氯化具有下列特性（i） - （iv）的特性的线性超低密度聚乙烯制备，所述聚乙烯通过使乙烯和α-烯烃共聚而制备，所述α-烯烃具有在包含至少含有镁和钛的固体催化剂组分和有机铝化合物的催化剂存在下存在3-12个碳原子。 - （i）熔体指数0.01-100g / 10分钟 - （ii）密度0.860-0.910g / cm 3 - （iii）通过差示扫描量热法 - （Tm）的最高峰值温度不低于100℃ - （Tm） - （ iv）沸腾正己烷不少于10％ - 不溶物重量 -

8. 发明授权

US4849390A Catalysts for polymerization of olefins 失效
标题翻译：用于烯烃聚合的催化剂
公开(公告)号：US4849390A
公开(公告)日：1989-07-18
申请号：US38949
申请日：1987-04-16
申请人： Akira Sano , Kunimichi Kubo , Kazuo Matsuura
发明人： Akira Sano , Kunimichi Kubo , Kazuo Matsuura
IPC分类号： C08F10/00 , C08F4/02 , C08F4/60 , C08F4/64
CPC分类号： C08F4/025 , Y10S526/901 , Y10S526/909
摘要： A catalyst for polymerization of olefins is disclosed which comprises a titanium and/or vanadium compound supported on a silicon and/or aluminum oxide carrier. This carrier has peculiar characteristics including a specified proportion of highly spherical oxide particles, a selected average pore size and a specified proportion of a selected particle size range before and after ultrasonic treatment, whereby there is obtained a catalyst having increased bulk density, narrow particle size distribution and high fluidity.

9. 发明授权

US6077804A Olefin polymerization catalyst and process for preparing polyolefins 失效
标题翻译：烯烃聚合催化剂和制备聚烯烃的方法
公开(公告)号：US6077804A
公开(公告)日：2000-06-20
申请号：US858120
申请日：1997-05-19
申请人： Yoshio Tajima , Naoki Kataoka , Akira Sano , Kazuo Matsuura
发明人： Yoshio Tajima , Naoki Kataoka , Akira Sano , Kazuo Matsuura
IPC分类号： C08F4/642 , C08F4/60 , C08F4/652 , C08F4/658 , C08F4/659 , C08F4/6592 , C08F10/00
CPC分类号： C08F10/00 , C08F4/65904 , C08F4/65912 , C08F4/65916 , C08F4/6592
摘要： According to the present invention, there are provided a catalyst and a process for the preparation of polyolefins having a relatively wide molecular weight distribution, good particle properties, a narrow composition distribution in copolymerization and a high molecular weight and being less sticky. The catalyst is prepared by contacting the following constituents (1) to (4) with one another:(1) a compound represented by the general formula Me.sup.1 R.sup.1.sub.p (OR.sup.2).sub.q X.sub.4-p-q, where Me.sup.1 is Zr, Ti or Hf, R.sup.1 and R.sup.2 are each independently a hydrocarbon group having 1 to 24 carbon atoms, X is a halogen atom, p and q are each an integer in the ranges of 0.ltoreq.p.ltoreq.4 and 0.ltoreq.q.ltoreq.4 , provided 0.ltoreq.p+q.ltoreq.4;(2) a compound represented by the general formula Me.sup.2 R.sup.3.sub.m (OR.sup.4).sub.n X.sup.2.sub.z-m-n, where Me.sup.2 is a Group I-III element in the Periodic Table, R.sup.3 and R.sup.4 are each independently a hydrocarbon group having 1 to 24 carbon atoms, X.sup.2 is a halogen atom or a hydrogen atom, provided when X.sup.2 is a hydrogen atom, Me.sup.2 is a Group III element in the Periodic Table, z is the valence of Me.sup.2, m and n are each an integer in the ranges of 0.ltoreq.m.ltoreq.z, and 0.ltoreq.n.ltoreq.z, provided 0.ltoreq.m+n.ltoreq.z;(3) an organocyclic compound having conjugated double bonds; and(4) a modified organoaluminum compound containing Al--O--Al bond, and thereafter contacting the resulting contact reaction product with the following component (5):(5) an inorganic carrier and/or a particulate polymer carrier.
摘要翻译：根据本发明，提供了一种催化剂和制备具有较宽分子量分布，良好的颗粒性能，窄的共聚合成分布和高分子量且不易粘的聚烯烃的方法。通过使下述成分（1）〜（4）彼此接触来制备催化剂：（1）由通式Me1R1p（OR2）qX4-pq表示的化合物，其中Me1为Zr，Ti或Hf，R1和R2 各自独立地为具有1〜24个碳原子的烃基，X为卤素原子，p和q各自为0≤p≤4且0≤q≤4的整数，提供0

10. 发明授权

US5804679A Process for preparing polyolefins 失效
标题翻译：聚烯烃的制备方法
公开(公告)号：US5804679A
公开(公告)日：1998-09-08
申请号：US881936
申请日：1997-06-25
申请人： Akira Sano , Takeichi Shiraishi , Kunihiro Suzuki , Mitsuo Okamoto , Katumi Usui , Hiroyuki Shimizu , Kazuo Matsuura
发明人： Akira Sano , Takeichi Shiraishi , Kunihiro Suzuki , Mitsuo Okamoto , Katumi Usui , Hiroyuki Shimizu , Kazuo Matsuura
IPC分类号： C08F4/656 , C08F10/00
CPC分类号： C08F10/00 , Y10S526/901
摘要： Polyolefins exhibiting better particle properties are prepared by polymerizing an olefin or olefins in the presence of a catalyst comprising a solid catalyst component being prepared by the reaction of the following components �I! and �II!: �I! a reaction product obtained by reacting the following components (1), (2) and (3) with one another: (1) a silicon oxide and/or an aluminum oxide; (2) a reaction product obtained by the reaction of a magnesium halide and compound represented by the general formula Me(OR).sub.n X.sub.z-n wherein Me represents an element of Groups I to IV in the Periodic Table, z represents the valence of the element Me, n is 0
摘要翻译：表现出更好的颗粒性能的聚烯烃通过在包含通过以下组分[I]和[II]的反应制备的固体催化剂组分的催化剂存在下聚合烯烃或烯烃来制备：[I] 以下组分（1），（2）和（3）彼此：（1）氧化硅和/或氧化铝; （2）通过卤化镁与通式Me（OR）n X z-n表示的化合物反应获得的反应产物，其中Me表示周期表中第I至IV族的元素，z表示元素的化合价 Me，n为0

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